plastic pollution

塑料污染
  • 文章类型: Journal Article
    塑料污染的增加对海洋生物构成了严重威胁。微塑料(MP)的摄入可能对生物体本身和最终消费者构成风险。通过对胃肠道的分析,再加上对肌肉组织的稳定同位素分析,这项研究提供了有关在Tyrrenian中部海域捕获的两种商业海洋物种的MP污染与生态之间关系的见解:Aristaeomorphafoliacea和Parapenaeuslongirostris。进行稳定同位素分析以确定营养位置和营养生态位宽度。胃肠道被处理,并在FT-IR光谱法下分析所得的MPs以估计其发生,丰度,以及被摄入议员的类型学。该物种的营养水平相似(P.龙珠TP=3±0.10,落叶TP=3.1±0.08),具有重要的营养生态位重叠,其中38%和52%的龙舌兰假单胞菌和落叶假单胞菌摄入了MP,分别。尽管就每个个体的MP丰度而言,物种水平差异可能并不明显,在摄入颗粒的类型中发现了高度的差异。这项研究为国会议员如何进入海洋营养网提供了有价值的见解,强调同位素生态位分析应与其他方法相结合,以详细解释MP摄入的差异。
    Increasing plastic contamination poses a serious threat to marine organisms. Microplastics (MPs) ingestion can represent a risk for the organism itself and for the ultimate consumer. Through the analysis of the gastrointestinal tract, coupled with stable isotope analysis on the muscle tissue, this study provides insights into the relationship between MPs pollution and ecology in two commercial marine species caught in the Central Tyrrhenian Sea: Aristaeomorpha foliacea and Parapenaeus longirostris. Stable isotope analysis was conducted to determine the trophic position and the trophic niche width. The gastrointestinal tracts were processed, and the resultant MPs were analysed under FT-IR spectroscopy to estimate the occurrence, abundance, and typology of the ingested MPs. The trophic level of the species was similar (P. longirostris TP = 3 ± 0.10 and A. foliacea TP = 3.1 ± 0.08), with an important trophic niche overlap, where 38% and 52% of P. longirostris and A. foliacea has ingested MPs, respectively. Though species-level differences may not be evident regarding MP\'s abundance per individual, a high degree of dissimilarity was noted in the typologies of ingested particles. This research provides valuable insights into how MPs enter marine trophic webs, stressing that isotopic niche analysis should be combined with other methods to explain in detail the differences in MPs ingestion.
    导出

    更多引用

    收藏

    翻译标题摘要

    我要上传

       PDF(Pubmed)

