Textiles

纺织品
  • 文章类型: Journal Article
    本研究旨在探索与控制公共卫生领域纺织品中微生物增殖相关的基本功能要求。在这里,三种抗菌剂,特别是氨基甲酸碘丙基丁酯(IPBC),1-羟基吡啶-2-硫酮锌(ZPT),和2-辛基-3-异噻唑啉酮(OIT),根据其显著的效果选择织物整理,最小的毒性,成本效益,和化学稳定性。利用金黄色葡萄球菌(S.金黄色葡萄球菌)和大肠杆菌(E.大肠杆菌)作为代表性细菌菌株,测量了单个和组合抗菌剂的最小抑制浓度(MIC50),并且对其抗菌效果进行了严格评估.同时,抗菌效果,白度,彻底检查抗菌处理后织物的机械耐久性。结果表明,三种抗微生物剂的一些组合引起对金黄色葡萄球菌和大肠杆菌两者的累加效应。值得注意的是,以IPBC的当量比,ZPT,和OIT,总浓度为0.2wt.%,对两种细菌菌株的抑制率均超过99%。应用于尼龙织物时,处理过的材料表现出显著的抗菌性能,在处理过的尼龙的白度和拉伸强度中观察到最小的降低。这项研究提供了与具有抗菌性能的纺织品生产相关的可行策略。
    This study aims to explore the essential functional requirements associated with controlling the proliferation of microbes in the domain of textiles used in public health areas. Herein, three antimicrobial agents, specifically iodopropylbutylcarbamate (IPBC), 1-hydroxypyridine-2-thioketone zinc (ZPT), and 2-octyl-3-isothiazolinone (OIT), were chosen for fabric finishing based on their notable effectiveness, minimal toxicity, cost-efficiency, and chemical stability. Utilizing Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) as representative bacterial strains, the Minimum Inhibitory Concentration (MIC50) of individual and combined antimicrobial agents was measured, and their antimicrobial effectiveness was rigorously evaluated. Concurrently, the antimicrobial effectiveness, whiteness, and mechanical durability of the fabric following antimicrobial treatment were thoroughly examined. The results demonstrate that some combinations of the three antimicrobial agents elicit additive effects on both S. aureus and E. coli. Notably, at an equivalent ratio of IPBC, ZPT, and OIT and a total concentration of 0.2 wt. %, the inhibition rates against both bacterial strains surpass 99%. Upon application to nylon fabric, the treated material demonstrates significant antimicrobial properties, with minimal reduction observed in the whiteness and tensile strength of the treated nylon. This study provides practicable strategies relevant to the production of textiles endowed with antimicrobial properties.
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  • 文章类型: Journal Article
    通过水热合成开发了ZnO纳米棒无纺布(ZNRN),以促进预防呼吸道病原体的传播。通过响应面法提高了ZNRN的超疏水性和抗菌性能。合成的材料表现出显著的防水性,水接触角为163.9°,因此对大肠杆菌的抗菌率为91.8%(E.大肠杆菌)和79.75%的金黄色葡萄球菌(S.金黄色葡萄球菌)。这表明具有较薄肽聚糖的大肠杆菌可能比金黄色葡萄球菌更容易被杀死。这项研究确定了合成条件对抗菌效果的显着影响,全面的多变量分析阐明了潜在的相关性。此外,通过SEM和XRD分析对ZNRN的ZnO纳米棒结构进行了表征。它赋予超疏水性(从而防止细菌粘附到ZNRN表面)和抗菌能力(从而通过刺穿这些纳米棒破坏细胞)的性质。因此,希望将两个这样的特征对齐,以帮助支持个人防护设备的开发,这有助于避免呼吸道感染的传播。
    ZnO nanorod nonwoven fabrics (ZNRN) were developed through hydrothermal synthesis to facilitate the prevention of the transmission of respiratory pathogens. The superhydrophobicity and antibacterial properties of ZNRN were improved through the response surface methodology. The synthesized material exhibited significant water repellency, indicated by a water contact angle of 163.9°, and thus demonstrated antibacterial rates of 91.8% for Escherichia coli (E. coli) and 79.75% for Staphylococcus aureus (S. aureus). This indicated that E. coli with thinner peptidoglycan may be more easily killed than S. aureus. This study identified significant effects of synthesis conditions on the antibacterial effectiveness, with comprehensive multivariate analyses elucidating the underlying correlations. In addition, the ZnO nanorod structure of ZNRN was characterized through SEM and XRD analyses. It endows the properties of superhydrophobicity (thus preventing bacteria from adhering to the ZNRN surface) and antibacterial capacity (thus damaging cells through the puncturing of these nanorods). Consequently, the alignment of two such features is desired to help support the development of personal protective equipment, which assists in avoiding the spread of respiratory infections.
