composite materials

复合材料
  • 文章类型: Journal Article
    具有聚合物基体的纳米复合材料为研究传统材料以外的新功能提供了巨大的机会。全球社会正逐渐倾向于使用复合材料和纳米复合材料。这篇综述旨在报道复合材料杂化填料的最新进展和理解。各种分析的影响,表征,并考虑了杂化填料的力学性能。将杂化填料引入到聚合物基质中增强了由杂化填料和聚合物之间的协同相互作用产生的复合材料和纳米复合材料的宏观和微观性能。在这次审查中,强调了在开发复合材料和纳米复合材料的生产中使用混合填料的协同影响。混合填料的使用提供了一种可行的方法来改善机械,热,和这些精密材料的电性能。本研究通过对最近的研究进行全面分析,解释了将混合填料安装到复合材料和纳米复合材料基体中的许多策略和方法。此外,几种填料的协同相互作用,包括有机-无机,纳米-微米,和生物基填料,经过充分调查。检查了从各种填料的协同组合获得的性能益处,以及它们在各种学科中的未来应用。此外,严格审查了与使用混合填料有关的困难和机会,在材料科学这一迅速发展的领域,提出了对未来研究路径的看法。
    Nanocomposites with polymer matrix provide tremendous opportunities to investigate new functions beyond those of traditional materials. The global community is gradually tending toward the use of composite and nanocomposite materials. This review is aimed at reporting the recent developments and understanding revolving around hybridizing fillers for composite materials. The influence of various analyses, characterizations, and mechanical properties of the hybrid filler are considered. The introduction of hybrid fillers to polymer matrices enhances the macro and micro properties of the composites and nanocomposites resulting from the synergistic interactions between the hybrid fillers and the polymers. In this review, the synergistic impact of using hybrid fillers in the production of developing composite and nanocomposite materials is highlighted. The use of hybrid fillers offers a viable way to improve the mechanical, thermal, and electrical properties of these sophisticated materials. This study explains the many tactics and methodologies used to install hybrid fillers into composite and nanocomposite matrices by conducting a thorough analysis of recent research. Furthermore, the synergistic interactions of several types of fillers, including organic-inorganic, nano-micro, and bio-based fillers, are fully investigated. The performance benefits obtained from the synergistic combination of various fillers are examined, as well as their prospective applications in a variety of disciplines. Furthermore, the difficulties and opportunities related to the use of hybrid fillers are critically reviewed, presenting perspectives on future research paths in this rapidly expanding area of materials science.
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  • 文章类型: Journal Article
    进行了有限元分析(FEA),以检查单搭接准各向同性(QI)和交叉层(CP)混合螺栓连接/粘结(HBB)结构在拉伸剪切载荷下的行为。影响复合材料接头强度的几个关键设计因素,失效条件,并对优化连接性能的负载共享机制进行了评估。对孔周围和沿粘合剂层的应力集中的研究突出表明,与仅螺栓连接的接头相比,HBB接头受益于显着较低的应力。特别是CP配置。模拟结果证实了三螺栓HBB接头中中间螺栓的冗余。发现粘合剂的刚度和塑性行为是定义接头从螺栓连接类型过渡的重要因素。在负载共享占主导地位的地方,连接到粘合接头。负载共享潜力,被称为关节性能的指标,通过减少重叠长度来改进,使用低刚度,高塑性粘合剂,并在QI铺层配置中使用较厚的层压板。提高边缘距离与孔直径和垫圈尺寸的比率证明有利于减小粘合剂层内的应力。从而提高了接头强度。
    A finite element analysis (FEA) was conducted to examine the behaviour of single-lap quasi-isotropic (QI) and cross-ply (CP) hybrid bolted/bonded (HBB) configurations subjected to tensile shear loading. Several critical design factors influencing the composite joint strength, failure conditions, and load-sharing mechanisms that would optimise the joining performance were assessed. The study of the stress concentration around the holes and along the adhesive layer highlights the fact that the HBB joints benefit from significantly lower stresses compared to only bolted joints, especially for CP configurations. The simulation results confirmed the redundancy of the middle bolt in a three-bolt HBB joint. The stiffness and plastic behaviour of the adhesive were found to be important factors that define the transition of the behaviour of the joint from a bolted type, where load sharing is predominant, to a bonded joint. The load-sharing potential, known as an indicator of the joint\'s performance, is improved by reducing the overlap length, using a low-stiffness, high-plasticity adhesive, and using thicker laminates in the QI layup configuration. Enhancing both the ratio of the edge distance to the hole diameter and washer size proves advantageous in reducing stresses within the adhesive layer, thereby improving the joint strength.