  • 文章类型: Journal Article
    微塑料(MP)污染现在是一个全球性的关键问题,并且已经成为对多种类型的栖息地相当担忧的主题,特别是在与海洋相连的沿海地区的泻湖中。议员们很担心,特别是因为地表水中的漂浮MP可以被许多海洋生物摄入。东南亚的海岸线上有几个泻湖,但宋卡泻湖是泰国唯一拥有丰富生物多样性的出口。迄今为止,在这个泻湖中,对MP的研究很少,因此,迫切需要更多地了解MP在泻湖水中的存在。
    我们调查宋卡泻湖地表水中的国会议员,泰国。在2022年12月的雨季和2023年2月的旱季,在泻湖的十个站点进行了采样。用过氧化氢消化样品以除去有机物质,随后使用饱和氯化钠进行密度分离。在立体显微镜下目测检查MPs以描述和确定形状,尺寸,和颜色。使用显微傅里叶变换红外(FTIR)光谱仪鉴定聚合物类型。此外,使用多参数探头测量了地表水的原位水质。进行了Mann-WhitneyU测试,以研究雨季和旱季之间MP水平和水质参数的变化。相关性分析(Spearmanrho)用于确定MP与水质之间相关性的显著性(p<0.05)。
    在所有十个采样点检测到MPs。最丰富的MPs是小型类(<500µm,主要由纤维组成)。在地表水中看到五种类型的聚合物,包括聚对苯二甲酸乙二醇酯,人造丝,聚丙烯,聚酯,和聚(乙烯:丙烯)。人造丝和聚酯是主要的聚合物。此外,议员在雨季和旱季最主要的颜色是黑色和蓝色,分别。雨季和旱季MPs的平均含量分别为0.43±0.18和0.34±0.08项目/L,分别。Mann-WhitneyU检验表明,干湿季节的水质存在显着差异(p<0.05)。相关分析(Spearmanrho)表明,在雨季,MPs与总溶解固体(TDS)值之间存在显着的负相关关系(r=-0.821,p=<0.05)。揭示了大量的MP可能分散在TDS浓度低的地表水体内。根据总体调查结果,泻湖地表水中的MP污染未发现受季节性环境的影响。河流流入泻湖,尤其是U-Taphao河,可能是导致泻湖中MP污染负荷增加的主要途径。这些结果可以作为基线数据,进行与来源相关的进一步研究工作,命运,分布,以及国会议员对其他沿海泻湖的影响。
    UNASSIGNED: Microplastic (MP) pollution is now a global critical issue and has been the subject of considerable worry for multiple various types of habitats, notably in lagoons which are coastal areas connected to the ocean. MPs are of concern, particularly because floating MP in surface water can be ingested by a number of marine organisms. There are several lagoons along Southeast Asia\'s coastline, but Songkhla Lagoon is Thailand\'s only exit with a rich biodiversity. To date, there has been little research undertaken on MP in this lagoon, so there is a pressing need to learn more about the presence of MP in the lagoon\'s water.
    UNASSIGNED: We investigate MPs in the surface water of Songkhla Lagoon, Thailand. Sampling took place at ten stations in the lagoon during the wet season in December 2022 and the dry season in February 2023. Samples were digested with hydrogen peroxide to remove organic matter followed by density separation using saturated sodium chloride. MPs were visually examined under a stereo microscope to describe and determine the shape, size, and color. Polymer type was identified using a micro Fourier transform infrared (FTIR) spectrometer. Moreover, the in-situ of water quality of the surface water was measured using a multi-parameter probe. A Mann-Whitney U test was performed to investigate the variations in MP levels and water quality parameters between the wet and dry seasons. Correlation analysis (Spearman rho) was used to determine the significance of correlations between MP and water quality (p < 0.05).
    UNASSIGNED: MPs were detected at all ten of the sites sampled. The most abundant MPs were small size class (<500 µm, primarily consisting of fibers). Five types of polymers were seen in surface water, including polyethylene terephthalate, rayon, polypropylene, polyester, and poly (ethylene:propylene). Rayon and polyester were the dominant polymers. Additionally, the most dominant color of MPs in the wet and dry season was black and blue, respectively. The mean contents of MPs in the wet and dry season were 0.43 ± 0.18 and 0.34 ± 0.08 items/L, respectively. The Mann-Whitney U test suggested a significant difference between water quality in the wet and dry seasons (p < 0.05). Correlation analysis (Spearman rho) indicated a negative significant difference relationship between the MPs and the values of total dissolved solid (TDS) in the wet season (r = -0.821, p = <0.05), revealing that the large amounts of MPs may possibly be dispersed within surface water bodies with low TDS concentrations. Based on the overall findings, MP pollution in the surface water of the lagoon is not found to be influenced by the seasonal context. Rivers flowing into the lagoon, especially the U-Taphao River, may be a principal pathway contributing to increased MP pollution loading in the lagoon. The results can be used as baseline data to undertake further research work relevant to sources, fates, distribution, and impacts of MPs in other coastal lagoons.
    导出

    更多引用

    收藏

    翻译标题摘要

    我要上传

       PDF(Pubmed)

