Emerging pollutants

新兴污染物
  • 文章类型: Journal Article
    近年来,水产养殖迅速发展,以解决粮食短缺问题,并提供高质量的水产品。然而,这种增长导致了大量废水的释放,含有新出现的污染物,如抗生素,微塑料(MPs),和抗生素抗性基因(ARGs)。本研究调查了这些污染物在水产养殖环境中的发生和相互作用。混合污染物,如MPs和共存吸附剂,广泛存在,可能包括抗生素,重金属,抗性基因,和病原体。MPs上化学污染物水平的升高可能导致选择性压力下抗性基因的出现,由细菌群落和水平基因转移(HGT)促进。议员充当载体,将污染物转移到食物网中。各种技术,包括膜技术,凝血,和高级氧化,已经进行了污染物去除试验,每一个都有其优点和缺点。未来的研究应集中在水产养殖废水中新兴污染物的生态友好处理技术上。这篇综述提供了对理解和解决新发展的毒素的见解,旨在开发有效的水产养殖废水处理集成系统。
    In recent years, aquaculture has expanded rapidly to address food scarcity and provides high-quality aquatic products. However, this growth has led to the release of significant effluents, containing emerging contaminants like antibiotics, microplastics (MPs), and antibiotic resistance genes (ARGs). This study investigated the occurrence and interactions of these pollutants in aquaculture environment. Combined pollutants, such as MPs and coexisting adsorbents, were widespread and could include antibiotics, heavy metals, resistance genes, and pathogens. Elevated levels of chemical pollutants on MPs could lead to the emergence of resistance genes under selective pressure, facilitated by bacterial communities and horizontal gene transfer (HGT). MPs acted as vectors, transferring pollutants into the food web. Various technologies, including membrane technology, coagulation, and advanced oxidation, have been trialed for pollutants removal, each with its benefits and drawbacks. Future research should focus on ecologically friendly treatment technologies for emerging contaminants in aquaculture wastewater. This review provided insights into understanding and addressing newly developing toxins, aiming to develop integrated systems for effective aquaculture wastewater treatment.
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  • 文章类型: Journal Article
    厌氧氨氧化(anammox)是一种很有前途的生物处理富氮,低碳废水。然而,厌氧氨氧化技术在实际工程中的应用容易受到环境因素的限制。近年来,厌氧氨氧化恢复策略取得了相当大的进展。最新的进展极大地帮助解决了anammox抑制后反应性能差的问题。这篇综述系统地概述了在常规环境因素和新兴污染物抑制后恢复厌氧氨氧化性能的策略。此外,全面总结了旨在提高厌氧氨氧化活性和提高脱氮性能的策略,为该领域当前的研究前景提供有价值的见解。该评论有助于全面了解基于厌氧氨氧化技术的恢复策略。
    Anaerobic ammonium oxidation (anammox) is a promising biological method for treating nitrogen-rich, low-carbon wastewater. However, the application of anammox technology in actual engineering is easily limited by environmental factors. Considerable progress has been investigated in recent years in anammox restoration strategies, significantly addressing the challenge of poor reaction performance following inhibition. This review systematically outlines the strategies employed to recover anammox performance following inhibition by conventional environmental factors and emerging pollutants. Additionally, comprehensive summaries of strategies aimed at promoting anammox activity and enhancing nitrogen removal performance provide valuable insights into the current research landscape in this field. The review contributes to a comprehensive understanding of restoration strategies of anammox-based technologies.
