high temperature

高温
  • 文章类型: Journal Article
    为研究高温和碳纤维钢筋对混凝土材料动态力学性能的影响,马弗炉被用来处理两种标本,普通和碳纤维钢筋混凝土,在25、200、400和600°C的高温下。使用霍普金森压杆(SHPB)测试装置结合高速摄像装置,对高温暴露后的两个试样进行冲击压缩试验,观察试样的裂纹扩展过程。高温和碳纤维增强对峰值应力的影响,能量耗散密度,分析了混凝土的裂纹扩展和分形维数。结果表明,在25、200、400和600°C下,素混凝土试件的相应峰值强度分别为88.37、93.21、68.85和54.90MPa,分别,高温暴露后的峰强度先略有增加,然后迅速下降。在25、200、400和600°C高温作用后,对应于碳纤维钢筋混凝土试样的平均峰值强度是普通混凝土的1.13、1.13、1.21和1.19倍,分别,平均破碎能耗密度为普通混凝土的1.27、1.31、1.73和1.59倍,分别。碳纤维钢筋的加入显著增强了混凝土结构的抗冲击能力和耗能能力,温度越高,增长越显著。温度升高会增加裂纹扩展的数量和宽度,碳纤维钢筋的高抗拉强度和与混凝土材料的协同作用降低了试件的裂纹扩展程度。混凝土的分形维数在1.92至2.68之间,碳纤维钢筋混凝土试样的分形维数在1.61至2.42之间,在25、200、400和600°C下高温作用后,素混凝土试样的相应分形维数的平均值分别是纤维增强混凝土试样的1.19、1.21、1.10和1.11倍,分别。碳纤维筋的掺入降低了混凝土在冲击荷载作用下的破裂和破碎程度,提高了混凝土结构的安全性和稳定性。
    To investigate the effects of high temperature and carbon fiber-bar reinforcement on the dynamic mechanical properties of concrete materials, a muffle furnace was used to treat two kinds of specimens, plain and carbon fiber-bar reinforced concrete, at high temperatures of 25, 200, 400 and 600 °C. Impact compression tests were carried out on two specimens after high-temperature exposure using a Hopkinson pressure bar (SHPB) test setup combined with a high-speed camera device to observe the crack extension process of the specimens. The effects of high temperature and carbon fiber-bar reinforcement on the peak stress, energy dissipation density, crack propagation and fractal dimension of the concrete were analyzed. The results showed that the corresponding peak strengths of the plain concrete specimens at 25, 200, 400, and 600 °C were 88.37, 93.21, 68.85, and 54.90 MPa, respectively, and the peak strengths after the high-temperature exposure first increased slightly and then decreased rapidly. The mean peak strengths corresponding to the carbon fiber-bar reinforced concrete specimens after high-temperature action at 25, 200, 400, and 600 °C are 1.13, 1.13, 1.21, and 1.19 times that of plain concrete, respectively, and the mean crushing energy consumption densities are 1.27, 1.31, 1.73, and 1.59 times that of plain concrete, respectively. The addition of carbon fiber-bar reinforcement significantly enhanced the impact resistance and energy dissipation of the concrete structure, and the higher the temperature was, the more significant the increase. An increase in temperature increases the number of crack extensions and width, and the high tensile strength of the carbon fiber-bar reinforcement and the synergistic effect with the concrete material reduce the degree of crack extension in the specimen. The fractal dimension of the concrete ranged from 1.92 to 2.68, that of the carbon fiber-bar reinforced concrete specimens ranged from 1.61 to 2.42, and the mean values of the corresponding fractal dimensions of the plain concrete specimens after high-temperature effects at 25, 200, 400, and 600 °C were 1.19, 1.21, 1.10, and 1.11 times those of the fiber-reinforced concrete specimens, respectively. The incorporation of carbon fiber-bar reinforcement reduces the degree of rupture and fragmentation of concrete under impact loading and improves the safety and stability of concrete structures.