  • 文章类型: Journal Article
    近几十年来,由于塑料污染引起的全球环境危机,塑料废物管理受到了广泛关注。塑料的多才多艺和耐用性质导致其在各个领域的广泛使用。然而,其不可生物降解的性质有助于不可持续的生产实践,导致垃圾填埋场的广泛使用,并对海洋生态系统和食物链构成威胁。为了解决这些环境问题,通过研究处理塑料废物的替代方法,最近解决了许多挑战,随着建筑业成为一个有希望的选择。将塑料废料掺入混凝土中不仅具有经济效益,而且还提供了常规处置方法的有效替代方案。本文介绍了不同实验研究的结果,其中一些可以在文献中找到,另一些是新的,讨论了塑料垃圾融入混凝土的可行性及其对力学性能的影响。不同尺寸的影响,性质,治疗,和百分比的塑料废物在混凝土混合物中的处理,以提供进一步的数据,帮助理解在文献中的非统一的结果,坚信只有进一步的观察才能帮助理解塑料骨料混凝土的力学原理。实验研究强调,一个参数比其他参数更好,可以考虑比较不同的实验研究是重量的变化(由于混合物中塑料的有效体积),确定一种降低机械特性的孔隙率增加。然而,在某些情况下,这似乎不一致。因此,需要进一步研究,以完善生产方法和优化混合设计。
    Plastic waste management has received significant attention in recent decades due to the urgent global environmental crisis caused by plastic pollution. The versatile and durable nature of plastic has led to its widespread usage across various sectors. However, its nonbiodegradable nature contributes to unsustainable production practices, leading to extensive landfill usage and posing threats to marine ecosystems and the food chain. To address these environmental concerns, numerous challenges have been recently addressed through investigating alternative approaches for disposing of plastic waste, with the construction sector emerging as a promising option. Incorporating plastic waste materials into concrete not only offers economic benefits but also provides a valid alternative to conventional disposal methods. This paper presents the results of different experimental studies, some of them available in the literature and others new, discussing the feasibility of integrating plastic waste into concrete and its impact on mechanical properties. The influence of different sizes, natures, treatments, and percentages of plastic waste in the concrete mixtures is dealt with in order to provide further data for helping to understand the nonunivocal results in the literature, under the conviction that only further observations can help to understand the mechanics of concrete with plastic aggregates. The experimental investigation highlighted that one parameter that is better than others and can be considered to compare different experimental investigations is the variation in weight (due to the effective volume of plastics in the mix), determining a sort of increasing of porosity that degrades the mechanical characteristics. However, this seems inconsistent in some cases. Therefore, the need for further research is highlighted to refine production methods and optimize mix designs.
    导出

    更多引用

    收藏

    翻译标题摘要

    我要上传

       PDF(Pubmed)

  • 文章类型: Journal Article
    术语微塑料(MPs)描述了可以在大小上变化的颗粒的异质混合物,颜色,和形状。一旦释放到环境中,国会议员对野生动物有各种毒理学和物理效应。SongThrush(Turdusphilomelos)是一种迁徙物种,在深秋和冬季呆在意大利。这项研究的目的是评估,量化、并描述了在意大利普利亚地区狩猎的SongThrushes中微塑料的存在。这些鸟类(n=360)在巴里乡村被猎杀,并由猎人捐赠用于研究目的。MPs根据它们在纤维中的形状进行分类,电影,碎片,和颗粒;然后,根据它们的颜色将它们分开并测量颗粒的长度。应用尼康图像分析软件进行垫料尺寸测量。在总共360只鸟中,在12月射击的129只鸟和1月射击的128只鸟的胃中检测到国会议员。摄入的大多数MP是在所有受污染的鸟类中观察到的纤维。在每个污染的样品中观察到膜碎片。在所有发现的议员中,31.75%为红色,30.13%是黑色的,25.91%是蓝色的,而其他颜色的代表较少。这项研究提供了在普利亚地区越冬的SongThrushes中MPs生物积累的首次分析,鹅口疮的高污染证实了MPs在陆地生态系统中的普遍存在。
    The term microplastics (MPs) describes a heterogeneous mixture of particles that can vary in size, color, and shape. Once released into the environment, MPs have various toxicological and physical effects on wildlife. The Song Thrush (Turdus philomelos) is a migratory species, staying in Italy in late autumn and winter. The aim of this study is to assess, quantify, and characterize the presence of microplastics in Song Thrushes hunted in the Apulia region of Italy. The birds (n = 360) were hunted in the Bari countryside and donated for research purposes by hunters. MPs were classified in relation to their shape in fibers, films, fragments, and pellets; then, they were divided according to their color and the length of the particles was measured. Nikon image analysis software was applied to the litter size measurements. Of the total of 360 birds, MPs were detected in the stomachs of 129 birds shot in December and 128 birds shot in January. The majority of ingested MPs were fibers that were observed in all contaminated birds. Film fragments were observed in every contaminated specimen. Among all the MPs found, 31.75% were red, 30.13% were black, and 25.91% were blue, while the other colors were less represented. This study provides the first analysis of MPs bioaccumulation in Song Thrushes wintering in the Apulia region, and the high contamination of thrushes confirmed the ubiquity of MPs in terrestrial ecosystems.
    导出

