SEM

SEM
  • 文章类型: Journal Article
    背景:该理论模型基于社会交换理论的原则,以审查组织良性与工作绩效之间的联系,以及组织公民行为的中介作用和工作场所排斥的调节作用。在巴基斯坦进行了一项调查,从为多家私营和商业银行工作的486名员工那里收集数据。
    方法:将软问卷和硬问卷分发给参与者,使用社交媒体平台进行软问卷,并与员工开会进行硬问卷。在数据收集中采用了7点李克特量表,变量的测量是从可靠和有效的来源进行调整的。进行人口统计学分析以总结从参与者收集的样本。使用SPSS对人口统计结果进行分析,而测量模型和路径分析是使用结构方程建模与智能PLS-4进行的。
    结果:研究结果表明,组织美德与工作绩效之间存在显著的正相关关系,以组织公民行为为中介。此外,在组织公民行为对组织良性与工作绩效之间关系的中介中,观察到工作场所排斥的负调节作用。
    结论:研究结果有助于在巴基斯坦银行业实施社会交换理论和相关概念,为组织内部实施良性做法和阻止银行排斥行为以提高整体绩效提供实用指导。该研究表明,可以制定有关在组织中实施良性做法的政策,通过为社交聚会和培训员工提供平台,可以避免工作场所排斥。管理者应采用适当的领导风格和相关的沟通模式来影响组织氛围,这也有助于减少排斥在组织中的影响。此外,应建立完全保密的投诉小组,以减少排斥。
    BACKGROUND: This theoretical model has been drawn on principles of social exchange theory to scrutinize the connection between organizational virtuousness and job performance with the mediating role of Organizational citizenship behavior and moderating role of workplace ostracism. A survey was conducted in Pakistan, gathering data from 486 employees working for various private and commercial banks.
    METHODS: Soft and hard questionnaires were distributed to the participants, with social media platforms used for the soft questionnaires and meetings with employees for the hard questionnaires. A 7-point Likert scale was employed in data collection, and measures for the variables were adapted from reliable and valid sources. A demographic analysis was performed to summarize the sample collected from participants. The demographics results were analyzed using SPSS, while the measurement model and path analysis were conducted using Structural Equational Modeling with Smart PLS-4.
    RESULTS: The study\'s findings showed a significant and positive relationship between organizational virtuousness and job performance, with organizational citizenship behavior serving as a mediator. Additionally, a negative moderation of workplace ostracism was observed in the mediation of organizational citizenship behavior toward the relationship between organizational virtuousness and job performance.
    CONCLUSIONS: The study\'s results contribute to the implementation of social exchange theory and related concepts in the banking sector of Pakistan, providing practical guidance for implementing virtuous practices within organizations and discouraging ostracism in banks to enhance overall performance. The study suggests that policies regarding the implementation of virtuous practices in organizations can be established, and workplace ostracism can be avoided by providing a platform for social gatherings and training employees. Managers should adopt appropriate leadership styles and relevant communication patterns to impact the organizational climate which can also help reduce the influence of ostracism in the organization. Additionally, a complaint cell should be established with complete confidentiality to reduce ostracism.
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  • 文章类型: Journal Article
    提高学习参与度是在线教育的关键挑战。虽然先前的研究强调了反馈的重要性,最近的研究已经将重点转移到学生对反馈的看法上,这显著影响了学习表现。然而,关于这些感知如何影响在线学习成果的经验证据是有限的。借鉴自决理论,本研究通过使用SEM分析反馈感知之间的关系来解决这一差距,学业自我效能感,考试焦虑,和在线学习参与。共有402名中国职业院校学生(18-19岁)完成了问卷调查,使用SPSS和Mplus进行统计分析。研究发现,反馈感知直接影响在线学习投入,并通过学业自我效能感和考试焦虑间接影响在线学习投入,总效应值为0.416。这些发现为教育工作者提供了宝贵的见解,并为未来关于反馈感知和在线学习参与的研究提供了方向。
    Enhancing learning engagement is a critical challenge in online education. While previous research underscores the importance of feedback, recent studies have shifted focus to students\' perceptions of feedback, which significantly impact learning performance. However, empirical evidence on how these perceptions affect online learning outcomes is limited. Drawing on Self-Determination Theory, this study addresses this gap by employing SEM to analyze the relationships among feedback perception, academic self-efficacy, test anxiety, and online learning engagement. A total of 402 Chinese vocational college students (ages 18-19) completed questionnaires, with statistical analysis conducted using SPSS and Mplus. The study found that perception of feedback directly influences online learning engagement and indirectly affects it through academic self-efficacy and test anxiety, with a total effect value of 0.416. The findings offer valuable insights for educators and suggest directions for future research on feedback perception and online learning engagement.