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  • 文章类型: Journal Article
    碳纤维增强聚醚醚酮(CF/PEEK)复合材料广泛应用于航空航天,医疗器械,和汽车行业,以其卓越的机械性能和耐高温性而闻名。尽管有这些优势,动态载荷条件下CF/PEEK的热机械耦合行为尚不清楚。本研究旨在探讨CF/PEEK在高应变率下的热机械耦合效应。采用霍普金森杆冲击测试和扫描电子显微镜(SEM)进行详细表征。我们的发现表明,温度的升高导致屈服强度的显着降低,峰值应力,和CF/PEEK的比能量吸收,而断裂应变没有显著影响。例如,在200°C,屈服强度,峰值应力,比能量吸收下降了39%,37%,38%,分别,与它们在20°C下的值相比。此外,随着应变率的增加,屈服强度,峰值应力,比能量吸收,和断裂应变均表现出应变硬化效应。然而,随着应变率的进一步增加,4000s-1以上,应变速率对屈服强度和峰值应力的增强作用逐渐减弱。在高速冲击条件下,温度和应变率的交互作用显著影响了CF/PEEK的力学性能。虽然应变率通常增强了这些性能,随着温度的升高,应变硬化对屈服强度的影响减弱,温度和应变率都有助于增加比能量吸收。微损伤机理分析表明,纤维与基体之间的界面脱粘和滑动在静态压缩下比在动态压缩下更为明显。从而降低了应力传递的效率。此外,较高的温度导致PEEK基质软化并表现出增加的粘弹性行为,进而影响材料的韧性和应力传递机制。这些见解具有重大的工程意义,特别是CF/PEEK复合材料的优化设计和在极端环境中的应用。
    Carbon-fiber-reinforced polyetheretherketone (CF/PEEK) composites are widely utilized in aerospace, medical devices, and automotive industries, renowned for their superior mechanical properties and high-temperature resistance. Despite these advantages, the thermomechanical coupling behavior of CF/PEEK under dynamic loading conditions is not well understood. This study aims to explore the thermomechanical coupling effects of CF/PEEK at elevated strain rates, employing Hopkinson bar impact tests and scanning electron microscopy (SEM) for detailed characterization. Our findings indicate that an increase in temperature led to significant reductions in the yield strength, peak stress, and specific energy absorption of CF/PEEK, while fracture strain had no significant effect. For instance, at 200 °C, the yield strength, peak stress, and specific energy absorption decreased by 39%, 37%, and 38%, respectively, compared to their values at 20 °C. Furthermore, as the strain rate increased, the yield strength, peak stress, specific energy absorption, and fracture strain all exhibited strain-hardening effects. However, as the strain rate further increased, above 4000 s-1, the enhancing effect of the strain rate on the yield strength and peak stress gradually diminished. The interaction of the temperature and strain rate significantly affected the mechanical performance of CF/PEEK under high-speed impact conditions. While the strain rate generally enhanced these properties, the strain-hardening effect on the yield strength weakened as the temperature increased, and both the temperature and strain rate contributed to the increase in specific energy absorption. Microdamage mechanism analysis revealed that interface debonding and sliding between the fibers and the matrix were more pronounced under static compression than under dynamic compression, thereby diminishing the efficiency of stress transfer. Additionally, higher temperatures caused the PEEK matrix to soften and exhibit increased viscoelastic behavior, which in turn affected the material\'s toughness and the mechanisms of stress transfer. These insights hold substantial engineering significance, particularly for the optimization of CF/PEEK composite design and applications in extreme environments.