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  • 文章类型: Journal Article
    新兴污染物(EP)包括在环境中发现的具有潜在风险的天然或合成物质,但是直到最近才被识别或监控。EP由各种类别组成,包括杀虫剂,制药,荷尔蒙,霉菌毒素,和内分泌干扰化学物质(EDCs)。通过几种途径,EP可以获得食物,当超过安全浓度时,可能会导致健康影响。牛奶,作为一种高营养的食品,被许多不同年龄的消费者大量消费,是一个重要的食物矩阵,应该定期监测EP。在文学中,大量的研究致力于测定乳品奶中不同的EP,采用不同的分析技术来做到这一点。基于色谱的技术是用于分析牛奶中EP的最普遍手段,表现出显著的效率,灵敏度,和这个特定目的的准确性。在进行色谱分析之前,从复杂的基质如牛奶中提取EP是必不可少的。这篇综述全面涵盖了2018年至2023年使用色谱方法提取和随后检测和测定牛奶中EP的相关研究论文。
    Emerging pollutants (EPs) encompass natural or synthetic substances found in the environment that pose potential risks, but which have only recently been recognized or monitored. EPs consist of various categories, including pesticides, pharmaceuticals, hormones, mycotoxins, and endocrine-disrupting chemicals (EDCs). Through several pathways, EPs can access food, potentially leading to health impacts when safe concentrations are exceeded. Milk, being a highly nutritious food product that is heavily consumed by many consumers of different ages, is a crucial food matrix where EPs should be regularly monitored. In the literature, a large number of studies have been dedicated to the determination of different EPs in dairy milk, employing different analytical techniques to do so. Chromatography-based techniques are the most prevalent means used for the analysis of EPs in milk, demonstrating significant efficiency, sensitivity, and accuracy for this specific purpose. The extraction of EPs from a complex matrix like milk is essential prior to performing chromatographic analysis. This review comprehensively covers relevant research papers on the extraction and subsequent detection and determination of EPs in milk using chromatographic methods from 2018 to 2023.
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  • 文章类型: Journal Article
    塑料污染是全球关注的问题,近年来变得越来越严重。大多数研究都集中在海洋环境中塑料污染的影响上。然而,在陆地和淡水环境中越来越多地检测到塑料,主要的内陆来源包括垃圾填埋场,它可以被广泛的生物所接近。由于许多原因,鸟类是污染物的有效生物指标,包括它们的高流动性和营养水平的高种内和种间变化。与海洋物种相比,淡水和陆生鸟类在塑料污染研究中的代表性不足。我们回顾了106项研究(从1994年起),这些研究发现了居住在淡水和/或陆地栖息地的鸟类中的塑料。识别知识差距。72项研究仅针对大型塑料(碎片>5毫米),与22个微塑料(碎片<5毫米)研究相比。进一步的12项研究将塑料确定为微塑料和大型塑料。没有研究调查纳米塑料(颗粒<100nm)暴露。迄今为止的研究具有地理和物种偏见,而忽略了自由生活淡水中的纳米塑料固存,陆地和海洋鸟类。在这里提供的基线搜索基础上,我们敦促研究人员开发和验证标准化的现场采样技术和实验室分析方案,如拉曼光谱,以便对陆地和淡水环境中的微米和纳米塑料及其中的物种进行定量和识别。未来的研究应该始终如一地报告内在化和背景浓度,类型,塑料的尺寸和形式。这将有助于更好地了解塑料污染的来源及其接触陆地和淡水环境鸟类的途径,更全面地了解对鸟类的潜在影响。
    Plastic pollution is a global concern that has grown ever more acute in recent years. Most research has focused on the impact of plastic pollution in marine environments. However, plastic is increasingly being detected in terrestrial and freshwater environments with key inland sources including landfills, where it is accessible to a wide range of organisms. Birds are effective bioindicators of pollutants for many reasons, including their high mobility and high intra- and interspecific variation in trophic levels. Freshwater and terrestrial bird species are under-represented in plastic pollution research compared to marine species. We reviewed 106 studies (spanning from 1994 onwards) that have detected plastics in bird species dwelling in freshwater and/or terrestrial habitats, identifying knowledge gaps. Seventy-two studies focused solely on macroplastics (fragments >5 mm), compared to 22 microplastic (fragments <5 mm) studies. A further 12 studies identified plastics as both microplastics and macroplastics. No study investigated nanoplastic (particles <100 nm) exposure. Research to date has geographical and species\' biases while ignoring nanoplastic sequestration in free-living freshwater, terrestrial and marine bird species. Building on the baseline search presented here, we urge researchers to develop and validate standardised field sampling techniques and laboratory analytical protocols such as Raman spectroscopy to allow for the quantification and identification of micro- and nanoplastics in terrestrial and freshwater environments and the species therein. Future studies should consistently report the internalised and background concentrations, types, sizes and forms of plastics. This will enable a better understanding of the sources of plastic pollution and their routes of exposure to birds of terrestrial and freshwater environments, providing a more comprehensive insight into the potential impacts on birds.
