这项研究的目的是获得三种含有GO和HA-Ag的实验性树脂基水泥,用于后部修复。样品(S0,S1和S2)共享相同的聚合物基质(BisGMA,TEGDMA)和粉末混合物(生物玻璃(La2O3和Sr-Zr),石英,GO,和HA-Ag),不同百分比的氧化石墨烯(0%,0.1%,0.2%GO)和银掺杂羟基磷灰石(10%,9.9%,9.8%HA-Ag)。物理化学性质(吸水性,转换程度),机械性能(DTS,CS,FS),结构性能(SEM,AFM),和抗菌性能(金黄色葡萄球菌,粪肠球菌,变形链球菌,牙龈卟啉单胞菌,和大肠杆菌)进行了调查。结果表明,除了径向拉伸试验,随着%GO的增加而增加。28天后,吸水率随着%GO的增加而增加。在吸水28天后,样品的表面结构没有显示出重大变化。抗菌作用根据所测试的样品和细菌菌株而变化。在增加%GO和降低%HA-Ag后,我们观察到更明显的抗菌作用。GO的存在,即使是很小的百分比,改善了试验水泥的性能。
The aim of this study was to obtain three experimental resin-based cements containing GO and HA-Ag for posterior restorations. The samples (S0, S1, and S2) shared the same polymer matrix (BisGMA, TEGDMA) and powder mixture (bioglass (La2O3 and Sr-Zr), quartz, GO, and HA-Ag), with different percentages of graphene oxide (0%, 0.1%, 0.2% GO) and silver-doped hydroxyapatite (10%, 9.9%, 9.8% HA-Ag). The physical-chemical properties (water absorption, degree of conversion), mechanical properties (DTS, CS, FS), structural properties (SEM, AFM), and antibacterial properties (Staphylococcus aureus, Enterococcus faecalis, Streptococcus mutans, Porphyromonas gingivalis, and Escherichia coli) were investigated. The results showed that the mechanical properties, except for the diametral tensile test, increased with the rise in the %GO. After 28 days, water absorption increased with the rise in the %GO. The surface structure of the samples did not show major changes after water absorption for 28 days. The antibacterial effects varied depending on the samples and bacterial strains tested. After increasing the %GO and decreasing the %HA-Ag, we observed a more pronounced antibacterial effect. The presence of GO, even in very small percentages, improved the properties of the tested experimental cements.