    更多引用

    收藏

    翻译标题摘要

    我要上传

       PDF(Pubmed)

  • 文章类型: Journal Article
    微塑料(MPs)遍布环境,渗入食物来源和人体,引起人们对其对人类健康影响的担忧。这篇综述集中在三个关键问题上:(i)人类最接触哪种类型的聚合物?(ii)在食品和人类样品中发现的MPs的普遍形状是什么?(iii)数据是否受到颗粒大小检测限的影响?通过系统的文献分析,我们已经探索了在食物和人体样本中发现的聚合物类型和形状的数据。数据提供了聚酯是人类中最常见的聚合物的证据,其次是聚酰胺,聚氨酯,聚丙烯,和聚丙烯酸酯。纤维在所有类别中都是主要的形状,表明纺织业潜在的环境污染。对人类和饮用水的研究报告了小颗粒的数据,与环境研究中检测到的更大尺寸的MP相反,特别是海鲜。确定了不同报告中尺寸检测方法的差异,这可能会影响一些讨论的趋势。本研究强调需要对MPs与生物系统之间的相互作用以及MPs对毒性的影响进行更全面的研究。与标准化分析方法一起准确评估污染水平和人体暴露。了解这些动态对于制定有效的策略以减轻MP污染对环境和健康的影响至关重要。
    Microplastics (MPs) pervade the environment, infiltrating food sources and human bodies, raising concerns about their impact on human health. This review is focused on three key questions: (i) What type of polymers are humans most exposed to? (ii) What are the prevalent shapes of MPs found in food and human samples? (iii) Are the data influenced by the detection limit on the size of particles? Through a systematic literature analysis, we have explored data on polymer types and shapes found in food and human samples. The data provide evidence that polyester is the most commonly detected polymer in humans, followed by polyamide, polyurethane, polypropylene, and polyacrylate. Fibres emerge as the predominant shape across all categories, suggesting potential environmental contamination from the textile industry. Studies in humans and drinking water reported data on small particles, in contrast to larger size MPs detected in environmental research, in particular seafood. Discrepancies in size detection methodologies across different reports were identified, which could impact some of the discussed trends. This study highlights the need for more comprehensive research on the interactions between MPs and biological systems and the effects of MPs on toxicity, together with standardised analytical methodologies to accurately assess contamination levels and human exposure. Understanding these dynamics is essential for formulating effective strategies to mitigate the environmental and health implications of MP pollution.
    导出

    更多引用

    收藏

    翻译标题摘要

    我要上传

       PDF(Pubmed)

