BACKGROUND: The majority of existing industries in Ethiopia discharge untreated effluents into nearby water bodies, streams and open land. The wastewater generated by Gondar malt factory (GMF) was disposed freely and join a natural wetland implemented for the treatment of the wastewater. The objective of the study was to analyze and characterize wastewater from GMF and to evaluate the effectiveness of the wetland for the treatment purpose.
METHODS: Different Physicochemical quality indicators (color, turbidity pH, temperature, Total Dissolved solids, Total Suspended solids, total solid, conductivity, alkalinity, hardness, nitrate, phosphate, sulfate, free chlorides, heavy metals-(Cd, Cr, Fe, Mn, and Pb)and Biological Oxygen Demand were measured according to the standard procedures. Data was analyzed using Statistical Package for Social Sciences (SPSS-25). Analysis of Variance (ANOVA) was used to find whether significant differences existed in the different sampling stations for the parameters studied. P value less than 0.05 was considered to show significant difference.
RESULTS: The results of this study revealed that most of the quality indicators were improved in value after the water passed through the wetland except for alkalinity M, sulfite, Mn, temperature and pH. From ANOVA result, it was noted that there was a significant mean difference between the stations except for chromium, manganese and lead. The result showed that the wetland plays a great role in the removal of pollutants where the best performance was obtained at removal efficiency of 96.188% PO4HR,75.63% Nitrate,>99% Cl2, ammonia and nitrite 99.99%, 92.77% sulfate,84.36% Total hardness,87.43% color, and for others it is ranged between 30 and 60%.
CONCLUSIONS: the study concluded that GMF wetland was almost effective and had potential in treatment of the wastewater from the discharging facilities (especially for nutrients, alkalinity P, hardness, color and chloride). It is recommended that wetlands should be conserved and used as wastewater treatment facility.

Water resources play a crucial role in sustaining life on earth yet chemicals of emerging concern (CECs) arising from extensive human applications are an increasing threat towards their existence. In this study, we examined the occurrence, removal and potential risk of CECs found in rivers and wastewater treatment plants (WWTPs) in western Kenya. Samples were prepared by solid-phase extraction and analysed using high performance liquid chromatography-mass spectrometry with a target list of 785 compounds. Out of these, 333 and 352 (influent 322, effluent 265) compounds were quantified in rivers and wastewater respectively, with pharmaceuticals, industrial compounds, and pesticides being frequently detected in both rivers and WWTPs. Compounds with highest concentrations included saccharin (9.9 μg/L), metformin (7.5 μg/L), and oxypurinol (6.5 μg/L) in rivers whereas caffeine (280 μg/L), deoxycholic acid (179 μg/L), 2-oxindole (10.9 μg/L) and ibuprofen (8.1 μg/L) were found at high concentrations in WWTPs. Based on the types of crops grown, samples from maize growing regions recorded the highest number of pesticides (75) which coincided with the spraying season. The WWTP showed the capacity to eliminate some compounds although the removal efficiencies varied greatly with 204 compounds exhibiting an average removal efficiency exceeding 50 %. Based on the risk assessment, crustaceans had the highest potential risk for toxicity with toxic unit (TU) values up to 5.4 driven primarily by diazinon and dichlorvos followed by algae (TU up to 0.07) and fish (TU up to 0.01) in rivers. A similar trend was observed in WWTP with diazinon (TU up to 5.5), diuron (TU up to 0.07) and carbendazim (TU up to 0.006) driving the risk for crustaceans, algae and fish respectively. These findings highlight the significance of surface water and WWTPs as sources and sinks of CECs in the environment translating to potential risks on aquatic organisms and humans.

The presence of emerging organic micropollutants (OMPs) in drinking and potable waters is a matter of great concern due to the health hazards associated with these. In this work, we present the preparation and application of a thin-film nanocomposite (TFN) membrane containing functionalized graphene oxide to effectively remove low-molecular-weight OMPs from water. Graphene oxide was functionalized with amino silane to enhance its cross-linking capability during the formation of the polyamide active layer via interfacial polymerization of diethylene triamine and trimesoyl chloride. The TEM analysis showed that amino silane functionalized GO had 2-3 layered sheets, while non-functionalized graphene oxide appeared multilayered or stacked. XPS analysis confirmed the successful functionalization of GO. Characterization of the membranes with advanced techniques confirmed the successful incorporation of the GO and its functionalization: spectra from Fourier Transform Infra Red spectroscopy had the characteristic peaks of GO and NH groups; scanning Electron Microscopy (SEM) images showed a continuous presence of GO nanosheets. Contact angle measurements showed the TFN membranes to be more hydrophilic than their thin film composite (TFC) counterparts. Incorporating functionalized oxide nanosheets in the active polyamide layer produced additional water permeation channels, resulting in an improvement of ∼25 % in permeate flux compared to the pristine TFC and the TFN membrane with non-functionalized GO. The removal efficiencies of four OMPs commonly found in natural waters: Amitriptylene HCl (ATT HCl) and Bisphenol-A (BPA), Acetaminophen (ACT), and Caffeine (CFN) were determined for the synthesized membranes. The TFN membrane with functionalized GO outperformed its TFC counterpart with ∼100 % removal for BPA, ∼ 90 % for CFN and ATT HCl, and ∼80 % removal for the low molecular weight ACT. The high-efficiency rejection of OMPs was attributed to the synergistic effects of size exclusion as well as the reduced specific interactions between the functional groups.

