Disposal

处置
  • 文章类型: Journal Article
    危险废V2O5-WO3/TiO2催化剂的表征和评估对于确定其处理或最终处置至关重要。这项研究采用了热方法来模拟由商业V2O5-WO3/TiO2催化剂衍生的废催化剂的制备,并研究了失活过程中载体变化的结构-活性关系。结果表明,催化剂载体经历了两个过程:晶粒尺寸的增加和晶体结构的转变。结构和催化研究均表明,催化剂失活的晶粒尺寸为24.62nm,并且CaWO4的形成发生在结晶转变之前。比表面积易于增加晶粒尺寸。选择性催化还原反应涉及布朗斯台德酸和路易斯酸位点的参与。载体的失活过程最初影响布朗斯台德酸位点,其次是路易斯酸位点的减少,导致NH3吸附能力下降和氧化。相关分析表明,催化剂的物理化学性质的变化降低了NO的转化率,顺序为晶粒尺寸>总酸量>表面积。如果载体颗粒尺寸小于25nm,则推荐回收用过的催化剂。这项调查的结果有助于扩展数据库,以评估和了解用于处置的废催化剂的物理化学性质。
    Characterization and evaluation of hazardous spent V2O5-WO3/TiO2 catalysts are critical to determining their treatment or final disposal. This study employs a thermal approach to simulate the preparation of spent catalysts derived from commercial V2O5-WO3/TiO2 catalysts and investigate the structure-activity relationship of the carrier changes during the deactivation process. The results indicate that the catalyst carrier undergoes two processes: an increase in grain size and a transformation in crystal structure. Both structural and catalytic investigations demonstrate that the grain size for catalyst deactivation is 24.62 nm, and the formation of CaWO4 occurs before the crystalline transformation. The specific surface area is susceptible to an increase in grain size. The reactions of selective catalytic reduction involve the participation of both Brønsted acid and Lewis acid sites. The deactivation process of the carrier initially affects Brønsted acid sites, followed by a reduction in Lewis acid sites, resulting in a decline in NH3 adsorption capacity and oxidation. Correlation analysis reveals that changes in the physicochemical properties of the catalyst reduce the NO conversion, with the order being The grain size > Total acid amount > The surface area. It is recommended to recycle the spent catalyst if the carrier grain size is less than 25 nm. The findings of this investigation contribute to expanding the database for evaluating and understanding the physicochemical properties of spent catalysts for disposal.
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  • 文章类型: Journal Article
    城市固体废物管理系统在中国温室气体排放中起着至关重要的作用。尽管政府实施了许多改善城市生活垃圾管理制度的政策,这些改进对城市温室气体减排的影响在很大程度上仍未被探索。这项研究对城市生活垃圾部门的直接和下游温室气体排放进行了全面分析,包括卫生垃圾填埋场,转储,焚化,和生物治疗,从2001年到2021年,通过采用政府间气候变化专门委员会(IPCC)建议的清单方法,在中国352个城市中使用。结果表明,(1)中国城市生活垃圾行业的温室气体排放量在2018年达到70.6Tg的CO2当量峰值,随后在2021年大幅下降至47.6Tg的CO2当量;(2)城市生活垃圾行业温室气体减排效益最高的城市是过去20年的历史排放热点,(3)随着2030年零填埋政策的潜在实现,预计二氧化碳当量将额外减少203.7Tg,随着减排重点向华南城市(21.9%),东北地区(17.8%),和中国西南地区(17.3%)。这项研究强调,即使没有明确的MSW部门减排目标,这一部门的改进大大减少了中国的温室气体排放。
    Municipal solid waste (MSW) management systems play a crucial role in greenhouse gas (GHG) emissions in China. Although the government has implemented many policies to improve the MSW management system, the impact of these improvements on city-level GHG emission reduction remains largely unexplored. This study conducted a comprehensive analysis of both direct and downstream GHG emissions from the MSW sector, encompassing sanitary landfill, dump, incineration, and biological treatment, across 352 Chinese cities from 2001 to 2021 by adopting inventory methods recommended by the Intergovernmental Panel on Climate Change (IPCC). The results reveal that (1) GHG emissions from the MSW sector in China peaked at 70.6 Tg of CO2 equiv in 2018, followed by a significant decline to 47.6 Tg of CO2 equiv in 2021, (2) cities with the highest GHG emission reduction benefits in the MSW sector were historical emission hotspots over the past 2 decades, and (3) with the potential achievement of zero-landfilling policy by 2030, an additional reduction of 203.7 Tg of CO2 equiv is projected, with the emission reduction focus toward cities in South China (21.9%), Northeast China (17.8%), and Southwest China (17.3%). This study highlights that, even without explicit emission reduction targets for the MSW sector, the improvements of this sector have significantly reduced GHG emissions in China.
