Waste

废物
  • 文章类型: Journal Article
    由于其增强的安全属性和环境相容性,可持续阻燃剂的发展正在获得动力。一个有效的策略是利用废料作为化学成分的主要来源,这可以帮助减轻与传统阻燃剂相关的环境问题。本文综述了近年来废弃阻燃剂的阻燃性研究,根据工业等废物类型对它们进行分类,食物,植物废物。本文重点介绍了这一领域的最新进展,关注它们对热稳定性的影响,阻燃性,烟雾抑制,和聚合物材料的机械性能。该研究还提供了使用的官能化方法和涉及改性聚合物体系的关键因素的总结。最后,确定了他们的主要挑战和未来前景。
    The development of sustainable flame retardants is gaining momentum due to their enhanced safety attributes and environmental compatibility. One effective strategy is to use waste materials as a primary source of chemical components, which can help mitigate environmental issues associated with traditional flame retardants. This paper reviews recent research in flame retardancy for waste flame retardants, categorizing them based on waste types like industrial, food, and plant waste. The paper focuses on recent advancements in this area, focusing on their impact on the thermal stability, flame retardancy, smoke suppression, and mechanical properties of polymeric materials. The study also provides a summary of functionalization methodologies used and key factors involved in modifying polymer systems. Finally, their major challenges and prospects for the future are identified.
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  • 文章类型: Journal Article
    为了评估人工晶状体(IOL)植入过程中人工晶状体(IOL)浪费的发生率和成本,以及它的原因。
    对2016-2020年中国一家三级眼科医院的485名患者的数据进行了回顾性分析。主要结果是发病率,成本,以及IOL特性不同的原因。检查病例以确定IOL材料,设计,程序细节,和浪费的原因。
    在研究期间,在73,246例IOL植入中,有485例(6.62‰)发生了IOL废物。在研究期间,人工晶体废物的总费用为429,850.26元人民币(CNY),每个程序的平均费用为2,442.33元人民币。人工晶状体性能比较表明,聚甲基丙烯酸甲酯(PMMA)材料(39,2.05%),三件式设计(142,1.49%),和继发性IOL植入(26,2.16%)与IOL浪费有关,差异有统计学意义。人工晶体浪费的原因是损坏(107,60.80%),患者原因(37,21.26%),无菌错误(22,12.50%),IOL质量问题(8,4.55%),和损失(2,1.14%)。
    人工晶状体废物的发生率低,但由于大量的白内障手术,仍然会导致巨大的成本负担。PMMA材料,三件套设计,和二次植入被确定为增加IOL浪费的因素。损害成为浪费的主要原因,很大程度上归因于人为错误。因此,制定减轻IOL浪费的策略势在必行.
    UNASSIGNED: To evaluate the incidence and cost of intraocular lens(IOL) waste during IOL implantation, as well as the reasons for it.
    UNASSIGNED: A retrospective analysis was conducted on the data of 485 patients from the IOL waste registers of a single tertiary eye hospital in China during 2016-2020. The primary outcomes were the incidence, cost, and reasons for different IOL properties. Cases were examined to ascertain IOL material, design, procedural details, and causes of waste.
    UNASSIGNED: IOL waste occurred in 485 (6.62‰) of the 73,246 IOL implantations during the study period. The total cost of IOL waste was 429, 850.26 Chinese Yuan (CNY) related to waste with an average cost of 2, 442.33 CNY per procedure during the study period. Comparisons between IOL properties showed that polymethyl methacrylate (PMMA) material (39, 2.05%), three-piece design (142, 1.49%), and secondary IOL implantation (26, 2.16%) were associated with IOL wastage, and the difference was statistically significant. The causes of IOL waste were damage (107, 60.80%), patient reasons (37, 21.26%), aseptic errors (22, 12.50%), IOL quality problems (8, 4.55%), and loss (2, 1.14%).
    UNASSIGNED: The incidence of IOL waste is low, but still leads to a significant cost burden due to a large number of cataract surgeries. PMMA material, three-piece design, and secondary implantation were identified as factors increasing IOL waste. Damage emerged as the primary reason for waste, largely attributed to human error. Therefore, the development of strategies to mitigate IOL waste is imperative.
