composite materials

复合材料
  • 文章类型: Journal Article
    这项研究的目的是根据经验评估符合内燃机进气过滤标准的纤维材料的性能。过滤效率和准确性的特点,以及流动阻力的特性,是根据过滤过程中积聚在滤床中的粉尘质量确定的。测试的单层过滤材料包括纤维素,聚酯,和玻璃微纤维。还检查了多层过滤介质如纤维素-聚酯-纳米纤维和纤维素-聚酯。一种由聚酯组成的新型复合滤床,玻璃超细纤维,和纤维素及其过滤特性进行了评估。利用特定的空气过滤质量因素,结果表明,该复合材料具有高的预过滤效率(99.98%),过滤前时间短(qs=4.21%),高精度(dpmax=1.5-3µm)过滤器的整个寿命,与其他测试材料相比,吸尘系数高60-250%。由一组具有不同过滤参数的材料构成的过滤复合床可以是,由于其高过滤效率,准确度,和吸尘,发动机进气的优良过滤材料。复合材料的过滤参数将取决于过滤层的类型及其相对于气溶胶流的顺序。本文介绍了各种过滤材料的选择和测试方法。
    The purpose of this study was to empirically evaluate the performance of fibrous materials that meet the criteria for inlet air filtration in internal combustion engines. The characteristics of filtration efficiency and accuracy, as well as the characteristics of flow resistance, were determined based on the mass of dust accumulated in the filter bed during the filtration process. Single-layer filter materials tested included cellulose, polyester, and glass microfiber. Multilayer filter media such as cellulose-polyester-nanofibers and cellulose-polyester were also examined. A new composite filter bed-consisting of polyester, glass microfiber, and cellulose-and its filtration characteristics were evaluated. Utilizing specific air filtration quality factors, it was demonstrated that the composite is characterized by high pre-filtration efficiency (99.98%), a short pre-filtration period (qs = 4.21%), high accuracy (dpmax = 1.5-3 µm) for the entire lifespan of the filter, and a 60-250% higher dust absorption coefficient compared to the other tested materials. A filtration composite bed constructed from a group of materials with different filtration parameters can be, due to its high filtration efficiency, accuracy, and dust absorption, an excellent filter material for engine intake air. The composite\'s filtration parameters will depend on the type of filter layers and their order relative to the aerosol flow. This paper presents a methodology for the selection and testing of various filter materials.
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  • 文章类型: Journal Article
    背景:基于环氧树脂体系的传统导电粘合剂经常遇到诸如高脆性和低耐热性的问题。因此,提高导电胶的热性能和机械性能尤为重要。在这项研究中,通过分子动力学构建不同的交联模型,研究了SWCNT-Ag和SWCNT填料对DGEBA/DETA/Ag导电胶体系热性能的影响。最终结果表明,SWCNT和SWCNT-Ag的添加可以显着改善导电粘合剂的热性能。然而,SWCNT-Ag表面上的纳米银颗粒充当导电粘合剂中SWCNT和Ag之间连接的桥梁。因此,SWCNT-Ag对DGEBA/DETA/Ag导电胶体系的热性能有更积极的影响。
    方法:在本文中,利用MaterialsStudio软件研究了SWCNT-Ag对传统DGEBA/DETA/Ag导电胶体系热性能的影响。体积收缩,玻璃化转变温度,热膨胀系数,基于COMPASS力场计算了材料的热导率。导热系数采用反向非平衡分子动力学方法计算。最后,通过比较几组计算数据,发现SWCNT-Ag对导电胶体系的热性能有积极影响。
    BACKGROUND: Traditional conductive adhesives based on epoxy resin system often encounter problems such as high brittleness and low heat resistance. Therefore, it is particularly important to improve the thermal and mechanical properties of the conductive adhesive. In this study, the effects of SWCNT-Ag and SWCNT fillers on the thermal properties of DGEBA/DETA/Ag conductive adhesive system were studied by using molecular dynamics to construct different cross-linking models. The final results show that the addition of SWCNT and SWCNT-Ag can significantly improve the thermal properties of the conductive adhesive. However, the nanosilver particles on the surface of SWCNT-Ag act as a bridge for the connection between SWCNT and Ag in the conductive adhesive. Therefore, SWCNT-Ag has a more positive impact on the thermal properties of DGEBA/DETA/Ag conductive adhesive system.