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  • 文章类型: Journal Article
    本文探讨了使用人工神经网络预测组合木梁的复合剪切键的柔度系数的可能性。柔量系数决定了已建成的木梁的应力和挠度。本文分析了当前设计带有剪切键的木质组合木梁的理论方法,以及将其应用于现代建筑的可能方法。设计方法之一,基于顺应性系数的使用,还详细讨论了。这项研究的新颖之处在于,文章的作者收集,分析,以及由不同研究人员获得并在其他研究中发表的关于组合木梁的复合剪切键的柔度系数实验值的组合数据。第一次,本文作者根据文献分析和作者收集的数据,生成了用于预测遵从系数的输入和输出数据表。作为这项研究的结果,文章的作者提出了一种人工神经网络(ANN)架构,并确定了顺从系数kw和ki的平均绝对百分比误差,等于0.054%和0.052%,分别。所提出的体系结构可用于使用各种复合剪切键设计组合木梁的实际应用。
    This article explores the possibility of predicting the compliance coefficients for composite shear keys of built-up timber beams using artificial neural networks. The compliance coefficients determine the stresses and deflections of built-up timber beams. The article analyzes current theoretical methods for designing wooden built-up timber beams with shear keys and possible ways of applying them in modern construction. One of the design methods, based on the use of the compliance coefficients, is also discussed in detail. The novelty of this research is that the authors of the article collected, analysed, and combined data on the experimental values of the compliance coefficient for composite shear keys of built-up timber beams obtained by different researchers and published in other studies. For the first time, the authors of this article generated a table of input and output data for predicting compliance coefficients based on the analysis of the literature and collected data by the authors. As a result of this research, the article\'s authors proposed an artificial neural network (ANN) architecture and determined the mean absolute percentage error for the compliance coefficients kw and ki, which are equal to 0.054% and 0.052%, respectively. The proposed architecture can be used for practical application in designing built-up timber beams using various composite shear keys.
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  • 文章类型: Journal Article
    这项研究的目的是根据经验评估符合内燃机进气过滤标准的纤维材料的性能。过滤效率和准确性的特点,以及流动阻力的特性,是根据过滤过程中积聚在滤床中的粉尘质量确定的。测试的单层过滤材料包括纤维素,聚酯,和玻璃微纤维。还检查了多层过滤介质如纤维素-聚酯-纳米纤维和纤维素-聚酯。一种由聚酯组成的新型复合滤床,玻璃超细纤维,和纤维素及其过滤特性进行了评估。利用特定的空气过滤质量因素,结果表明,该复合材料具有高的预过滤效率(99.98%),过滤前时间短(qs=4.21%),高精度(dpmax=1.5-3µm)过滤器的整个寿命,与其他测试材料相比,吸尘系数高60-250%。由一组具有不同过滤参数的材料构成的过滤复合床可以是,由于其高过滤效率,准确度,和吸尘,发动机进气的优良过滤材料。复合材料的过滤参数将取决于过滤层的类型及其相对于气溶胶流的顺序。本文介绍了各种过滤材料的选择和测试方法。
    The purpose of this study was to empirically evaluate the performance of fibrous materials that meet the criteria for inlet air filtration in internal combustion engines. The characteristics of filtration efficiency and accuracy, as well as the characteristics of flow resistance, were determined based on the mass of dust accumulated in the filter bed during the filtration process. Single-layer filter materials tested included cellulose, polyester, and glass microfiber. Multilayer filter media such as cellulose-polyester-nanofibers and cellulose-polyester were also examined. A new composite filter bed-consisting of polyester, glass microfiber, and cellulose-and its filtration characteristics were evaluated. Utilizing specific air filtration quality factors, it was demonstrated that the composite is characterized by high pre-filtration efficiency (99.98%), a short pre-filtration period (qs = 4.21%), high accuracy (dpmax = 1.5-3 µm) for the entire lifespan of the filter, and a 60-250% higher dust absorption coefficient compared to the other tested materials. A filtration composite bed constructed from a group of materials with different filtration parameters can be, due to its high filtration efficiency, accuracy, and dust absorption, an excellent filter material for engine intake air. The composite\'s filtration parameters will depend on the type of filter layers and their order relative to the aerosol flow. This paper presents a methodology for the selection and testing of various filter materials.
