One of the most talked about issues of the 21st century is climate change, as it affects not just our health but also forestry, agriculture, biodiversity, the ecosystem, and the energy supply. Greenhouse gases are the primary cause of climate change, having dramatic effects on the environment. Climate change has an impact on the function and composition of the terrestrial microbial community both directly and indirectly. Changes in the prevailing climatic conditions brought about by climate change will lead to modifications in plant physiology, root exudation, signal alteration, and the quantity, makeup, and diversity of soil microbial communities. Microbiological activity is very crucial in organic production systems due to the organic origin of microorganisms. Microbes that benefit crop plants are known as plant growth-promoting microorganisms. Thus, the effects of climate change on the environment also have an impact on the abilities of beneficial bacteria to support plant growth, health, and root colonization. In this review, we have covered the effects of temperature, precipitation, drought, and CO2 on plant-microbe interactions, as well as some physiological implications of these changes. Additionally, this paper highlights the ways in which bacteria in plants\' rhizosphere react to the dominant climatic conditions in the soil environment. The goal of this study is to analyze the effects of climate change on plant-microbe interactions.

Monolithic aerogels are promising candidates for use in atmospheric environmental purification due to their structural advantages, such as fine building block size together with high specific surface area, abundant pore structure, etc. Additionally, monolithic aerogels possess a unique monolithic macrostructure that sets them apart from aerogel powders and nanoparticles in practical environmental clean-up applications. This review delves into the available synthesis strategies and atmospheric environmental applications of monolithic aerogels, covering types of monolithic aerogels including SiO2, graphene, metal oxides and their combinations, along with their preparation methods. In particular, recent developments for VOC adsorption, CO2 capture, catalytic oxidation of VOCs and catalytic reduction of CO2 are highlighted. Finally, challenges and future opportunities for monolithic aerogels in the atmospheric environmental purification field are proposed. This review provides valuable insights for designing and utilizing monolithic aerogel-based functional materials.

In the face of 21st-century challenges driven by population growth and resource depletion, understanding the intricacies of climate change is crucial for environmental sustainability. This review systematically explores the interaction between rising atmospheric CO2 concentrations and soil microbial populations, with possible feedback effects on climate change and terrestrial carbon (C) cycling through a meta-analytical approach. Furthermore, it investigates the enzymatic activities related to carbon acquisition, gene expression patterns governing carbon and nitrogen metabolism, and metagenomic and meta-transcriptomic dynamics in response to elevated CO2 levels. The study reveals that elevated CO2 levels substantially influence soil microbial communities, increasing microbial biomass C and respiration rate by 15 % and upregulating genes involved in carbon and nitrogen metabolism by 12 %. Despite a 14 % increase in C-acquiring enzyme activity, there is a 5 % decrease in N-acquiring enzyme activity, indicating complex microbial responses to CO2 changes. Additionally, fungal marker ratios increase by 14 % compared to bacterial markers, indicating potential ecosystem changes. However, the current inadequacy of data on metagenomic and meta-transcriptomic processes underscores the need for further research. Understanding soil microbial feedback mechanisms is crucial for elucidating the role of rising CO2 levels in carbon sequestration and climate regulation. Consequently, future research should prioritize a comprehensive elucidation of soil microbial carbon cycling, greenhouse gas emission dynamics, and their underlying drivers.

BACKGROUND: One of the leading causes of morbidity and mortality worldwide is out-of-hospital cardiac arrest. Early defibrillation and high-quality cardiopulmonary resuscitation (CPR) have improved survival. The main goal of CPR is to achieve return of spontaneous circulation (ROSC), which is assessed by looking for a pulse, analyzing the heart rhythm, and assessing carbon dioxide levels. The use of cartography during CPR to confirm the correct position of the endotracheal tube during intubation or to assess the effectiveness of chest compressions has increased significantly in the last years. The aim of this review was to identify correlations between end-tidal carbon dioxide levels and the likelihood of ROSC in patients with out-of-hospital cardiac arrest.
METHODS: A literature search was performed in MEDLINE (via Pubmed), Scopus, Web of Science, and Google Scholar databases from September to November 2022. Keywords combined with the Boolean operators (AND/OR) were used in both free text and Medical Subject Headings. Studies on adult patients published between 01/01/2016 and 28/09/2022 were searched, with no geographical restrictions.
RESULTS: At the end of the selection process, 14 studies were included that investigated capnography in out-of-hospital CPR and reported at least 1 outcome between end-tidal carbon dioxide and ROSC or survival.
CONCLUSIONS: Capnography is an advantageous tool due to its noninvasive characteristics, ease of use, and immediacy of data. In out-of-hospital cardiac arrest, the use of the end-tidal carbon dioxide appears to be an appropriate complementary tool to support clinical decisions, such as correct positioning of the endotracheal tube, optimizing ventilation in CPR, and as a predictor of ROSC.