  • 文章类型: Journal Article
    塑料污染是一个广泛和日益关注的问题,由于其转化为微塑料(MPs),会危害生物和生态系统。这项研究,旨在使用泰国西部保护区内外的便利采样来识别陆生脊椎动物粪便中的塑料污染。我们假设在所有脊椎动物的粪便中都可以检测到MPs,主要以黑色小碎片的形式。我们预测了不同保护区同一物种粪便中的MP数量不同。此外,我们预计表明人类存在的因素,景观特征,scat重量,以及水中的MP丰富,土壤,沉积物会影响粪便中塑料的存在。在研究的12种陆地物种中,在90个样本中的41.11%中发现了潜在的MP,包括亚洲象(Elephasmaximus)在内的八个物种共有83件,埃尔德鹿(Rucervuseldii),Dhole(Cuonalpinus),高尔(Bosgaurus),桑巴鹿(Rusaunicolor),野猪(Susscrofa),北方红muntjac(Muntiacusvaginalis),和蝴蝶蜥蜴(Leiolepisbelliana)。具体来说,3.61%的所有潜在的MP(三片)是大型塑料,其余96.39%被认为是潜在的MPs,丰度为0.92±1.89项。scat-1或8.69±32.56项目.100g-1dw。有和没有潜在塑料和物种的粪便数量之间存在关联(χ2=20.88,p=0.012)。大多数潜在的塑料是纤维(95.18%),以黑色(56.63%)或蓝色(26.51%)为主,74.70%小于两毫米。尽管物种和塑料形态之间没有显著关联,颜色,和尺寸,按这些特征分类的丰度差异很大。FTIR鉴定52.38%为天然纤维,38.10%作为合成纤维(人造丝,聚氨酯(PUR),聚对苯二甲酸乙二醇酯(PET),聚丙烯(PP),和PUR与棉混合),和9.52%作为PET和聚氯乙烯(PVC)的碎片。与人类有关的因素与在陆地野生动物粪便中发现的潜在塑料的发生有关。这项研究提高了对热带保护区塑料污染的认识,揭示了国会议员的广泛存在,即使是远离人类住区地区的少数议员也是如此。监测粪便中的塑料为评估受威胁物种的塑料污染提供了一种非侵入性方法。因为它允许容易收集和分类识别,而不伤害活的动物。然而,必须采取严格的措施来确保质量,以防止外源性MP污染。这些发现强调了提高人们对陆地生态系统中塑料污染的认识的重要性。特别是关于农业和灌溉系统中使用的服装和塑料材料的塑料制品。
    Plastic pollution is a widespread and growing concern due to its transformation into microplastics (MPs), which can harm organisms and ecosystems. This study, aimed to identify plastic pollution in the feces of terrestrial vertebrates using convenience sampling both inside and outside protected areas in Western Thailand. We hypothesized that MPs are likely to be detectable in the feces of all vertebrate species, primarily in the form of small black fragments. We predicted varying quantities of MPs in the feces of the same species across different protected areas. Furthermore, we expected that factors indicating human presence, landscape characteristics, scat weight, and the MP abundance in water, soils, and sediments would influence the presence of plastics in feces. Among 12 terrestrial species studied, potential MPs were found in 41.11% of 90 samples, totaling 83 pieces across eight species including the Asian elephant (Elephas maximus), Eld\'s deer (Rucervus eldii), Dhole (Cuon alpinus), Gaur (Bos gaurus), Sambar deer (Rusa unicolor), Wild boar (Sus scrofa), Northern red muntjac (Muntiacus vaginalis), and Butterfly lizard (Leiolepis belliana). Specifically, 3.61% of all potential MPs (three pieces) were macroplastics, and the remaining 96.39% were considered potential MPs with the abundance of 0.92 ± 1.89 items.scat-1 or 8.69 ± 32.56 items.100 g-1 dw. There was an association between the numbers of feces with and without potential plastics and species (χ2 = 20.88, p = 0.012). Most potential plastics were fibers (95.18%), predominantly black (56.63%) or blue (26.51%), with 74.70% smaller than two millimeters. Although there were no significant associations between species and plastic morphologies, colors, and sizes, the abundance classified by these characteristics varied significantly. FTIR identified 52.38% as natural fibers, 38.10% as synthetic fibers (rayon, polyurethane (PUR), polyethylene terephthalate (PET), polypropylene (PP), and PUR blended with cotton), and 9.52% as fragments of PET and Polyvinyl Chloride (PVC). Human-related factors were linked to the occurrence of potential plastics found in the feces of land-dwelling wildlife. This study enhances the understanding of plastic pollution in tropical protected areas, revealing the widespread of MPs even in small numbers from the areas distant from human settlements. Monitoring plastics in feces offers a non-invasive method for assessing plastic pollution in threatened species, as it allows for easy collection and taxonomic identification without harming live animals. However, stringent measures to assure the quality are necessitated to prevent exogenous MP contamination. These findings underscore the importance of raising awareness about plastic pollution in terrestrial ecosystems, especially regarding plastic products from clothing and plastic materials used in agriculture and irrigation systems.
    导出