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  • 文章类型: Journal Article
    糖尿病是一种长期的疾病,如果糖尿病患者感染了血液传播传染病,并且没有遵循适当的注射器处置方法,他们有很长一段时间将感染传染给他人的危险。而在中国,关于在家中处理尖锐物体的研究较少。因此,有必要翻译和本地化知识-态度-实践问卷关于急剧处置糖尿病患者,以评估当前的患者知识水平,态度,和实践,并改善促进安全锐器处理实践的基础。
    这项调查是一项横断面研究。对有关尖锐处置的知识-态度-实践问卷进行了本地化和调试,并进行了信度和效度测试。然后用一般特征问卷对334例患者进行调查,关于尖锐处置的知识-态度-实践问卷,并对患者锐器处置执业水平的影响因素进行分析。
    态度部分的Cronbach\'sα值为0.864,内容效度指数为0.923。知识和实践部分符合大陆语言公约,易于理解,没有任何歧义。大多数(52%)的参与者知识贫乏,对处置尖锐物体持中立态度。糖尿病患者的锐器处置实践很差,因为约90%的患者将其使用过的锐器直接丢弃到生活垃圾中。此外,我们发现教育水平,知识和态度是糖尿病患者利器处置实践的主要预测因素(R2=0.573,p<0.001).
    关于尖锐处置的知识-态度-实践问卷的中文版在中国具有适用性。在中国,目前处置用过的利器的做法是不恰当的。此外,大多数受试者的知识和态度水平较低。提高人们的认识,并鼓励糖尿病患者遵循适当的锐器处置方法,需要持续的教育和当地量身定制的安全尖锐处置替代方案。
    UNASSIGNED: Diabetes Mellitus is a long duration disease, and if a person with diabetes is infected with a blood-borne infectious disease and proper syringe disposal practices are not followed, they run the danger of transmitting the infection to others for a very long period. Whereas fewer research has been done in China on the handing of sharp objects at home. Therefore, there is a need to translate and localize the Knowledge-Attitude-Practice Questionnaire regarding sharp disposal for diabetic patients to assess the current level of patient knowledge, attitudes, and practices and to improve the basis for promoting safe sharps handling practices.
    UNASSIGNED: This investigation was a cross-sectional study. The Knowledge-Attitude-Practice Questionnaire regarding sharp disposal was localized and debugged and tested for reliability and validity, and then 334 patients were investigated by General Characteristics Questionnaire, Knowledge- Attitude-Practice Questionnaire regarding sharp disposal, and the influencing factors of practice level regarding sharp disposal of patients were analyzed.
    UNASSIGNED: The Cronbach\'s α value of the attitude section was 0.864 and the content validity index was 0.923. The knowledge and practice sections are in line with continental language conventions and are easy to understand without any ambiguity. The majority (52%) of the participants had poor knowledge and a neutral attitude toward disposing of sharp objects. Sharps disposal practices among diabetes mellitus patients were poor since about 90% of patients dispose of their used sharps directly into the household waste. Furthermore, we found that level of education, knowledge and attitude were the major predictors of practices regarding sharps disposal among diabetic patients (R 2 = 0.573, p < 0.001).
    UNASSIGNED: The Chinese version of the Knowledge-Attitude-Practice Questionnaire regarding sharp disposal has applicability in China. In China, current practice of disposing used sharps is improper. Additionally, the majority of the subjects had low levels of knowledge and attitudes. To raise awareness and encourage diabetic patients to follow appropriate sharps disposal practices, there needs to be ongoing education and a locally tailored safe sharp disposal alternative accessible.
