Despite incineration is an important emission source of toxic pollutants, such as heavy metals and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), it is still one of the most widely used methods for the management of municipal solid waste. The current paper summarizes the results of a 20-year follow-up study of the emissions of PCDD/Fs by a municipal solid waste incinerator (MSWI) in Sant Adrià de Besòs (Catalonia, Spain). Samples of ambient air, soils and herbage were periodically collected near the facility and the content of PCDD/Fs was analyzed. In the last (2017) survey, mean levels in soil were 3.60 ng WHO-TEQ/kg (range: 0.40-10.6), being considerably higher than the mean concentrations of PCDD/Fs in soil samples collected near other MSWIs in Catalonia. Moreover, air PCDD/F concentrations were even higher than those found in a previous (2014) survey, as they increased from 0.026 to 0.044 pg WHO-TEQ/m3. Ultimately, the PCDD/F exposure would be associated to a cancer risk (2.5 × 10-6) for the population living in the surrounding area. Globally, this information indicates that the MSWI of Sant Adrià de Besòs could have had a negative impact on the environment and potentially on public health, being an example of a possible inappropriate management for years. The application of Best Available Techniques to minimize the emission of PCDD/Fs and other chemicals is critical.

As anthropogenic disturbance on deep-sea seamount ecosystems grows, there is an urgent need for a better understanding of the biodiversity and community structure in benthic ecosystems, which can vary at local and regional scales. A survey of the benthic megafauna on two adjacent deep-water seamounts in the northwestern Pacific Ocean was conducted, which are covered by cobalt-rich crusts, to assess the biodiversity patterns and dissimilarity of assemblage composition. Based on a multidisciplinary dataset generated from video recordings, multibeam bathymetry data, and near-bottom currents, environmental and spatial factors impacting the megabenthic communities were explored. Results showed that these two deep-water seamounts were dominated by hexactinellids, crinoids, and octocorals. The seamounts were able to support diverse and moderately abundant megafauna, with a total of 6436 individuals classified into 94 morphospecies. The survey covered a distance of 52.2 km across a depth range of 1421-3335 m, revealing multiple distinct megabenthic assemblages. The megabenthic communities of the two deep-water seamounts, with comparable environmental conditions, exhibited similarities in overall density, richness, and faunal lists, while dissimilarities in the relative abundance of taxa and assemblage composition. No gradual depth-related change in terms of abundance, richness, or species turnover was observed across the two seamounts, despite the statistical significance of depth in structuring the overall communities. The spatial distribution of megabenthic communities displayed a discontinuous and patchy pattern throughout the two deep-water seamounts. This patchiness was driven by the interactive effects of multiple environmental factors. Near-bottom currents and microhabitat features were the primary drivers influencing their dissimilarities in megabenthic community structure. This case study on the megabenthic community structure of two adjacent seamounts with cobalt-rich crusts can serve as an environmental baseline, providing a reference status for the conservation and management of seamount ecosystems, particularly valuable for areas being considered for deep-sea mining.

The largest anthropogenic source of carbon dioxide emissions is the global energy system, which means transforming the global energy system is one of the most significant ways to reduce greenhouse gas emissions and mitigate climate change. Buildings play a critical role in our transition to a lower-carbon future, accounting for approximately 47% of global energy consumption and about 25% of global greenhouse gas emissions. Renewable hydrogen represents one of the most environmentally friendly options for energy generation. This study presents an energetic, economic, and environmental impact of a self-sufficient system for energy production from renewable energy sources in buildings. To achieve this objective, a hydrogen-based generation system was selected to meet all the electrical requirements of tertiary building in Algeria throughout the year. The results indicate that the hybrid renewable energy system can avoid the emission of approximately 1056 tons of carbon dioxide per year. Furthermore, the payback period is 7 years. These results clearly demonstrate that the integration of hydrogen energy in buildings is the optimal choice for environmental sustainability.

