nanomaterials

纳米材料
  • 文章类型: Journal Article
    从这个角度来看,作者对(纳米)材料安全性交流的发展和经验发表了看法。我们希望与科学界分享我们的经验,以便使它们对未来的交流活动有用。我们介绍了科学传播项目达娜的长期工作,DaNa2.0和DaNa4.0,从2009年到2023年运行。从21世纪初开始,纳米技术研究开始,与公众就纳米材料的安全性进行交流仍然很新,面临着许多挑战的项目。今天,科学传播对于科学发现的传播是必不可少的,而基于事实的方法,如DaNa“知识库材料”,可以与公众进行值得信赖的对话。这个长期项目系列为纳米材料安全方面的交流做出了重大贡献,甚至可能是全球最大的公共资助项目系列。
    In this perspective, the authors give their view on the developments and experiences on communicating on (nano)materials safety. We would like to share our experiences with the scientific community in order to make them useful for future communication activities. We present the long-term work of the science communication projects DaNa, DaNa2.0 and DaNa4.0, running from 2009 to 2023. Starting in the early 2000s with the beginnings of nanotechnology research, communication on the safety of nanomaterials with the public was still very new and faced the projects with many challenges. Today, science communication is indispensable for the dissemination of scientific findings and a fact-based approach like the DaNa \"Knowledge Base Materials\" creates a trustworthy dialogue with the public. This long-term project series has made a significant contribution to communication on the safety of nanomaterials, perhaps even the largest among publicly funded project series worldwide.
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  • 文章类型: Journal Article
    2050年的气候中立是欧盟27+英国的目标。罗马尼亚也不例外,它假设逐步减轻能源部门产生的污染,到2030年,根据“适合55岁”,可再生能源的份额必须达到总能耗的42.5%。对于传统来源产生的其余能量,天然气和/或煤炭,现代技术将被用来保留气态的氢气。即使它们不是温室气体,化石燃料燃烧产生的NO和SO2,对环境和生物多样性造成负面影响。不同材料的吸附能力,内部开发的三种纳米材料和三种商业吸附剂,NO和SO2都是通过气相色谱法解决的,元素分析,和傅里叶变换红外光谱。在研究条件下,Fe-BTC已被证明是分离效率和吸附能力的优异材料,并且在NO(80.00cm3/g)和SO2(63.07cm3/g)的情况下都具有通用性。与商业吸附剂相比,所有开发的纳米材料都产生了优异的结果。压力的增加增强了吸收过程的性能,虽然温度表现出相反的影响,通过阻挡表面上的活动中心。
    Climate neutrality for the year 2050 is the goal assumed at the level of the EU27+UK. As Romania is no exception, it has assumed the gradual mitigation of pollution generated by the energy sector, and by 2030, according to \'Fit for 55\', the share of energy from renewable sources must reach 42.5% from total energy consumption. For the rest of the energy produced from traditional sources, natural gas and/or coal, modern technologies will be used to retain the gaseous noxes. Even if they are not greenhouse gases, NO and SO2, generated from fossil fuel combustion, cause negative effects on the environment and biodiversity. The adsorption capacity of different materials, three nanomaterials developed in-house and three commercial adsorbents, both for NO and SO2, was tackled through gas chromatography, elemental analysis, and Fourier-transform infrared spectroscopy. Fe-BTC has proven to be an excellent material for separation efficiency and adsorption capacity under studied conditions, and is shown to be versatile both in the case of NO (80.00 cm3/g) and SO2 (63.07 cm3/g). All the developed nanomaterials generated superior results in comparison to the commercial adsorbents. The increase in pressure enhanced the performance of the absorption process, while temperature showed an opposite influence, by blocking the active centers on the surface.
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  • 文章类型: Journal Article
    背景:最近的综述概述了与胃肠道肿瘤有关的主要纳米材料,并描述了这些材料的基本特性。然而,纳米材料在胃癌中的应用研究热点和趋势尚不清楚。
    目的:展示纳米材料在GC中的应用研究的知识结构和演化趋势。
    方法:从WebofScienceCoreCollection检索到与纳米材料在GC中的应用有关的出版物,用于本系统综述和文献计量学研究。VOSviewer和CiteSpace用于文献计量和可视化分析。
    结果:从2000年到2022年,纳米材料在GC中的应用发展迅速。关键词共现分析表明,相关研究课题分为三个簇:(1)纳米材料在GC处理中的应用;(2)纳米材料在GC诊断中的应用及毒性;(3)纳米材料对GC细胞生物学行为的影响。复合物,银纳米粒子,和绿色合成是最新的高频关键词,代表了有希望的未来研究方向。
    结论:纳米材料在GC诊断和治疗中的应用及其对GC细胞的作用机制是近23年来研究该领域的主要课题。
    BACKGROUND: Recent reviews have outlined the main nanomaterials used in relation to gastrointestinal tumors and described the basic properties of these materials. However, the research hotspots and trends in the application of nanomaterials in gastric cancer (GC) remain obscure.