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  • 文章类型: Journal Article
    多环芳烃(PAHs)引起的污染是一个重要的问题。考虑到在共污染期间环境中PAHs的快速改性以形成取代的PAHs,这种担忧变得更加成问题。这篇综述旨在将文献计量分析与对机械见解的严格研究相结合,从而对PAH修复的不断发展的研究趋势有了更全面的了解。结果表明,该领域的研究多年来取得了进展,并于2022年达到顶峰,这可能是由于资源转向新兴污染物,暗示环境研究重点的动态性质。在这一年里,发布了158,147份文件,占2000年至2023年间该领域出版物总数的7%。鉴定并比较了用于PAH修复的不同修复方法。生物修复,去除效率>90%,已被证明是最好的技术,因为它具有成本效益,并且易于在原位和非原位进行大规模操作。已经详细讨论了PAH修复的当前挑战。实施针对污染物去除和有价值的化合物回收的创新和可持续技术对于建立更强大的水管理未来是必要的。
    Pollution caused by polycyclic aromatic hydrocarbons (PAHs) is a significant concern. This concern has become more problematic given the rapid modification of PAHs in the environment during co-contamination to form substituted PAHs. This review aims to integrate bibliometric analysis with a rigorous study of mechanistic insights, resulting in a more comprehensive knowledge of evolving research trends on PAH remediation. The results show that research in this field has progressed over the years and peaked in 2022, potentially due to the redirection of resources toward emerging pollutants, hinting at the dynamic nature of environmental research priorities. During this year, 158,147 documents were published, representing 7 % of the total publications in the field between 2000 and 2023. The different remediation methods used for PAH remediation were identified and compared. Bioremediation, having >90 % removal efficiency, has been revealed to be the best technique because it is cost-effective and easy to operate at large scale in situ and ex-situ. The current challenges in PAH remediation have been detailed and discussed. Implementing innovative and sustainable technologies that target pollutant removal and valuable compound recovery is necessary to build a more robust future for water management.
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  • 文章类型: Journal Article
    加剧的全球水资源短缺和更严格的水指令正在导致再生水使用的增加,需要开发新的具有成本效益的高级水处理方法,为人口提供安全的水。在这个意义上,过乙酸(PAA,CH3C(O)OOH)是一种环境友好的消毒剂,有可能在不久的将来挑战大型污水处理厂中氯的主导地位。PAA可以作为H2O2的替代氧化剂进行Fenton反应,最近证明,在中性pH值和阴离子存在下,它比H2O2更有效地降解新兴污染物。PAA通过均相和非均相铁基材料活化产生-除了HO•和FeO2-更有选择性的CH3C(O)O•和CH3C(O)OO•自由基,被典型的HO·猝灭剂稍微清除(例如,碳酸氢盐),将PAA的用途扩展到复杂的水基质。这反映在过去几年中铁-PAA出版物的指数级进展中。尽管最近发表了一些关于PAA一般性质和在水处理中的用途的评论,铁基材料对PAA活化的研究和环境应用没有说明,尽管取得了可喜的进展。鉴于这些陈述,在这里,我们对铁基PAA活化系统的类型进行了全面审查,并分析了迄今为止采用的各种铁化合物(例如,亚铁和三价铁盐,高铁酸盐(VI),尖晶石铁氧体),使用外部铁还原/螯合剂(例如,吡啶甲酸,l-半胱氨酸,硼)和紫外可见光照射系统,分析每个案例所涉及的机制。铁与PAA活化的比较还讨论了其他过渡金属(特别是钴)。这项工作旨在提供对基于Fe/PAA的过程的透彻了解,促进对其优点和局限性的有用见解,被忽视的问题,和前景,导致其普及和专有技术的增加。
    The exacerbated global water scarcity and stricter water directives are leading to an increment in the recycled water use, requiring the development of new cost-effective advanced water treatments to provide safe water to the population. In this sense, peracetic acid (PAA, CH3C(O)OOH) is an environmentally friendly disinfectant with the potential to challenge the dominance of chlorine in large wastewater treatment plants in the near future. PAA can be used as an alternative oxidant to H2O2 to carry out the Fenton reaction, and it has recently been proven as more effective than H2O2 towards emerging pollutants degradation at circumneutral pH values and in the presence of anions. PAA activation by homogeneous and heterogeneous iron-based materials generates - besides HO• and FeO2+ - more selective CH3C(O)O• and CH3C(O)OO• radicals, slightly scavenged by typical HO• quenchers (e.g., bicarbonates), which extends PAA use to complex water matrices. This is reflected in an exponential progress of iron-PAA publications during the last few years. Although some reviews of PAA general properties and uses in water treatment were recently published, there is no account on the research and environmental applications of PAA activation by Fe-based materials, in spite of its gratifying progress. In view of these statements, here we provide a holistic review of the types of iron-based PAA activation systems and analyse the diverse iron compounds employed to date (e.g., ferrous and ferric salts, ferrate(VI), spinel ferrites), the use of external ferric reducing/chelating agents (e.g., picolinic acid, l-cysteine, boron) and of UV-visible irradiation systems, analysing the mechanisms involved in each case. Comparison of PAA activation by iron vs. other transition metals (particularly cobalt) is also discussed. This work aims at providing a thorough understanding of the Fe/PAA-based processes, facilitating useful insights into its advantages and limitations, overlooked issues, and prospects, leading to its popularisation and know-how increment.
