rheology

流变学
  • 文章类型: Journal Article
    这项研究提供了关于在不同水果类型中配制水果馅料中利用各种水胶体的当前发展的全面回顾。它们对纹理属性的影响,流变性能,热稳定性,脱水收缩,和填充物的营养优势,并优化其特性,以符合消费者的喜好。综述还重点介绍了影响水果馅料的各种因素,包括水果的选择,处理方法,水胶体的固有性质和浓度,以及它们的协同作用。在深度,关于pH等参数影响的科学工作,总可溶性固体,还讨论了水果馅料中的糖含量。此外,本文重点介绍了在包括糕点在内的烘焙产品中使用水胶体开发的各种水果馅料的利用,塔特莱特,松饼,饼干,等等。审查表明,亲水胶体提供了一系列技术功能属性,有助于加强水果填充物的结构和热稳定性,从而延长其保质期。其进一步确定,水胶体的掺入通过减轻过量糖或各种其他不太有利的成分的必要性而促进更健康的食品的开发。在烘焙产品中加入水果馅料显著增加了这些烘焙食品的价值主张,有助于整体提高质量和感官价值。
    This study offers a comprehensive review of current developments regarding the utilization of diverse hydrocolloids in formulating fruit fillings across different fruit types, their impact on textural attributes, rheological properties, thermal stability, syneresis, and nutritional advantages of fillings and optimization of its characteristics to align with consumer preferences. The review also focuses on the various factors influencing fruit fillings, including the selection of fruits, processing methodologies, the inherent nature and concentration of hydrocolloids, and their synergistic interactions. In depth, scientific work on the impact of the parameters such as pH, total soluble solids, and sugar content within the fruit fillings was also discussed. Additionally, this article focuses on the utilization of the diverse fruit fillings developed by using hydrocolloids in bakery products including pastry, tartlet, muffins, cookies, and so forth. The review establishes that hydrocolloids offer a spectrum of techno-functional attributes conducive to strengthening both the structural and thermal stability of fruit fillings, consequently extending their shelf life. It further establishes that incorporating of hydrocolloids facilitates the development of healthier food products by mitigating the necessity of excessive sugar or various other less favorable ingredients. The incorporation of fruit fillings in bakery products significantly increases the value proposition of these baked goods, contributing to their overall enhancement of quality and sensory value.
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  • 文章类型: Journal Article
    纳米粒子因其独特的表面结构和纳米效应而引起了人们的广泛关注,它呈现出像声音一样的新颖特征,光,电力,磁性,和热性能。然而,两个关键缺陷阻碍了它们的应用:(1)高熔融温度导致的加工性差(例如,>1000°C)对于某些无机纳米粒子;(2)由于纳米粒子容易聚集而引起的纳米效应的限制。为了解决这些问题,在二十一世纪初,成功设计和制造了具有硬核和柔性有机链的无溶剂纳米流体(SNFs)。有前途的SNFs技术不仅解决了纳米材料的分散问题,而且还赋予了纳米颗粒新的功能化。到目前为止,许多研究人员一直致力于开发不同的核心和灵活的有机聚合物链,以赋予SNFs特定的功能,例如电导率,荧光,润滑性,等等。然而,关于功能性SNFs的制备和应用研究进展的综述报道很少。为了更好地了解SNF,本文对发展进行了全面调查,fabrication,以及功能性SNF的应用。
    Nanoparticles have aroused widespread interest because of their unique surface structure and nano effect, which presents novel characteristics like as sound, light, electricity, magnetism, and thermal properties. However, two critical defects have hindered their applications: (1) poor processability resulting from the high melting temperature (e.g., >1000 °C) for some inorganic nanoparticles; (2) the restriction of the nano effect caused by the easy aggregation of the nanoparticles. To solve those issues, solvent-free nanofluids (SNFs) with hard cores and flexible organic chains were successfully designed and fabricated at the beginning of the twenty-first century. The promising technology of SNFs not only solved the dispersion problem of nanomaterials but also imparted novel functionalization to nanoparticles. Up to now, many researchers have been devoted to developing diverse cores and flexible organic polymer chains to endow SNFs with particular functions, such as conductivity, fluorescence, lubricity, and so on. However, there are few review reports on the research progress in the fabrication and applications of functional SNFs. To gain a better understanding of SNFs, this paper presents an overall investigation into the development, fabrication, as well as the applications of functional SNFs.