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  • 文章类型: Journal Article
    回转窑(RK)焚烧技术在废物管理中占有重要地位,旨在减少污染,回收能量,尽量减少浪费。通过增强氧气分布均匀性和促进燃料转化,在RK中进行氧气载体(OC)辅助的废物焚烧显示出明显的好处。然而,在RK的垃圾焚烧过程中,OC对与灰分有关的碱和重金属的影响仍然未知。在这项研究中,在废物燃烧过程中,锰矿石和钛铁矿作为OCs被引入RK,重点关注它们对底灰的影响以及碱和重金属的行为。结果表明,锰矿表现出降低的反应性,由于氧消耗过程中的Mn2O3转化为Mn3O4,而钛铁矿保持良好的反应性,由于持续富集的Fe2O3颗粒,即使在RK多次循环。当OCs在床的活性层和被动层之间移动时,OCs颗粒表面上的多孔结构验证了涉及空气氧化和燃料还原的循环反应。多孔OCs颗粒为气相中的K提供了丰富的吸附位点,表面沉积的钾迁移到颗粒中,提高了OCs吸附钾的能力。添加OCs促进稳定的形成,挥发性较低的重金属化合物(As,Cr,Pb,和Zn),并增强其在底灰中的保留,同时确保浸出毒性保持在中国国家标准限值以下。这项研究增强了对焚烧中OCs的理解,指导废物管理实践和环境可持续性的重要参考。
    Rotary kiln (RK) incineration technology gains prominence in waste management, aiming to reduce pollution, recover energy, and minimize waste. Oxygen-carrier (OC)-aided incineration of waste in the RK demonstrates notable benefits by enhancing oxygen distribution uniformity and facilitating fuel conversion. However, the effects of OC on ash-related alkali and heavy metals during waste incineration in the RK remain unknown. In this study, manganese ore and ilmenite as OCs are introduced into RK during waste combustion, focusing on their effects on the bottom ashes and the behavior of alkali and heavy metals. Results show that manganese ore exhibits a decreasing reactivity due to oxygen depletion during the conversion from Mn2O3 to Mn3O4, while ilmenite maintains good reactivity due to sustained enrichment of Fe2O3 on the particles even after multiple cycles in RK. The porous structure on the surface of OCs particles verifies the cyclic reaction involving oxidation by air and reduction by fuel as OCs move between the active and passive layers of the bed. The porous OCs particles offer abundant adsorption sites for K from the gaseous phase, with surface-deposited K migrating into the particles and enhancing the OCs\' capacity for K adsorption. Adding OCs promotes the formation of stable, less volatile compounds of heavy metals (As, Cr, Pb, and Zn) and enhances their retention in bottom ash while ensuring the leaching toxicity remains below Chinese national standard limits. This study enhances the understanding of OCs in incineration, guiding vital references for waste management practices and environmental sustainability.
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  • 文章类型: Journal Article
    废电石渣(CS),广泛应用于脱硫,通常不用于脱硝。在这里,为了很好地实现废物控制,使用KOH改性电石渣(KCS),开发了一种简便高效的脱硝策略。使用一系列物理和化学表征研究了各种KCS样品。性能测试结果表明,KOH浓度和反应温度是影响KCS脱硝效率的主要因素,经1.5mol/LKOH(KCS-1.5)改性的CS在300℃下可达到100%脱硝效率。这种优异的去除效率是由于来自KCS的含氧官能团的催化氧化。进一步的研究表明,KOH处理显著增加了氧空位的浓度,硝基化合物,和CS的基本站点。这项研究为未来废物CS的资源化利用提供了一种新的策略。
    Waste calcium carbide slags (CS), which are widely applied to desulfurisation, are not typically used in denitration. Herein, to well achieve waste control by waste, a facile and high-efficiency denitration strategy is developed using KOH to modify the calcium carbide slags (KCS). Various KCS samples were investigated using a series of physical and chemical characterisations. The performance test results showed that the KOH concentration and reaction temperature are the main factors affecting the denitration efficiency of KCS, and CS modified with 1.5 mol/L KOH (KCS-1.5) can achieve 100% denitration efficiency at 300°C. Such excellent removal efficiency is due to the catalytic oxidation of the oxygen-containing functional groups derived from the KCS. Further studies showed that KOH treatment significantly increased the concentration of oxygen vacancies, nitro compounds, and basic sites of CS. This study provides a novel strategy for the resource utilisation of waste CS in the future.
