Heritage sites built with natural stone are at risk from fires, which can alter stone properties and compromise its structural integrity. Over 60 studies in the past three decades have examined fire impact on natural stone, providing insights for their prevention and restoration. The primary objectives are to develop effective strategies to mitigate fire risks, protect heritage structures, and ensure the preservation of our cultural legacy. Two noteworthy Portuguese limestones used as heritage building materials: Lioz (LL) and grey Ançã stone (GAS), were studied regarding the effect of high-temperature exposure for simulating fire at 200 °C, 400 °C and 600 °C, followed by cooling in water to reproduce fire extinguish in natural stone buildings. The findings provided insights into how the different temperatures impact the stone morphological, physical and mechanical properties. Color measurements (CIE L*a*b*) showed a color difference from 3 to 32 %; SEM-EDS confirmed microstructure modifications after fire exposure with cracks formation and intragranular porosity development. Among the diverse physical and mechanical properties of the stones, uniaxial compressive strength decreased from 1 to 33 %, Leeb D hardness decreased up to 12.2 %, lowering in open porosity was detected in the range 70-289 % and ultrasound speed propagation were significantly affected after thermal cycle at 600 °C with a negative variation reaching 49 %. Results from TGA show a loss of mass due to retained water (∼40 °C) and loss of hydration water at ∼ 120 °C in both limestones. The total mass loss (∼42-∼44 %) is associated with the loss of H2O, CO2. In conclusion, stones with higher toughness and compression strength exhibited reduced damage at high temperatures due to their enhanced resistance to fracturing under stress. As limestone\'s mechanical strength decreases under high temperatures, it\'s advisable to increase its thickness to ensure sufficient support for loads and intended conditions of use. The deficiency of analysis on limestone\'s mechanical decay from fire reveals a significant knowledge gap regarding the complete extent of damage and deterioration in stone heritage structures.

The development of deep high-temperature oil and gas reservoirs gives rise to a rise in reservoir temperature along with the depth of the oil reservoir, thereby imposing higher requirements on the heat resistance of fracturing fluid. Guar gum fracturing fluid has difficulty tolerating temperatures exceeding 160 °C, thereby demanding the development of corresponding cross-linking agents, temperature stabilizers, and other additives to enhance the thermal stability of the fracturing system. Considering the distinctive characteristics of deep and ultra-deep reservoirs, such as extreme burial depth (exceeding 6000 m), ultra-high temperature (higher than 160 °C), and high fracturing pressure, an experimental modification of a guar gum fracturing fluid system was carried out, specifically tailored for ultra-high temperatures. The experiment identified and selected individual agents for ultra-high temperature fracturing fluids, including crosslinking agents, thermal stabilizers, flowback aids, and clay inhibitors. Through rigorous experimentation, these key agents for an ultra-high temperature fracturing fluid system have been successfully developed, including the optimal thickener GBA1-2, crosslinking agent BA1-1, anti-swelling agent FB-1, and gel breaker TS-1. The evaluation of diverse additive dosages has facilitated the development of an optimal guar fracturing fluid system, which exhibits outstanding high-temperature resistance while minimizing damage and friction. The outcomes of our experiments indicate that even after subjecting our ultra-high temperature fracturing fluid to 2 h of shearing at 170 s-1 at 180 °C, its viscosity remained above 200 mPa s-a distinct proof of its superior performance in withstanding high temperatures. This achievement represents a substantial progress in providing a suitable fracturing fluid system for the transformation and stimulation of ultra-deep and ultra-high temperature reservoirs, and also lays a solid foundation for further exploration and application in related fields in the future.

To investigate the effects of high temperature and carbon fiber-bar reinforcement on the dynamic mechanical properties of concrete materials, a muffle furnace was used to treat two kinds of specimens, plain and carbon fiber-bar reinforced concrete, at high temperatures of 25, 200, 400 and 600 °C. Impact compression tests were carried out on two specimens after high-temperature exposure using a Hopkinson pressure bar (SHPB) test setup combined with a high-speed camera device to observe the crack extension process of the specimens. The effects of high temperature and carbon fiber-bar reinforcement on the peak stress, energy dissipation density, crack propagation and fractal dimension of the concrete were analyzed. The results showed that the corresponding peak strengths of the plain concrete specimens at 25, 200, 400, and 600 °C were 88.37, 93.21, 68.85, and 54.90 MPa, respectively, and the peak strengths after the high-temperature exposure first increased slightly and then decreased rapidly. The mean peak strengths corresponding to the carbon fiber-bar reinforced concrete specimens after high-temperature action at 25, 200, 400, and 600 °C are 1.13, 1.13, 1.21, and 1.19 times that of plain concrete, respectively, and the mean crushing energy consumption densities are 1.27, 1.31, 1.73, and 1.59 times that of plain concrete, respectively. The addition of carbon fiber-bar reinforcement significantly enhanced the impact resistance and energy dissipation of the concrete structure, and the higher the temperature was, the more significant the increase. An increase in temperature increases the number of crack extensions and width, and the high tensile strength of the carbon fiber-bar reinforcement and the synergistic effect with the concrete material reduce the degree of crack extension in the specimen. The fractal dimension of the concrete ranged from 1.92 to 2.68, that of the carbon fiber-bar reinforced concrete specimens ranged from 1.61 to 2.42, and the mean values of the corresponding fractal dimensions of the plain concrete specimens after high-temperature effects at 25, 200, 400, and 600 °C were 1.19, 1.21, 1.10, and 1.11 times those of the fiber-reinforced concrete specimens, respectively. The incorporation of carbon fiber-bar reinforcement reduces the degree of rupture and fragmentation of concrete under impact loading and improves the safety and stability of concrete structures.

