Shaping hard and brittle materials, e.g. cermets, at micrometer resolution has long been known challenging for both mechanical machining and high energy beam based additive manufacturing. Digital light processing (DLP), which features great printing quality and decent precision, unfortunately lacks capability to deal with the popular slurry-typed cermet precursor due to the tremendous optical absorption by its particles. Here, an innovative protocol based on a versatile collapsable matrix is devised to allow high-precision printing of WC-Co cermets on DLP platform. By tuning the external environment, this matrix attenuates composite powders to facilitate photopolymerization at the printing stage, and shrinks to condense green parts prior to thermal sintering. The as-obtained samples by collapsable matrix assisted DLP can reach a relative density of ≈90%, a record-breaking resolution of ≈10 µm, and a microhardness of up to 14.5 GPa. Complex delicate structures, including school emblem, honeycomb, and micro-drill can be directly fabricated, which has never been achieved before. Impressively, the as-obtained micro-drill is able to be directly used in drilling tasks. The above strategy represents a great progress in DLP by enabling shaping strong light attenuating materials at high resolution. Such advantages are ideal for the next generation ceramic-metal composite additive manufacturing.

Mineral identification and quantification are key to the understanding and, hence, the capacity to predict material properties. The method of choice for mineral quantification is powder X-ray diffraction (XRD), generally using a Rietveld refinement approach. However, a successful Rietveld refinement requires preliminary identification of the phases that make up the sample. This is generally carried out manually, and this task becomes extremely long or virtually impossible in the case of very large datasets such as those from synchrotron X-ray diffraction computed tomography. To circumvent this issue, this article proposes a novel neural network (NN) method for automating phase identification and quantification. An XRD pattern calculation code was used to generate large datasets of synthetic data that are used to train the NN. This approach offers significant advantages, including the ability to construct databases with a substantial number of XRD patterns and the introduction of extensive variability into these patterns. To enhance the performance of the NN, a specifically designed loss function for proportion inference was employed during the training process, offering improved efficiency and stability compared with traditional functions. The NN, trained exclusively with synthetic data, proved its ability to identify and quantify mineral phases on synthetic and real XRD patterns. Trained NN errors were equal to 0.5% for phase quantification on the synthetic test set, and 6% on the experimental data, in a system containing four phases of contrasting crystal structures (calcite, gibbsite, dolomite and hematite). The proposed method is freely available on GitHub and allows for major advances since it can be applied to any dataset, regardless of the mineral phases present.

The study focuses on harnessing recycled materials to create sustainable and efficient composites, addressing both environmental issues related to waste management and industrial requirements for materials with improved vibration damping properties. The research involves the analysis of the physico-mechanical properties of the obtained composites and the evaluation of their performance in practical applications. Composite materials were tested in terms of their tensile strength and vibration damping capabilities, considering stress-strain diagrams, vibration amplitudes, frequency response functions (FRFs) and vibration modes. The research results have shown that by adding PVC and FA to the rubber-based matrix composition, the stiffness decreases and elasticity increases. The use of FA in the structure of composite materials causes an increase in the vibration damping possibilities due to the fact that it contributes to the chemical properties of the analyzed composite materials. Additionally, the use of PVC results in increased material elasticity, as evidenced by the higher damping factor compared to materials containing only rubber. Simultaneously, the addition of FA and PVC in specific proportions (60 phr) can lead to a decrease in stiffness and a greater increase in the damping factor. The incorporation of PVC and fly ash (FA) particles into rubber-based matrix composites reduces their stiffness and increases their elasticity. These effects are due to the fact that FA particles behave as extensions of chemical bonds during traction, which contributes to the increase in yield elongation. In addition, the use of flexible PVC increases the elasticity of the material, which is evidenced by the increase in the damping factor.

To explore advanced oxidation catalysts, peroxymonosulfate (PMS) activation by Co-Ni-Mo/carbon nanotube (CNT) composite catalysts was investigated. A compound of NiCo2S4, MoS2, and CNTs was successfully prepared using a simple one-pot hydrothermal method. The results revealed that the activation of PMS by Co-Ni-Mo/CNT yielded an exceptional Rhodamine B decolorization efficiency of 99% within 20 min for the Rhodamine B solution. The degradation rate of Co-Ni-Mo/CNT was 4.5 times higher than that of Ni-Mo/CNT or Co-Mo/CNT, and 1.9 times as much than that of Co-Ni/CNT. Additionally, radical quenching experiments revealed that the principal active groups were 1O2, surface-bound SO4•-, and •OH radicals. Furthermore, the catalyst exhibited low metal ion leaching and favorable stability. Mechanism studies revealed that Mo4+ on the surface of MoS2 participated in the oxidation of PMS and the transformation of Co3+/Co2+ and Ni3+/Ni2+. The synergism between MoS2 and NiCo2S4 reduces the charge transfer resistance between the catalyst and solution interface, thus accelerating the reaction rate. Interconnected structures composed of metal sulfides and CNTs can also enhance the electron transfer process and afford sufficient active reaction sites. Our work provides a further understanding of the design of multi-metal sulfides for wastewater treatment.