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  • 文章类型: Journal Article
    C2光合作用是光合途径,其中在叶束鞘(BS)组织中增强了光呼吸CO2的释放和固定。C2光合作用的演变被认为是C4光合作用起源的重要一步,强调研究C2进化的重要性。在这项研究中,生理,解剖学,超微结构,在6种非C4Tribulus物种和4种C4Tribulus物种中研究了叶片光合组织的免疫组织化学特性。在42°C时,T.cristatus在没有呼吸(C*)的情况下表现出21µmolmol-1的光合CO2补偿点,低于73µmolmol-1的C3平均C*。Tribulusastrocarpus在42°C时的C*值为55µmolmol-1,介于C3物种和C2T.cristatus之间。甘氨酸脱羧酶(GDC)在BS组织中的分配与较低的C*相关。Tribuluscrystatus和T.astrocarpus将其GDC的86%和30%分配给BS组织,分别,远高于11%的C3平均值。因此,Tribulusastrocarpus表现出较弱的C2(称为sub-C2)表型。线粒体向BS的分配增加,BS细胞的长宽比降低,存在于非C4物种中,表明在C2和C4进化中的潜在作用。
    C2 photosynthesis is a photosynthetic pathway in which photorespiratory CO2 release and refixation are enhanced in leaf bundle sheath (BS) tissues. The evolution of C2 photosynthesis has been hypothesized to be a major step in the origin of C4 photosynthesis, highlighting the importance of studying C2 evolution. In this study, physiological, anatomical, ultrastructural, and immunohistochemical properties of leaf photosynthetic tissues were investigated in six non-C4 Tribulus species and four C4 Tribulus species. At 42°C, T. cristatus exhibited a photosynthetic CO2 compensation point in the absence of respiration (C*) of 21 µmol mol-1, below the C3 mean C* of 73 µmol mol-1. Tribulus astrocarpus had a C* value at 42°C of 55 µmol mol-1, intermediate between the C3 species and the C2 T. cristatus. Glycine decarboxylase (GDC) allocation to BS tissues was associated with lower C*. Tribulus cristatus and T. astrocarpus allocated 86% and 30% of their GDC to the BS tissues, respectively, well above the C3 mean of 11%. Tribulus astrocarpus thus exhibits a weaker C2 (termed sub-C2) phenotype. Increased allocation of mitochondria to the BS and decreased length-to-width ratios of BS cells, were present in non-C4 species, indicating a potential role in C2 and C4 evolution.
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  • 文章类型: Journal Article
    高强度混凝土(HSC)具有很高的抗压强度,高密度,出色的耐用性,和抗渗性,但其变形能力较弱。添加纤维可以改善HSC的物理和机械性能。此外,HSC结构可能面临火灾威胁。在灭火过程中,由于不同部位与水的接触条件不同,高温混凝土的破坏机理复杂。因此,有必要对纤维增强HSC在高温作用后的不同冷却方式下的行为进行针对性的研究。在本文中,选择聚乙烯醇纤维(PVA纤维)加入到HSC中进行高温实验研究,为了探索明显的变化,故障模式,不同冷却方式对纤维增强HSC的质量损失率和残余抗压强度和抗折强度的影响。测试结果表明,随着加热温度的升高,样品表面的颜色从深蓝灰色过渡到白色,试样表面裂纹数量逐渐增加。随着加热温度的升高,机械强度逐渐降低。在一致的加热温度下,机械强度最初上升,然后随着纤维含量的增加而下降。在PVA纤维含量为0.2%和0.3%时,获得了最大的抗压强度和抗弯强度,分别。对于不同的温度和纤维含量,自然冷却后的机械强度一般高于浸泡冷却后的机械强度。此外,进行了X射线多晶衍射(XRD)和扫描电子显微镜(SEM)测试,以分析高温暴露后纤维增强的HSC的组成变化和微观结构。伴随着对影响物理和机械性能变化的因素的解释。因此,这项研究的结果可以为HSC在工程结构中的应用提供有价值的参考,并有助于HSC技术的进步。
    High-strength concrete (HSC) has a high compressive strength, high density, excellent durability, and seepage resistance, but its deformation ability is weak. Adding fibers can improve the physical and mechanical properties of HSC. Additionally, the HSC structure may face the threat of fire. In the process of fire extinguishing, the damage mechanism of high-temperature-resistant concrete is complicated due to the different contact conditions with water at different locations. Hence, it is essential to conduct pertinent research on the behavior of fiber-reinforced HSC with different cooling methods after high-temperature action. In this paper, polyvinyl alcohol fiber (PVA fiber) was selected to be added into the HSC to carry out high-temperature experimental research, so as to explore the apparent changes, failure pattern, and mass loss rate of the fiber-reinforced HSC using different cooling methods and analyze the influence of its residual compressive strength and flexural strength. The test results suggest that, with the increase in heating temperature, the color of the specimen\'s surface