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  • 文章类型: Journal Article
    在这项研究中,牛粪生物质转化为生物炭(BC)。通过在900°C下一步热解获得BC900,而BC700-900和BC900-700是通过在700-900°C和900-700°C的温度范围内的两步热解获得的,分别。研究BCs对水中四环素(TC)的吸附性能及应用价值。使用扫描电子显微镜和作图分析对样品进行了表征,傅里叶变换红外光谱,X射线衍射,和热重分析。随后,反应时间的影响,吸附剂用量,温度,pH值,并对离子强度进行了分析。根据吸附动力学的拟合结果,热解BCs表现出与伪二次动力学模型更好的拟合。吸附等温线表明单层吸附在吸附剂表面,BC900-700的最大吸附容量分别为158.93mg/g,BC700-900的最大吸附容量为150.15mg/g,BC900的最大吸附容量为142.56mg/g。此外,模拟废水和再生实验结果表明,BC900-700不仅在废水中具有优异的吸附性能,而且具有显着的再生能力。与实际应用中的一步热解BCs相比,本研究中的两步热解BCs具有更高的吸附能力。这些发现为进一步探索吸附机理和优化工艺提供了见解。
    In this study, cow dung biomass was converted into biochar (BC). BC900 was obtained through one-step pyrolysis at 900 °C, while BC700-900 and BC900-700 were obtained via two-step pyrolysis at temperature ranges of 700-900 °C and 900-700 °C, respectively. The primary objective was to investigate the adsorption performance and application value of BCs for tetracycline (TC) in water. The samples underwent characterization using scanning electron microscopy and mapping analysis, Fourier transform infrared spectroscopy, X-ray diffraction, and thermogravimetric analysis. Subsequently, the effects of reaction time, adsorbent dosage, temperature, pH, and ionic strength were analyzed. Based on the fitting results of adsorption kinetics, the pyrolytic BCs exhibited a better fit with the pseudo-secondary kinetic model. The adsorption isotherm indicated monolayer adsorption on the surface of the adsorbents, with maximum adsorption capacities of 158.93 mg/g for BC900-700, 150.15 mg/g for BC700-900, and 142.56 mg/g for BC900, respectively. Furthermore, results from simulated wastewater and regeneration experiments demonstrated that BC900-700 exhibited not only excellent adsorption performance in wastewater but also remarkable regeneration capabilities. The two-step pyrolysis BCs in this study displayed a higher adsorption capacity compared to the one-step pyrolysis BCs in practical applications. These findings provide insights for further exploring the adsorption mechanism and optimizing the process.
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  • 文章类型: Review
    海参具有很高的经济价值,在大多数贸易形式中,他们的体壁通常是唯一被收获和出售的部分。海参的器官,统称为内脏,经常被丢弃,造成土地和水污染。然而,废弃的海参内脏含有各种营养成分,可用于许多应用。因此,这篇综述强调了海参的生物和经济方面,随后对其内部器官的营养价值和可能的应用进行了严格的讨论,包括作为水产养殖业中的功能性饲料添加剂,天然睾酮的来源,用于性别逆转和单性群体的生产,针对中枢神经系统疾病的神经保护剂和化妆品成分,特别适用于皮肤美白和抗衰老产品。该评论进一步强调了内脏的增值潜力,以最大限度地发挥其经济潜力,从而为海参废物的再利用提供了巨大的前景,从而减少海参渔业部门对环境的负面影响。
    Sea cucumbers have high economic value, and in most forms of trade, their body wall is typically the only part that is harvested and sold. The organs of the sea cucumber, collectively known as the viscera, are frequently discarded, contributing to land and water pollution. However, discarded sea cucumber viscera contain various nutrients that can be used in many applications. Therefore, this review highlights the biological and economic aspects of sea cucumbers, followed by a critical discussion of the nutritional value of their internal organs and possible applications, including as functional feed additives in the aquaculture industry, sources of natural testosterone for application in sex reversal and production of monosex population, of neuroprotective agents against central nervous system disorders and of cosmetic ingredients, especially for skin whitening and anti-ageing products. The review further highlights the valorisation potential of viscera to maximize their economic potential, thus providing an enormous prospect for reusing sea cucumber waste, thereby reducing the negative impact of the sea cucumber fishery sector on the environment.