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  • 文章类型: Journal Article
    伤口愈合是皮肤组织修复和再生的关键但复杂的生物学过程,其产生于细胞和分子水平上共同工作的各种系统。快速伤口愈合和与传统伤口修复技术相关的问题正在用多功能材料克服。随着时间的推移,这一研究领域引起了极大的关注。金属有机骨架(MOFs),由于它们独特的物理化学特性,除了其他生物学应用外,现在还被认为是一类有前途的非常适合伤口愈合的多孔材料。这篇详细的文献综述概述了MOFs在伤口愈合应用中的最新进展。我们已经讨论了合成,基本的生物医学特性,伤口愈合机制,基于MOF的敷料材料,以及它们的伤口愈合应用。已经讨论了MOFs可能的主要挑战和局限性,以及结论和未来前景。文献综述的概述从几个角度论述了基于MOFs的伤口愈合,并涵盖了该主题的最新发展。读者可能会发现MOF如何通过产生更多的创造性来推进这一学科,有用的,和成功的敷料。它影响了后代用于皮肤伤口愈合和再生的生物材料的发展。
    Wound healing is a critical but complex biological process of skin tissue repair and regeneration resulting from various systems working together at the cellular and molecular levels. Quick wound healing and the problems associated with traditional wound repair techniques are being overcome with multifunctional materials. Over time, this research area has drawn significant attention. Metal-organic frameworks (MOFs), owning to their peculiar physicochemical characteristics, are now considered a promising class of well-suited porous materials for wound healing in addition to their other biological applications. This detailed literature review provides an overview of the latest developments in MOFs for wound healing applications. We have discussed the synthesis, essential biomedical properties, wound-healing mechanism, MOF-based dressing materials, and their wound-healing applications. The possible major challenges and limitations of MOFs have been discussed, along with conclusions and future perspectives. This overview of the literature review addresses MOFs-based wound healing from several angles and covers the most current developments in the subject. The readers may discover how the MOFs advanced this discipline by producing more inventive, useful, and successful dressings. It influences the development of future generations of biomaterials for the healing and regeneration of skin wounds.
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  • 文章类型: Journal Article
    轻质纤维素衍生碳基复合气凝胶的研制,宽的带宽和强吸收仍然是一个具有挑战性的任务。在这项工作中,通过化学交联和高温碳化两阶段工艺制备了纤维素衍生的碳/还原氧化石墨烯复合气凝胶。结果表明,所制备的二元复合气凝胶具有独特的轻质特性和三维多孔网络结构,由表氯醇化学交联。此外,氧化石墨烯(GO)的质量浓度对复合气凝胶的电磁参数和微波吸收性能有显著影响。当GO浓度为1.5mg/mL时,所得二元复合气凝胶具有最佳的微波耗散能力。值得注意的是,在厚度为2.47mm和填充率为17.5wt%的情况下,最小反射损耗达到-50.42dB。同时,厚度为2.73mm的复合气凝胶显示出7.28GHz的宽有效吸收带宽,跨越整个Ku波段并延伸到X波段的一部分。还通过计算机模拟技术模拟了二元复合气凝胶在远场中的雷达横截面贡献。此外,提出了潜在的微波衰减机理。相信本文的研究结果将为制备纤维素衍生碳基复合气凝胶作为高效宽带微波吸收剂提供参考。
    The development of cellulose derived carbon-based composite aerogels with light weight, broad bandwidth and strong absorption remains a challenging task. In this work, the cellulose derived carbon/reduced graphene oxide composite aerogels were prepared by a two-stage process of chemical crosslinking and high-temperature carbonization. The results revealed that the as-fabricated binary composite aerogels had a unique lightweight characteristic and three-dimensional porous network structure, which was chemically crosslinked by epichlorohydrin. Furthermore, the weight concentration of graphene oxide (GO) had a notable influence on the electromagnetic parameters and microwave absorption properties of the composite aerogels. The obtained binary composite aerogel possessed the optimal microwave dissipation capability when the concentration of GO was 1.5 mg/mL. Remarkably, the minimum reflection loss reached -50.42 dB at a thickness of 2.47 mm and a filling ratio of 17.5 wt%. Concurrently, the composite aerogel with a comparable thickness of 2.73 mm showed a wide effective absorption bandwidth of 7.28 GHz, spanning the total Ku-band and extending into a portion of the X-band. The radar cross section contribution of binary composite aerogels in the far-field was also simulated by computer simulation technique. In addition, the potential microwave attenuation mechanism was proposed. It was believed that the results of this paper would offer a reference for the preparation of cellulose derived carbon-based composite aerogels as efficient and broadband microwave absorbers.