transitions from dark blue-gray to white, and the quantity of surface cracks on the specimen gradually rises. The mechanical strength gradually decreases as the heating temperature increases. At a consistent heating temperature, the mechanical strength initially rises, and then falls with an increase in fiber content. The maximum compressive strength and flexural strength were achieved at PVA fiber contents of 0.2% and 0.3%, respectively. For different temperatures and fiber contents, the mechanical strength after natural cooling is generally higher than that after immersion cooling. In addition, X-ray polycrystalline diffractometry (XRD) and scanning electron microscopy (SEM) tests were conducted to analyze the compositional alterations and microstructure of the fiber-reinforced HSC following high-temperature exposure, accompanied by an explanation of the factors influencing the alterations in the physical and mechanical properties. Therefore, the findings of this study can serve as a valuable reference for the utilization of HSC in engineering structures and contribute to the advancement of HSC technology.
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  • 文章类型: Journal Article
    从了解地壳和俯冲带Na辅助碳循环的地球化学过程的角度出发,研究高P-T条件下Na碳酸盐稳定性及其在含水碳酸盐流体中的转化是相关的。在高P-T条件下对金刚石砧室(DAC)中含Na的碳酸盐-水-Fe-金属系统的原位拉曼研究表明,碳酸盐分解时会形成甲酸盐和其他有机化合物,这与碳酸盐在干燥中的行为不同系统。另外使用XRD和FTIR方法来确定相组成。含水流体中的含钠碳酸盐(NahcoliteNaHCO3,短铁矿Na2Ca2(CO3)3和松质岩Na7Ca[(CO3)1.5Al6Si6O24]·2H2O)在中等P-T参数下分解形成简单的碳酸盐和甲酸盐(作为主要的有机分子)(高于0.2GPa,200°C)。我们的实验结果直接证实了Horita和Berndt(Science,1999)关于碳酸盐-水-金属体系中有机甲酸酯的可能产率。在Fe金属存在的情况下,水性流体中的NahcoliteNaHCO3分解为无水相:natriteγ-Na2CO3,菱铁矿,磁铁矿(由于Fe钢垫片的溶解),甲酸钠和可能的甲酸钠和甲酸甲酯的有机分子结晶溶剂化物。短铁矿衰变为无水相:文石CaCO3,Na-Ca-甲酸盐和无定形相。Cancrinite分解为未识别的碳酸盐-铝硅酸盐相,Na-Ca-甲酸盐和未知的有机分子晶体。由于DAC中使用的Fe钢垫片的溶解,该系统中还形成了磁铁矿。本研究为地壳和上地幔中碳酸盐对有机物的非生物形成过程提供了新的见解。
    The study of Na-carbonates stability and their transformations in aqueous carbonate fluid under high P-T conditions is relevant from the point of view of the understanding geochemical processes of the Na-assisted carbon circulation in the Earth\'s crust and subduction zones. In situ Raman study of Na-bearing carbonate-water-Fe-metal system in diamond anvil cell (DAC) at high P-T conditions revealed that carbonates decompose with abiogenic formation of formates and other organic compounds that differs from behavior of carbonates in dry system. XRD and FTIR methods have been used additionally to determine the phase composition. Na-bearing carbonates (nahcolite NaHCO3, shortite Na2Ca2(CO3)3 and cancrinite Na7Ca[(CO3)1.5Al6Si6O24]⋅2H2O) in aqueous fluid decompose to form simple carbonates and formates (as dominant organic molecules) at moderate P-T parameters (above ∼0.2 GPa, 200 °C). Our experimental results directly confirm the hypothesis of Horita and Berndt (Science, 1999) about possible yield of organic formates in the carbonate-water-metal system. Nahcolite NaHCO3 in aqueous fluid in the presence of Fe metal decomposes into anhydrous phases: natrite γ-Na2CO3, siderite, magnetite (due to dissolution of Fe steel gasket), Na-formate and likely organic molecular crystalline solvate of Na-formate and methyl formate. Shortite decays into anhydrous phases: aragonite CaCO3, Na-Ca-formates and an amorphous phase. Cancrinite decomposes to unidentified carbonate-alumonosilicate phases, Na-Ca-formates and unknown organic molecular crystal. Magnetite is also formed in this system due to dissolution of Fe steel gasket used in DAC. The present study provides a new insight in processes of abiogenic formation of organic matter from carbonates in the crust and upper mantle.