    METHODS: In this paper, the influence of SWCNT-Ag on the thermal properties of traditional DGEBA/DETA/Ag conductive adhesive system was studied by using Materials Studio software. The volume shrinkage, glass transition temperature, thermal expansion coefficient, and thermal conductivity of the material were calculated based on COMPASS force field. The thermal conductivity is calculated by using reverse non-equilibrium molecular dynamics method. Finally, it is found that SWCNT-Ag has a positive effect on the thermal properties of the conductive adhesive system by comparing several groups of calculation data.
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  • 文章类型: Journal Article
    由于其可调整的机械性能和设计灵活性,薄层复合材料的使用迅速增加。考虑到粘接的复合材料接头,在其他主要应力因素中,剥离应力是导致失败的关键因素。因此,增强碳纤维增强聚合物(CFRP)层压板的整个厚度可以被认为是一种提高接头强度的方法。在层压板中的常规CFRP层之间局部使用薄层可以增强强度,由于刚度的突然变化意味着载荷传递不是单调的。因此,以下研究检查了在经受横向拉伸载荷时,在整个厚度范围内逐渐改变薄层对CFRP层压板行为的影响。为了实现这一目标,CFRP层压板通过使用不同的商业上可获得的预浸料薄层来逐渐改性,通过减少应力集中,从而改善整体结构性能。除了进行实验研究,还利用具有代表性体积元素(RVE)的Abaqus软件在微观尺度上进行了数值评估。参考配置的比较,其中包括不同厚度的各种薄层和传统的CFRP层压板,通过建议的渐进配置,强度和材料成本均有显著提高。此外,提出的RVE模型在准确预测预制层压板的强度方面表现出了很有前途的能力。
    The use of thin-ply composite materials has rapidly increased due to their tailorable mechanical properties and design flexibility. Considering an adhesively bonded composite joint, peel stress stands out as a key contributor leading to failure among other primary stress factors. Therefore, the reinforcement of carbon fiber-reinforced polymer (CFRP) laminates throughout the thickness could be considered as an approach to improve the joint strength. Using thin plies locally between the conventional CFRP layers in a laminate can enhance the strength, as the sudden change in stiffness means that the load transfer is not monotonous. Consequently, the following study examined the effect of altering thin plies gradually throughout the thickness on the behaviour of the CFRP laminates when subjected to transverse tensile loading. To achieve this goal, the CFRP laminates were gradually modified by using different commercially accessible prepreg thin plies, leading to an improved overall structural performance by reducing stress concentrations. Besides conducting an experimental study, a numerical assessment was also carried out utilizing Abaqus software with a Representative Volume Element (RVE) at the micro scale. The comparison of reference configurations, which involved various thin plies with different thicknesses and traditional CFRP laminates, with the suggested gradual configuration, demonstrated a notable enhancement in both strength and material cost. Furthermore, the proposed RVE model showed promising capability in accurately forecasting the strength of fabricated laminates.
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  • 文章类型: Journal Article
    考虑到玻璃纤维游艇不同部位的结构强度要求不同,碳纤维/玻璃纤维混合加固可应用于特殊区域的夹芯板蒙皮。本文设计并制备了12个由纯碳纤维组成的泡沫夹芯板样品,碳纤维/玻璃纤维混合物,纯玻璃纤维皮肤,和PVC和SAN泡沫三明治,参考玻璃纤维游艇外板的叠层结构。通过对低速冲击实验的对比分析,边缘压缩实验,短梁三点弯曲实验,我们寻求针对局部结构的最佳碳纤维/玻璃纤维混合铺层设计方案,以指导生产。结果表明,合理的混合碳纤维在玻璃纤维蒙皮中的铺设可以有效降低夹层结构的低速冲击损伤,减少边缘压缩损伤,提高夹层结构的抗弯和抗压性能。抗冲击性,耐压缩性,SAN夹层结构的抗剪切能力强于PVC夹层结构。碳纤维/玻璃纤维混合SAN泡沫夹层结构可用于弓形等特殊零件的局部结构加固,侧面,和玻璃纤维游艇的主甲板。
    Considering the different structural strength requirements of different parts of fiberglass yachts, carbon fiber/glass fiber hybrid reinforcement can be applied to the skins of sandwich panels in special areas. This paper designs and prepares 12 foam sandwich panel samples composed of pure carbon fiber, a carbon fiber/glass fiber hybrid, pure glass fiber skin, and PVC and SAN foam sandwich, with reference to the layup structure of the outer panel of a fiberglass yacht. Through a comparative analysis of low-speed impact experiments, edge compression experiments, and short beam three-point bending experiments, we seek the optimal carbon fiber/glass fiber hybrid layup design scheme for local structures to guide production. The results show that a reasonable hybrid carbon fiber layup in fiberglass skin can effectively reduce the low-speed impact damage of the sandwich structure, reduce edge compression damage, and improve the bending and compression resistance of sandwich structure. The impact resistance, compression resistance, and shear resistance of the SAN sandwich structure are stronger than the PVC sandwich structure. The carbon fiber/glass fiber hybrid SAN foam sandwich structure can be used for the local structural reinforcement of special parts such as the bow, side, and main deck of fiberglass yachts.
