natural dye

天然染料
  • 文章类型: Journal Article
    纺织工业中合成染料的使用大多是不可降解的,它们是致癌的,严重污染环境。由于天然染料具有减轻与合成着色剂相关的环境挑战的潜力,最近获得了极大的关注。这项调查的重点是提取源自红木树的天然染料,以及探索黄麻织物着色的环保技术。衍生的染料是从桃花心树的不同部分获得的:即,树皮,水果,和木材残留物。采用水性提取方法,固有的着色剂经过精心分离,随后在使用各种媒染剂类别进行适当的媒染后,将其应用于黄麻织物。详尽的评估包括清洗,光,摩擦,并且在使用三种不同的桃花心木树衍生染料进行染色的黄麻织物上进行了抗汗性。值得注意的是,用木材废料来源的染料处理过的黄麻织物表现出值得称赞的优异的抗性。这种染色过程的功效通过不同的表征技术得到进一步证实,包括扫描电子显微镜(SEM)和傅里叶变换红外光谱(FTIR),明确肯定了桃花心木衍生染料成功粘合到黄麻织物表面。纺织业,特别是使用大量的染色操作,设计的颜色和合成化学品,通过将排放物直接倾倒入水体,正在对海上环境造成严重破坏。合成颜色通常用于染色黄麻织物,这对健康和环境有重大影响。因此,关于环境挑战,在纺织工业中,使用红木树的天然提取染料对黄麻织物进行染色可以替代合成染料。
    The use of synthetic dyes in the textile industry is mostly non-degradable, which are carcinogenic and pollute the environment severely. Natural dyes have gained significant attention recently due to their potential to mitigate the environmental challenges associated with synthetic colorants. This investigation is centered around the extraction of natural dyes sourced from mahogany trees and the exploration of environmentally friendly techniques for coloring jute fabric. The derived dyes were procured from distinct segments of the mahogany tree: namely, the bark, fruits, and wood remnants. Employing an aqueous extraction methodology, inherent coloring agents were meticulously separated and subsequently applied to jute fabric subsequent to appropriate mordanting employing a variety of mordant categories. An exhaustive assessment encompassing wash, light, rubbing, and perspiration resistance was conducted on jute fabric that was subjected to dyeing using three distinct variants of mahogany tree-derived dyes. Notably, jute fabric treated with wood wastage-sourced dye exhibited commendable to exceptional resistance properties. The efficacy of this dyeing process was further substantiated through diverse characterization techniques, inclusive of scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR), which unequivocally affirmed the successful bonding of mahogany-derived dyes onto the surface of the jute fabric. The textile industry, particularly dyeing operations that use large, designed colors and synthetic chemicals, is wreaking havoc on the sea-going environment by dumping emissions directly into bodies of water. Synthetic colors are commonly used to dye jute fabric, which has major health and environmental consequences. Therefore, concerning the environmental challenges, the dyeing of jute fabric using naturally extracted dyes from mahogany trees can be a suitable alternative to synthetic dyes in the textile industry.
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  • 文章类型: Journal Article
    在染色行业中使用天然染料成为合成染料的替代品,已知含有有害化学物质,可能对环境和人类健康构成威胁。本研究涉及从决明子花瓣中提取黄色染料,使用超声波浴(40KHz,输入功率为500)优化提取过程,超声波探头(390W,455W,520W,585瓦,和650瓦),和常规加热(30°C的加热罩,40°C,50°C,60°C,和70°C),染料的表征,以及染色(棉,丝绸,和皮革)不使用媒染剂。进一步评价提取的黄色染料以确定其对皮肤细菌的抗菌活性。使用UV-可见光分光光度分析进行染料提取优化,结果表明,使用超声波水浴提取在50°C下45分钟,甲醇提取物(287和479nm)中获得最大的黄色,其次是超声波探头和直接加热。基于FTIR光谱,显然,OH存在于约3300cm-1处,而CH在约2900cm-1处延伸。1608cm-1的特征峰与基于蒽醌的化合物具有惊人的相似性。此外,使用超声波水浴染色技术在50°C下持续45分钟,棉花的黄色,丝绸,皮革染色效果最佳。由于用沸腾的肥皂液洗涤两次后可有效去除颜色,染色棉和丝织物显示出良好的洗涤和摩擦牢度。关于抗菌活性,在甲醇中提取后,染料对所有病原体都具有很高的活性。观察到对假单胞菌的最大抑制作用。MIC值为1.56mg/ml。
    Using natural dyes in dyeing industries becomes an alternative to synthetic dyes, which are known to contain harmful chemicals that can pose risks to the environment and human health. This study involves the extraction of yellow dye from Cassia alata flower petals, optimization of the extraction process using an ultrasonic bath (40 KHz and an input power of 500), ultrasonic probe (390 W, 455 W, 520 W, 585 W, and 650 W), and conventional heating (heating mantle with 30 °C, 40 °C, 50 °C, 60 °C, and 70 °C), characterization of the dye, as well as dyeing (cotton, silk, and leather) without using a mordant. The extracted yellow dye was further evaluated to determine its antibacterial activity against skin bacteria. Dye extraction optimization using UV-Visible spectrophotometric analysis revealed that the maximum yellow color in methanol extract (287 and 479 nm) was obtained at 50 °C for 45 min using ultrasonic water bath extraction, followed by the ultrasonic probe and direct heating. Based on the FTIR spectra, it is evident that OH is present at approximately 3300 cm-1, while CH stretches at around 2900 cm-1. A characteristic peak at 1608 cm-1 bears a striking similarity to anthraquinonoid-based compounds. Also, using the ultrasonic water bath dyeing technique at 50 °C for 45 min, the yellow color of cotton, silk, and leather was dyed optimally. Due to effective color removal after two washings with boiling soap liquid, the dyed cotton and silk fabric displayed good washing and rubbing fastness. Regarding antibacterial activity, the dye was highly active against all pathogens after extraction in methanol. The maximum inhibition was observed against Pseudomonas sp. with a MIC value of 1.56 mg/ml.