    OBJECTIVE: To demonstrate the knowledge structure and evolutionary trends of research into the application of nanomaterials in GC.
    METHODS: Publications related to the application of nanomaterials in GC were retrieved from the Web of Science Core Collection for this systematic review and bibliometric study. VOSviewer and CiteSpace were used for bibliometric and visualization analyses.
    RESULTS: From 2000 to 2022, the application of nanomaterials in GC developed rapidly. The keyword co-occurrence analysis showed that the related research topics were divided into three clusters: (1) The application of nanomaterials in GC treatment; (2) The application and toxicity of nanomaterials in GC diagnosis; and (3) The effects of nanomaterials on the biological behavior of GC cells. Complexes, silver nanoparticles, and green synthesis are the latest high-frequency keywords that represent promising future research directions.
    CONCLUSIONS: The application of nanomaterials in GC diagnosis and treatment and the mechanisms of their effects on GC cells have been major themes in this field over the past 23 years.
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  • 文章类型: Journal Article
    肽基材料的开发是近年来生物材料研究中最具挑战性的方面之一。肽的组装主要受氢键等作用力的控制,疏水相互作用,静电相互作用,和π-π积累。多肽具有结构简单、容易合成,良好的生物相容性,无毒性,易于修改,等。这些因素使多肽成为理想的生物医用材料,在生物医用材料中具有广阔的应用前景,因此受到了广泛的关注。在这次审查中,介绍了肽自组装的机理和分类及其在生物医学和水凝胶中的应用。
    The development of peptide-based materials is one of the most challenging aspects of biomaterials research in recent years. The assembly of peptides is mainly controlled by forces such as hydrogen bonding, hydrophobic interaction, electrostatic interaction, and π-π accumulation. Peptides have unique advantages such as simple structure, easy synthesis, good biocompatibility, non-toxicity, easy modification, etc. These factors make peptides turn into ideal biomedical materials, and they have a broad application prospect in biomedical materials, and thus have received wide attention. In this review, the mechanism and classification of peptide self-assembly and its applications in biomedicine and hydrogels were introduced.
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  • 文章类型: Journal Article
    在提出的研究中,测试了各种来源的各种杂种和单一纳米材料作为辣根过氧化物酶固定化的新型平台。进行了彻底的表征,以建立固定的支持材料的适用性,以及生物催化剂的活性和稳定性保留,进行了分析和讨论。获得的系统的物理化学表征证明了酶在所有提供的材料上的成功沉积。辣根过氧化物酶在所有测试支持物上的固定效率高于70%。然而,对于多壁碳纳米管和由壳聚糖制成的杂化物,磁性纳米粒子,和硒离子,达到90%。对于这些材料,固定化产率超过80%,导致大量的固定化酶。产生的系统显示出与游离酶相同的最佳pH和温度条件;但是,在更广泛的条件下,固定化酶活性超过50%。最后,可重复使用性研究和储存稳定性测试表明,辣根过氧化物酶固定在壳聚糖杂种上,磁性纳米粒子,在10个重复的催化循环和20天的储存后,硒离子保留了其初始活性的80%左右。在所有测试材料中,最有利于固定化的是上述壳聚糖基杂化材料。所讨论的材料中存在的硒添加剂赋予其补充性质,所述补充性质增加酶的固定化产率并改善酶稳定性。获得的结果证实了这些纳米材料在酶的结构稳定性和制造的生物催化剂的高催化活性方面作为酶固定化的有用平台的适用性。
    In the presented study, a variety of hybrid and single nanomaterials of various origins were tested as novel platforms for horseradish peroxidase immobilization. A thorough characterization was performed to establish the suitability of the support materials for immobilization, as well as the activity and stability retention of the biocatalysts, which were analyzed and discussed. The physicochemical characterization of the obtained systems proved successful enzyme deposition on all the presented materials. The immobilization of horseradish peroxidase on all the tested supports occurred with an efficiency above 70%. However, for multi-walled carbon nanotubes and hybrids made of chitosan, magnetic nanoparticles, and selenium ions, it reached up to 90%. For these materials, the immobilization yield exceeded 80%, resulting in high amounts of immobilized enzymes. The produced system showed the same optimal pH and temperature conditions as free enzymes; however, over a wider range of conditions, the immobilized enzymes showed activity of over 50%. Finally, a reusability study and storage stability tests showed that horseradish peroxidase immobilized on a hybrid made of chitosan, magnetic nanoparticles, and selenium ions retained around 80% of its initial activity after 10 repeated catalytic cycles and after 20 days of storage. Of all the tested materials, the most favorable for immobilization was the above-mentioned chitosan-based hybrid material. The selenium additive present in the discussed material gives it supplementary properties that increase the immobilization yield of the enzyme and improve enzyme stability. The obtained results confirm the applicability of these nanomaterials as useful platforms for enzyme immobilization in the contemplation of the structural stability of an enzyme and the high catalytic activity of fabricated biocatalysts.