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  • 文章类型: Journal Article
    在减少金属合金在牙科学中的使用的全球背景下,已经开始考虑金属替代。在提议更换的材料中,聚醚醚酮可能具有有趣的特性,尤其是在可移动假牙框架中。这项研究的目的是评估与非金属CAD/CAM材料和玻璃纤维柱相比,PEEK柱和芯的抗断裂性。准备了40个拔出的上颌中切牙以接收桩。根据是否使用LuxaCam®PEEK重建样品,将样品分为四组,Enamic®,NumerysGF®或LuxaPost®。对样品进行斜压试验,并用ANOVA和Student's试验(或取决于条件的非参数检验)对结果进行统计分析。玻璃纤维桩和NumerysGF®显示出比LuxaCam®PEEK和Enamic®显著更高的抗断裂性。Enamic组没有发现唯一的牙齿骨折,这将这些样本与其他三组显著区分开来。在我们的研究中,看来,具有混合陶瓷的柱和芯的概念永远不会导致独特的牙齿骨折。通过根据所用材料对结果进行加权,我们的数据,首次在这种PEEK块上获得,无法确认使用PEEK进行嵌体核心概念的可能性,在特定情况下,当材料被认为是在患者出现过敏或全身性疾病禁忌症树脂或金属时除外。
    The thinking about metallic replacement has begun in a global context of reducing metallic alloys\' use in odontology. Among the materials proposed for their replacement, poly(etheretherketone) may present interesting properties, especially in removable dentures\' frames. The purpose of this study is to evaluate fracture resistance of PEEK posts-and-cores compared to non-metallic CAD/CAM materials and fiber glass posts. Forty extracted maxillary central incisors were prepared to receive posts. Samples were divided into four groups depending on whether they had been reconstructed with LuxaCam® PEEK, Enamic®, Numerys GF® or LuxaPost®. Samples were submitted to an oblique compressive test and results were statistically analyzed with ANOVA and Student\'s tests (or non-parametric tests depending on the conditions). Glass fiber posts and Numerys GF® reveal a significantly higher fracture resistance than LuxaCam® PEEK and Enamic®. No exclusively dental fracture has been noted for the Enamic group, which significantly distinguishes these samples from the three other groups. In our study, it appears that the conception of posts and cores with hybrid ceramic never conducts to a unique tooth fracture. By weighting the results according to the materials used, our data, obtained for the first time on this type of PEEK block, cannot confirm the possibility of using PEEK for inlay-core conception, excepted for specific cases when the material is considered in a patient presenting allergies or systemic disease contraindicating resin or metal.
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  • 文章类型: Journal Article
    本文介绍了磁性纳米粒子溶胶-凝胶法合成钴(II)铁氧体和基于它的有机-无机复合材料的结果。使用X射线相分析对获得的材料进行表征,扫描和透射电子显微镜,Scherrer,Brunauer-Emmett-Teller(BET)方法。提出了一种复合材料的形成机理,其包括其中过渡元素阳离子螯合物络合物与柠檬酸反应并随后在加热下分解的凝胶化阶段。已经证明了使用该方法获得基于钴(II)铁氧体和有机载体的有机无机复合材料的基本可能性。建立复合材料形成以导致样品表面积的显著(5-9倍)增加。形成具有显影表面的材料:通过BET方法测量的表面积为83-143m2/g。所得复合材料具有足够的磁性以在磁场中可移动。因此,多功能材料合成的广泛可能性为医学中的各种应用开辟了。
    The article presents results for the magnetic nanoparticles sol-gel method synthesis of cobalt (II) ferrite and organic-inorganic composite materials based on it. The obtained materials were characterized using X-ray phase analysis, scanning and transmission electron microscopy, Scherrer, Brunauer-Emmett-Teller (BET) methods. A composite materials formation mechanism is proposed, which includes a gelation stage where transition element cation chelate complexes react with citric acid and subsequently decompose under heating. The fundamental possibility of obtaining an organo-inorganic composite material based on cobalt (II) ferrite and an organic carrier using the presented method has been proved. Composite materials formation is established to lead to a significant (5-9 times) increase in the sample surface area. Materials with a developed surface are formed: the surface area measured by the BET method is 83-143 m2/g. The resulting composite materials have sufficient magnetic properties to be mobile in a magnetic field. Consequently, wide possibilities for polyfunctional materials synthesis open up for various applications in medicine.