In this study, a microbial fuel cell was constructed using Raoultella sp. XY-1 to efficiently degrade tetracycline (TC) and assess the effectiveness of the electrochemical system. The degradation rate reached 83.2 ± 1.8 % during the 7-day period, in which the system contained 30 mg/L TC, and the degradation pathway and intermediates were identified. Low concentrations of TC enhanced anodic biofilm power production, while high concentrations of TC decreased the electrochemical activity of the biofilm, extracellular polymeric substances, and enzymatic activities associated with electron transfer. Introducing electrogenic bacteria improved power generation efficiency. A three-strain hybrid system was fabricated using Castellaniella sp. A3, Castellaniella sp. A5 and Raoultella sp. XY-1, leading to the enhanced TC degradation rate of 90.4 % and the increased maximum output voltage from 200 to 265 mV. This study presents a strategy utilizing tetracycline-degrading bacteria as bioanodes for TC removal, while incorporating electrogenic bacteria to enhance electricity generation.

Increasing consumption of pharmaceuticals and the respective consequences for the aquatic environment have been the focus of many studies over the last thirty years. Various aspects in this field were investigated, considering diverse pharmaceutical groups and employing a wide range of research methodologies. Various questions from the perspectives of different research areas were devised and answered, resulting in a large mix of individual findings and conclusions. Collectively, the results of the studies offer a comprehensive overview. The large variety of methods and strategies, however, demands close attention when comparing and combining information from heterogeneous projects. This review critically examines the application of diverse sampling techniques as well as analytical methods in investigations concerning the behavior of pharmaceutically active compounds (PhACs) and contrast agents (CAs) in wastewater treatment plants (WWTPs). The combination of sampling and analysis is discussed with regard to its suitability for specific scientific problems. Different research focuses need different methods and answer different questions. An overview of studies dealing with the fate and degradation of PhACs and CAs in WWTPs is presented, discussing their strategic approaches and findings. This review includes surveys of anticancer drugs, antibiotics, analgesics and anti-inflammatory drugs, antidiabetics, beta blockers, hormonal contraceptives, lipid lowering agents, antidepressants as well as contrast agents for X-ray and magnetic resonance imaging.

Solar Fenton is an important and extensively used advanced oxidation process (AOP) to degrade pharmaceutical pollutants. The objective of this study was to evaluate the performance of simultaneous degradation of the mixed pollutants (amoxicillin, acetaminophen, and ciprofloxacin) for an aqueous solution using the solar Fenton process. Operating parameters such as pH, iron doses, H2O2 doses, pollutant concentrations, and time were studied. From the experimental results, the ideal conditions were obtained for the removal of mixed pollutants such as pH 3, Fe2+ 0.04 mM, H2O2 4 mM, the concentration of the mixed pollutants 5 mg/L, solar radiation 400 W/m2, and time 10 min, respectively. The pseudo-first-order kinetics were utilized to investigate the degradation efficacy of the mixed pollutants. The result of the study indicates that the degradation efficiency was > 99% for the mixed pollutants. A maximum of 63% mineralization was observed, and hydroxyl radical scavenger effects were studied. The best optimal conditions were applied to assess the spiked wastewater (municipal wastewater (MWW) and hospital wastewater (HWW)). The highest elimination rates for AMX, ACET, and CIP were observed as 65%, 89%, and 85% for MWW and 76%, 92%, and 80% for HWW, respectively. The degraded by-products were detected by LC-ESI-MS in the water matrix (aqueous solution and spiked wastewater), and ECOSAR analysis was performed for the transformed products. The study concluded that the solar Fenton technique is promising and effective for the removal of mixed pollutants from the water matrix.