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  • 文章类型: Journal Article
    该研究通过使用盐酸在不同的pH水平和时间间隔下从成熟和未成熟的香蕉皮中提取果胶,解决了食品工业中全球水果废物的问题。在pH1.5和250分钟的条件下,未成熟的香蕉皮果胶的最佳结果为16.46%,具有良好的特性。在松饼开发中,七个处理(M0,M1,M2,M3,M4,M5和M6)准备和分析的形态,营养成分,和感官参数。M4治疗,在pH1.5和250分钟下利用未成熟的香蕉皮中的果胶,显示卓越的品质与降低的过氧化值,游离脂肪酸,水分损失百分比,和硬度。感官评估表明由于较低的脂肪含量而具有较高的可接受性。总之,从未成熟的香蕉皮中提取果胶被证明是有希望作为面包店食品中的脂肪替代品,保持松饼质量,同时解决食品工业中水果废物的挑战。
    The study addresses global fruit waste concerns in the food industry by extracting pectin from both ripe and unripe banana peels at varying pH levels and time intervals using hydrochloric acid. The best results were observed for unripe banana peel pectin at pH 1.5 and 250 min exhibiting a yield of 16.46% and favorable characteristics. In muffin development, seven treatments (M0, M1, M2, M3, M4, M5 and M6) are prepared and analyzed for morphology, nutritional content, and sensory parameters. The M4 treatment, utilizing pectin from unripe banana peel at pH 1.5 and 250 min, displays superior qualities with reduced peroxide value, free fatty acids, percent moisture loss, and hardness. Sensory evaluations indicate high acceptability due to lower fat content. In conclusion, the extraction of pectin from unripe banana peels proves promising as a fat replacer in bakery items, maintaining muffin quality while addressing fruit waste challenges in the food industry.
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  • 文章类型: Journal Article
    包裹在Cladoceranepippia中的滞育胚胎是有性生殖的结果,并增加了遗传多样性。它们也是物种绕过恶劣环境条件并在空间和时间上分散的重要手段。一旦被释放,ephippia通常沉入底栖动物并留在那里直到孵化。使用Sars方法(孵化沉积物以识别剑角幼虫),可以评估产卵库的生物多样性。然而,即使样品在各种条件下孵育,不可能保证所有人都孵化了。很少有钥匙可以通过仅使用海马形态来促进对剑角的识别。我们的目标是分析一些来自墨西哥的Cladoceranephippia,开发一种使用易于识别的特征来识别它们的方法。来自阿瓜斯卡连特斯(墨西哥)11属水域的23种锁骨物种的Ephippia(Alona,Biapertura,Ceriodapnia,Chydorus,水蚤,Dunhevedia,伊利克伦,Macrothrix,莫伊纳,Pleuroxus,和Simocephalus)进行了分析。在我们的分析中,选择了六个形态特征,这些形态特征允许在物种(-组)水平上鉴定阿菲皮亚。结果表明,通过适当的功能目录,可以识别出一些epippia。
    Diapausing embryos encased within cladoceran ephippia result from sexual reproduction and increase genetic diversity. They are also important means by which species bypass harsh environmental conditions and disperse in space and time. Once released, ephippia usually sink to the benthos and remain there until hatching. Using the Sars\' method (incubating sediments to identify cladoceran hatchlings), ephippial egg bank biodiversity can be evaluated. Yet, even when samples are incubated under a variety of conditions, it is not possible to warrant that all have hatched. Few keys are available that facilitate the identification of cladocerans by using only ephippial morphology. Our goal was to analyze some cladoceran ephippia from Mexico, to develop a means to identify them using easily recognizable characteristics. Ephippia of 23 cladoceran species from waters in Aguascalientes (México) in 11 genera (Alona, Biapertura, Ceriodaphnia, Chydorus, Daphnia, Dunhevedia, Ilyocryptus, Macrothrix, Moina, Pleuroxus, and Simocephalus) were analyzed. In our analysis six morphological features were selected that permitted the identification of ephippia to species(-group) level. The results demonstrate that with a proper catalog of features, some ephippia can be identified.