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  • 文章类型: Journal Article
    植物染料由于其来源有限,在纺织工业中的应用一直十分有限,不完整的颜色空间,和狭窄的色域,等。因此,研究天然染料的色彩特性和色域以及相应的染色工艺对于完成天然染料的色彩空间及其应用至关重要。在这项研究中,黄柏树皮的水提取物(P.amurense)用作染料。染色性能,色域,研究了染色棉织物的颜色评价,并获得了最佳染色条件。结果表明,最佳染色工艺是以1:50的液比进行预媒染,P.amurense染料浓度为5.2g/L,媒染剂浓度(硫酸铝钾)为5g/L,染色温度为70°C,染色时间30分钟,媒染时间15分钟,和pH5。通过对染色工艺的优化,获得最大色域范围,亮度L*值为74.33至91.23,a*值为-0.89至2.96,b*值为4.62至34.08,色度C*值为5.49至34.09,色调角h°值为57.35°至91.57°。获得从浅黄色到深黄色的颜色,其中12种颜色是根据Pantone匹配系统确定的。耐皂洗色牢度,摩擦,染色棉织物上的阳光均达到3级或以上,进一步扩大了天然染料的适用性。
    The application of plant dyes in the textile industry has been very limited due to their limited sources, incomplete color space, and narrow color gamut, etc. Therefore, studies of the color properties and color gamut of natural dyes and the corresponding dyeing processes are essential for completing the color space of natural dyes and their application. In this study, water extract from the bark of Phellodendron amurense (P. amurense) was used as a dye. Dyeing properties, color gamut, and color evaluation of dyed cotton fabrics were studied, and optimal dyeing conditions were obtained. The results showed that the optimal dyeing process was pre-mordanting with liquor ratio at 1:50, P. amurense dye concentration at 5.2 g/L, mordant concentration (aluminum potassium sulfate) at 5 g/L, dyeing temperature at 70 °C, dyeing time of 30 min, mordanting time of 15 min, and pH 5. Through the optimization of the dyeing process, a maximum color gamut range was obtained with lightness L* value from 74.33 to 91.23, a* value from -0.89 to 2.96, b* value from 4.62 to 34.08, chroma C* value from 5.49 to 34.09, and hue angle h° value from 57.35° to 91.57°. Colors from light yellow to dark yellow were obtained, among which 12 colors were identified according to the Pantone Matching Systems. The color fastness against soap-washing, rubbing, and sunlight on the dyed cotton fabrics all reached grade 3 level or above, further expanding the applicability of natural dyes.
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  • 文章类型: Journal Article
    The aerial parts of the Argy Worm Wood (AWW) plant have been used in different Chinese foods as a colorant and a taste enhancer for a long time. Despite its application as a food colorant, it has rarely been considered for the coloration of textiles. Keeping in mind the variation in color strength due to the change in phytochemical contents by seasonal change and other variables, the extraction of AWW aerial parts was optimized using the Taguchi method. Optimization was performed on the basis of total phytochemical contents (phenols, flavonoids, and tannins) in the extracted solutions. For this purpose, two different solvent systems, namely sodium hydroxide/water (NaOH/water) and ethanol/water (EtOH/water), were applied through a simple aqueous extraction method at varying levels of solvent concentration, and extraction temperature and duration. Maximum phytochemicals yield of 21.96% was obtained using NaOH/water system with 9 g/L NaOH/water at 85 °C for 20 min and 25.5% with 75% aqueous ethanol at 85 °C for 40 min. Optimized extracts were characterized by UV-Vis and FTIR spectrophotometry, which showed the presence of multiple phytochemicals in the extracts. The dyeing temperature and time were also optimized. Dyed cotton fabrics showed medium to high colorfastness to washing and excellent antibacterial and UV radiation absorption properties. The effect of pre-mordanting with salts of iron and copper was also studied on the color fastness properties. Cotton fabrics dyed with two different solvent system extracts displayed various shades of brown with NaOH/water, and green with aqueous ethanol with and without pre-mordanting. The present study provides the textile industry with a promising source of functional bio-colorant and a value-adding approach for the AWW plant industry.
