这篇综述包括合成方法的汇编以及I组和II组以外的硼氢化物的几种性质,即,过渡金属,主要群体,镧系元素,和act系元素。报告的性质包括晶体结构,分解温度,离子电导率,光致发光,等。,可用时。编制的性质反映了丰富的化学性质和可能的硼氢化物在储氢等领域的应用,需要离子导体的电子设备,催化作用,或光致发光。在审查结束时,包括两个简短但必不可少的部分:所有报告的硼氢化物的分解温度与阳离子的鲍林电负性的汇编,并简要讨论了乙硼烷排放过程中可能发生的反应,包括一些减少这种不便的策略,特别是用于储氢的目的。
This review consists of a compilation of synthesis methods and several properties of
borohydrides beyond Groups I and II, i.e., transition metals, main group, lanthanides, and actinides. The reported properties include crystal structure, decomposition temperature, ionic conductivity, photoluminescence, etc., when available. The compiled properties reflect the rich chemistry and possible
borohydrides\' application in areas such as hydrogen storage, electronic devices that require an ionic conductor, catalysis, or photoluminescence. At the end of the review, two short but essential sections are included: a compilation of the decomposition temperature of all reported
borohydrides versus the Pauling electronegativity of the cations, and a brief discussion of the possible reactions occurring during diborane emission, including some strategies to reduce this inconvenience, particularly for hydrogen storage purposes.