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  • 文章类型: Journal Article
    从血液中快速吸收水以浓缩红细胞和血小板,从而触发快速关闭,对止血很重要.在这里,膨胀凝固壳聚糖织物是通过以聚乳酸(PLA)长丝为芯层和以高亲水性羧乙基壳聚糖(CECS)纤维为鞘层的环锭纺丝来设计和制造的,以及随后编织获得的PLA@CECS包芯纱。由于CECS纤维的单向快速吸收能力,壳聚糖织物可以通过浓缩血液实现红细胞和血小板的快速聚集,从而促进血凝块的形成。此外,针织物中形成的线圈的环结构可以通过吸收水分来帮助它们膨胀以封闭它们的毛孔,提供有效的密封出血。此外,它们有足够的机械性能,抗穿透能力,在潮湿条件下具有良好的组织粘附能力,可以在止血过程中形成物理屏障来抵抗血压并防止它们从伤口上脱落,从而协同加强止血。因此,织物在兔肝脏中表现出优异的止血性能,脾,脾与股动脉穿刺损伤模型对比纱布组。这种壳聚糖织物是用于控制出血的有前途的止血材料。
    The rapid absorption of water from the blood to concentrate erythrocytes and platelets, thus triggering quick closure, is important for hemostasis. Herein, expansion-clotting chitosan fabrics are designed and fabricated by ring spinning of polylactic acid (PLA) filaments as the core layer and highly hydrophilic carboxyethyl chitosan (CECS) fibers as the sheath layer, and subsequent knitting of obtained PLA@CECS core spun yarns. Due to the unidirectional fast-absorption capacity of CECS fibers, the chitosan fabrics can achieve erythrocytes and platelets aggregate quickly by concentrating blood, thus promoting the formation of blood clots. Furthermore, the loop structure of coils formed in the knitted fabric can help them to expand by absorbing water to close their pores, providing effective sealing for bleeding. Besides, They have enough mechanical properties, anti-penetrating ability, and good tissue-adhesion ability in wet conditions, which can form a physical barrier to resist blood pressure during hemostasis and prevent them from falling off the wound, thus enhancing hemostasis synergistically. Therefore, the fabrics exhibit superior hemostatic performance in the rabbit liver, spleen, and femoral artery puncture injury model compared to the gauze group. This chitosan fabric is a promising hemostatic material for hemorrhage control.