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  • 文章类型: Journal Article
    固体火箭发动机(SRM)是一种使用固态燃料/氧化剂混合物的火箭发动机;最常用的推进剂是作为燃料的端羟基聚丁二烯(HTPB)和作为氧化剂的高氯酸铵/钾。为了增加这种车辆的飞行范围,重量必须尽可能地减轻。可以加工的可能元件是燃烧室的涂层:裙部。本文的目的是研究承受内压载荷和轴向推力的圆柱形裙部的行为,并比较由航空用标准钢制成的裙部与碳纤维增强复合材料裙部的性能。电机测试用例取自ONERAC1xb,流场采用轴对称k-ω湍流模型进行仿真。碳纤维增强复合材料裙部是一个圆柱壳,具有对称且平衡的叠层[90/0/45/-45]s。要检查复合层完整性,采用Hashin的破坏准则,同时使用线性化屈曲方法来评估裙部的屈曲行为。采用经典层压板理论对复合材料铺层进行建模。
    A solid rocket motor (SRM) is a rocket engine that uses a fuel/oxidizer mixture in a solid state; the most commonly employed propellants are Hydroxyl-Terminated Polybutadiene (HTPB) as the fuel and ammonium/potassium perchlorate as the oxidizer. To increase the flight range of this kind of vehicle, the weight has to be reduced as much as possible. A possible element that can be worked on is the coating of the combustion chamber: the skirt. The aim of this paper is to investigate the behavior of a cylindrical skirt subjected to internal pressure load and axial thrust and to compare the performance of a skirt made of a standard steel for aeronautics purposes with a carbon-fiber-reinforced composite skirt. The motor test case is taken from the ONERA C1xb and the flowfield is simulated with an axisymmetric k-ω turbulence model. The carbon-fiber-reinforced composite skirt is a cylindrical shell with a symmetric and balanced layup [90/0/45/-45]s. To check composite layer integrity, Hashin\'s failure criteria were adopted while linearized buckling methods were used to assess the buckling behavior of the skirt. The composite layup was modeled by adopting the classical laminate theory.
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  • 文章类型: Randomized Controlled Trial
    背景:在复杂的修复治疗中评估新的垂直闭塞尺寸(VDO)被认为是放置修复体之前的必要步骤。
    目的:这项随机对照试验(RCT)旨在评估中度至重度牙齿磨损患者在修复治疗前使用VDO升高评估的效果。关于OHRQoL,高速公路空间(FWS)和修复措施。
    方法:纳入42例牙齿磨损患者,并随机分配到使用可移动矫正器(RA)的测试阶段或无测试阶段。恢复性治疗包括使用VDO增加的复合修复体修复所有牙齿。OHIP-score,高速公路空间(FWS)在基线和召回预约时(1个月和1年)评估修复体的临床可接受性.在材料碎裂或基牙敏感性增加的情况下,对修复的干预进行评分,这可能与咬合过载有关。ANCOVA分析,单变量Cox回归,t检验,并进行描述性分析(p<0.05)。
    结果:41例患者在1年后完成临床随访。用RA测试VDO对OHIP评分没有显著影响(p=0.14)。RA组FWS减少,与对照组相比,在1年时显著降低(p=0.01,95CI-1.09至-0.15)。对修复的早期干预没有影响(p=0.94)。
    结论:该RCT显示,在牙齿磨损患者的修复治疗之前,不需要使用可移除的矫正器对增加的VDO进行功能测试。
    BACKGROUND: Evaluation of a new vertical dimension of occlusion (VDO) in complex restorative treatments is considered a necessary step prior to placement of restorations.
    OBJECTIVE: This randomised controlled trial (RCT) aimed to assess the effects of using an evaluation of a VDO increase before restorative treatment in patients with moderate-to-severe tooth wear, on OHRQoL, freeway space (FWS) and interventions to restorations.