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  • 文章类型: Journal Article
    在这项工作中,根据分子标记分析(线粒体COI,16SrDNA和核ITS2)和形态特征。我们的结果表明,在所研究的材料中至少存在五种遗传谱系,这些遗传谱系也可以通过其分段环状模式在形态上进行鉴定。针状棘的数量和形状,以及管状裂片的长度和形状。Orbiniellapetersenae的物种名称被分配给其中一个谱系,将其地理和垂直分布限制在冰岛和扬马延以北的深海地区,和三个谱系被描述为新物种(即,OrbiniellagriegiMeca&Budaeva,sp.11月。,OrbiniellamayhemiMeca&Budaeva,sp.11月。,和OrbiniellaaporiMeca&Budaeva,sp.11月。)将该属中已知物种的数量提高到25个。在我们的研究中,仅在格陵兰-冰岛-苏格兰山脊以北报告了三种深海Orbiniella物种,在山脊以南发现了一种深海物种。沿山脊和挪威架子上分布着一种浅水物种。
    In this work, the diversity of the genus Orbiniella in the Nordic Seas and the North Atlantic waters south of Iceland is studied based on the analyses of molecular markers (mitochondrial COI, 16S rDNA and nuclear ITS2) and morphological characters. Our results showed the presence of at least five genetic lineages in the studied material which could also be morphologically identified by their segmental annulation patterns, the number and the shape of acicular spines, and the length and the shape of pygidial lobes. The species name Orbiniellapetersenae is assigned to one of the lineages restricting its geographical and vertical distribution to the deep-sea areas north of Iceland and Jan Mayen, and three lineages are described as new species (i.e., Orbiniellagriegi Meca & Budaeva, sp. nov., Orbiniellamayhemi Meca & Budaeva, sp. nov., and Orbiniellaparapari Meca & Budaeva, sp. nov.) elevating the number of known species in the genus to 25. Three deep-sea species of Orbiniella in our study are reported only north of the Greenland-Iceland-Scotland Ridge, one deep-sea species found south of the ridge. A single shallow-water species is distributed along the ridge and on the Norwegian shelf.