    更多引用

    收藏

    翻译标题摘要

    我要上传

       PDF(Pubmed)

  • 文章类型: Journal Article
    这篇综述揭示了线性经济流行和管理不善做法在罗马尼亚水生和陆地环境塑料污染中的作用以及相关的知识差距,同时概述了下游和上游减少塑料污染和采取循环经济战略的解决方案。因此,这项研究的主要目的是调查罗马尼亚背景下有关所有这些需求的科学知识阶段。
    这项工作整合了两种主要方法:(i)由WebofScience和Scopus数据库提供的文献计量分析,以揭示罗马尼亚与塑料废物有关的同行评审文献的当前覆盖范围,以及(ii)基于主题的审查,以强调与塑料废物管理有关的主要主题,塑料污染,以及罗马尼亚符合循环经济原则的缓解方案。
    减少塑料污染需要科学知识,多部门合作,和社会意识。在此之后,塑料废物和塑料污染的主题似乎在考虑罗马尼亚作为案例研究的文献中被研究不足,集中在2020年左右,强调,这样,塑料废物的趋势关注及其在当前研究环境中的管理。我们的分析指出:(i)罗马尼亚正面临着巨大的塑料污染,需要在废物管理方面进行扎实的改进;(ii)在罗马尼亚的大多数地理区域中,针对宏观和微观塑料问题进行的同行评审研究很少;(iii)塑料废物管理仍未得到充分研究,虽然地方一级的废物统计数据很少;(iv)循环经济转型的前景仍然有限,未来几年塑料污染。
    确定了一些知识差距,必须在未来的研究中加以弥补,例如(i)根据区域废物管理绩效调整管理不善的塑料废物水平,并确定城市和农村地区的乱扔垃圾率,以改善塑料污染建模投入;(ii)检查与垃圾填埋场和废物进口相关的塑料污染;(iii)评估部门对与城市相关的水生环境的宏观和微塑料污染的贡献,旅游目的地,农业,等。;(iv)确定流域中塑料的保留水平和河岸植被的作用;(v)分析所有类型淡水环境中的微塑料存在以及大塑料碎片和微塑料之间的相互联系;(vi)评估与管理不善有关的跨界河流的塑料负荷;(vii)确定空气中微塑料的浓度,土壤,和其他土地利用生态系统。
    UNASSIGNED: This review reveals the role of linear economy prevalence and mismanagement practices in plastic pollution of aquatic and terrestrial environments and related knowledge gaps in Romania while outlining downstream and upstream solutions to reduce plastic pollution and adopt circular economy strategies. Thus, the major aim of this study is the investigation of the stage of scientific knowledge concerning all these demands in the Romanian context.
    UNASSIGNED: This work integrates two main approaches: (i) a bibliometric analysis fed by Web of Science and Scopus databases to reveal the current coverage of peer-reviewed literature related to plastic waste in Romania and (ii) a subject-based review to underline the main themes related to plastic waste management, plastic pollution, and mitigating options in Romania in line with circular economy principles.
    UNASSIGNED: Reducing plastic pollution requires scientific knowledge, multi-sectoral cooperation, and societal awareness. Following this, the topics of plastic waste and plastic pollution appeared to be under-investigated in the literature considering Romania as a case study and concentrated around the 2020 year, emphasizing, in this way, the trendiness of plastic waste concerns and their management in the current research landscape. Our analysis points out that: (i) Romania is facing massive plastic pollution requiring solid improvements in waste management performances; (ii) few peer-reviewed research studies are performed in Romania for both macro and microplastic concerns with unknown pollution levels in most of its geographical regions; (iii) the plastic waste management is still understudied here, while waste statistics are poorly available at local levels; (iv) the perspectives of circular economy transition are still limited, feeding the plastic pollution in the coming years.
    UNASSIGNED: Several knowledge gaps are identified and must be covered by future research such as (i) adjusting mismanaged plastic waste levels to regional waste management performances and determining littering rates in urban and rural areas to improve the plastic pollution modeling inputs; (ii) examining plastic pollution associated with landfill sites and waste imports; (iii) assessing the sectoral contributions to macro and microplastic pollution of aquatic environments related to municipalities, tourist destinations, agriculture, etc.; (iv) determining retention levels of plastic in river basins and role of riparian vegetation; (v) analyzing microplastics presence in all types of freshwater environments and interlinkage between macroplastic fragmentation and microplastic; (vi) assessing the plastic loads of transboundary rivers related to mismanagement practices; (vii) determining concentrations of microplastics in air, soil, and other land use ecosystems.
    导出