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  • 文章类型: Journal Article
    合成纺织纤维的磨损是产生环境微塑料纤维(MPF)的重要因素。专门设计用于表面清洁的聚合物海绵在正常使用期间具有释放MPF的倾向的程度仍然未知。这里,使用往复式磨擦器研究了具有不同支柱密度的三聚氰胺清洁海绵(也称为“魔术橡皮擦”)对不同粗糙度的金属表面的摩擦学行为。在各种条件下由海绵磨损形成的MPF根据其形态进行了表征,composition,和数量。它们主要由具有线性或支化纤维形态(长度为10-405μm)的聚(三聚氰胺-甲醛)聚合物组成,它们是通过海绵开放细胞内支柱的变形和断裂形成的,由摩擦诱导的聚合物分解促进。MPF生产的速率和能力通常随着金属表面粗糙度和支柱密度的增加而增加。分别。海绵磨损可释放650万MPF/g,这可能表明,由于海绵消费,全球总排放量为4.9万亿MPF。我们的研究揭示了迄今为止尚未认识到的环境MPF污染源,并强调需要评估与这些新形式的MPF相关的暴露风险。
    The abrasion of synthetic textile fibers is a significant factor in the generation of environmental microplastic fibers (MPFs). The extent to which polymer sponges designed specifically for surface cleaning have a tendency to release MPFs during normal use remains unknown. Here, the tribological behaviors of melamine cleaning sponges (also known as \"magic erasers\") with different strut densities against metal surfaces of different roughness were investigated using a reciprocating abrader. The MPFs formed by sponge wear under various conditions were characterized in terms of their morphology, composition, and quantity. They were mainly composed of poly(melamine-formaldehyde) polymer with linear or branched fiber morphologies (10-405 μm in length), which were formed through deformation and fracture of the struts within open cells of the sponges, facilitated by friction-induced polymer decomposition. The rate and capability of MPF production generally increased with increasing roughness of the metal surface and density of the struts, respectively. The sponge wear could release 6.5 million MPFs/g, which could suggest a global overall emission of 4.9 trillion MPFs due to sponge consumption. Our study reveals a hitherto unrecognized source of the environmental MPF contamination and highlights the need to evaluate exposure risks associated with these new forms of MPFs.
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  • 文章类型: Journal Article
    近年来,具有抗菌和抗粘附性能的生态友好织物受到越来越多的关注。在这里,通过酯化和聚合合成了天然薄荷醇改性聚丙烯酸酯(PMCA)抗菌粘合剂,通过曼尼希反应制备了天然蝶芪接枝壳聚糖(PGC)抗菌剂。通过耐用的PMCA浸涂整理,然后进行PGC的逐层自组装,制备了抗菌和抗粘连的棉织物。结果表明,双功能棉织物对金黄色葡萄球菌和大肠杆菌的抗菌粘附率和抗菌率均达到99.9%。与薄荷醇单独处理的棉织物相比,其抗菌粘附率分别提高了36.1%和40.1%。同时针对金黄色葡萄球菌,双功能棉织物的抗菌率分别提高了56.7%和36.4%,分别,来自壳聚糖和蝶芪处理的织物。针对大肠杆菌,改善分别为89.4%和24.8%,分别。经过20次家庭洗涤,该双功能棉织物对这两个物种保持了>80%的原始抗粘连和抗菌率。该双功能棉织物还具有安全和优异的耐磨性。
    Ecofriendly fabrics with antibacterial and anti-adhesion properties have been attracted an increasing attention in recent years. Herein, natural menthol modified polyacrylate (PMCA) antibacterial adhesion agent was synthesized by esterification and polymerisation while natural pterostilbene-grafted-chitosan (PGC) antibacterial agent was prepared through Mannich reaction. The antibacterial and anti-adhesion cotton fabric was fabricated through durable PMCA dip finishing and then layer-by-layer self-assembly of PGC. The results showed that the antibacterial adhesion rates and antibacterial rates of the dual-function cotton fabric against Staphylococcus aureus and Escherichia coli reached up to 99.9 %. Its antibacterial adhesion rates improved by 36.1 % and 40.1 % in comparison with those of cotton fabric treated by menthol alone. Meanwhile against S. aureus, the dual-function cotton fabrics improved the antibacterial rates by 56.7 % and 36.4 %, respectively, from those of chitosan- and pterostilbene-treated fabrics. Against E. coli, the improvements were 89.4 % and 24.8 %, respectively. After 20 household washings, the dual-function cotton fabric maintained >80 % of its original anti-adhesion and antibacterial rates against both species. The dual-function cotton fabric also possessed safe and excellent wearability.