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  • 文章类型: Journal Article
    本研究试图通过知识共享(KNS)来调查巴基斯坦高等教育机构(HEI)变革型领导者(TFL)与追随者成果创新工作行为(IWB)和任务绩效之间的动态联系。使用定量设计,采用了一种采用的结构来获得HEI领导者和员工行为的响应。通过SmartPLS通过结构方程建模(SEM)技术分析获得的信息。结果描述了大学变革型领导与员工之间的直接联系。创新工作行为以及任务绩效。结果进一步假设,在HEI的背景下,KNS调解了变革型领导与员工TSP之间的关系。令人惊讶的是,KNS无法明显成为中介变量,以加强巴基斯坦HEIs部门的变革型领导力与IWB员工之间的关系。除了增强高等教育领导力的理论理解,本文的结果认为,促进知识共享文化对于现有和未来的HEIs领导者来说都是宝贵的资产,以促进创新和创造力的文化。尽管最近的研究调查了KNS作为中介的作用,然而,本研究首次使用KNS作为IWB和任务绩效的同期干预变量。该研究还证实了社会交换机制在加强领导者成员连续体之间关系方面的理论基础。
    This research tries to investigate the dynamic link between higher education institution (HEIs) transformational leaders (TFL) and follower\'s outcome innovative work behavior (IWB) and Task Performance) through Knowledge sharing (KNS) in Pakistan. Using quantitative design an adopted construct was used to obtain response from HEIs leaders and employees behavior. The obtained information was analyzed through structural equation modeling (SEM) technique via Smart PLS. Results depict that direct link between University Transformational leadership and employees Innovative work behavior as well as Task Performance. The results further postulate that KNS mediate the relationship between Transformational leadership and employees TSP in the context of HEIs. Surprisingly, KNS could not evident to become a mediating variable to strengthen the relationship between transformational Leadership and employees IWB in the HEIs sector of Pakistan. In addition to enhancing the theoretical comprehension of higher education leadership, the outcomes of this article provide that promoting knowledge sharing culture is valuable asset for both existing and future HEIs leaders in order to promote the culture of innovation and creativity. Although recent studies investigate the role of KNS as a mediator, however the current study use KNS as contemporaneous intervening variable for IWB and Task Performance for the first time. The study also confirms theoretical underpinning of social exchange mechanism in strengthening the relationship between leader member\'s continuum.
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  • 文章类型: Journal Article
    本文介绍了经过化学处理的非合金结构钢和合金(马氏体)钢表面几何结构的表征结果。磷化前,对样品进行热处理。研究了样品的表面和横截面。使用扫描电子显微镜(SEM)进行了详细的研究,XRD,金相显微镜,化学成分分析和分形分析。表面几何形状的特征包括圆度等参数,圆度,坚固性,费雷特的直径,分水岭直径,分形维数和角频率,通过对SEM图像的数值处理进行计算。
    The article presents the results of the characterization of the geometric structure of the surface of unalloyed structural steel and alloyed (martensitic) steel subjected to chemical processing. Prior to phosphating, the samples were heat-treated. Both the surfaces and the cross-sections of the samples were investigated. Detailed studies were made using scanning electron microscopy (SEM), XRD, metallographic microscopy, chemical composition analysis and fractal analysis. The characteristics of the surface geometry involved such parameters as circularity, roundness, solidity, Feret\'s diameter, watershed diameter, fractal dimensions and corner frequencies, which were calculated by numerical processing of SEM images.
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  • 文章类型: Journal Article
    使用磁性纳米粒子(MNPs)用于体外加热应用导致更高的场强,因此,可以使用具有较高矫顽力的粒子,与体内应用相比。在这项研究中,我们报道了六铁钡(BaFe12O19)纳米颗粒作为磁性加热的潜在颗粒的合成和表征。使用沉淀法,然后进行高温煅烧,我们首先研究了不同合成参数对颗粒性质的影响。第二,铁钡比(Fe/Ba=r)在2和12之间变化。振动样品磁力测定,扫描电子显微镜和X射线衍射进行表征。发现煅烧温度(Tcal)对所得磁性能有相当大的影响,矫顽力(HC)从Tcal=800-1000°C时的370kA/m以上降低到Tcal=1200°C时的HC=45-70kA/m。我们将HC的这一下降主要归因于在高Tcal下完全多畴颗粒的形成。对于不同的Fe/Ba比,通过XRD在小r(钡过剩)样品中检测到BaFe2O4作为附加相的增加量,降低粒子的磁化强度。在增加的r样品中发现HC减少。晶体尺寸范围为47nm至240nm,并且在SEM图像中看到大的团聚体。报道的粒子,由于其可控的矫顽力,可以是生物医学或生物技术领域的体外加热应用的候选人。
    Using magnetic nanoparticles (MNPs) for extracorporeal heating applications results in higher field strength and, therefore, particles of higher coercivity can be used, compared to intracorporeal applications. In this study, we report the synthesis and characterization of barium hexa-ferrite (BaFe12O19) nanoparticles as potential particles for magnetic heating. Using a precipitation method followed by high-temperature calcination, we first studied the influence of varied synthesis parameters on the particles\' properties. Second, the iron-to-barium ratio (Fe/Ba = r) was varied between 2 and 12. Vibrating sample magnetometry, scanning electron microscopy and X-ray diffraction were used for characterization. A considerable influence of the calcination temperature (Tcal) was found on the resulting magnetic properties, with a decrease in coercivity (HC) from values above 370 kA/m for Tcal = 800-1000 °C to HC = 45-70 kA/m for Tcal = 1200 °C. We attribute this drop in HC mainly to the formation of entirely multi-domain particles at high Tcal. For the varying Fe/Ba ratios, increasing amounts of BaFe2O4 as an additional phase were detected by XRD in the small r (barium surplus) samples, lowering the particles\' magnetization. A decrease in HC was found in the increased r samples. Crystal size ranged from 47 nm to 240 nm and large agglomerates were seen in SEM images. The reported particles, due to their controllable coercivity, can be a candidate for extracorporeal heating applications in the biomedical or biotechnological field.