    更多引用

    收藏

    翻译标题摘要

    我要上传

       PDF(Pubmed)

  • 文章类型: Journal Article
    锑(Sb)污染由于其毒性和广泛存在而引起重大的环境和健康问题,主要来自人为活动。这项研究解决了对Sb进行准确形态分析的迫切需要,特别是在水源中,强调其从聚对苯二甲酸乙二醇酯(PET)塑料材料的迁移。目前的方法主要集中在总Sb含量,为其形成留下了一个关键的知识空白。这里,我们提出了一种新颖的分析方法,该方法利用前端色谱与电感耦合等离子体质谱(FC-ICP-MS)进行水中Sb(III)和Sb(V)的快速形态分析。通过多元数据分析,实现了FC-ICP-MS方法的系统优化,导致150s的分析时间非常短,检测限低于1ngkg-1。然后将优化的方法应用于表征PET浸出,揭示了塑料老化和制造过程的显着影响,不仅对释放的Sb总量,而且对浸出的Sb物种的性质。这些证据证明了FC-ICP-MS方法在解决这种环境问题方面的有效性,考虑到Sb形态分析的简单性,对新标准进行基准测试,成本效益,绿色,以及在环境和健康监测中的广泛适用性。
    Antimony (Sb) contamination poses significant environmental and health concerns due to its toxic nature and widespread presence, largely from anthropogenic activities. This study addresses the urgent need for an accurate speciation analysis of Sb, particularly in water sources, emphasizing its migration from polyethylene terephthalate (PET) plastic materials. Current methodologies primarily focus on total Sb content, leaving a critical knowledge gap for its speciation. Here, we present a novel analytical approach utilizing frontal chromatography coupled with inductively coupled plasma mass spectrometry (FC-ICP-MS) for the rapid speciation analysis of Sb(III) and Sb(V) in water. Systematic optimization of the FC-ICP-MS method was achieved through multivariate data analysis, resulting in a remarkably short analysis time of 150 s with a limit of detection below 1 ng kg-1. The optimized method was then applied to characterize PET leaching, revealing a marked effect of the plastic aging and manufacturing process not only on the total amount of Sb released but also on the nature of leached Sb species. This evidence demonstrates the effectiveness of the FC-ICP-MS approach in addressing such an environmental concern, benchmarking a new standard for Sb speciation analysis in consideration of its simplicity, cost effectiveness, greenness, and broad applicability in environmental and health monitoring.
    导出

