Electrospinning

静电纺丝
  • 文章类型: Journal Article
    随着可再生能源技术的发展,对高效储能系统的需求正在增长。超级电容器作为高效的电能存储装置,因其优异的功率密度而备受关注,快速充电和放电能力,和长循环寿命。纳米碳纤维因其优异的力学性能,被广泛用作超级电容器的电极材料,电导率,和重量轻。尽管环境因素越来越多地推动循环经济概念在材料科学中的应用,木质素是一种未被充分利用但有前途的环保超级电容器电极材料。木质素基纳米碳纤维因其独特的化学稳定性,是制备高性能超级电容器电极材料的理想选择,丰度,和环境友好。静电纺丝是一种众所周知的技术,用于生产大量均匀的木质素基纳米纤维,是大规模生产具有特定直径的木质素基碳纳米纤维的最简单方法。本文综述了利用静电纺丝技术制备木质素基碳纳米纤维的最新研究进展,讨论了它们在超级电容器中的应用前景,并分析了当前面临的挑战和未来的发展方向。这有望对后续研究产生启发作用。
    With the development of renewable energy technologies, the demand for efficient energy storage systems is growing. Supercapacitors have attracted considerable attention as efficient electrical energy storage devices because of their excellent power density, fast charging and discharging capabilities, and long cycle life. Carbon nanofibers are widely used as electrode materials in supercapacitors because of their excellent mechanical properties, electrical conductivity, and light weight. Although environmental factors are increasingly driving the application of circular economy concepts in materials science, lignin is an underutilized but promising environmentally benign electrode material for supercapacitors. Lignin-based carbon nanofibers are ideal for preparing high-performance supercapacitor electrode materials owing to their unique chemical stability, abundance, and environmental friendliness. Electrospinning is a well-known technique for producing large quantities of uniform lignin-based nanofibers, and is the simplest method for the large-scale production of lignin-based carbon nanofibers with specific diameters. This paper reviews the latest research progress in the preparation of lignin-based carbon nanofibers using the electrospinning technology, discusses the prospects of their application in supercapacitors, and analyzes the current challenges and future development directions. This is expected to have an enlightening effect on subsequent research.
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  • 文章类型: Journal Article
    癌症,一个世界范围内复杂和多维的医学问题,可以通过恶性肿瘤的生长或附近组织的定植来鉴定,这归因于由几种影响因素促进的细胞的无法控制的增殖和分裂,包括家族史,暴露于污染物,生活方式的选择,某些感染。发展背后的复杂过程,扩展,癌症的进展仍在研究中。然而,根据癌症的类型和阶段以及患者的个性,有多种治疗方法可用于癌症的诊断和治疗。生物活性化合物强化纳米纤维为基础的先进疗法是癌症检测和治疗的革命性模型,通过探索独特的特性特异性靶向黑色素瘤细胞,例如增加有效载荷的表面积,以及纳米结构材料的成像和生物传感能力,对功能器官的损害最小。该研究的目的是获得有关使用生物材料制造的纳米纤维(NFs)在促进癌症管理方面的潜力的知识,并对最近的发展举措进行全面概述。挑战,以及未来的调查策略。几种制造方法,比如静电纺丝,自组装,相分离,绘图,生物相容性NFs的离心纺丝以及表征技术,已在审查中详细说明。
    Cancer, a complicated and multi-dimensional medical concern worldwide, can be identified via either the growth of malignant tumours or colonisation of nearby tissues attributing to uncontrollable proliferation and division of cells promoted by several influential factors, including family history, exposure to pollutants, choice of lifestyle, and certain infections. The intricate processes underlying the development, expansion, and advancement of cancer are still being studied. However, there are a variety of therapeutic alternatives available for the diagnosis and treatment of cancer depending on the type and stage of cancer as well as the patient\'s individuality. The bioactive compoundsfortified nanofiber-based advanced therapies are revolutionary models for cancer detection and treatment, specifically targeting melanoma cells via exploring unique properties, such as increased surface area for payload, and imaging and bio-sensing capacities of nano-structured materials with minimal damage to functioning organs. The objective of the study was to gain knowledge regarding the potentiality of Nanofibers (NFs) fabricated using biomaterials in promoting cancer management along with providing a thorough overview of recent developmental initiatives, challenges, and future investigation strategies. Several fabrication approaches, such as electrospinning, self-assembly, phase separation, drawing, and centrifugal spinning of bio-compatible NFs along with characterization techniques, have been elaborated in the review.