This study focused on evaluating the sensitivity and limitations of the simplified equipment used in the Digital Image Correlation (DIC) technique, comparing them with the analog extensometer, based on the mechanical property data of a composite made of fiberglass and epoxy resin. The objectives included establishing a methodology based on the literature, fabricating samples through manual lamination, conducting mechanical tests according to the ASTM D3039 and D3518 standards, comparing DIC with the analog extensometer of the testing machine, and contrasting the experimental results with classical laminate theory. Three composite plates with specific stacking sequences ([0]3, [90]4, and [±45]3) were fabricated, and samples were extracted for testing to determine tensile strength, modulus of elasticity, and other properties. DIC was used to capture deformation fields during testing. Comparisons between data obtained from the analog extensometer and DIC revealed differences of 11.1% for the longitudinal modulus of elasticity E1 and 5.6% for E2. Under low deformation conditions, DIC showed lower efficiency due to equipment limitations. Finally, a theoretical analysis based on classical laminate theory, conducted using a Python script, estimated the longitudinal modulus of elasticity Ex and the shear strength of the [±45]3 laminate, highlighting a relative difference of 31.2% between the theoretical value of 7136 MPa and the experimental value of 5208 MPa for Ex.

Chitosan has established itself as a multifunctional and auspicious biomaterial within the domain of tissue engineering, presenting a decade of uninterrupted advancements and novel implementations. This article provides a comprehensive overview of the most recent developments in chitosan-based tissue engineering, focusing on significant progress made in the last ten years. An exploration is conducted of the various techniques utilized in the modification of chitosan and the production of scaffolds, with an analysis of their effects on cellular reactions and tissue regeneration. The investigation focuses on the integration of chitosan with other biomaterials and the addition of bioactive agents to improve their functionalities. Upon careful analysis of the in vitro and in vivo research, it becomes evident that chitosan effectively stimulates cell adhesion, proliferation, and differentiation. Furthermore, we offer valuable perspectives on the dynamic realm of chitosan-based approaches tailored to distinct tissue categories, including nerve, bone, cartilage, and skin. The review concludes with a discussion of prospective developments, with particular attention given to possible directions for additional study, translational implementations, and the utilization of chitosan to tackle existing obstacles in the field of tissue engineering. This extensive examination provides a significant amalgamation of the advancements achieved over the previous decade and directs scholars towards uncharted territories in chitosan-based tissue engineering.

Na3V2(PO4)2F3 (NVPF), a typical sodium superionic conductor (NASICON) type structure, has attracted much interest as a potential positive electrode in sodium-ion battery. However, the inherently poor electronic conductivity of phosphates compromises the electrochemical properties of this material. Here, we develop a general strategy to improve the electrochemical performance by preparing a new composite material \"polyaniline (PANI)@NVPF\" using a Pickering emulsion method. The X-ray diffraction and Raman results indicated a successful PANI coating without affecting the NASICON-type structure of NVPF, and they enhanced the interfacial bonding between the two components. Also, thermogravimetric analysis and scanning electron microscopy analyses revealed that the PANI content influenced the thermal stability and morphology of the nanocomposites. As a result, the sodium test cells exhibited multielectron reactions and a better rate performance for PANI@NVPF nanocomposites as compared to NVPF. Specifically, 2%PANI@NVPF maintained 70% of its initial capacity at 5C. Ex-situ electron paramagnetic resonance revealed the existence of mixed valence states of vanadium (V4+/V3+) in both discharge and charge processes. Consequently, the successful PANI coating into the sodium superionic conductor framework improved the sodium diffusion channels with a measurable increase of diffusion coefficients with cycling (ca. 3.25 × 10-11 cm2 s-1). Therefore, PANI@NVPF nanocomposites are promising cathode candidates for high-rate sodium-ion battery applications.