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  • 文章类型: Journal Article
    纳米技术已经成为一项革命性的技术,已经在石油和天然气行业应用了十多年,跨越上游,中游,和下游部门。纳米技术为原油和天然气的勘探做出了重大贡献,在地下和深水环境中。对改善钻井工艺也起到了至关重要的作用,能够从地球表面下开采石油和天然气资源。纳米颗粒,具有其独特的物理和化学性质,例如高比表面积,高孔隙体积,和小尺寸,在石油工业中显示出相当大的潜力。已经进行了广泛的研究,以探索用于高级应用的各种类型的纳米颗粒,包括石油勘探,钻孔,生产,和提高石油采收率(EOR)。此外,纳米材料已经在下游和中间部门找到了应用,例如原油精炼,天然气加工,以及石油产品的运输和储存。纳米材料合成方法的不断进步,探索新的纳米材料用途,了解纳米材料的非凡特性将继续使它们在石油和天然气领域越来越有价值。石油和天然气行业认识到纳米技术和纳米颗粒的潜力,并在该领域的研究和开发方面进行了大量投资。这篇综合综述旨在总结纳米技术的成功应用,同时应对相关挑战。它是该领域未来研究和应用努力的宝贵资源,强调纳米技术在石油和天然气行业的潜力。
    Nanotechnology has emerged as a revolutionary technology that has been applied in the oil and gas industry for over a decade, spanning the upstream, midstream, and downstream sectors. Nanotechnology has made significant contributions to the exploration of crude oil and natural gas, both in underground and deep-water environments. It has also played a crucial role in improving the drilling process, enabling the extraction of oil and gas resources from beneath the Earth\'s surface. Nanoparticles, with their unique physical and chemical properties, such as high specific surface area, high pore volume, and small size, have demonstrated considerable potential in the oil industry. Extensive research has been conducted to explore various types of nanoparticles for advanced applications, including oil exploration, drilling, production, and enhanced oil recovery (EOR). Moreover, nanomaterials have found applications in downstream and intermediate sectors, such as crude oil refining, natural gas processing, and transportation and storage of petroleum products. Ongoing advancements in nanomaterial synthesis methods, the exploration of new nanomaterial uses, and understanding the remarkable properties of nanomaterials will continue to make them increasingly valuable in the oil and gas sector. The oil and gas industry recognises the potential of nanotechnology and nanoparticles and is investing significantly in research and development in this area. This comprehensive review aims to summarise successful applications of nanotechnology while addressing associated challenges. It serves as a valuable resource for future research and application endeavours in the field, highlighting the potential of nanotechnology in the oil and gas industry.