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  • 文章类型: Journal Article
    静电纺丝彻底改变了半导体金属氧化物(SMO)气体传感器领域,这是气体检测的关键。SMO以其高灵敏度而闻名,快速反应,和特殊的选择性对各种类型的气体。当通过静电纺丝合成时,他们获得了无与伦比的优势。这些包括高孔隙率,大的比表面积,可调节的形态和组成,和多样化的结构设计,提高气体传感性能。本文探讨了通过静电纺丝制备的各种结构和组成的SMO在气体传感器中的应用。它强调了增强气体传感性能的策略,如贵金属改性和过渡金属掺杂,稀土元素,和金属阳离子,所有这些都有助于提高灵敏度和选择性。我们还研究了用聚合物或碳纳米纤维制造复合SMO,解决了高工作温度的挑战。此外,这篇综述讨论了分层结构和核壳结构的优点。尖晶石和钙钛矿结构的使用也因其独特的化学组成和晶体结构而被探索。这些结构可用于对特定气体的高灵敏度和选择性。这些方法强调了创新材料集成和结构设计在实现高性能气体传感器方面的关键作用,指出了这个快速发展的领域未来的研究方向。
    Electrospinning has revolutionized the field of semiconductor metal oxide (SMO) gas sensors, which are pivotal for gas detection. SMOs are known for their high sensitivity, rapid responsiveness, and exceptional selectivity towards various types of gases. When synthesized via electrospinning, they gain unmatched advantages. These include high porosity, large specific surface areas, adjustable morphologies and compositions, and diverse structural designs, improving gas-sensing performance. This review explores the application of variously structured and composed SMOs prepared by electrospinning in gas sensors. It highlights strategies to augment gas-sensing performance, such as noble metal modification and doping with transition metals, rare earth elements, and metal cations, all contributing to heightened sensitivity and selectivity. We also look at the fabrication of composite SMOs with polymers or carbon nanofibers, which addresses the challenge of high operating temperatures. Furthermore, this review discusses the advantages of hierarchical and core-shell structures. The use of spinel and perovskite structures is also explored for their unique chemical compositions and crystal structure. These structures are useful for high sensitivity and selectivity towards specific gases. These methodologies emphasize the critical role of innovative material integration and structural design in achieving high-performance gas sensors, pointing toward future research directions in this rapidly evolving field.
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  • 文章类型: Journal Article
    水安全和工业废水处理是全球关注的重大问题。环境污染的主要问题之一是纺织和染料行业的染料废水的排放,导致日益严重的水污染问题,中毒供水,损害生态系统。已发现传统的废水处理方法效率低下,和生物吸附技术和机制已被证明是传统方法的成功替代品。最近的发展使人们认识到纤维材料是一种环境友好的选择,并在多个行业中得到广泛应用。包括废水处理。这篇综述探讨了通过静电纺丝技术生产的纤维材料作为废水处理吸附剂的潜力,同时,用于去除吸附物,如油,染料,重金属,和其他物质,正如文献报道的那样。纺织废水过滤结构,通过静电纺丝生产,进行了总结,并讨论了合成和天然聚合物用于此目的的用途。还提到了电纺纺织废水过滤结构的局限性。静电纺丝纳米纤维膜似乎是过滤纺织废水的非常有前途的途径,因此有助于水的再利用和减少水道的污染。
    Water security and industrial wastewater treatment are significant global concerns. One of the main issues with environmental contamination has been the discharge of dye wastewater from the textile and dye industries, contributing to an ever-growing problem with water pollution, poisoning water supplies, and harming the ecosystem. The traditional approach to wastewater treatment has been found to be inefficient, and biosorption techniques and mechanisms have been proven to be a successful replacement for conventional methods. Recent developments have led to the recognition of fibrous materials as an environmentally friendly option with broad application in several industries, including wastewater treatment. This review explores the potential of fibrous materials produced by the electrospinning technique as adsorbents for wastewater treatment, while at the same time, for the removal of adsorbates such as oil, dyes, heavy metals, and other substances, as reported in the literature. Textile wastewater filtering structures, produced by electrospinning, are summarized and the use of synthetic and natural polymers for this purpose is discussed. The limitations of electrospun textile wastewater filtering structures are also mentioned. Electrospun nanofibrous membranes appear to be a very promising route to filter textile wastewater and therefore contribute to water reuse and to reducing the contamination of water courses.