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  • 文章类型: Journal Article
    目标:不安全的阿片类药物相关做法可能导致滥用,分流,和意外用药过量。在这项研究中,我们旨在描述有关存储的模式和信念,处置,中国癌症患者在家中使用阿片类药物,尚不清楚。
    方法:于2022年10月至2023年6月在湖北省进行了多中心横断面调查。我们收集了仓库的信息,处置,以及在肿瘤科癌症疼痛住院患者中使用阿片类药物。Logistic回归用于评估与阿片类药物的不安全处置和使用相关的因素。
    结果:调查包括221名患者,中位年龄为62岁。只有3.2%的人把阿片类药物锁在钥匙下,49.8%的人不知道适当的处置方法。近五分之一(19.5%)的人报告收到了阿片类药物安全储存(14.0%)和/或处置(10.0%)的信息。共有44.3%的人报告共享使用不安全(1.8%),亏损(4.1%),或服用阿片类药物的剂量高于处方(42.5%)。未获得阿片类药物安全处置信息的患者(OR=4.57,P=.0423),有饮酒史(OR=1.91,P=.0399),使用吗啡以外的阿片类药物(OR=2.31,P=.0461)的不安全处置方法的可能性更高。具有副学士学位/学士学位或以上学位的人不太可能不安全地处置(OR=0.36,P=.0261)和使用(OR=0.31,P=.0127)阿片类药物。
    结论:相当比例的中国癌症患者在储存过程中表现出不安全的做法,处置,和使用阿片类药物。该研究强调迫切需要实施常规教育计划和药物“收回”举措,以改善与阿片类药物相关的做法。
    OBJECTIVE: Unsafe opioid-related practices can lead to abuse, diversion, and accidental overdoses. In this study, we aimed to describe the patterns and beliefs regarding the storage, disposal, and use of opioids among Chinese patients with cancer in their home settings, which remain unclear.
    METHODS: A multicenter cross-sectional survey was conducted in Hubei Province from October 2022 to June 2023. We collected information on the storage, disposal, and use of opioids among cancer pain inpatients in the oncology department. Logistic regression was used to estimate the factors associated with unsafe disposal and use of opioids.
    RESULTS: The survey included 221 patients with a median age of 62 years. Only 3.2% stored their opioids under lock and key, and 49.8% were unaware of proper disposal methods. Nearly one-fifth (19.5%) reported having received information on the safe storage (14.0%) and/or disposal (10.0%) of opioids. A total of 44.3% reported unsafe use by sharing (1.8%), losing (4.1%), or taking opioids at a higher dose than prescribed (42.5%). Patients who did not receive information on the safe disposal of opioids (OR = 4.57, P = .0423), had a history of alcohol use (OR = 1.91, P = .0399), and used opioids other than morphine (OR = 2.31, P = .0461) had higher odds of unsafe disposal practices. Individuals with an associate degree/bachelor\'s degree or above were less likely to dispose of (OR = 0.36, P = .0261) and use (OR = 0.31, P = .0127) opioids unsafely.
    CONCLUSIONS: A significant proportion of Chinese patients with cancer exhibit unsafe practices in the storage, disposal, and use of opioids. The study highlights an urgent need for implementing routine education programs and drug \"take-back\" initiatives to improve opioid-related practices.
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  • 文章类型: Journal Article
    由于对居民的远距离影响,水生和土壤生态系统健康,食物垃圾处理成为发展中国家城市垃圾战略的重点。上海是中国领先的城市,它的食物废物管理的演变可以预示着国家未来的未来。在这个城市,从1986年到2020年,公开倾销,逐步禁止食物垃圾填埋和焚烧,取而代之的是集中堆肥和厌氧消化等回收方式。这项研究选择了十个场景,曾在上海用于食品/混合废物处理,并分析了1986-2020年期间的环境影响变化。生命周期评估表明,尽管食物垃圾的产生迅速增加,总环境影响,由FAETP主导,显示大幅下降96.09%,GWP下降了28.14%。应大力提高沼气和填埋气的收集率,以减少对环境的影响,厌氧消化和堆肥植物的残留物质量应得到改善,并以合法的方式加以利用。上海可持续食物废物管理目标的驱动力涉及经济发展,环境法规和配套的国家/地方标准。
    Due to the far distance impact on resident, aquatic and soil ecosystem health, food waste disposal becomes the focus of municipal waste strategy in developing countries. Shanghai is a leading city in China, its evolution of food waste management can indicate the coming future of the nation. In this city, from 1986 to 2020, the open dumping, landfill and incineration of food waste had been gradually banned, replaced by centralized compost and anaerobic digestion and other recovery ways. This study selected ten scenarios, ever used for food/mixed waste disposal in Shanghai, and analyzed the environmental impact change during the period 1986-2020. Life cycle assessment showed that although the generation of food waste raised rapidly, the total environmental impact, which was dominated by Freshwater Aquatic Ecotoxicity Potential, displayed a sharp decrease as 96.09 %, and Global Warming Potential decreased by 28.14 %. Substantial efforts should be made to improve the collection rate of biogas and landfill gas to reduce environmental impact, and quality of residues from anaerobic digestion and compost plants should be improved and utilized in its legal ways. Driving forces for the goal of sustainable food waste management in Shanghai involved economic development, environmental regulations and the supporting national/local standards.