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  • 文章类型: Journal Article
    菊花是世界上最受欢迎的切花,它们的颜色是一个关键的装饰特征。这些颜色的形成会受到高温的影响。然而,高温胁迫下控制菊花颜色褪色的调控机制尚不清楚。本研究调查了高温对紫菊颜色和生化反应的影响。四个紫色菊花品种暴露于常温和高温条件下。高温胁迫在紫菊品种中引起了不同的响应。\'紫凤车\'和\'ChrystalRegal\'保持颜色稳定性,而“子红拓”和“子连”表现出明显的褪色,特别是在早期开花阶段。这种褪色与酶活性降低有关,特别是查尔酮异构酶(CHI),二氢黄酮醇4-还原酶(DFR),和花青素合成酶(ANS),表明在热应激下颜色发展的关键时期。此外,紫连的褪色与过氧化物酶(POD)和多酚氧化酶(PPO)活性的增加密切相关。相反,β-葡萄糖苷酶(βG)活性的降低可能对“子风车”的颜色稳定性有很大贡献。基因Cse_sc027584.1_g010.1(PPO)和Cse_sc031727.1_g010.1(POD)可能有助于高温条件下\'紫红拓\'和\'紫莲\'花瓣中花青素的降解,同时在开花早期保持“紫风车”和“水晶富豪”中花色苷的稳定性。这项研究的发现为菊花花色响应高温胁迫的生理生化机制提供了新的见解。
    Chrysanthemums are among the world\'s most popular cut flowers, with their color being a key ornamental feature. The formation of these colors can be influenced by high temperatures. However, the regulatory mechanisms that control the fading of chrysanthemum flower color under high-temperature stress remain unclear. This study investigates the impact of high temperatures on the color and biochemical responses of purple chrysanthemums. Four purple chrysanthemum varieties were exposed to both normal and elevated temperature conditions. High-temperature stress elicited distinct responses among the purple chrysanthemum varieties. \'Zi Feng Che\' and \'Chrystal Regal\' maintained color stability, whereas \'Zi Hong Tuo Gui\' and \'Zi lian\' exhibited significant color fading, particularly during early bloom stages. This fading was associated with decreased enzymatic activities, specifically of chalcone isomerase (CHI), dihydroflavonol 4-reductase (DFR), and anthocyanidin synthase (ANS), indicating a critical period of color development under heat stress. Additionally, the color fading of \'Zi Lian\' was closely related to the increased activity of the peroxidase (POD) and polyphenol oxidase (PPO). Conversely, a reduction in β-glucosidase (βG) activity may contribute significantly to the color steadfastness of \'Zi Feng Che\'. The genes Cse_sc027584.1_g010.1 (PPO) and Cse_sc031727.1_g010.1 (POD) might contribute to the degradation of anthocyanins in the petals of \'Zi Hong Tuo Gui\' and \'Zi Lian\' under high-temperature conditions, while simultaneously maintaining the stability of anthocyanins in \'Zi Feng Che\' and \'Chrystal Regal\' at the early bloom floral stage. The findings of this research provide new insights into the physiological and biochemical mechanisms by which chrysanthemum flower color responds to high-temperature stress.