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  • 文章类型: Journal Article
    下颌骨是昆虫口器最重要的附属物之一。它们的形态功能组织与饮食偏好的变化相关。在这项研究中,我们研究了两种饮食习惯不同的瓢虫的下颌骨的超微结构和金属组成:Harmoniaaxyridis(一种食虫物种)和Subcoccinellavigintiquatuorpunctata(一种植食性物种)。使用扫描和透射电子显微镜研究了超微结构组织,而金属组成是使用能量色散X射线光谱(EDX)研究的。两种物种之间的一般组织和金属富集模式存在显着差异。H.axyridis的下颌骨很大,并且有两个牙齿的磨牙部分,顶端显示双裂顶端。相比之下,S.vigintiquatuorpunctata表现出一个磨牙区域,其顶端有几颗牙齿。研究表明,H.axyridis的牙齿和假体之间的金属含量存在显着差异。Mn是牙齿中含量最高的元素,而Cl在假体中更丰富。在vigintiquatuorpunctata的情况下,Si是假肢中最丰富的元素,而Mn则更多地存在于牙齿中。这两个物种之间的比较表明,牙齿和假肢的元素组成均显示出显着变化。这些发现强调了饮食偏好在塑造这两种瓢虫下颌骨结构和金属组成变化中的作用。
    The mandibles are among the most important appendages of insects\' mouthparts. Their morpho-functional organization is correlated with the variation in dietary preferences. In this study, we investigated the ultrastructural organization and metal composition of the mandibles of two ladybird species with different dietary habits: Harmonia axyridis (an entomophagous species) and Subcoccinella vigintiquatuorpunctata (a phytophagous species). The ultrastructural organization was studied using Scanning and Transmission Electron Microscopy, whereas the metal composition was investigated using Energy-Dispersive X-ray spectroscopy (EDX). Significant differences were observed in the general organization and metal enrichment pattern between the two species. The mandibles of H. axyridis are large and present a molar part with two teeth, with the apical one showing a bifid apex. In contrast, S. vigintiquatuorpunctata exhibited a molar region with several teeth on its apical part. The study revealed significant differences in metal content between the teeth and the prostheca of H. axyridis. Mn was the most abundant element in teeth, whereas Cl was more abundant in the prostheca. In the case of S. vigintiquatuorpunctata, Si was the most abundant element in the prostheca, while Mn was more present in the teeth. A comparison between the two species revealed that both teeth and prostheca showed significant variation in the elemental composition. These findings underscore the role of dietary preferences in shaping the structural and metal composition variations in the mandibles of these two ladybird species.