Due to their high accuracy, excellent stability, minor size, and low cost, silicon piezoresistive pressure sensors are used to monitor downhole pressure under high-temperature, high-pressure conditions. However, due to silicon\'s temperature sensitivity, high and very varied downhole temperatures cause a significant bias in pressure measurement by the pressure sensor. The temperature coefficients differ from manufacturer to manufacturer and even vary from batch to batch within the same manufacturer. To ensure high accuracy and long-term stability for downhole pressure monitoring at high temperatures, this study proposes a temperature compensation method based on bilinear interpolation for piezoresistive pressure sensors under downhole high-temperature and high-pressure environments. A number of calibrations were performed with high-temperature co-calibration equipment to obtain the individual temperature characteristics of each sensor. Through the calibration, it was found that the output of the tested pressure measurement system is positively linear with pressure at the same temperatures and nearly negatively linear with temperature at the same pressures, which serves as the bias correction for the subsequent bilinear interpolation temperature compensation method. Based on this result, after least squares fitting and interpolating, a bilinear interpolation approach was introduced to compensate for temperature-induced pressure bias, which is easier to implement in a microcontroller (MCU). The test results show that the proposed method significantly improves the overall measurement accuracy of the tested sensor from 21.2% F.S. to 0.1% F.S. In addition, it reduces the MCU computational complexity of the compensation model, meeting the high accuracy demand for downhole pressure monitoring at high temperatures and pressures.

Carbon-fiber-reinforced polyetheretherketone (CF/PEEK) composites are widely utilized in aerospace, medical devices, and automotive industries, renowned for their superior mechanical properties and high-temperature resistance. Despite these advantages, the thermomechanical coupling behavior of CF/PEEK under dynamic loading conditions is not well understood. This study aims to explore the thermomechanical coupling effects of CF/PEEK at elevated strain rates, employing Hopkinson bar impact tests and scanning electron microscopy (SEM) for detailed characterization. Our findings indicate that an increase in temperature led to significant reductions in the yield strength, peak stress, and specific energy absorption of CF/PEEK, while fracture strain had no significant effect. For instance, at 200 °C, the yield strength, peak stress, and specific energy absorption decreased by 39%, 37%, and 38%, respectively, compared to their values at 20 °C. Furthermore, as the strain rate increased, the yield strength, peak stress, specific energy absorption, and fracture strain all exhibited strain-hardening effects. However, as the strain rate further increased, above 4000 s-1, the enhancing effect of the strain rate on the yield strength and peak stress gradually diminished. The interaction of the temperature and strain rate significantly affected the mechanical performance of CF/PEEK under high-speed impact conditions. While the strain rate generally enhanced these properties, the strain-hardening effect on the yield strength weakened as the temperature increased, and both the temperature and strain rate contributed to the increase in specific energy absorption. Microdamage mechanism analysis revealed that interface debonding and sliding between the fibers and the matrix were more pronounced under static compression than under dynamic compression, thereby diminishing the efficiency of stress transfer. Additionally, higher temperatures caused the PEEK matrix to soften and exhibit increased viscoelastic behavior, which in turn affected the material\'s toughness and the mechanisms of stress transfer. These insights hold substantial engineering significance, particularly for the optimization of CF/PEEK composite design and applications in extreme environments.

High-strength concrete (HSC) boasts excellent compressive strength and durability, making it a popular choice in various engineering applications. However, under the impact of high temperatures, HSC tends to crack easily, so it is combined with polyvinyl alcohol fiber (PVA fiber) to explore its engineering application prospect. This paper investigated the physical and mechanical characteristics of HSC reinforced with PVA fibers subjected to different heating temperatures and cooling techniques. The experimental results reveal a correlation between rising temperatures and observable changes in the specimens: a progressively lighter surface hue, an augmented frequency of cracking, and a considerable escalation in the mass loss rate, particularly after the temperature exceeds 400 °C. Regarding mechanical properties, the dynamic elastic modulus and compressive and flexural strength all decrease as the heating temperature increases. As the amount of PVA fiber rises while maintaining a steady temperature, these measurements initially show an increase followed by a decrease. The fiber contents yielding the best compressive and flexural strength are 0.2% and 0.3%, in that order. Considering the influence of cooling methods, water spray cooling has a greater impact on physical and mechanical properties than natural cooling. Furthermore, SEM was employed to scrutinize the microstructure of HSC, enhancing comprehension of the alterations in its physical and mechanical characteristics. The findings of this research offer significant information regarding the high-temperature behavior of HSC, serving as a valuable resource for guiding the design, building, and upkeep of structures that incorporate HSC. Additionally, this study will aid in advancing the progress and utilization of HSC technology.