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  • 文章类型: Journal Article
    关于对海鲜质量的影响,热应激越来越受到关注。然而,热应激对海鲜感官特性的影响仍然未知。在这项研究中,使用电子鼻表征了用慢性热应激(30°C)处理8周的新鲜牡蛎(Crassostreaariakensis)的感官特性,电子舌,感官评价,HS-SPME-GC-MS,LC-MS和转录组学。总的来说,慢性热应激降低了牡蛎的整体感官特性。构建的代谢网络。根据423个差异代谢物和166个差异表达基因的富集结果,结果表明,慢性热应激对牡蛎感官特性的负面影响与氧化应激有关,蛋白质降解,脂质氧化,和核苷酸代谢。研究结果为热应激对牡蛎感官特性的影响提供了有价值的见解,这对于确保高质量海鲜的可持续供应和维护食品安全至关重要。
    Heat stress has received growing concerns regarding the impact on seafood quality. However, the effects of heat stress on the sensory properties of seafood remain unknown. In this study, the sensory properties of fresh oyster (Crassostrea ariakensis) treated with chronic heat stress (30 °C) for 8 weeks were characterized using electronic nose, electronic tongue, sensory evaluation, HS-SPME-GC-MS, LC-MS and transcriptomics. Overall, chronic heat stress reduced the overall sensory properties of oysters. The metabolic network constructed. based on enrichment results of 423 differential metabolites and 166 differentially expressed genes, showed that the negative effects of chronic heat stress on the sensory properties of oysters were related to oxidative stress, protein degradation, lipid oxidation, and nucleotide metabolism. The results of the study provide valuable insights into the effects of heat stress on the sensory properties of oysters, which are important for ensuring a sustainable supply of high-quality seafood and maintaining food safety.
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  • 文章类型: Journal Article
    热成形是提高超薄板材成形性的有效途径,如不锈钢和纯钛。然而,在热成形过程中,工具和高温金属板之间的摩擦系数增加会对材料流动产生负面影响,可能导致严重的局部变薄甚至开裂。这项研究探讨了0.1毫米厚的铁素体不锈钢(FSS)和商业纯钛(CP-Ti)板材在高温下的摩擦行为。开发了一种摩擦测试设备来测量这些金属板从室温(25°C)到600°C的摩擦系数。FSS片的摩擦系数随温度单调增加,而CP-Ti片的含量先增加后减少。摩擦后的显微镜检查表明,摩擦块与不锈钢摩擦时,在摩擦块的表面上形成了堆积的边缘,有助于较高的摩擦系数。这项研究为理解超薄金属板热成形过程中的摩擦行为提供了基础。
    Hot forming is an effective approach for improving the formability of ultrathin metal sheets, such as those made of stainless steel and pure titanium. However, the increased friction coefficient between the tool and the high-temperature metal sheet negatively affects material flow during hot forming, potentially resulting in severe local thinning or even cracking. This study explores the frictional behavior of 0.1 mm thick ferritic stainless steel (FSS) and commercially pure titanium (CP-Ti) sheets at elevated temperatures. A friction testing apparatus was developed to measure the friction coefficients of these metal sheets from room temperature (25 °C) up to 600 °C. The friction coefficient of the FSS sheet increased monotonically with temperature, whereas that of the CP-Ti sheet first increased and then decreased. Post-friction testing microscopic examination demonstrated that built-up edges formed on the surfaces of the friction blocks when rubbed against the stainless steel, contributing to the higher friction coefficients. This study provides a foundation for understanding frictional behavior during the hot forming of ultrathin metal sheets.