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  • 文章类型: Journal Article
    背景:基于环氧树脂体系的传统导电粘合剂经常遇到诸如高脆性和低耐热性的问题。因此,提高导电胶的热性能和机械性能尤为重要。在这项研究中,通过分子动力学构建不同的交联模型,研究了SWCNT-Ag和SWCNT填料对DGEBA/DETA/Ag导电胶体系热性能的影响。最终结果表明,SWCNT和SWCNT-Ag的添加可以显着改善导电粘合剂的热性能。然而,SWCNT-Ag表面上的纳米银颗粒充当导电粘合剂中SWCNT和Ag之间连接的桥梁。因此,SWCNT-Ag对DGEBA/DETA/Ag导电胶体系的热性能有更积极的影响。
    方法:在本文中,利用MaterialsStudio软件研究了SWCNT-Ag对传统DGEBA/DETA/Ag导电胶体系热性能的影响。体积收缩,玻璃化转变温度,热膨胀系数,基于COMPASS力场计算了材料的热导率。导热系数采用反向非平衡分子动力学方法计算。最后,通过比较几组计算数据,发现SWCNT-Ag对导电胶体系的热性能有积极影响。
    BACKGROUND: Traditional conductive adhesives based on epoxy resin system often encounter problems such as high brittleness and low heat resistance. Therefore, it is particularly important to improve the thermal and mechanical properties of the conductive adhesive. In this study, the effects of SWCNT-Ag and SWCNT fillers on the thermal properties of DGEBA/DETA/Ag conductive adhesive system were studied by using molecular dynamics to construct different cross-linking models. The final results show that the addition of SWCNT and SWCNT-Ag can significantly improve the thermal properties of the conductive adhesive. However, the nanosilver particles on the surface of SWCNT-Ag act as a bridge for the connection between SWCNT and Ag in the conductive adhesive. Therefore, SWCNT-Ag has a more positive impact on the thermal properties of DGEBA/DETA/Ag conductive adhesive system.
    METHODS: In this paper, the influence of SWCNT-Ag on the thermal properties of traditional DGEBA/DETA/Ag conductive adhesive system was studied by using Materials Studio software. The volume shrinkage, glass transition temperature, thermal expansion coefficient, and thermal conductivity of the material were calculated based on COMPASS force field. The thermal conductivity is calculated by using reverse non-equilibrium molecular dynamics method. Finally, it is found that SWCNT-Ag has a positive effect on the thermal properties of the conductive adhesive system by comparing several groups of calculation data.
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  • 文章类型: Journal Article
    复合材料工件深孔的视觉测量是航空航天部件机器人装配的关键步骤。装配孔的定位精度对零件的装配质量有很大影响。然而,复合材料表面的复杂纹理和深孔入口和出口边缘成像之间的相互干扰对孔检测提出了极大的挑战。提出了一种基于径向惩罚拉普拉斯算子的复合材料深孔视觉测量方法,通过抑制视觉噪声和增强孔边缘特征来解决该问题。再加上一种新颖的拐点去除算法,这种方法能够精确检测复合材料部件中直径为10毫米、深度为50毫米的孔,实现0.03毫米的测量精度。
    The visual measurement of deep holes in composite material workpieces constitutes a critical step in the robotic assembly of aerospace components. The positioning accuracy of assembly holes significantly impacts the assembly quality of components. However, the complex texture of the composite material surface and mutual interference between the imaging of the inlet and outlet edges of deep holes significantly challenge hole detection. A visual measurement method for deep holes in composite materials based on the radial penalty Laplacian operator is proposed to address the issues by suppressing visual noise and enhancing the features of hole edges. Coupled with a novel inflection-point-removal algorithm, this approach enables the accurate detection of holes with a diameter of 10 mm and a depth of 50 mm in composite material components, achieving a measurement precision of 0.03 mm.