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  • 文章类型: Journal Article
    疏浚是抑制天然湖泊内源性污染的最有效方法之一。然而,如果疏浚沉积物的处置会产生相当大的环境和经济成本,那么疏浚的数量和范围都将受到限制。使用疏浚的沉积物作为采矿后土壤改良剂进行矿山复垦,有利于可持续的疏浚和生态恢复。本研究结合了一项具有生命周期评估的田间种植实验,以确认通过矿山复垦处理沉积物的实际有效性。以及其在环境和经济方面优于其他替代方案。结果表明,沉积物为矿山基质提供了丰富的有机质和氮,刺激植物生长,增加光合固碳密度,其次是增强植物根系吸收和改善土壤对重金属的固定作用。建议将矿山基质与沉积物的比例设定为2:1,以显着提高黑麦草的产量,同时降低地下水污染和土壤污染物的积累水平。由于电力和燃料的大幅减少,矿山开垦对全球变暖的环境影响最小(2.63×10-2千克二氧化碳当量。/kgDS),化石耗竭(6.81×10-3千克石油当量。/DS),人体毒性(2.29×10-5kg1,4-DBeq/kgDS),光化学氧化剂的形成(7.62×10-5kgNOxeq。/kgDS),和陆地酸化(6.69×10-5千克SO2当量。/kgDS)。矿山复垦的成本(0.260元/kgDS)也低于水泥生产(0.965元/kgDS)和未烧砖生产(0.268元/kgDS)。利用淡水灌溉和电力脱水是矿山复垦的关键因素。通过这次综合评价,经验证,疏浚沉积物用于矿山复垦的处理在环境和经济上都是可行的。
    Dredging is one of the most effective methods for inhibiting the endogenous contamination of natural lakes. However, both the amount and the scope of dredging will be restricted if the disposal of the dredged sediment incurs considerable environmental and economic costs. The use of dredged sediments as a post-mining soil amendment for mine reclamation benefits both sustainable dredging and ecological restoration. This study incorporates a field planting experiment with a life cycle assessment to confirm the practical effectiveness of sediment disposal via mine reclamation, as well as its environmental and economic superiority over other alternative scenarios. The results show that the sediment offered plentiful organic matter and nitrogen for mine substrate, stimulating plant growth and increasing photosynthetic carbon fixation density, followed by enhanced plant root absorption and an improved soil immobilization effect on heavy metals. A 2:1 ratio of mine substrate to sediment is recommended to significantly promote the yield of ryegrass while reducing levels of groundwater pollution and soil contaminant accumulation. Due to the significant reduction in electricity and fuel, mine reclamation had minimal environmental impacts on global warming (2.63 × 10-2 kg CO2 eq./kg DS), fossil depletion (6.81 × 10-3 kg oil eq./DS), human toxicity (2.29 × 10-5 kg 1,4-DB eq/kg DS), photochemical oxidant formation (7.62 × 10-5 kg NOx eq./kg DS), and terrestrial acidification (6.69 × 10-5 kg SO2 eq./kg DS). Mine reclamation also had a lower cost (CNY 0.260/ kg DS) than cement production (CNY 0.965/kg DS) and unfired brick production (CNY 0.268/kg DS). The use of freshwater for irrigation and electricity for dehydration were the key factors in mine reclamation. Through this comprehensive evaluation, the disposal of dredged sediment for mine reclamation was verified to be both environmentally and economically feasible.