The current work investigated emerging fields for generating and consuming hydrogen and synthetic Fischer-Tropsch (FT) fuels, especially from detrimental greenhouse gases, CO2 and CH4. Technologies for syngas generation ranging from partial oxidation, auto-thermal, dry, photothermal and wet or steam reforming of methane were adequately reviewed alongside biomass valorisation for hydrogen generation, water electrolysis and climate challenges due to methane flaring, production, storage, transportation, challenges and opportunities in CO2 and CH4 utilisation. Under the same conditions, dry reforming produces more coke than steam reforming. However, combining the two techniques produces syngas with a high H2/CO ratio, which is suitable for producing long-chain hydrocarbons. Although the steam methane reforming (SMR) process has been industrialised, it is well known to consume significant energy. However, coke production via catalytic methane decomposition, the prime hindrance to large-scale implementation of these techniques for hydrogen production, could be addressed by coupling CO with CO2 conversion to alter the H2/CO ratio of syngas, increasing the reaction temperatures in dry reforming, or increasing the steam content fed in steam reforming. Optimised hydrogen production and generation of green fuels from CO2 and CH4 can be achieved by implementing these strategies.

BACKGROUND: The importance of building ventilation to protect health has been more widely recognized since the COVID-19 pandemic. Outdoor air ventilation in buildings dilutes indoor-generated air pollutants (including bioaerosols) and reduces resulting occupant exposures. Many countries and organizations have advisory guidelines or mandatory standards for minimum ventilation rates (VRs) to maintain indoor air quality (IAQ). Because directly measuring VRs is often difficult, many IAQ guidelines instead specify indoor concentration limits for carbon dioxide (CO2), using CO2 exhaled by building occupants as an indicator of VR. Although indoor CO2 guidelines are common, the evidence basis for the various CO2 limits has not been clear.
OBJECTIVE: To review current indoor CO2 guidelines worldwide and the supportive evidence provided.
METHODS: We identified worldwide CO2-based guidelines for IAQ or ventilation, along with any supportive evidence provided. We excluded occupational guidelines for CO2 levels ≥5000 ppm.
RESULTS: Among 43 guidelines identified, 35 set single CO2 concentration limits and eight set multi-tiered limits; 16 mentioned no specific human effect to be controlled, 19 specified only odor dissatisfaction, five specified non-infectious health effects, and three specified airborne infectious disease transmission. The most common indoor CO2 limit was 1000 ppm. Thirteen guidelines specified maximum CO2 limits as extended time-weighted averages, none with evidence linking averaged limits to occupant effects. Of only 18 guidelines citing evidence to support limits set, we found this evidence persuasive for eight. Among these eight guidelines, seven set limits to control odor perception. One provided 17 scientifically-based CO2 limits, for specific example space uses and occupancies, to control long-range COVID-19 transmission indoors.
CONCLUSIONS: Many current indoor carbon dioxide (CO2) guidelines for indoor air quality specified no adverse effects intended for control. Odor dissatisfaction was the effect mentioned most frequently, few mentioned health, and three mentioned control of infectious disease. Only one CO2 guideline was developed from scientific models to control airborne transmission of COVID-19. Most guidelines provided no supportive evidence for specified limits; few provided persuasive evidence. No scientific basis is apparent for setting one CO2 limit for IAQ across all buildings, setting a CO2 limit for IAQ as an extended time-weighted average, or using any arbitrary one-time CO2 measurement to verify a desired VR.