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  • 文章类型: Journal Article
    在这项研究中,首先研究了N80和TP125V钢在含CO2-O2的页岩气田产出水中的腐蚀行为。此外,研究了这些钢的局部腐蚀,以阐明好氧和缺氧对钢腐蚀的影响。结果表明,N80和TP125V钢在好氧条件下的腐蚀速率低于CO2-O2存在下的腐蚀速率。具体来说,在100°C的温度和CO2-O2环境中溶解氧(DO)浓度为4mg/L时,N80和TP125V钢表现出最高的腐蚀速率,值为0.13mm/y和0.16mm/y,分别,由具体的重量损失测量确定。相反,在有氧条件下,这些速率降低到0.022mm/y和0.049mm/y。此外,在CO2-O2环境中也观察到DO浓度为4mg/L的N80和TP125V钢的严重局部腐蚀。最后,很明显,点蚀是影响页岩气田产出水中N80和TP125V钢的主要腐蚀类型。
    In this study, the corrosion behavior of N80 and TP125V steels was delved firstly into produced water from shale gas fields containing CO2-O2. Moreover, the localized corrosion of these steels was investigated to elucidate the effects of aerobic and anoxic on steel corrosion. The results indicated that the corrosion rates of N80 and TP125V steels under aerobic conditions were lower compared to those in the presence of CO2-O2. Specifically, at temperature of 100 °C and with dissolved oxygen (DO) concentration of 4 mg/L in the CO2-O2 environment, the N80 and TP125V steels exhibited the highest corrosion rate, with values of 0.13 mm/y and 0.16 mm/y, respectively, as determined by specific weight loss measurements. Conversely, these rates decreased to 0.022 mm/y and 0.049 mm/y under aerobic conditions. Furthermore, severe localized corrosion of N80 and TP125V steels with a DO concentration of 4 mg/L was also observed in the CO2-O2 environment. Finally, it was evident that pitting corrosion is the predominant type of corrosion affecting N80 and TP125V steels in the produced water from shale gas fields.
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  • 文章类型: Journal Article
    Li4SiO4似乎是燃烧后捕集CO2的优异吸附剂。我们的工作有助于了解天然阿尔及利亚硅藻土作为SiO2来源在高温下合成Li4SiO4以捕获CO2的作用。为此,我们使用各种摩尔%(化学计量和过量)的煅烧天然硅藻土和纯SiO2。要选择最佳构图,在N2中的各种CO2流量下,使用TGA测量获得在500°C下在制备的Li4SiO4上的CO2吸附等温线。在硅藻土(10%ND-LS)中具有10%摩尔SiO2的吸附剂表现出最佳的CO2吸收,可能是由于各种因素,如不同的二次相的含量。在400至500°C下对该选择的10%ND-LS和具有用硅藻土和纯SiO2获得的化学计量组成的那些进行比较研究。获得的等温线显示了CO2吸附的吸热特性。此外,等排热的演化突出了所涉及的CO2/Li4SiO4相互作用的性质,通过考虑双壳机制。最后,实验吸附等温线面对一些众所周知的吸附模型,以解释在我们制备的吸附剂上发生的现象。Freundlich和Jensen-Seaton模型与实验结果具有更好的相关性。
    The Li4SiO4 seems to be an excellent sorbent for CO2 capture at post-combustion. Our work contributes to understanding the effect of the natural Algerian diatomite as a source of SiO2 in the synthesis of Li4SiO4 for CO2 capture at high temperature. For this purpose, we use various molar % (stoichiometric and excess) of calcined natural diatomite and pure SiO2. To select the best composition, CO2 sorption isotherms at 500 °C on the prepared Li4SiO4 are obtained using TGA measurements under various flows of CO2 in N2. The sorbent having 10% molar SiO2 in diatomite (10%ND-LS) exhibits the best CO2 uptake, probably due to various factors such as the content of the different secondary phases. A comparative study was performed at 400 to 500 °C on this selected 10%ND-LS and those with stoichiometric composition obtained with diatomite and pure SiO2. The obtained isotherms show the endothermic character of CO2 sorption. In addition, the evolution of isosteric heat highlights the nature of the involved CO2/Li4SiO4 interactions, by considering the double-shell mechanism. Finally, the experimental sorption isotherms are confronted with some well-known adsorption models to explain the phenomenon occurring over our prepared sorbents. Freundlich and Jensen-Seaton models present a better correlation with the experimental results.
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