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  • 文章类型: Journal Article
    在这项研究中,改性聚酰胺纤维用作生物载体,以在多级生物接触氧化反应器(MBCOR)中富集致密的生物膜,在该反应器中建立了分区的废水处理区(WTZ)和生物强化区(BAZ),以增强甲基橙的去除(MO)及其代谢物,同时最大程度地减少污泥产量。WTZ表现出高生物质负载能力(5.75±0.31g/g填料),在不同曝气条件下,8h内MO去除率在68%至86%之间,其中最主要的叶绿素属发挥了重要作用。在BAZ,假黄单胞菌是优势属,而碳饥饿刺激了化学异养和需氧化学异养基因的富集,从而增强了细胞释放底物的微生物利用率,MO及其代谢中间体。这些结果揭示了MBCOR有效消除MO及其代谢物的生物增强机制。
    In this study, modified polyamide fibers were used as biocarriers to enrich dense biofilms in a multi-stage biological contact oxidation reactor (MBCOR) in which partitioned wastewater treatment zone (WTZ) and bioaugmentation zone (BAZ) were established to enhance the removal of methyl orange (MO) and its metabolites while minimizing sludge yields. WTZ exhibited high biomass loading capacity (5.75 ± 0.31 g/g filler), achieving MO removal rate ranging from 68 % to 86 % under different aeration condition within 8 h in which the most dominant genus Chlorobium played an important role. In the BAZ, Pseudoxanthomonas was the dominant genus while carbon starvation stimulated the enrichment of chemoheterotrophy and aerobic_chemoheterotrophy genes thereby enhanced the microbial utilization of cell-released substrates, MO as well as its metabolic intermediates. These results revealed the mechanism bioaugmentation on MBCOR in effectively eliminating both MO and its metabolites.
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  • 文章类型: Journal Article
    具有阻燃和火灾预警功能的智能纺织品受到越来越多的关注。然而,提高智能纺织品的火灾预警响应灵敏度和长期响应能力是当务之急。在这项研究中,采用由壳聚糖(CS)和植酸(PA)组成的生物基阻燃剂和由碳纳米管(CNTs)和氧化石墨烯(GO)组成的碳基纳米材料逐层组装复合涂层制备阻燃防火棉织物。PA-GO/CS-CNTs涂层棉织物表现出优异的阻燃性,极限氧指数(LOI)值为31%,当火焰消除时,涂层织物可以迅速自动熄灭。通过降低45.77%的峰值热释放率,涂层织物的火灾危险性显著降低,总热释放量的29.69%和总烟产生量的81.9%。PA-GO/CS-CNT涂层棉织物表现出超快速的火灾预警响应,响应时间为1.0s。涂层棉织物的火灾预警响应时间可持续超过600s,表明其具有连续火灾预警响应特性。该研究为制备具有阻燃和火灾预警功能的智能防火纺织品提供了一种新的策略,以拓宽其在火灾预警中的应用。
    Smart textiles with flame retardant and fire-warning functions have received more and more attention. However, improving the fire-warning response sensitivity and long-term responsiveness of the smart textiles is a top priority. In this research, flame retardant and fire-warning cotton fabrics were prepared by layer-by-layer assembly composite coating consisting of bio-based flame retardants composed of chitosan (CS) and phytic acid (PA) and carbon-based nanomaterials composed of carbon nanotubes (CNTs) and graphene oxide (GO). The PA-GO/CS-CNTs coated cotton fabric showed excellent flame retardancy with a limiting oxygen index (LOI) value of 31 %, and the coated fabrics could self-extinguish rapidly when the flame was removed. The fire hazard of the coated fabric was significantly reduced by reducing the 45.77 % of peak heat release rate, 29.69 % of total heat release and 81.9 % of total smoke production. The PA-GO/CS-CNTs coated cotton fabric showed ultra-fast fire warning response with the response time of 1.0 s. And the fire-warning response time of the coated cotton fabric could last longer than 600 s revealing it possessed the continuous fire warning response property. This research provides a new strategy to prepare the smart fireproof textiles with flame retardant and fire-warning functions to broaden its application in early fire-warning.