Given the exponential population growth and remarkable socio-economic advancements, coastal areas face increasingly complex challenges in eco-environmental management due to anthropogenic pressures. With the current emphasis on high-quality economic development, there is an urgent need to establish and evaluate a comprehensive indicator system to ensure the sustainable development of the coastal eco-environment and to meet evolving management demands. Research on the coordinated development level of coastal eco-environmental complex system, based on the concept of land-sea coordination, plays a pivotal role in promoting the resolution of eco-environmental issues in coastal areas, achieving sustainable socio-economic development in these regions. In this study, we construct an indicator system for the eco-environmental complex system in Jiaozhou Bay (JZB) coastal zone, China, comprising six sub-systems and thirty indicators. The comprehensive development level and coupling coordination degree model (CCDM) are employed in this study to analyze the indicator system in 1980-2020, aiming to elucidate the processes involved in the improvements in this complex system. The findings indicate: (i) the system\'s comprehensive development level evaluation and coupling coordination degree (CCD) exhibit a two-stage pattern: a declining trend in 1980-2005, followed by a rising trend in 2005-2020. (ii) despite improvements, the comprehensive development level and the CCD of the system in 2020 still hold potential for further enhancement compared to 1980; and (iii) policymaking and changes in anthropogenic pressures in coastal areas are the primary factors influencing the performance of the system. In the future, policymaking can reduce anthropogenic pressures on the coastal eco-environment, improve the comprehensive development level and CCD of the complex system, and encourage a commitment to sustainable development.

Ensuring water supply under climate change scenarios is a global concern, and groundwater resources play a crucial role. Aquifer depletion is a worldwide trend, and Chile is no exception. Through a statistical approach with strong hydrogeological criteria, the groundwater overexploitation phenomenon is studied in Central Chile, the most populated region in this mountainous country. With this purpose, we assess the evolution of groundwater levels and pumping between 1970 and 2020 by analysing 26,065 groundwater rights and 222 observation wells. Withdrawals increased from 498 hm3 in 1970 to 8883 hm3 in 2020. We recognised two general trends in groundwater levels: a quasi-steady state hydrodynamic regime pre-1988 and sustained decline post-1988, exacerbated since 2010 with the start of the Megadrought. Although groundwater recharge is expected to decrease during this severe drought, the declining trend strongly correlates with pumping but not with precipitation changes. Climate forcing is usually invoked to warrant the dramatic depletion of groundwater resources, but we demonstrated that all analysed aquifers have been overexploited since much earlier than 2010. Finally, the Chilean aquifers\' overexploitation is a clear example of the consequences of prioritising the water offer over the water demand regulation, which hinders the United Nations\' sustainable development goals accomplishment.

Geologically saline zones with scarce pluviometry are areas susceptible to salinization of their natural drainage. However, the salinization of the receiving water systems can be accelerated with the implementation of irrigation. This work aims to analyze the effects of irrigation on some zones transformed into irrigation land, from the beginning of the process until its complete consolidation. To this end, salt balances are evaluated as a whole and for each significant chemical element. The study zone is the irrigable area of the Lerma basin (Spain), where hydrosaline balances have been carried out since the hydrological year 2004 (before the implementation of irrigation) until 2020 (after the consolidation of irrigation). The implementation of irrigation in the area has doubled the mass of exported salts up to an average of 3177 kg/ha irrigable·year, for the entire study period. 55 % of that amount results from a global mineral dissolution, although this process seems to decrease with time as these minerals are being flushed from the soil. Before irrigation was implemented, the general global dissolution pattern produced more concentration of most ions (SO42-, Cl-, Mg2+, Na+, and K+) in the water outputs than in the water inputs. After the implementation of irrigation, there were more water inputs than outputs in the balance and that was shown by the decrease in the dissolved HCO3- and Ca2+.These results indicate that the consolidation of irrigation progressively decreases the induced salinization in the water systems that receive the irrigation return flows. Further studies are required to expand the general understanding of the process and its effects, quantify the different geochemical processes involved, and identify possible additional environmental issues induced by irrigation.

Geologically \"saline\" zones with scarce pluviometry, which are already susceptible to the salinization of natural drainage, can experience the acceleration of the salinization of the receiving water systems with the implementation of irrigation. The main objective of this paper is to analyze the geochemical processes that control the variations of the hydrosaline balance due to the implementation of irrigation of the Lerma basin (Spain) from the beginning of its transformation into irrigation land (2004) until the consolidation of irrigation (2020). The results of this study evidence the dissolution of some mineral phases, such as halite, gypsum, and dolomite, and the precipitation of others, such as calcite. Additionally, the final composition of the irrigation return flows cannot be explained without consideration of the NaCa exchange. Part of the dissolved Ca2+ is deposited in the soil, which, in turn, contributes with Na+ to the solution. These natural processes are accelerated with irrigation but progressively slow down as the soil salts are washed with time. Although less evident, there is an additional negative agroenvironmental effect associated with the precipitation of calcite and the possible formation of petrocalcic horizons in the soil. The results obtained herein indicate that studies focusing on the salinity of irrigated zones should go a step further and include the geochemical processes in quantifying the global mass of exported salts.