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  • 文章类型: Journal Article
    Bixaorellana是一棵以红色闻名的小树,包含在种皮中的油溶性色素,用作天然染料和食用色素。在这项研究中,我们组装并表征了B.orellana完整的叶绿体基因组,作为未来遗传研究的资源。总长度为159,825bp,叶绿体基因组由89,476bp的大型单拷贝(LSC)区域组成,一个19,617bp的小的单拷贝(SSC)区域,和两个每个25,356bp的反向重复(IR)区。共预测127个基因,由83个蛋白质编码基因组成,36个tRNA基因,和8个rRNA基因。系统发育分析证实了拟南芥在拟南芥中的位置。
    Bixa orellana is a small tree known for its red, oil-soluble pigment contained in the seed coat that is used as a natural dye and food coloring. In this study, we assembled and characterized the complete chloroplast genome of B. orellana as a resource for future genetic studies. With a total length of 159,825 bp, the chloroplast genome comprised of a large single-copy (LSC) region of 89,476 bp, a small single-copy (SSC) region of 19,617 bp, and two inverted repeat (IR) regions of 25,356 bp each. A total of 127 genes were predicted, consisting of 83 protein-coding genes, 36 tRNA genes, and 8 rRNA genes. Phylogenetic analysis confirmed the position of B. orellana within the order Malvales.
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  • 文章类型: Journal Article
    最近,天然染料由于其环保的特点,在各种传统和先进的应用中有着越来越广泛的应用。然而,改善天然染料的可染性仍然是一项具有挑战性的任务。本研究旨在使用由m-反式谷氨酰胺酶组成的生物纳米媒染剂实现具有改善的可染性的多目标羊毛,m-TGase,和膨润土纳米粘土。使用不同浓度的m-TGase和膨润土通过声化学方法处理羊毛纤维。通过场发射扫描电子显微镜(FESEM)检查了羊毛织物样品的表面形态,和傅里叶变换红外辐射(FTIR)。Further,在不同条件下处理的羊毛样品被应用于madder进行可染性检查。颜色坐标的最佳条件,颜色强度,K/S,m-TGase和膨润土对处理过的羊毛织物的洗涤牢度,也被检查过。结果揭示了m-TGase之间良好的相互作用,膨润土,和羊毛纤维。此外,表面形态受到酶浓度变化的强烈影响,因此额外添加m-TGase会导致SEM图像中明显的损伤鳞片或较少的角质层表面。此外,结果表明,处理后的羊毛样品的K/S值优于未处理的样品。的确,其中,5%浓度的m-TGase和膨润土的生物纳米媒染剂具有最大的建设性K/S值。同样,ΔE和抗菌研究的结果也证实了其优越性。
    Recently, natural dyes have a widening scope in various traditional and advanced applications due to their eco-friendly environment. However, improved dyeability of natural dyes still remains a challenging task. This research was aimed to achieve multi-objective wool with improved dyeability using bio-nano-mordant composed of m-Trans-glutaminase, m-TGase, and bentonite nanoclay. Wool fiber was treated through sonochemical method using different concentrations of m-TGase and bentonite. The surface morphology of wool fabric samples was examined by field emission-scanning electron microscopy (FESEM), and Fourier transform Infrared Radiation (FTIR). Further, wool samples treated at different conditions were applied to madder for dyeability examination. The optimum conditions of color coordinates, color strength, K/S, and washing fastness of madder on treated wool fabric with m-TGase and bentonite, were also examined. The results revealed well-made interactions among m-TGase, bentonite, and wool fibers. In addition, surface morphology was strongly influenced by variations in enzyme concentrations so that extra addition of m-TGase lead to clear damage scales or less cuticle surface in SEM images. Moreover, the results showed that the value of K/S for treated wool samples was better than untreated samples. Indeed, amongst all, 5% concentrations of bio-nano-mordant for m-TGase and bentonite have the most constructive K/S values. Similarly, results of ΔE and antibacterial investigations also confirmed its superiority.
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