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  • 文章类型: Journal Article
    该研究探讨了三层纺织服装供应链中不确定需求下的战略定价和质量改进决策。根据面料制造商(FM)是否在质量上进行投资,以及服装制造商(GM)或服装零售商(GR)是否愿意分担成本,构建了五个博弈模型来考察不同成员成本分担对最优决策和利润的影响。通过进行理论和数值分析,我们发现:(1)GM或GR的成本分担对质量改进起着积极的作用,至于谁的成本分担根据成本分担的比例在提高质量方面表现更好,质量改进是最高的,两个成员同时分担成本。(2)当两个成员同时分担成本时,FM获得最高的利润,然而,谁的成本分摊对调频公司更有利可图,也与成本分摊比例有关;简而言之,FM总是从成本分摊中受益,无论一个成员这样做还是两个成员这样做。(3)当只有GR(GM)分担成本时,GM(GR)获得最高利润,结果表明,如果一个成员分担了成本,参与费用分摊的其他成员是否可以根据其比例使前者受益。具体来说,当GM(GR)选择分担成本且比例相对较低时,GR(GM)加入成本分摊对前者有利;否则,是有害的。
    The study explores the strategic pricing and quality improvement decisions under uncertain demand in a three-layer textile and garment supply chain. According to whether the fabric manufacturer (FM) invests in quality or not and whether the garment manufacturer (GM) or garment retailer (GR) is willing to share the costs or not, five game models are constructed to investigate the impact of different members\' cost sharing on the optimal decisions and profits. By conducting a theoretical and numerical analysis, we find that: (1) The GM\'s or GR\'s cost sharing plays a positive effect on the quality improvement, as for whose cost sharing performs better in improving the quality depending on the proportion of cost sharing, and the quality improvement is highest with both members share the costs simultaneously. (2) The FM receives the highest profit when both members share the costs simultaneously, however, whose cost sharing is more profitable for the FM is also related to the proportion of cost sharing; in short, the FM always benefits from the cost sharing, no matter one member does this or two members do this. (3) The GM (GR) gains the highest profit when only the GR (GM) shares the costs, and the results indicate that if one member has shared the costs, whether the other member engaging in cost sharing could benefit the former depending on their proportions. Specifically, when the GM (GR) chooses to share the costs and the proportion is relatively low, the GR(GM) joining in cost sharing is beneficial to the former; otherwise, is harmful.
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  • 文章类型: Journal Article
    木质纤维素主要由疏水性木质素和亲水性多糖聚合物组成,为绿色生物炼油厂提供不可或缺的碳源1,2。经过化学处理,木质素由于有害的分子内和分子间交联而受到损害,这阻碍了下游过程3,4。当前的价值化范式旨在避免形成新的C-C键,被称为冷凝,通过阻断或稳定木质素5-7的脆弱部分。尽管一直在努力通过掺入酚类添加剂8,9来提高生物质的利用率,但利用木质素的缩合倾向仍未被证实可以使木质素和碳水化合物增值为高价值产品。在这里,我们通过使用具有高亲核性的木质素衍生的酚在催化芳基化途径中引导C-C键形成来利用倾向性。选择性浓缩的木质素,以接近定量的产量分离,同时保留其突出的可裂解β-醚单元,可以在涉及芳基迁移和转移氢化的串联催化过程中解锁。木材中的木质素由此转化为良性双酚(34-48重量%),其代表其基于化石的对应物的性能有利的替代品。来自纤维素的脱木素纸浆和来自木聚糖的木糖共同生产用于纺织纤维和可再生化学品。这种冷凝驱动的策略代表了一个关键的进步,以其他有前途的单酚为导向的方法针对有价值的平台化学品和材料,从而有助于整体生物量的增值。
    Lignocellulose is mainly composed of hydrophobic lignin and hydrophilic polysaccharide polymers, contributing to an indispensable carbon resource for green biorefineries1,2. When chemically treated, lignin is compromised owing to detrimental intra- and intermolecular crosslinking that hampers downstream process3,4. The current valorization paradigms aim to avoid the formation of new C-C bonds, referred to as condensation, by blocking or stabilizing the vulnerable moieties of lignin5-7. Although there have been efforts to enhance biomass utilization through the incorporation of phenolic additives8,9, exploiting lignin\'s proclivity towards condensation remains unproven for valorizing both lignin and carbohydrates to high-value products. Here we leverage the proclivity by directing the C-C bond formation in a catalytic arylation pathway using lignin-derived phenols with high nucleophilicity. The selectively condensed lignin, isolated in near-quantitative yields while preserving its prominent cleavable β-ether units, can be unlocked in a tandem catalytic process involving aryl migration and transfer hydrogenation. Lignin in wood is thereby converted to benign bisphenols (34-48 wt%) that represent performance-advantaged replacements for their fossil-based counterparts. Delignified pulp from cellulose and xylose from xylan are co-produced for textile fibres and renewable chemicals. This condensation-driven strategy represents a key advancement complementary to other promising monophenol-oriented approaches targeting valuable platform chemicals and materials, thereby contributing to holistic biomass valorization.