UNASSIGNED: Inhalation of high concentrations of carbon dioxide (CO₂) at atmospheric pressure can be toxic with dose-dependent effects on the cardiorespiratory system or the central nervous system. Exposure to both hyperbaric and hypobaric environments can result in decompression sickness (DCS). The effects of CO₂ on DCS are not well documented with conflicting results. The objective was to review the literature to clarify the effects of CO₂ inhalation on DCS in the context of hypobaric or hyperbaric exposure.
UNASSIGNED: The systematic review included experimental animal and human studies in hyper- and hypobaric conditions evaluating the effects of CO₂ on bubble formation, denitrogenation or the occurrence of DCS. The search was based on MEDLINE and PubMed articles with no language or date restrictions and also included articles from the underwater and aviation medicine literature.
UNASSIGNED: Out of 43 articles, only 11 articles were retained and classified according to the criteria of hypo- or hyperbaric exposure, taking into account the duration of CO₂ inhalation in relation to exposure and distinguishing experimental work from studies conducted in humans.
UNASSIGNED: Before or during a stay in hypobaric conditions, exposure to high concentrations of CO₂ favors bubble formation and the occurrence of DCS. In hyperbaric conditions, high CO₂ concentrations increase the occurrence of DCS when exposure occurs during the bottom phase at maximum pressure, whereas beneficial effects are observed when exposure occurs during decompression. These opposite effects depending on the timing of exposure could be related to 1) the physical properties of CO₂, a highly diffusible gas that can influence bubble formation, 2) vasomotor effects (vasodilation), and 3) anti-inflammatory effects (kinase-nuclear factor and heme oxygenase-1 pathways). The use of O₂-CO₂ breathing mixtures on the surface after diving may be an avenue worth exploring to prevent DCS.

One of the most promising approaches to address the global challenge of climate change is electrochemical carbon capture and utilization. Solid electrolytes can play a crucial role in establishing a chemical-free pathway for the electrochemical capture of CO2. Furthermore, they can be applied in electrocatalytic CO2 reduction reactions (CO2RR) to increase carbon utilization, produce high-purity liquid chemicals, and advance hybrid electro-biosystems. This review article begins by covering the fundamentals and processes of electrochemical CO2 capture, emphasizing the advantages of utilizing solid electrolytes. Additionally, it highlights recent advancements in the use of the solid polymer electrolyte or solid electrolyte layer for the CO2RR with multiple functions. The review also explores avenues for future research to fully harness the potential of solid electrolytes, including the integration of CO2 capture and the CO2RR and performance assessment under realistic conditions. Finally, this review discusses future opportunities and challenges, aiming to contribute to the establishment of a green and sustainable society through electrochemical CO2 valorization.

Microalgae-mediated industrial flue gas biofixation has been widely discussed as a clean alternative for greenhouse gas mitigation. Through photosynthetic processes, microalgae can fix carbon dioxide (CO2) and other compounds and can also be exploited to obtain high value-added products in a circular economy. One of the major limitations of this bioprocess is the high concentrations of CO2, sulfur oxides (SOx), and nitrogen oxides (NOx) in flue gases, according to the origin of the fuel, that can inhibit photosynthesis and reduce the process efficiency. To overcome these limitations, researchers have recently developed new technologies and enhanced process configurations, thereby increased productivity and CO2 removal rates. Overall, CO2 biofixation rates from flue gases by microalgae ranged from 72 mg L-1 d -1 to over 435 mg L-1 d-1, which were directly influenced by different factors, mainly the microalgae species and photobioreactor. Additionally, mixotrophic culture have shown potential in improving microalgae productivity. Progress in developing new reactor configurations, with pilot-scale implementations was observed, resulting in an increase in patents related to the subject and in the implementation of companies using combustion gases in microalgae culture. Advancements in microalgae-based green technologies for environmental impact mitigation have led to more efficient biotechnological processes and opened large-scale possibilities.

Effective municipal solid waste (MSW) management is a crucial component for sustainable cities, as inefficient waste disposal contributes to the release of about a billion tons of CO2-eq in greenhouse gases (GHG) annually. With escalating global waste generation, there is an untapped opportunity to integrate carbon dioxide removal (CDR) technologies into existing MSW management processes. This review explores current research on utilizing MSW for CDR, emphasizing its potential for both energy generation and carbon sequestration. The investigation covers three waste management practices: landfilling, waste-to-energy (WtE), and biochar production, revealing two paths for carbon sequestration. First, MSW serves as a feedstock in bioenergy with carbon capture and storage (BECCS), acting as a carbon-neutral resource that avoids fossil fuel and energy crop use, reducing GHG emissions and generating value through energy production. Second, direct storage of organic MSW and its derivatives, like biochar, in various carbon sinks allows for extended sequestration, offering a comprehensive approach to address the challenges of waste management and climate change mitigation. Moreover, this review advocates for an extended exploration into several subjects including in-depth analysis of waste, research on MSW-derived biochar recalcitrance across different carbon sinks, and understanding the symbiotic connections with GHG-emitting sectors like agriculture and energy. Finally, this review emphasizes the necessity of conducting life-cycle assessment studies to fully discern the benefits and assess the impacts of any future endeavors exploring the role of MSW in carbon sequestration.