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  • 文章类型: Journal Article
    伤口感染可能会破坏正常的伤口愈合过程。大量的抗生素经常用于预防病原体感染;然而,这可能导致抗性发展。具有抗微生物性质的生物材料在减少抗生素使用和促进伤口愈合方面具有有希望的应用。丝胶(SS)由于其优异的生物相容性和抗氧化剂,已被越来越多地探索用于皮肤伤口愈合的应用,抗菌,和抗紫外线性能。近年来,具有更广的抗微生物谱的基于SS的复合生物材料已被广泛研究,并证明在促进伤口愈合方面具有良好的功效。这篇综述总结了各种抗菌药物,包括金属纳米颗粒,天然提取物,和抗生素,已掺入SS复合材料中用于伤口愈合并阐明其作用机理。已经揭示了基于SS的生物材料可以通过缓释负载的抗微生物剂实现持续的抗微生物活性。负载抗微生物剂的SS复合材料可以通过抗感染促进伤口愈合,抗炎,止血,血管生成,和胶原蛋白沉积。制造方法,好处,并简要讨论了载药SS材料的局限性。本文旨在加深对SS基抗菌复合材料新进展和方向的理解,并指导未来的生物医学研究。
    Wound infections may disrupt the normal wound-healing process. Large amounts of antibiotics are frequently used to prevent pathogenic infections; however, this can lead to resistance development. Biomaterials possessing antimicrobial properties have promising applications for reducing antibiotic usage and promoting wound healing. Silk sericin (SS) has been increasingly explored for skin wound healing applications owing to its excellent biocompatibility and antioxidant, antimicrobial, and ultraviolet-resistant properties. In recent years, SS-based composite biomaterials with a broader antimicrobial spectrum have been extensively investigated and demonstrated favorable efficacy in promoting wound healing. This review summarizes various antimicrobial agents, including metal nanoparticles, natural extracts, and antibiotics, that have been incorporated into SS composites for wound healing and elucidates their mechanisms of action. It has been revealed that SS-based biomaterials can achieve sustained antimicrobial activity by slow-release-loaded antimicrobial agents. The antimicrobial-loaded SS composites may promote wound healing through anti-infection, anti-inflammation, hemostasis, angiogenesis, and collagen deposition. The manufacturing methods, benefits, and limitations of antimicrobial-loaded SS materials are briefly discussed. This review aims to enhance the understanding of new advances and directions in SS-based antimicrobial composites and guide future biomedical research.
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  • 文章类型: Journal Article
    环氧树脂的固化是一个复杂的热化学过程,难以使用现有的传感系统进行监测。我们通过使用长周期纤维光栅来监测环氧树脂的固化过程。环氧树脂的折射率在固化过程中增加,并且可以测量以确定固化程度。我们采用了对外部介质折射率敏感的长周期光纤光栅来测量树脂的折射率变化。我们观察到,随着树脂折射率的增加,长周期光纤光栅的共振深度增加,我们的模拟很好地描述了这一点,考虑了与辐射模式的耦合。我们证明了可以使用现象学模型从光栅共振的深度估算固化程度。同时,长周期光纤光栅对固化过程中引起的温度变化和内部应变敏感。这些因素可能会影响固化程度的测量,也应加以解决。
    The curing of epoxy resin is a complex thermo-chemical process that is difficult to monitor using existing sensing systems. We monitored the curing process of an epoxy resin by using long-period fiber gratings. The refractive index of the epoxy resin increases during the curing process and can be measured to determine the degree of curing. We employed long-period fiber gratings that are sensitive to the refractive index of an external medium for the measurement of refractive index changes in the resin. We observed that the resonances of long-period fiber gratings increased their depth with the increased refractive index of the resin, which was well described by our simulation taking the coupling to radiation modes into account. We demonstrated that the degree of cure can be estimated from the depth of the grating resonances using a phenomenological model. At the same time, long-period fiber gratings are sensitive to temperature variations and internal strains that are induced during curing. These factors may affect the measurements of curing degree and should also be addressed.
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