Analysing municipal solid waste (MSW) management scenarios is relevant for planning future policies and actions toward a circular economy. Life cycle assessment (LCA) is appropriate for evaluating technologies of MSW treatment and their environmental impacts. However, in developing countries, advanced assessments are difficult to introduce due to the lack of technical knowledge, data and financial support. This research aims to assess the main potentialities of the introduction of waste-to-energy (WtE) systems in a developing Argentinean urban area considering the existing regulations about MSW recycling goals. The study was conducted with WRATE software and the proposed scenarios were current management, grate incineration of raw MSW and incineration of solid recovered fuel (SRF). In addition, a sensitivity analysis on the energy matrix was included. It was found that the production of SRF allows increasing the energy generation from waste by 200% and reducing the environmental impact of about 10% regarding the current MSW management system. Acidification Potential and Abiotic Depletion Potential were sensitive to changes in electricity mix. Results showed that if MSW reduction goals are achieved, changes in MSW composition will affect the performance of WtE plants and, in some cases, they will be not technically feasible. The outcomes of this study can be of interest for developing countries stakeholders and practitioners interested in LCA and sustainable MSW management.

Rivers are known for carrying out a fundamental role in the transportation of human debris from continental areas to the marine environment and have been identified as hotspots for plastic pollution. We characterized microplastics (MPs) along confluence areas in the Paraíba do Sul River basin, the biggest river in southeastern Brazil. This water body crosses highly industrialized areas, with the highest population density, and the major water demand in South America. Considering the important ecological function of this extensive watershed and the implications of MP pollution, we evaluate the spatial variation of MP concentration in the confluence areas and upstream from the confluence. Samples were taken from the superficial layer of the water column in February and June 2022, using manta net with 300 μm mesh size. A total of 19 categories and 2870 plastic particles were determined. The confluences areas of rivers showed the highest concentration of MPs, highlighting the confluences of the Paraiba do Sul and Muriaé rivers (0.71 ± 0.25 MP/m3), followed by Paraíba do Sul and Dois Rios rivers (0.42 ± 0.23 MP/m3) and Paraíba do Sul and Pomba rivers (0.38 ± 0.14 MP/m3). Black fibers were the main category, followed by blue fibers and blue fragments. The MPs in the surface waters of Paraíba do Sul River is significantly influenced by the sampling points spatiality. This result corroborates other studies around the world and reinforces the argument that affluents are important sources for the introduction of MPs in larger rivers. Nevertheless, our results provide a better understanding of the different contributing factors and occurrence of MPs in river basins.

Greenhouse gas emissions (i.e., carbon dioxide, methane, nitrous oxide) produced by agriculture contribute to global warming and climate change. Various practices followed by farmers in different environmental conditions contribute to the increase in the phenomena, and there is a need for immediate measures. The current study examines the environmental impact of barley production under rain-fed conditions in Cyprus. For this, four different nutrient management scenarios were investigated in order to evaluate the environmental performance of crop production, namely: (1) Nitrogen (20%), Phosphorous (20%), Potassium (10%); (2) Nitrogen (20%), Phosphorous (20%), Potassium (10%) and manure; (3) Nitrogen (25%), Phosphorous (10%), Potassium (0%); and (4) Nitrogen (25%), Phosphorous (10%), Potassium (0%) and manure. Data were collected from two different areas of Cyprus (Nicosia and Larnaca) through on-site visits and questionnaires. Life Cycle Assessment (LCA) was used as a method to quantify environmental impacts which were categorized into six impact categories: (i) acidification potential (AP), (ii) eutrophication potential (EP), (iii) global warming potential (GWP), (iv) ozone depletion potential (ODP), (v) photochemical, ozone creation potential (POCP), and (vi) terrestrial ecotoxicity (TAETP). LCA was used with system boundaries from field to harvest and a functional unit (FU) of one bale of hay. Research results showed that the addition of manure increased values in all impact categories. Comparing scenarios without manure (1 and 3) and with manure (2 and 4), the main process which contributed to GWP was field preparation, which resulted in 3 t CO2-Eq∙FU-1 and 46.96 t CO2-Eq∙FU-1, respectively. Furthermore, the highest contribution of sub-processes to GWP (kg CO2-Eq∙FU-1) was machinery maintenance (scenarios 2 and 4). The potential to reduce environmental impacts from barley and moreover, to mitigate the footprint of the agriculture sector in Cyprus is proposed by changing existing practices such as decreasing fuel consumption by agricultural machinery, and monitoring fertilizing and seeding. Conclusively, the carbon footprint of barley can be decreased through the improvement of nutrient management and cropping practices.