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  • 文章类型: Journal Article
    心血管疾病(CVD)仍然是全球死亡的主要原因。特别是,患有缺血性心脏病(IHD)且不适合手术或经皮血运重建技术的患者的治疗选择有限.此外,血运重建成功实施后,心肌有许多病理生理变化,包括但不限于缺血再灌注损伤,坏死,炎症改变,组织重塑,和运动障碍的壁运动。静电纺丝,纳米纤维支架制造技术,作为治疗心血管疾病的潜在治疗平台,最近已成为一种有吸引力的选择。由生物相容性材料制成的静电纺丝支架具有模拟天然细胞外基质的能力并且与药物递送相容。这些固有的属性,结合易于定制和低成本的生产,使静电纺丝支架成为治疗心血管疾病的活跃研究领域。在这次审查中,我们的目的是讨论静电纺丝的当前状态,从支架产生的基本原理到静电纺丝材料作为生物工程细胞外基质和药物递送载体在CVD治疗中的当前作用,特别强调心肌缺血的潜在临床应用。
    Cardiovascular disease (CVD) remains the leading cause of mortality worldwide. In particular, patients who suffer from ischemic heart disease (IHD) that is not amenable to surgical or percutaneous revascularization techniques have limited treatment options. Furthermore, after revascularization is successfully implemented, there are a number of pathophysiological changes to the myocardium, including but not limited to ischemia-reperfusion injury, necrosis, altered inflammation, tissue remodeling, and dyskinetic wall motion. Electrospinning, a nanofiber scaffold fabrication technique, has recently emerged as an attractive option as a potential therapeutic platform for the treatment of cardiovascular disease. Electrospun scaffolds made of biocompatible materials have the ability to mimic the native extracellular matrix and are compatible with drug delivery. These inherent properties, combined with ease of customization and a low cost of production, have made electrospun scaffolds an active area of research for the treatment of cardiovascular disease. In this review, we aim to discuss the current state of electrospinning from the fundamentals of scaffold creation to the current role of electrospun materials as both bioengineered extracellular matrices and drug delivery vehicles in the treatment of CVD, with a special emphasis on the potential clinical applications in myocardial ischemia.
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  • 文章类型: Journal Article
    静电纺丝已被公认为一种有效的技术,用于从基于聚合物的材料如聚乙烯醇(PVA)制造连续的纳米纤维,醋酸纤维素(CA),几丁质纳米晶体和其他。这些纳米纤维表现出化学和机械稳定性,高孔隙率,功能,高表面积和一维取向,使其在工业应用中极为有利。近年来,甲壳素-一种源自甲壳类和真菌细胞壁的生物聚合物-的研究由于其独特的结构排列而引起了人们的兴趣,优异的物理和化学性质,使其可生物降解,无毒和生物相容性。几丁质已广泛用于各种应用,如伤口敷料,药物输送,组织工程,膜,食品包装等。然而,几丁质由于其高度的结晶结构而不溶于大多数溶剂。需要适当的溶剂体系来溶解几丁质以最大化其应用并产生精细和光滑的电纺纳米纤维。本文重点介绍了通过溶解过程使用不同类型的溶剂体系制备甲壳素聚合物溶液的方法。还通过突出一些代表性实例讨论了加工参数的影响。最后,介绍了静电纺甲壳素纳米纤维在选定领域的应用现状。
    Electrospinning has been acknowledged as an efficient technique for the fabrication of continuous nanofibers from polymeric based materials such as polyvinyl alcohol (PVA), cellulose acetate (CA), chitin nanocrystals and others. These nanofibers exhibit chemical and mechanical stability, high porosity, functionality, high surface area and one-dimensional orientation which make it extremely beneficial in industrial application. In recent years, research on chitin - a biopolymer derived from crustacean and fungal cell wall - had gained interest due to its unique structural arrangement, excellent physical and chemical properties, in which make it biodegradable, non-toxic and biocompatible. Chitin has been widely utilized in various applications such as wound dressings, drug delivery, tissue engineering, membranes, food packaging and others. However, chitin is insoluble in most solvents due to its highly crystalline structure. An appropriate solvent system is required for dissolving chitin to maximize its application and produce a fine and smooth electrospun nanofiber. This review focuses on the preparation of chitin polymer solution through dissolution process using different types of solvent system for electrospinning process. The effect of processing parameters also discussed by highlighting some representative examples. Finally, the perspectives are presented regarding the current application of electrospun chitin nanofibers in selected fields.