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  • 文章类型: Journal Article
    开发新的动物饲料来源,建立可持续的食品升级循环系统,本研究阐明了新鲜蔬菜废物(FVW)的材料可行性和饲喂潜力。首先,杭州湿市场的FVW产量,中国被追踪和预测。结果表明,FVW在湿地市场的零售废物比率达到9.3%,预测2030年中国的FVW将达到9034kt。第二,研究表明,FVW的营养价值与传统苜蓿饲料相当,适合用作动物饲料。然而,我们发现微生物污染的可能性很高。因此,FVW应该有更严格的分类和收集方法。在这个前提下,FVW在湿市场的饲料利用潜力很大。到2030年,粗蛋白含量可能会取代苜蓿的2737kt,节省7.7E+08m3的水和75,018公顷的土地。
    To develop new animal feed sources and establish a sustainable food upcycling system, the material feasibility and feeding potential of fresh vegetable waste (FVW) were clarified in this study. First, the FVW output of wet markets in Hangzhou, China was tracked and predicted. The results showed that the retail waste ratio of FVW in wet markets reached 9.3 %, predicting that China\'s FVW will reach 9034 kt in 2030. Second, the study revealed that the nutritive value of FVW was comparable to that of traditional alfalfa feed, suitable for use as animal feed. However, we found a high probability of microbial contamination. Therefore, FVW should have stricter classification and collection methods. Under this premise, the feeding utilization potential of FVW in wet markets is large. In 2030, the crude protein content may replace 2737 kt of alfalfa, saving 7.7 E + 08 m3 of water and 75,018 ha of land.
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  • 文章类型: Journal Article
    红参和麦冬都是中药。它们在中国也被用作食物已有数千年的历史。这两种草药在许多传统中成药中经常使用。然而,这两种草药的碳水化合物成分在生产所述药物期间通常不使用,如参麦注射液,导致大量由碳水化合物组成的废物。在这项研究中,采用响应面法优化提取条件。采用在优化条件下煮沸的蒸馏水提取参麦注射液废多糖。由此得到参麦注射液废多糖(SMP)。通过阴离子交换色谱和凝胶过滤进一步纯化SMP。使用这种方法,获得中性多糖级分(SMP-NP)和酸性多糖级分(SMP-AP)。结构鉴定结果表明SMP-NP是一种左旋,SMP-AP是典型的酸性多糖。SMP-NP对5种不同的乳杆菌菌株的增殖表现出潜在的刺激活性。因此,SMP-AP可以促进IPEC-J2细胞的抗氧化防御。这些发现表明,参麦注射液废物可以用作益生元和抗氧化剂的资源。
    Red ginseng and Ophiopogon japonicus are both traditional Chinese medicines. They have also been used as food in China for thousands of years. These two herbs were frequently used in many traditional Chinese patent medicines. However, the carbohydrate compositions of these two herbs were not normally used during the production of said medicine, such as Shenmai injection, resulting in a large amount of waste composed of carbohydrates. In this study, the extraction conditions were optimized by response surface methodology. The Shenmai injection waste polysaccharide was extracted by using distilled water that was boiled under the optimized conditions. The Shenmai injection waste polysaccharide (SMP) was thereby obtained. SMP was further purified by anion exchange chromatography and gel filtration. With this method, a neutral polysaccharide fraction (SMP-NP) and an acidic polysaccharide fraction (SMP-AP) were obtained. The results of structure elucidation indicated that SMP-NP was a type of levan, and SMP-AP was a typical acidic polysaccharide. SMP-NP exhibited potential stimulation activity on the proliferation of five different Lactobacilli strains. Therefore, SMP-AP could promote the antioxidant defense of IPEC-J2 cells. These findings suggest that Shenmai injection waste could be used as a resource for prebiotics and antioxidants.