    更多引用

    收藏

    翻译标题摘要

    我要上传

       PDF(Pubmed)

  • 文章类型: Journal Article
    这项研究为撒丁岛海峡深海海底宏观垃圾的时空趋势提供了新的见解,在地中海中部(意大利)。在884至1528m之间的深度进行了拖网调查,因此集中在研究最少的海洋环境之一。所有考虑的地点都没有垃圾,塑料在数字上占主导地位(57%的项目),其次是金属(11%)和玻璃(16%)。记录的密度和重量介于49.9和499项km-2和1.4和1052kgkm-2之间。在污染最严重的地方,收集在网中的垃圾的重量是底栖大型动物生物量的九倍,and,总的来说,在60%的运输中,宏观凋落物质量超过了收集的生物量。此外,我们报告说,在大型垃圾存在更严重的地方,大型动物被观察到更丰富。需要更多的研究来阐明这种相关性的性质,在海底大型垃圾积累的热点地区,生物群更为丰富。
    This study provides new insights onto spatial and temporal trends of seafloor macro-litter in the abyssal seafloor of Sardinian channel, in central western Mediterranean (Italy). Trawl surveys were conducted at depths between 884 and 1528 m, thus focusing on one of the least investigated marine environments. None of the considered sites was litter free, with plastics being numerically dominant (57% of items), followed by metal (11%) and glass (16%). Recorded densities and weight ranged between 49.9 and 499 items km-2 and 1.4 and 1052 kg km-2. In the most contaminated sites, the weight of the litter collected in nets represented up to nine times the biomass of benthic megafauna, and, overall, in 60% of hauls macro-litter mass outweighed the biomass collected. Moreover, we report that megafauna was observed to be more abundant in sites where macro-litter presence was more severe. More studies are needed to elucidate the nature of this correlation, with biota being more abundant in hotspots of accumulation of seafloor macro-litter.
    导出

    更多引用

    收藏

    翻译标题摘要

    我要上传

       PDF(Pubmed)

  • 文章类型: Journal Article
    基础设施通常是微塑料研究的限制因素,影响科学产出和监测数据的生产。因此,需要国际项目来促进国家和区域科学中心的合作和发展。制定了英联邦垃圾计划和海洋国家伙伴关系计划,以支持全球南方国家对进入海洋的塑料采取行动。建立了一个国际实验室网络,以提供基础设施和国家能力来收集和处理环境样品中的微塑料。实验室网络还扩展到包括东英吉利大学开发的网络,英国。所有实验室都配备了类似的收集设备,环境样品中微塑料的处理和分析。在实验室设置期间,还在国家提供了统一的协议和培训,以确保实验室之间质量控制产出的可比性。需要这样的大型网络来产生可比的基线和监测评估。
    Infrastructure is often a limiting factor in microplastics research impacting the production of scientific outputs and monitoring data. International projects are therefore required to promote collaboration and development of national and regional scientific hubs. The Commonwealth Litter Programme and the Ocean Country Partnership Programme were developed to support Global South countries to take actions on plastics entering the oceans. An international laboratory network was developed to provide the infrastructure and in country capacity to conduct the collection and processing of microplastics in environmental samples. The laboratory network was also extended to include a network developed by the University of East Anglia, UK. All the laboratories were provided with similar equipment for the collection, processing and analysis of microplastics in environmental samples. Harmonised protocols and training were also provided in country during laboratory setup to ensure comparability of quality-controlled outputs between laboratories. Such large networks are needed to produce comparable baseline and monitoring assessments.
    导出

    更多引用

    收藏

    翻译标题摘要

    我要上传

       PDF(Pubmed)

公众号