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  • 文章类型: Journal Article
    针对新兴污染物(EP)对水生生物的潜在不利影响,在全球范围内提出了重大关切。我们仔细回顾了过去10年的相关研究。该研究侧重于五种典型的EP:药品和个人护理产品(PPCP),全氟烷基和多氟烷基物质(PFAS),饮用水消毒副产物(DBPs),溴化阻燃剂(BFR),和微塑料(MPs)。EP在全球水生环境中的存在依赖于来源,污水处理厂是EP的主要来源。多项研究一致表明,水环境中大多数EP的最终目的地是污泥和沉积物。同时,一些EP,例如PFAS,议员们,和BFR,具有长期的环境运输潜力。一些EP表现出明显的生物积累和生物放大趋势,而其他人则在生物和非生物处理过程中的降解方面面临挑战。结果表明,在大多数情况下,水环境中EP的生态风险较低,可能是由于潜在的稀释和降解。未来的研究主题应包括为水生环境增加EP检测项目,结合污染,并更新预测模型。
    Significant concerns on a global scale have been raised in response to the potential adverse impacts of emerging pollutants (EPs) on aquatic creatures. We have carefully reviewed relevant research over the past 10 years. The study focuses on five typical EPs: pharmaceuticals and personal care products (PPCPs), per- and polyfluoroalkyl substances (PFASs), drinking water disinfection byproducts (DBPs), brominated flame retardants (BFRs), and microplastics (MPs). The presence of EPs in the global aquatic environment is source-dependent, with wastewater treatment plants being the main source of EPs. Multiple studies have consistently shown that the final destination of most EPs in the water environment is sludge and sediment. Simultaneously, a number of EPs, such as PFASs, MPs, and BFRs, have long-term environmental transport potential. Some EPs exhibit notable tendencies towards bioaccumulation and biomagnification, while others pose challenges in terms of their degradation within both biological and abiotic treatment processes. The results showed that, in most cases, the ecological risk of EPs in aquatic environments was low, possibly due to potential dilution and degradation. Future research topics should include adding EPs detection items for the aquatic environment, combining pollution, and updating prediction models.
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  • 文章类型: Journal Article
    新兴污染物,一类目前未受到法律监管或监管不充分的化合物,由于它们对人类健康的潜在毒性作用,最近成为研究的焦点。肠道微生物群在人类健康中起着关键作用;它在暴露于一系列有毒环境化学物质时特别容易受到破坏和改变。包括新兴的污染物。环境污染物对肠道微生物组的干扰可能代表了环境化学物质通过其发挥毒性作用的机制。一种引起越来越多关注的机制。然而,关于新兴污染物与葡萄糖代谢之间的毒性联系的讨论仍未充分探索。这篇综述旨在通过肠道微生物群建立新兴污染物与葡萄糖代谢之间的联系,深入研究这些污染物对葡萄糖代谢的毒性影响以及肠道微生物群的潜在作用。
    Emerging pollutants, a category of compounds currently not regulated or inadequately regulated by law, have recently become a focal point of research due to their potential toxic effects on human health. The gut microbiota plays a pivotal role in human health; it is particularly susceptible to disruption and alteration upon exposure to a range of toxic environmental chemicals, including emerging contaminants. The disturbance of the gut microbiome caused by environmental pollutants may represent a mechanism through which environmental chemicals exert their toxic effects, a mechanism that is garnering increasing attention. However, the discussion on the toxic link between emerging pollutants and glucose metabolism remains insufficiently explored. This review aims to establish a connection between emerging pollutants and glucose metabolism through the gut microbiota, delving into the toxic impacts of these pollutants on glucose metabolism and the potential role played by the gut microbiota.