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  • 文章类型: Journal Article
    近半个世纪以来,热固性玻璃纤维增强聚合物(GFRP)在制造业和建筑业中得到了广泛的应用,但是这种材料产生的大量废物很难处理。为了解决这个问题,这项研究调查了热固性GFRP废料在正常强度混凝土(NSC)和受控低强度材料(CLSM)中的再利用。还评价了所得混凝土的机械性能和可加工性。准备混凝土试样,首先将热固性玻璃钢废料粉碎成颗粒状,然后与水泥混合,粉煤灰,和水形成圆柱形混凝土试样。结果表明,当热固性玻璃钢废骨料在混凝土中的比例增加时,NSC和CLSM的抗压强度会降低。然而,当将5%GFRP废料掺入CLSM时,抗压强度比不含GFRP的混凝土高7%。然而,通过添加适量的高效减水剂,可以提高CLSM的可加工性以满足工程标准。该发现表明,在生产期间在混合物中使用各种比例组合可以允许生产具有不同压缩强度需求的CLSM。此外,使用回收的热固性GFRP废物作为CLSM中传统骨料的新骨料替代品被发现是目前市场上使用的CLSM组合的更可持续的替代品。
    Thermoset glass fiber-reinforced polymers (GFRP) have been widely used in manufacturing and construction for nearly half a century, but the large amount of waste produced by this material is difficult to dispose of. In an effort to address this issue, this research investigates the reuse of thermoset GFRP waste in normal strength concrete (NSC) and controlled low-strength materials (CLSM). The mechanical performance and workability of the resulting concrete were also evaluated. To prepare the concrete specimens, the thermoset GFRP waste was first pulverized into granular pieces, which were then mixed with cement, fly ash, and water to form cylindrical concrete specimens. The results showed that when the proportion of thermoset GFRP waste aggregate in the concrete increased, the compressive strengths of NSC and CLSM would decrease. However, when incorporating 5% GFRP waste into CLSM, the compressive strength was 7% higher than concrete without GFRP. However, the workability of CLSM could be improved to meet engineering standards by adding an appropriate amount of superplasticizer. This finding suggests that the use of various combinations of proportions in the mixture during production could allow for the production of CLSM with different compressive strength needs. In addition, the use of recycled thermoset GFRP waste as a new aggregate replacement for traditional aggregates in CLSM was found to be a more sustainable alternative to the current CLSM combinations used in the market.
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  • 文章类型: Journal Article
    天然虾青素已广泛应用于食品中,化妆品,和医药工业由于其特殊的生物活性。虾壳是虾青素的主要天然生物来源之一。然而,虾青素恢复后,残留中仍含有大量的甲壳素。在这项研究中,使用离子液体(IL)1-乙基-3-甲基咪唑鎓乙酸盐([Emim]Ac)提取虾青素后的虾(南美白对虾)壳中的残留物用作生物吸附剂以从水溶液中去除氟化物。结果表明,IL的提取条件,包括固体/液体比,温度,时间,和颗粒大小,所有这些都在虾壳残留物去除氟化物中起着重要作用。用[Emim]Ac在100°C下处理2h的虾壳表现出明显的多孔结构,孔隙率与脱氟呈正线性相关(DF,%).此外,氟的吸附过程为非自发吸热,这与伪二阶和朗缪尔模型都很好地吻合。根据Langmuir模型计算的最大吸附容量为3.29mg/g,比大多数生物吸附剂更好。本研究为从虾加工废弃物中制备吸附剂去除废水中的氟提供了一种低成本、高效的方法。
    Natural astaxanthin has been widely used in the food, cosmetic, and medicine industries due to its exceptional biological activity. Shrimp shell is one of the primary natural biological sources of astaxanthin. However, after astaxanthin recovery, there is still a lot of chitin contained in the residues. In this study, the residue from shrimp (Penaeus vannamei) shells after astaxanthin extraction using ionic liquid (IL) 1-ethyl-3-methyl-imidazolium acetate ([Emim]Ac) was used as a bioadsorbent to remove fluoride from the aqueous solution. The results show the IL extraction conditions, including the solid/liquid ratio, temperature, time, and particle size, all played important roles in the removal of fluoride by the shrimp shell residue. The shrimp shells treated using [Emim]Ac at 100 °C for 2 h exhibited an obvious porous structure, and the porosity showed a positive linear correlation with defluorination (DF, %). Moreover, the adsorption process of fluoride was nonspontaneous and endothermic, which fits well with both the pseudo-second-order and Langmuir models. The maximum adsorption capacity calculated according to the Langmuir model is 3.29 mg/g, which is better than most bioadsorbents. This study provides a low-cost and efficient method for the preparation of adsorbents from shrimp processing waste to remove fluoride from wastewater.
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