    METHODS: Forty-two patients with tooth wear were included and randomly allocated to either a test phase with a Removable Appliance (RA) or no test phase. Restorative treatment consisted of restoration of all teeth using composite restorations in an increased VDO. OHIP-score, freeway space (FWS) and clinical acceptability of restorations were assessed at baseline and at recall appointments (1 month and 1 year). Intervention to restoration was scored in case of material chipping or when the abutment tooth had increased sensitivity that could be linked to occlusal overloading. ANCOVA analyses, Univariate Cox regression, t-tests and descriptive analyses were performed (p < .05).
    RESULTS: Clinical follow-up after 1 year was completed for 41 patients. No significant effect of testing the VDO with a RA could be found on the OHIP-score (p = .14). Reduction of FWS in the RA group, compared to the control group, was significantly lower at 1 year (p = .01, 95% CI -1.09 to -0.15). No effect on early interventions to restorations was found (p = .94).
    CONCLUSIONS: This RCT showed that a removable appliance is not indicated to functionally test the increased VDO prior to restorative treatment in patients with tooth wear.
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  • 文章类型: Journal Article
    通过再利用农业食品工业的废物或副产品来生产复合材料将是环境保护的挑战。本研究的重点是这个方向。在第一阶段,复合材料是用混合树脂基体(天然达玛树脂和环氧树脂的三种主要体积比例)和葵花籽切碎的外壳制成的。基于拉伸和压缩应力,得到了应力-应变和应变-应变图。用立体显微镜分析研究了破裂的表面积,并用高精度天平研究了水的吸收/损失。对振动行为进行了实验研究,确定阻尼系数及其自身的频率。在第二阶段,这些材料的研究得到了扩展。用与第一阶段相同类型的混合基质制备夹层复合材料。核心由葵花籽切碎的外壳和亚麻织物的外表面制成。这些复合材料被施加到弯曲(在三个点),得到力-变形图。所确定的机械性能允许完全或部分实现一些家具部件或建筑领域中使用的一些设备的这些复合材料。
    The production of composite materials through the reuse of waste or by-products from the agri-food industry will be a challenge for environmental protection. This study focuses in that direction. In the first stage, composites were made with the hybrid resin matrix (with three major volume proportions of natural Dammar resin and epoxy resin) and the reinforcing from shredded shells of sunflower seeds. Based on the tensile and compressive stresses, the stress-strain and strain-strain diagrams were obtained. The surface area of the rupture was investigated with stereo-microscopic analysis, and the absorption/loss of water was studied with a high precision balance. The vibration behavior was investigated experimentally, determining the damping coefficient and its own frequency. In the second stage, the study of these materials was extended. Sandwich composites were made with the same type of hybrid matrix as in the first stage. The core was made of shredded shells of sunflower seeds and the outer faces of linen fabric. These composites were applied to the bend (in three points), being obtained the force-deformation diagrams. The determined mechanical properties allow the complete or partial realization of these composites of some furniture components or of some equipment used in the field of constructions.
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  • 文章类型: Journal Article
    The purpose was to investigate the surface characteristics of various resin-based materials by immersing in probiotic beverages. A total of 420 disc-shaped samples (5 mm × 2 mm) were prepared from resin-based composites. Samples were divided into four groups and immersed for 10 min/day for 1 month in either a probiotic sachet, kefir, kombucha, or artificial saliva (control). Surface roughness was measured at baseline and 1 month. One sample of each of the tested materials was examined under nanoindentation to evaluate the reduced elasticity modulus and nanohardness scores. Scanning electron microscopy (SEM) was used to compare surface differences. Data were analyzed statistically using one-way ANOVA test and the significance was set at p < .05. The lowest roughness scores were observed in Z250, Estelite Bulk Fill, and HRi ENA in most of the test groups. Among conventional composites, Z250 group had the highest nanohardness and elasticity modulus scores. Among bulk-fill composites, Estelite Bulk Fill Flow had the lowest surface roughness after immersion in probiotic beverages and the highest nanohardness values. Reveal HD, as a bulk-fill group showed higher surface roughness and considerably lower nanohardness and elasticity modulus scores. Maximum height levels of samples were recorded. SEM images revealed voids and microcracks on the surfaces of test materials. Dentists may prefer Z250 as microhybrid and Estelite Bulk Fill Flow as bulk-fill composites for the restorations of patients who consume gut-friendly drinks regularly. When there are various types of materials, nanoindentation is a useful method for evaluating surface alterations and sensible comparisons.
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