Carbon Fiber Reinforced Polymers (CFRP) have become increasingly significant in real-world applications due to their superior strength-to-weight ratio, corrosion resistance, and high stiffness. These properties make CFRP an ideal material for reinforcing concrete structures, particularly in scenarios where weight reduction is crucial, such as in bridges and high-rise buildings. The transformative potential of CFRP lies in its ability to enhance the durability and load-bearing capacity of concrete structures while minimizing maintenance costs and extending the lifespan of the infrastructure. This research explores the impact of reinforcing structural elements with advanced composite materials on the strength and durability of concrete and reinforced concrete structures. By integrating Carbon Fiber Reinforced Polymer (CFRP) reinforcements, we subjected both rectangular and T-section concrete beams to comprehensive three-point bending tests, revealing a substantial increase in flexural strength by 45% and crack resistance due to CFRP reinforcement. The study revealed that CFRP reinforcement increased the flexural strength of concrete beams by 45% and improved crack resistance significantly. Additionally, the load-bearing capacity of the beams was enhanced by 40% compared to unreinforced specimens. These improvements were validated through finite element simulations, which showed a close alignment with the experimental data. Furthermore, an innovative simulation study was conducted using a finely tuned finite element numerical model within the Abaqus calculation code. This model accurately replicated the laboratory specimens in terms of shape, dimensions, and loading conditions. The simulation results not only validated the experimental observations but also provided deeper insights into the stress distribution and failure mechanisms of the reinforced beams. Novel aspects of this study include the identification of specific failure patterns unique to CFRP-reinforced beams and the introduction of an enhanced interaction model that more accurately reflects the composite behavior under load. In CFRP-reinforced beams, specific failure patterns were identified, including flexural cracks in the tension zone and debonding of the CFRP sheets. These patterns indicate the points of maximum stress concentration and potential weaknesses in the reinforcement strategy. The study revealed that while CFRP significantly improves the overall strength and stiffness, careful attention must be given to the bonding process and the quality of the adhesive used to ensure optimal performance. These findings contribute significantly to the understanding of material interactions and structural performance, offering new pathways for the design and optimization of composite-reinforced concrete structures. This research underscores the transformative potential of composite materials in elevating the structural integrity and longevity of concrete infrastructures.

This study aims to provide a high-value and environmentally friendly method for the application of coal-based solid waste. Modified fly ash/polyurethane (MFA/PU) and modified coal gangue powder/polyurethane (MCG/PU) composites were prepared by adding different contents of MFA and MCG (10%, 20%, 30%, 40%). At the filler content of 30%, the compressive strengths of MFA/PU and MCG/PU are 84.1 MPa and 46.3 MPa, respectively, likely due to an improvement in interface compatibility, as indicated by scanning electron microscopy (SEM). The MFA/PU and MCG/PU composites present their highest limiting oxygen index (LOI) values of 29% and 23.5%, respectively, when their filler content is 30%. MFA has advantages in improving the LOIs of composites. Cone calorimetry (CCT) and SEM demonstrate that the two composites exhibit similar condensed-phase flame-retardant behaviors during combustion, which releases CO2 in advance and accelerates the formation of a dense barrier layer. Compared with the MFA/PU composites, the MCG/PU composites could produce a more stable and dense barrier structure. Water quality tests show that heavy metals do not leak from FA and CG embedded in PU. This work provided a new strategy for the safe and high-value recycling of coal-based solid waste.

The design of an aircraft\'s internal structure, and therefore the appropriate choice of material type, is a direct function of the performed tasks and the magnitude and type of the acting loads. The design of a durable aircraft structure with appropriate stiffness and lightness requires knowledge of the loads that will be applied to the structure. Therefore, this paper presents the results of an aerodynamic experimental test and numerical analysis of a newly designed jet-propelled aerial target. The experimental tests were carried out in a low-speed wind tunnel for a wide range of angles of attack and sideslips. Moreover, they were performed for various configurations of the airplane model. In addition, the results of the experimental test were supplemented with the results of the numerical analysis performed using computational fluid dynamics methods. During numerical analysis, specialized software based on solving partial differential equations using the Finite Volumes Method was used. This article presents the methodology of the conducted research. The results of the aerodynamic analysis are presented in the form of diagrams showing the aerodynamic force and moment components as a function of the angle of attack and sideslip. In addition, qualitative results of the flow around the plane have been presented. The results obtained prove that the adopted methods are sufficient to solve these types of problem. The aerial system was positively verified during the qualification tests of the system at the Polish Air Force training range and finally received the type certificate.