This study investigates the effectiveness of vertical flow constructed wetlands (VFCWs) planted with a climbing ornamental plant for on-site treatment of real laundry wastewater. Specifically, the presence or absence of Trachelospermum jasminoides was evaluated for the removal performance of conventional pollutants (turbidity, TSS, COD, TP) and benzotriazoles (BTRs): 1H-benzotriazole (BTR), 5-methyl-1H-benzotriazole (5-TTR), 5-chlorobenzotriazole (CBTR), and xylytriazole (XTR). Results revealed that high removal efficiencies ranging from 92 to 98% were presented in both planted and unplanted systems for turbidity, TSS, and COD. Moreover, high removal rates were observed for CBTR and XTR, which were the only compounds found in real laundry wastewater, in both VFCW systems (planted: 100%; 94%; unplanted: 87%; 92%, respectively). The contribution of plants to the pollutant\'s removal was not statistically significant for all examined parameters. However, T. jasminoides demonstrated the ability to survive and grow without any visible symptoms under the harsh conditions of laundry wastewater, enabling the development of green facade. According to the findings, the application of VFCWs for on-site laundry wastewater treatment in buildings seems to be a highly promising solution, not only for primarily removing conventional pollutants but also for addressing emerging contaminants, specifically BTRs.

We compared the ability of one emergent (Sagittaria montevidensis), two floating (Salvinia minima and Lemna gibba), and one heterophyllous species (Myriophyllum aquaticum) to simultaneously remove sulfamethoxazole, sulfadiazine, ciprofloxacin, enrofloxacin, norfloxacin, levofloxacin, oxytetracycline, tetracycline, doxycycline, azithromycin, amoxicillin, and meropenem from wastewater in a mesocosm-scale constructed wetland over 28 days. Antibiotic concentrations in plants and effluent were analyzed using an LC-MS/MS to assess the removal rates and phytoremediation capacities. M. aquaticum did not effectively mitigate contamination due to poor tolerance and survival in effluent conditions. S. minima and L. gibba demonstrated superior efficiency, reducing the antibiotic concentrations to undetectable levels within 14 days, while S. montevidensis achieved this result by day 28. Floating macrophytes emerge as the preferable choice for remediation of antibiotics compared to emergent and heterophyllous species. Antibiotics were detected in plant tissues at concentrations ranging from 0.32 to 29.32 ng g-1 fresh weight, highlighting macrophytes\' ability to uptake and accumulate these contaminants. Conversely, non-planted systems exhibited a maximum removal rate of 65%, underscoring the persistence of these molecules in natural environments, even after the entire experimental period. Additionally, macrophytes improved effluent quality regardless of species by reducing total soluble solids and phosphate concentrations and mitigating ecotoxicological effects. This study underscores the potential of using macrophytes in wastewater treatment plants to enhance overall efficiency and prevent environmental contamination by antibiotics, thereby mitigating the harmful impact on biota and antibiotic resistance. Selecting appropriate plant species is crucial for successful phytoremediation in constructed wetlands, and actual implementation is essential to validate their effectiveness and practical applicability.

Permeable pavement is a technology that allows rainwater to infiltrate into the pavement. Permeable pavements not only help reduce surface runoff by allowing rainwater to infiltrate into the pavement, but also improve water quality with the filter layer that removes particulate matter pollutants. This study evaluated the particulate matter removal efficiency of bottom ash-sand mixtures as filter layers for removing fine (≤10 μm) or ultrafine (≤2.5 μm) particulate matter in the laboratory. Five filter media were tested: silica sand, bottom ash, and bottom ash-sand mixtures with 30:70, 50:50, and 70:30 ratios. The mixed filters exhibited more consistent and stable particulate matter removal efficiency over time than either the uniform sand or bottom ash filter. The 50:50 bottom ash-sand mixture demonstrated removal rates of 58.05% for 1.8 μm particles, 93.92% for 10 μm particles, and 92.45% for 60 μm particles. These findings highlight the potential of bottom ash-sand mixtures as effective filter media for removing PM10 road dust, although field validation with actual pavement systems is necessary.

Emerging pollutants (EPs) are prevalent in aquatic environments globally. Researchers strive to understand their occurrence and behavior prior to their release into the environment. In this study, we examined five wastewater treatment plants (WWTPs), collected 50 wastewater samples and 10 sludge samples. We explored the sources and destinations of phthalic acid esters (PAEs) within these WWTPs using mass balance equations. Wastewater treatment diminished the frequency and concentration of PAEs, and decreased the fraction of short-chain PAEs. We confirmed the increased concentration of PAEs post-primary treatment and modified the mass balance equation. Calculations suggest that weaker \"the mix\" in winter than in summer and stronger sedimentation in winter than in summer resulted in high efficiency of PAEs removal by winter wastewater treatment. The mass flux of biodegradation was influenced by the combination of biodegradation efficiency and the strength of the particular type of PAEs collected, with no seasonal differences. Mass fluxes for sludge sedimentation were mainly influenced by season and were higher in winter than in summer. This study enhances our understanding of emerging pollutants in manual treatment facilities and offers insights for optimizing wastewater treatment methods for water professionals.