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  • 文章类型: Journal Article
    背景:接触板方法被广泛接受,并用于卫生和污染水平至关重要的各个领域。有关接触板方法在实际医疗环境中采样织物微生物污染水平的适用性的证据有限。这项研究旨在评估接触板方法在实际医疗保健环境中检测医用织物上微生物污染的适用性,从而为织物微生物取样方法提供了基准。
    方法:在某医院三级产科病房,这项研究选择了24个靠近病床的隐私窗帘。1日,采用接触板和拭子法从隐私窗帘中收集微生物样本,Seven,14日,在他们被绞死后的第28天。计算了每个隐私窗帘表面上的总菌落数,并进行微生物鉴定。
    结果:排除时间的影响后,房间类型,以及检测到的微生物负荷上的窗帘位置,线性混合效应模型分析显示,与拭子法相比,接触板法的菌落计数较低(P<0.001).然而,接触平板法比拭子法分离出更多的微生物种类(P<0.001)。采用接触平板法分离出病原菌291株,采用拭子法分离出病原菌133株。两种采样方法对革兰氏阴性菌的检测无差异(P=0.089)。此外,双人房间窗帘的微生物负荷低于双人房间(P=0.021),窗户附近窗帘的微生物负荷低于门附近(P=0.004)。
    结论:接触板法在应变分离方面优于拭子法。拭子法更适合评价织物的细菌污染。
    BACKGROUND: The contact plate method is widely accepted and used in various fields where hygiene and contamination levels are crucial. Evidence regarding the applicability of the contact plate method for sampling fabric microbial contamination levels in real medical environments was limited. This study aimed to assess the applicability of the contact plate method for detecting microbial contamination on medical fabrics in a real healthcare environment, thereby providing a benchmark for fabric microbial sampling methods.
    METHODS: In a level three obstetrics ward of a hospital, twenty-four privacy curtains adjacent to patient beds were selected for this study. The contact plate and swab method were used to collect microbial samples from the privacy curtains on the 1st, 7th, 14th, and 28th days after they were hung. The total colony count on each privacy curtain surface was calculated, and microbial identification was performed.
    RESULTS: After excluding the effects of time, room type, and curtain location on the detected microbial load, the linear mixed-effects model analysis showed that contact plate method yielded lower colony counts compared to swab method (P < 0.001). However, the contact plate method isolated more microbial species than swab method (P < 0.001). 291 pathogenic strains were isolated using the contact plate method and 133 pathogenic strains were isolated via the swab method. There was no difference between the two sampling methods in the detection of gram-negative bacteria (P = 0.089). Furthermore, the microbial load on curtains in double-occupancy rooms was lower than those in triple-occupancy rooms (P = 0.021), and the microbial load on curtains near windows was lower than that near doors (P = 0.004).
    CONCLUSIONS: Contact plate method is superior to swab method in strain isolation. Swab method is more suitable for evaluating the bacterial contamination of fabrics.
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