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  • 工业化在全球范围内迅速扩张,导致各种有害污染物排放到生态系统中,导致广泛的环境污染,并构成紧迫的生态问题。在这种情况下,活性炭(AC)已经成为一种非常有前途的吸附剂,与传统形式相比,具有显著的优势。例如,AC表现出显著的吸附能力,使用KOH和KOH-CO2活性炭成功去除阿特拉津和布洛芬,实现90%和95%的令人印象深刻的吸附率,分别,在10mgL-1的初始剂量。此外,AC可以通过π-π堆积相互作用有效地吸附芳香族化合物。有机分子中的芳环可以与AC结构中的碳原子对齐并相互作用,导致有效吸附。在这次审查中,通过对最近的研究结果进行系统分析(主要是2015年至2023年),对AC的演变及其在吸附和修复新兴污染物中的广泛应用进行了深入的探索,包括染料,有机污染物,和有害气体,以及减轻这些新出现的污染物对生态系统的不利影响。它是研究人员的宝贵资源,专业人士,以及参与环境修复和污染控制的决策者,促进制定可持续和有效的战略,以减轻新兴污染物的全球影响。
    The rapid global expansion of industrialization has resulted in the discharge of a diverse range of hazardous contaminants into the ecosystem, leading to extensive environmental contamination and posing a pressing ecological concern. In this context, activated carbon (AC) has emerged as a highly promising adsorbent, offering significant advantages over conventional forms. For instance, AC has demonstrated remarkable adsorption capabilities, as evidenced by the successful removal of atrazine and ibuprofen using KOH and KOH-CO2-activated char, achieving impressive adsorption rates of 90% and 95%, respectively, at an initial dosage of 10 mg L-1. Moreover, AC can effectively adsorb aromatic compounds through π-π stacking interactions. The aromatic rings in organic molecules can align and interact with the carbon atoms in AC\'s structure, leading to effective adsorption. In this review, by employing a systematic analysis of recent research findings (majorly from 2015 to 2023), an in-depth exploration of AC\'s evolution and its wide-ranging applications in adsorbing and remediating emerging pollutants, including dyes, organic contaminants, and hazardous gases and mitigating the adverse impacts of such emerging pollutants on ecosystems have been discussed. It serves as a valuable resource for researchers, professionals, and policymakers involved in environmental remediation and pollution control, facilitating the development of sustainable and effective strategies for mitigating the global impact of emerging pollutants.
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  • 文章类型: Journal Article
    新兴污染物,如天然和人造化学品,杀虫剂,杀虫剂,表面活性剂,和其他生物制剂,如个人护理产品,化妆品,制药,许多工业排放阻碍了水生环境。纳米材料和微塑料,在污染物类别中,可以直接干扰海洋生态系统,并转化为对人类和动物的有害影响。他们要么不受控制,要么管理不善。由于它们对人类和环境健康的已知或怀疑的影响,一些化学品目前引起了人们的关注。水生生态受到这些毒素的威胁,已经在全世界传播。这篇综述评估了对水生生态系统和受污染水体产生影响的新兴和危险污染物的流行程度及其对非目标生物的毒性。发现微藻是补救上述风险的合适来源。基于微藻的缓解技术目前是针对所有此类污染物的新兴方法,包括上面讨论的其他类别。这些研究描述了植物修复的机制,提供可能显著影响污染物去除效率的愤怒因素,并讨论了微藻介导治疗的未来方向和挑战。
    Emerging pollutants such as natural and manufactured chemicals, insecticides, pesticides, surfactants, and other biological agents such as personal care products, cosmetics, pharmaceuticals, and many industrial discharges hamper the aquatic environment. Nanomaterials and microplastics, among the categories of pollutants, can directly interfere with the marine ecosystem and translate into deleterious effects for humans and animals. They are either uncontrolled or poorly governed. Due to their known or suspected effects on human and environmental health, some chemicals are currently causing concern. The aquatic ecology is at risk from these toxins, which have spread worldwide. This review assesses the prevalence of emerging and hazardous pollutants that have effects on aquatic ecosystems and contaminated water bodies and their toxicity to non-target organisms. Microalgae are found to be a suitable source to remediate the above-mentioned risks. Microalgae based mitigation techniques are currently emerging approaches for all such contaminants, including the other categories that are discussed above. These studies describe the mechanism of phycoremediation, provide outrage factors that may significantly affect the efficiency of contaminants removal, and discuss the future directions and challenges of microalgal mediated remediations.
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