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  • 文章类型: Journal Article
    核-壳结构是自然界中发现的同心圆结构。静电纺丝技术的快速发展为核壳纳米纤维的生产提供了更多的途径。核壳纳米纤维的纳米级效应和膨胀比表面积可以促进药物的溶解。通过采用巧妙的结构设计和明智的聚合物选择,可以制备专门的纳米纤维药物递送系统以实现药物的控制释放。核壳结构和材料的协同组合显示出增强药物利用效率和定制药物释放曲线的强大策略。因此,多室核壳纳米纤维对高效的疾病治疗具有很大的希望。然而,很少关注多室核壳纳米纤维对药物控释的影响。在这次审查中,我们介绍了多腔核壳纳米结构的不同制造技术,包括先进的静电纺丝技术和表面功能化。随后,我们综述了多腔核壳纳米纤维的不同控制药物释放行为及其对疾病治疗的潜在需求。基于电纺多室核壳纳米结构的控释行为的全面阐明可以激发新型控释系统的探索。此外,一旦这些具有可定制药物释放曲线的纤维走向工业大规模生产,它们将有可能促进药学的发展和各种疾病的治疗。本文分为:治疗方法和药物发现>新兴技术。
    Core-shell structure is a concentric circle structure found in nature. The rapid development of electrospinning technology provides more approaches for the production of core-shell nanofibers. The nanoscale effects and expansive specific surface area of core-shell nanofibers can facilitate the dissolution of drugs. By employing ingenious structural designs and judicious polymer selection, specialized nanofiber drug delivery systems can be prepared to achieve controlled drug release. The synergistic combination of core-shell structure and materials exhibits a strong strategy for enhancing the drug utilization efficiency and customizing the release profile of drugs. Consequently, multi-chamber core-shell nanofibers hold great promise for highly efficient disease treatment. However, little attention concentration is focused on the effect of multi-chamber core-shell nanofibers on controlled release of drugs. In this review, we introduced different fabrication techniques for multi-chamber core-shell nanostructures, including advanced electrospinning technologies and surface functionalization. Subsequently, we reviewed the different controlled drug release behaviors of multi-chamber core-shell nanofibers and their potential needs for disease treatment. The comprehensive elucidation of controlled release behaviors based on electrospun multi-chamber core-shell nanostructures could inspire the exploration of novel controlled delivery systems. Furthermore, once these fibers with customizable drug release profiles move toward industrial mass production, they will potentially promote the development of pharmacy and the treatment of various diseases. This article is categorized under: Therapeutic Approaches and Drug Discovery > Emerging Technologies.
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  • 文章类型: Systematic Review
    静电纺丝是生产超薄纳米纤维的最简单技术,这使得纳米技术能够在各种应用中使用。通过静电纺丝生产的纳米纤维材料由于其独特的性能和用途潜力而在生物医学应用中引起了极大的关注。近年来,人们越来越重视将可持续性原则纳入材料设计和生产。然而,静电纺纳米纤维,由于它们依赖与毒性等重大缺点相关的溶剂,可燃性,和处置挑战,经常达不到环保标准。由于溶剂选择有限,以及现代生活中对安全和卫生的高度关注,必须仔细评估在各种应用和消费产品中使用电纺纳米纤维的影响。这篇系统的综述旨在全面评估“绿色和天然”电纺聚合物纳米纤维以及更迷人和环保的商业技术领域的研究和开发现状,溶剂偏好,和其他绿色路线,尊重为生物医学应用量身定制的社会和法律限制。我们探索了来自可再生原料的生物相容性和可生物降解聚合物的利用,环保加工技术,和环境影响评估。我们的评论强调了绿色和天然电纺纳米纤维在满足各种生物医学应用的苛刻要求的同时解决可持续性问题的潜力。包括组织工程,药物输送,伤口愈合,诊断平台。我们分析了优势,挑战,以及这些材料的未来前景,提供对生物医学领域环境负责的纳米纤维技术不断发展的见解。
    Electrospinning is the simplest technique to produce ultrathin nanofibers, which enables the use of nanotechnology in various applications. Nanofibrous materials produced through electrospinning have garnered significant attention in biomedical applications due to their unique properties and versatile potential. In recent years, there has been a growing emphasis on incorporating sustainability principles into material design and production. However, electrospun nanofibers, owing to their reliance on solvents associated with significant drawbacks like toxicity, flammability, and disposal challenges, frequently fall short of meeting environmentally friendly standards. Due to the limited solvent choices and heightened concerns for safety and hygiene in modern living, it becomes imperative to carefully assess the implications of employing electrospun nanofibers in diverse applications and consumer products. This systematic review aims to comprehensively assess the current state of research and development in the field of \"green and natural\" electrospun polymer nanofibers as well as more fascinating and eco-friendly commercial techniques, solvent preferences, and other green routes that respect social and legal restrictions tailored for biomedical applications. We explore the utilization of biocompatible and biodegradable polymers sourced from renewable feedstocks, eco-friendly processing techniques, and the evaluation of environmental impacts. Our review highlights the potential of green and natural electrospun nanofibers to address sustainability concerns while meeting the demanding requirements of various biomedical applications, including tissue engineering, drug delivery, wound healing, and diagnostic platforms. We analyze the advantages, challenges, and future prospects of these materials, offering insights into the evolving landscape of environmentally responsible nanofiber technology in the biomedical field.