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  • 文章类型: Journal Article
    废弃口罩对环境构成严重威胁,包括自COVID-19爆发以来垃圾填埋场造成的海洋塑料污染和土壤污染风险。目前,已经报道了许多关于废弃口罩的处理和资源化利用的有效方法,包含物理,热化学,和基于溶剂的技术。至于物理技术,通过添加天然纤维或无机纳米颗粒,可以增强基于面罩的材料的机械性能,并赋予导电性或抗菌活性。关于热化学技术,催化热解可以产生相当多的氢气,这是一种环保资源,并将缓解能源危机。值得注意的是,溶剂型技术,作为一种更方便、更有效的方法,本文也考虑了这一点。这样,将面膜直接浸泡在特定的化学试剂中,改变聚丙烯的原始结构,获得多功能材料。随着可持续和通用试剂的研究,基于溶剂的技术在未来具有广阔的应用前景。这篇综述可以为利用废弃口罩资源和解决塑料污染问题提供指导。
    Waste masks pose a serious threat to the environment, including marine plastic pollution and soil pollution risks caused by landfills since the outbreak of COVID-19. Currently, numerous effective methods regarding disposal and resource utilization of waste masks have been reported, containing physical, thermochemical, and solvent-based technologies. As for physical technologies, the mechanical properties of the mask-based materials could be enhanced and the conductivity or antibacterial activity was endowed by adding natural fibers or inorganic nanoparticles. Regarding thermochemical technologies, catalytic pyrolysis could yield considerable hydrogen, which is an eco-friendly resource, and would mitigate the energy crisis. Noticeably, the solvent-based technology, as a more convenient and efficient method, was also considered in this paper. In this way, soaking the mask directly in a specific chemical reagent changes the original structure of polypropylene and obtains multi-functional materials. The solvent-based technology is promising in the future with the researches of sustainable and universally applicable reagents. This review could provide guidance for utilizing resources of waste masks and address the issues of plastic pollution.
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  • 文章类型: Journal Article
    未经批准:大多数糖尿病患者的胰岛素注射都是在家中进行的,从而产生许多用过的针头。不安全地处置这些家中的针头会导致针刺伤,血源性疾病传播,和环境污染。先前的研究表明,糖尿病患者的安全锐器处置实践的患病率和相关因素有不同的结果。
    UNASSIGNED:评估糖尿病患者中使用过的胰岛素针头安全处置的患病率和相关因素。
    UNASSIGNED:我们收集了来自中国一家三级医院的271名使用胰岛素的患者的数据。一个自行设计的工具被用来评估社会人口统计数据,疾病和治疗相关特征,锐器处置实践,糖尿病自我管理和锐器处置教育,以及对与不安全锐器处置相关的潜在风险的认识。采用多因素logistic回归分析探讨与安全锐器处置措施相关的因素。
    UASSIGNED:只有10.3%(28/271)的参与者以安全的方式处置了在家使用的胰岛素针头,14.8%(45/271)的参与者曾接受过锐器处置指导。先前的锐器处置说明(AOR=4.143,95%CI=1.642-10.450)和对血液传播病原体传播风险的认识(AOR=3.064,95%CI=1.332-7.046)与安全处置使用过的胰岛素针头有关。
    未经批准:在我们的研究中,安全锐器处置做法的普及率很低,少数受访者曾收到过关于锐器处置的指示。以前接受过指导并意识到血液传播病原体传播风险的参与者更有可能安全地处理锐器。我们的研究结果表明,卫生保健专业人员应注意糖尿病患者的锐器处置实践,并开展糖尿病教育计划,其中包括有关安全锐器处置方法和不安全锐器处置潜在危害的信息。
    Most insulin injections for people with diabetes are administered at home, thus generating many used needles. Unsafe disposal of these at-home needles can lead to needle stick injuries, blood-borne disease transmission, and environmental contamination. Previous studies have shown varying results on the prevalence of and factors associated with safe sharps disposal practices of people with diabetes.
    To assess the prevalence of and the factors associated with the safe disposal of used insulin needles among patients with diabetes.
    We collected data from 271 insulin-using patients at a tertiary care hospital in China. A self-designed instrument was used to assess sociodemographic data, disease- and treatment-related characteristics, sharps disposal practices, education on diabetes self-management and sharps disposal, and awareness of the potential risks associated with unsafe sharps disposal. Multivariate logistic regression analysis was used to explore factors associated with safe sharps disposal practices.