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  • 文章类型: Journal Article
    为了寻求先进的忆阻器技术,这项研究介绍了δ-甲脒碘化铅(δ-FAPbI3)纳米粒子(NPs)的合成及其自组装成纳米棒(NRs)。碘化物空位促进了这些NRs的形成,在较高浓度下促进单个NP的融合。值得注意的是,这些NR在环境条件下表现出稳健的稳定性,一个独特的优势归因于存在加帽配体和围绕共用八面体结构的晶格。当用作电阻式随机存取存储器件中的有源层时,这些NRs展示了特殊的双极开关特性。实现了显著的开/关比(105),超越了先前报道的低维钙钛矿衍生物和基于α-FAPbI3NP的器件的性能。这种增强的性能归因于低关态电流由于减少数量的卤化物空位,固有的低维度,以及在FTO衬底上的NRs的平行排列。这项研究不仅为开发用于忆阻器应用的优质材料提供了重要见解,而且为在先进电子设备中探索低维钙钛矿衍生物开辟了新途径。
    In the quest for advanced memristor technologies, this study introduces the synthesis of delta-formamidinium lead iodide (δ-FAPbI3) nanoparticles (NPs) and their self-assembly into nanorods (NRs). The formation of these NRs is facilitated by iodide vacancies, promoting the fusion of individual NPs at higher concentrations. Notably, these NRs exhibit robust stability under ambient conditions, a distinctive advantage attributed to the presence of capping ligands and a crystal lattice structured around face-sharing octahedra. When employed as the active layer in resistive random-access memory devices, these NRs demonstrate exceptional bipolar switching properties. A remarkable on/off ratio (105) is achieved, surpassing the performances of previously reported low-dimensional perovskite derivatives and α-FAPbI3 NP-based devices. This enhanced performance is attributed to the low off-state current owing to the reduced number of halide vacancies, intrinsic low dimensionality, and the parallel alignment of NRs on the FTO substrate. This study not only provides significant insights into the development of superior materials for memristor applications but also opens new avenues for exploring low-dimensional perovskite derivatives in advanced electronic devices.
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  • 文章类型: Journal Article
    纳米材料由于其技术和医学应用而引起了科学家的极大兴趣。特别是,金属和金属氧化物纳米颗粒已获得突出,因为它们的增强性能相比,它们的本体对应物。金属支持的纳米材料有望为解决当今最具挑战性的问题做出重大贡献。比如能量收集和环境修复。将纳米颗粒结合到传感器中显著提高了它们的精度和选择性。随着绿色化学的出现,绿色合成技术已被优先用于合成单组分和多组分纳米材料。在当前的审查中,我们已经解决了纳米粒子在各个领域的多维应用,包括表面涂层,生物传感,环境修复,能源设备,建筑,和纳米探测,等。本研究的重点是根据纳米材料的来源对其进行分类,尺寸,和组成,随着合成模式的探索。已经详细探索了合成纳米颗粒的生态友好和具有成本效益的绿色路线。Further,抗菌和细胞毒性潜力已经得到解决,并进行了毒性分析。该研究表明绿色合成纳米粒子的潜力增强,可以证明是传统材料的经济可行和生态友好的替代品。
    Nanomaterials have garnered the significant interest of scientists owing to their technological as well as medical applications. In particular, metal and metal oxide nanoparticles have gained prominence because of their enhanced performance as compared to their bulk counterparts. Metal-supported nanomaterials are anticipated to make major contributions to solving today\'s most challenging issues, like energy harvesting and environmental remediation. The incorporation of nanoparticles into sensors has significantly enhanced their precision and selectivity. With the advent of green chemistry, green synthetic techniques have been prioritized for the synthesis of single and multicomponent nanomaterials. In the current review, we have addressed the multidimensional applications of nanoparticles in various sectors, including surface coatings, biosensing, environmental remediation, energy devices, construction, and nano probing, etc. This study focuses on the categorization of nanomaterials according to their source, dimensions, and composition, along with the exploration of synthetic modes. The eco-friendly and cost-effective greener route for the synthesis of nanoparticles has been explored in detail. Further, the antibacterial and cytotoxic potential has been addressed, and toxicity analysis has been conducted. The study signifies the augmented potential of green synthesized nanoparticles that can prove as economically viable and eco-friendly alternatives to conventional materials.