Cattle are increasingly exposed to hot temperatures as a result of climate change, and a better understanding of behavioural responses could be beneficial for the diagnosis of heat loads. The changes in the positioning of key body parts, feeding behaviour, body maintenance, and respiratory dynamics were assessed in 24 Black Angus steers individually exposed to hot conditions and fed a finisher diet based on cereal grain or a substituted diet (8% of the grain replaced by an isoenergetic amount of lucerne hay). Increased respiration rate during the heat load period, compared to the recovery period, was associated with increased stepping, especially by left limbs. Cattle also reduced eating, grooming, and scratching during the heat load period. The lowered head, backward ear, vertical or raised tail, and increased respiration rate and panting persisted in cattle during the heat load period. Cattle on the cereal grain diet stood for longer and were more likely to hold their ears backward and tail vertical than those on the substituted diet. We conclude that these behaviours could be used to detect animals that are most affected and that changing from a cereal-based diet to a substituted diet containing a higher amount of fibre, such as lucerne hay, can reduce hyperthermic behavioural responses to a heat load.

To improve the stability of high-temperature water electrolysis, I prepared membrane electrode assemblies (MEAs) using a decal method and investigated their water electrolysis properties. Nafion 115 and crosslinked sulfonated polyphenylsulfone (CSPPSU) membranes were used. IrO2 was used as the oxygen evolution reaction (OER) catalyst, and Pt/C was used as the hydrogen evolution reaction (HER) catalyst. The conductivity of the CSPPSU membrane at 80 °C and 90% RH (relative humidity) is about four times lower than that of the Nafion 115 membrane. Single-cell water electrolysis was performed while measuring the current density and performing electrochemical impedance spectroscopy (EIS) at cell temperatures from 80 to 150 °C and the stability of the current density over time at 120 °C and 1.7 V. The current density of water electrolysis using Nafion 115 and CSPPSU membranes at 150 °C and 2 V was 1.2 A/cm2 for both. The current density of the water electrolysis using the CSPPSU membrane at 120 °C and 1.7 V was stable for 40 h. The decal method improved the contact between the CSPPSU membrane and the catalyst electrode, and a stable current density was obtained.

Building fire will seriously threaten human safety. Silica aerogel with low thermal conductivity and thermal stability as fire-retardant material has been widely used in building fireproof structures. However, the natural fragility of silica aerogel will limit its application. In this work, the effects of faults on the thermal stability of silica aerogel are studied by molecular dynamics simulation with large simulation time (20 ns). Additionally, the atomic model of silica aerogel with random faults is built by a straining structure (tensile strains are 10%, 20%, 30%, and 40%). It is found that when the tensile strain is less than 20%, the silica backbone can remain stable. The effects of faults on the thermal stability can be neglected. The silica backbone thermally vibrates during the heating process. However, when the tensile strain is over 30%, it is observed that the faults will enhance the silica backbone merging. Silica aerogel can be stable under 800 K. It is believed that the results of this study will pave the way for the development of fireproof materials.

The residual oil left behind after water flooding in petroleum reservoirs can be mobilized by surfactant formulations that yield ultralow interfacial tension (IFT) with oil. However, finding ultralow IFT surfactant formulations is difficult for high-temperature, off-shore, carbonate reservoirs. These reservoirs are often water-flooded with seawater (with a lot of divalent ions), which is often incompatible with many surfactants at high temperatures. The goal of this research is to develop a surfactant formulation for an off-shore carbonate reservoir at 100°C previously flooded by seawater. Surfactant-oil-brine phase behavior was studied for formulations, starting from a single surfactant to mixtures of surfactants and a co-solvent. Mixtures of three surfactants and one co-solvent were needed to produce ultralow IFT formulations for the oil of interest. The surfactant system with polymer mobility control was tested in crushed reservoir rock packs. The cumulative oil recovery was >99% for the surfactant-polymer (SP) flood with an optimal salinity gradient. The constant salinity SP floods with seawater increased oil recovery significantly beyond the water flood (cumulative oil recovery >91%), even though the recovery was lower than that of the optimal salinity gradient SP flood. Our experimental work demonstrates the effectiveness of the surfactant formulation for a high-temperature carbonate reservoir at seawater salinity.