    Only 10.3% (28/271) of participants disposed of used at-home insulin needles in a safe manner, and 14.8% (45/271) of participants had received previous instruction on sharps disposal. Previous sharps disposal instruction (AOR = 4.143, 95% CI = 1.642-10.450) and awareness of the risk of blood-borne pathogen transmission (AOR = 3.064, 95% CI = 1.332-7.046) were associated with safe disposal of used insulin needles.
    In our study, the prevalence of safe sharps disposal practices was low, and a minority of respondents had received previous instruction on sharps disposal. Participants who had previously received instruction and were aware of the risk of blood-borne pathogen transmission were more likely to handle sharps safely. Our study findings suggest that health care professionals should pay attention to sharps disposal practices of patients with diabetes and conduct diabetes education programs that include information on safe sharps disposal methods and potential hazards of unsafe sharps disposal.
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  • 文章类型: Journal Article
    吸附是最广泛采用的,有效,和可靠的处理工艺,从废水中去除无机和有机污染物。从废水流中去除污染物的吸附处理工艺的主要问题之一是废吸附剂的回收和可持续管理。这篇综述集中在新兴吸附剂的有效性以及如何回收用过的吸附剂,再生,并通过重复使用或安全处置进一步管理。评估了常规和新兴吸附剂对废水系统中有机和无机污染物的严格分析。各种回收和再生技术的废吸附剂,包括磁分离,过滤,热解吸和分解,化学解吸,超临界流体解吸,详细讨论了高级氧化工艺和微生物辅助吸附剂再生。涵盖了吸附剂的回收和再生的当前挑战以及用于解决这些问题的方法。用过的吸附剂通过再生进行管理,以便重复使用(如土壤改良剂,电容器,催化剂/催化剂载体)或涉及焚烧和填埋的安全处置。废吸附剂的可持续管理,包括回收和再生吸附剂以供再利用的过程,在资源回收和循环经济的背景下进行研究。最后,该审查结束了当前在回收和管理废吸附剂方面的缺点,以及该系统用于工业规模应用的经济和环境可行性的未来方向。
    Adsorption is the most widely adopted, effective, and reliable treatment process for the removal of inorganic and organic contaminants from wastewater. One of the major issues with the adsorption-treatment process for the removal of contaminants from wastewater streams is the recovery and sustainable management of spent adsorbents. This review focuses on the effectiveness of emerging adsorbents and how the spent adsorbents could be recovered, regenerated, and further managed through reuse or safe disposal. The critical analysis of both conventional and emerging adsorbents on organic and inorganic contaminants in wastewater systems are evaluated. The various recovery and regeneration techniques of spent adsorbents including magnetic separation, filtration, thermal desorption and decomposition, chemical desorption, supercritical fluid desorption, advanced oxidation process and microbial assisted adsorbent regeneration are discussed in detail. The current challenges for the recovery and regeneration of adsorbents and the methodologies used for solving those problems are covered. The spent adsorbents are managed through regeneration for reuse (such as soil amendment, capacitor, catalyst/catalyst support) or safe disposal involving incineration and landfilling. Sustainable management of spent adsorbents, including processes involved in the recovery and regeneration of adsorbents for reuse, is examined in the context of resource recovery and circular economy. Finally, the review ends with the current drawbacks in the recovery and management of the spent adsorbents and the future directions for the economic and environmental feasibility of the system for industrial-scale application.
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  • 文章类型: Journal Article
    UNASSIGNED: No live specimens of the snail Oncomelania hupensis (O. hupensis) and indigenous infected cases of schistosomiasis japonicum have been found in Guangdong Province since 1993, but live O. hupensis was found again in 2019. This study conducted O. hupensis identification and elimination.
    UNASSIGNED: In 2019, live O. hupensis specimens were detected by routine surveillance in areas in Qujiang of Shaoguan City and Yingde of Qingyuan City, and an emergency response was launched immediately.
    UNASSIGNED: The suspected habitat of O. hupensis in originally endemic areas of schistosomiasis in Guangdong is still complicated, so it is necessary to record suspected habitats comprehensively and carry out scientific routine surveillance for O. hupensis.
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