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  • 文章类型: Journal Article
    使用化学气相沉积(CVD)工艺合成了不同的纳米尺寸相。在约1150-1160°C下在{001}Si衬底上进行沉积。碳源是在氩气主气流中热分解丙酮(CH3)2CO。我们在两个((CH3)2CO+Ar)/Ar)比率下进行了实验,并且观察到在一小时的沉积过程之后沉积了两种视觉上不同类型的层。第一层类型,看起来更不均匀,有SiO2区域(约5%的表面面积的基板)旁边有闪亮的明亮和粗糙的路径,它的拉曼光谱对应于类金刚石碳,以(CH3)2CO+Ar)/Ar=1/5的比例沉积。第二层类型,在(CH3)2CO+Ar)/Ar=1/0比例下沉积,呈现均匀且颜色非常深棕色或黑色,其拉曼光谱指向富含缺陷的多层石墨烯。进行的结构研究揭示了金刚石和金刚石多型体的存在,很少有SiC纳米晶体,以及一些非连续混合的SiC和类石墨烯薄膜。进行的分子动力学模拟表明,没有可能在sp2杂化的碳上沉积sp3杂化,但是在不同的情况下,sp2-在sp2-和sp3-杂化碳上沉积sp3-存在完全现实的可能性。
    Different nano-sized phases were synthesized using chemical vapor deposition (CVD) processes. The deposition took place on {001} Si substrates at about 1150-1160 °C. The carbon source was thermally decomposed acetone (CH3)2CO in a main gas flow of argon. We performed experiments at two ((CH3)2CO + Ar)/Ar) ratios and observed that two visually distinct types of layers were deposited after a one-hour deposition process. The first layer type, which appears more inhomogeneous, has areas of SiO2 (about 5% of the surface area substrates) beside shiny bright and rough paths, and its Raman spectrum corresponds to diamond-like carbon, was deposited at a (CH3)2CO+Ar)/Ar = 1/5 ratio. The second layer type, deposited at (CH3)2CO + Ar)/Ar = a 1/0 ratio, appears homogeneous and is very dark brown or black in color and its Raman spectrum pointed to defect-rich multilayered graphene. The performed structural studies reveal the presence of diamond and diamond polytypes and seldom SiC nanocrystals, as well as some non-continuously mixed SiC and graphene-like films. The performed molecular dynamics simulations show that there is no possibility of deposition of sp3-hybridized on sp2-hybridized carbon, but there are completely realistic possibilities of deposition of sp2- on sp2- and sp3- on sp3-hybridized carbon under different scenarios.
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  • 文章类型: Journal Article
    最近,由于优越的稳定性和较低的毒性风险,开发无铅卤化物双钙钛矿材料引起了人们的极大兴趣。在这项工作中,具有ITO/ETL/Cs2AgBiBr6/Cu2O/Au多层结构的无铅钙钛矿太阳能电池(PSC),以Cs2AgBiBr6双钙钛矿作为太阳能吸收层,一些电子传输层(ETL)和Cu2O作为空穴传输层已经被引入。然后,吸收层和ETL材料的各种厚度的影响,像ZnO,C60,CdS,SnO2,苯基-C61-丁酸甲酯(PCBM),和TiO2,对器件性能(包括光电转换效率(PCE),填充因子(FF%),短路电流密度(Jsc),和开路电压(VOC))在太阳能电池模拟器(SCAPS-1D)的帮助下进行检查。值得注意的是,在所有ETL材料的情况下,吸收层的最佳厚度被确定为400nm。然后,最大PCE值为20.08%,17.63%,14.07%,12.11%,14.94%,含有ZnO的太阳能电池获得了18.83%,C60,CdS,SnO2,PCBM,和TiO2作为ETL,分别。这些结果表明,设计/开发具有与Pb基PSC相当的PCE的无铅卤化物双钙钛矿器件是可行的,前提是合适的/相容的材料将用于下一代太阳能电池的多层结构中。
    Recently, due to the superior stability and lower risk of toxicity, the development of Pb-free halide double perovskite materials has revived excellent interest. In this work, Pb-free perovskite solar cells (PSCs) with ITO/ETL/Cs2AgBiBr6/Cu2O/Au multilayer structures with Cs2AgBiBr6 double perovskite as the solar light absorber layer, some electron transport layers (ETLs) and Cu2O as a hole transport layer have been introduced. Then, the effects of various thicknesses of the absorber layer and also ETL materials, like ZnO, C60, CdS, SnO2, phenyl-C61-butyric acid methyl ester (PCBM), and TiO2, on the device performance (including photoelectronic conversion efficiency (PCE), fill factor (FF%), short circuit current density (Jsc), and open-circuit voltage (VOC)) were examined with the help of a solar cell simulator (SCAPS-1D). It is noteworthy that, in the case of all ETL materials, the optimal thickness of the absorber layer was determined to be 400 nm. Then, the maximum PCE values of 20.08%, 17.63%, 14.07%, 12.11%, 14.94%, and 18.83% were obtained for the solar cells containing ZnO, C60, CdS, SnO2, PCBM, and TiO2 as the ETL, respectively. These results show that designing/developing Pb-free halide double perovskite devices having comparable PCEs with the Pb-based PSCs is feasible, provided that proper/compatible materials will be used in the multilayer structure of the next generations of solar cells.
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