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  • 文章类型: Journal Article
    聚乙烯醇是最有吸引力的聚合物之一,具有广泛的用途,生物相容性,低毒性,良好的机械性能,成本相对较低。本文重点介绍了聚乙烯醇静电纺丝的最新进展,并总结了该过程的参数(电压,距离,流量,和收集器),溶液(分子量和浓度),和环境(湿度和温度),以了解对结构的影响,机械,基于聚乙烯醇的静电纺丝基质的化学性质。通过探索包括伤口敷料在内的生物医学应用的文献综述,强调了聚(乙烯醇)静电纺丝在生物医学应用中的重要性。药物输送,组织工程,和生物传感器。该研究还强调了通过电喷雾聚乙烯醇形成颗粒的新的有希望的领域。综述了使用不同聚乙烯醇基质的局限性和优点,并提出了一些未来的建议,以推进这一研究领域。
    Poly(vinyl alcohol) is one of the most attractive polymers with a wide range of uses because of its water solubility, biocompatibility, low toxicity, good mechanical properties, and relatively low cost. This review article focuses on recent advances in poly(vinyl alcohol) electrospinning and summarizes parameters of the process (voltage, distance, flow rate, and collector), solution (molecular weight and concentration), and ambient (humidity and temperature) in order to comprehend the influence on the structural, mechanical, and chemical properties of poly(vinyl alcohol)-based electrospun matrices. The importance of poly(vinyl alcohol) electrospinning in biomedical applications is emphasized by exploring a literature review on biomedical applications including wound dressings, drug delivery, tissue engineering, and biosensors. The study also highlights a new promising area of particles formation through the electrospraying of poly(vinyl alcohol). The limitations and advantages of working with different poly(vinyl alcohol) matrices are reviewed, and some recommendations for the future are made to advance this field of study.
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  • 文章类型: Journal Article
    Zein,一种来源于玉米的蛋白质生物聚合物,由于其有利的物理属性,作为包装食品的一种有前途和环保的选择而受到关注。静电纺丝技术的引入大大推进了玉米醇溶蛋白基纳米材料的生产。这种尖端技术可以创建具有可定制结构的纳米纤维,提供高表面积和可调的机械和热属性。此外,静电纺丝工艺允许整合各种添加剂,如抗氧化剂,抗菌剂,和调味化合物,进入玉米醇溶蛋白纳米纤维,增强其食品保存功能。在这次全面审查中,用于制作玉米醇溶蛋白基纳米纤维的各种静电纺丝技术,我们深入研究它们的增强特性。此外,该综述通过掺入多种成分,阐明了玉米醇溶蛋白纳米纤维在活性和智能包装材料中的潜在应用。总之,这篇综述强调了玉米醇溶蛋白基纳米复合材料在食品包装领域的广阔前景,为食品工业提供可持续和创新的解决方案。
    Zein, a protein-based biopolymer derived from corn, has garnered attention as a promising and eco-friendly choice for packaging food due to its favorable physical attributes. The introduction of electrospinning technology has significantly advanced the production of zein-based nanomaterials. This cutting-edge technique enables the creation of nanofibers with customizable structures, offering high surface area and adjustable mechanical and thermal attributes. Moreover, the electrospinning process allows for integrating various additives, such as antioxidants, antimicrobial agents, and flavoring compounds, into the zein nanofibers, enhancing their functionalities for food preservation. In this comprehensive review, the various electrospinning techniques employed for crafting zein-based nanofibers, and we delve into their enhanced properties. Furthermore, the review illuminates the potential applications of zein nanofibers in active and intelligent packaging materials by incorporating diverse constituents. Altogether, this review highlights the considerable prospects of zein-based nanocomposites in the realm of food packaging, offering sustainable and innovative solutions for food industry.
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