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  • 文章类型: Journal Article
    目的:本研究试图开发和评估一个探索性模型,和药物使用或获取行为相互作用,影响阿片类药物参与过量。
    方法:我们进行了探索性和验证性因子分析(EFA/CFA),以确定十种药物获取和使用行为的因子结构。然后,我们评估了包含已识别因素的替代结构方程模型,增加人口统计学和社会心理属性作为过去一年阿片类药物过量的预测因素。
    方法:我们使用了两项研究的访谈数据,这些研究招募了滥用阿片类药物的参与者,这些参与者接受了基于社区的注射器服务计划的服务。第一个调查了当前对药物检查的态度(N=150)。第二个是RCT评估远程医疗与现场医疗预约阿片类药物使用障碍治疗转诊(N=270)。
    方法:人口统计包括性别,年龄,种族/民族,教育,和社会经济地位。心理社会措施是无家可归,心理困扰,和创伤。自我报告的药物相关危险行为包括单独使用,有了新的供应商,使用阿片类药物与苯二氮卓类药物/酒精,更喜欢芬太尼。过去一年涉及阿片类药物的过量被分为没有或任何经历。
    结果:EFA/CFA揭示了双因素结构,其中一个因素反映了药物获取和第二个药物使用行为。所选择的模型(CFI=.984,TLI=.981,RMSEA=.024)占过量剂量概率方差的13.1%。代表心理社会属性的潜在变量与过去一年的过量用药概率的增加间接相关(β=.234,p=.001),由EFA/CFA介导,确定了潜在变量:药物获取(β=.683,p<.001)和药物使用(β=.567,p=.001)。药物使用行为(β=.287,p=.04)而非药物获取行为(β=.105,p=.461)也具有显著,对过去一年过量的积极直接影响。没有人口统计学特征是显着的直接或间接用药过量预测因素。
    结论:心理社会属性,尤其是无家可归,通过与危险药物获取和药物使用行为的关联增加过量的可能性。需要进一步的研究来在阿片类药物相关过量的高风险人群中复制这些发现,以评估普遍性并完善用于评估心理社会特征的指标。
    OBJECTIVE: This study sought to develop and assess an exploratory model of how demographic and psychosocial attributes, and drug use or acquisition behaviors interact to affect opioid-involved overdoses.
    METHODS: We conducted exploratory and confirmatory factor analysis (EFA/CFA) to identify a factor structure for ten drug acquisition and use behaviors. We then evaluated alternative structural equation models incorporating the identified factors, adding demographic and psychosocial attributes as predictors of past-year opioid overdose.
    METHODS: We used interview data collected for two studies recruiting opioid-misusing participants receiving services from a community-based syringe services program. The first investigated current attitudes toward drug-checking (N = 150). The second was an RCT assessing a telehealth versus in-person medical appointment for opioid use disorder treatment referral (N = 270).
    METHODS: Demographics included gender, age, race/ethnicity, education, and socioeconomic status. Psychosocial measures were homelessness, psychological distress, and trauma. Self-reported drug-related risk behaviors included using alone, having a new supplier, using opioids with benzodiazepines/alcohol, and preferring fentanyl. Past-year opioid-involved overdoses were dichotomized into experiencing none or any.
    RESULTS: The EFA/CFA revealed a two-factor structure with one factor reflecting drug acquisition and the second drug use behaviors. The selected model (CFI = .984, TLI = .981, RMSEA = .024) accounted for 13.1% of overdose probability variance. A latent variable representing psychosocial attributes was indirectly associated with an increase in past-year overdose probability (β = .234, p = .001), as mediated by the EFA/CFA identified latent variables: drug acquisition (β = .683, p < .001) and drug use (β = .567, p = .001). Drug use behaviors (β = .287, p = .04) but not drug acquisition (β = .105, p = .461) also had a significant, positive direct effect on past-year overdose. No demographic attributes were significant direct or indirect overdose predictors.
    CONCLUSIONS: Psychosocial attributes, particularly homelessness, increase the probability of an overdose through associations with risky drug acquisition and drug-using behaviors. Further research is needed to replicate these findings with populations at high-risk of an opioid-related overdose to assess generalizability and refine the metrics used to assess psychosocial characteristics.
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