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  • 文章类型: Journal Article
    Emulsions in the form of creams, lotions, gels or foams are the most widely used personal care formulations to improve the condition and feel of the skin. Achieving an optimal balance between their performance, effectiveness and sensory profile is essential, with the sensory profile being a key factor in consumer satisfaction and the success of these products in the market. Well-established methods using highly trained and semi-trained panels (e.g. Spectrum descriptive analysis, Flash Profile method, Quantitative Descriptive Analysis method and \'Check-all-that-apply\') are available and commonly used for the sensory assessment of personal care products. Nevertheless, a common drawback among all these methods is their inherent cost, both in terms of financial resources and time requirements. In recent years, research studies have emerged to address this limitation by investigating potential correlations between tactile sensory attributes and instrumental data associated with the physical characteristics of topical formulations. In other words, significant efforts have been invested in the development of robust instrumental methods specifically designed to accurately predict the sensory description that a panel of assessors could establish. These methods are not only faster, cheaper and more objective compared to traditional sensory testing, but they can also be applied to formulations that have not undergone extensive safety and toxicological testing. This review summarizes the most relevant findings, trends and current challenges in predicting tactile sensory attributes of personal care emulsions based on instrumental parameters.
    Les émulsions sous forme de crèmes, lotions, gels ou mousses sont les formulations de soins personnels les plus largement utilisées pour améliorer l\'état et la sensation de la peau. Il est essentiel de parvenir à un équilibre parfait entre leur performance, leur efficacité et leur profil sensoriel, ce dernier étant un facteur clé de la satisfaction des consommateurs et du succès de ces produits sur le marché. Des méthodes bien établies utilisant des panels hautement qualifiés et semi‐qualifiés sont disponibles et couramment utilisées pour l\'évaluation sensorielle des produits de soins personnels. Néanmoins, un inconvénient commun à toutes ces méthodes est leur coût inhérent, tant en termes de ressources financières que de temps. Ces dernières années, nous avons assisté à l\'émergence d\'études de recherche tentant de remédier à ces limites en étudiant les corrélations potentielles entre les descripteurs sensoriels tactiles et les données instrumentales associées aux caractéristiques physiques des formulations topiques. En d\'autres termes, des efforts importants ont été déployés dans le développement de méthodes instrumentales robustes spécifiquement conçues pour prédire avec précision la description sensorielle qu\'un panel d\'évaluateurs pourrait établir. Ces méthodes sont non seulement plus rapides, moins coûteuses et plus objectives par rapport aux tests sensoriels traditionnels, mais elles peuvent également être appliquées à des formulations qui n\'ont pas été entièrement testées en termes de sécurité et de profils toxicologiques. La présente revue résume les résultats, tendances et défis actuels les plus pertinents dans la prédiction des attributs sensoriels tactiles des émulsions de soins personnels à partir de paramètres instrumentaux.
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  • 文章类型: Journal Article
    纤维素衍生物的应用包括羧甲基纤维素(CMC),聚阴离子纤维素(PAC),羟乙基纤维素(HEC),纤维素纳米原纤维(CNFs),纤维素纳米晶体(CNCs)获得了巨大的兴趣,特别是作为水基钻井液(WBDFs)的环保添加剂。这是由于它们的可持续性,可生物降解,和生物相容性。此外,纤维素纳米材料(CNM),包括CNF和CNCs,具有独特的特性,如纳米级尺寸,一个大的表面积,以及独特的机械,热,和流变性能使它们与WBDF中使用的其他添加剂相比脱颖而出。高表面水化能力,与膨润土强烈的相互作用,CNM结构中复杂网络的存在使它们能够在WBDF中充当有效的流变改性剂。此外,CNM的纳米尺寸和易于调节的表面化学性质使它们适合作为有效的降滤失剂以及页岩抑制剂,因为它们具有渗透能力,吸收,并堵塞暴露地层内的纳米孔,并防止水进一步渗透到地层中。本文综述了近年来纤维素衍生物的应用进展,包括CMC,PAC,HEC,CNFs,和CNCs,作为WBDF中的添加剂。首先讨论纤维素衍生物的结构和合成,其次是它们作为流变学的具体应用,降滤失剂,和WBDFs中的页岩抑制添加剂。最后,概述了挑战和未来前景,以指导在WBDF中有效利用纤维素衍生物作为添加剂的进一步研究和开发。
    The application of cellulose derivatives including carboxymethyl cellulose (CMC), polyanionic cellulose (PAC), hydroxyethyl cellulose (HEC), cellulose nanofibrils (CNFs), and cellulose nanocrystals (CNCs) has gained enormous interest, especially as environmentally friendly additives for water-based drilling fluids (WBDFs). This is due to their sustainable, biodegradable, and biocompatible nature. Furthermore, cellulose nanomaterials (CNMs), which include both CNFs and CNCs, possess unique properties such as nanoscale dimensions, a large surface area, as well as unique mechanical, thermal, and rheological performance that makes them stand out as compared to other additives used in WBDFs. The high surface hydration capacity, strong interaction with bentonite, and the presence of a complex network within the structure of CNMs enable them to act as efficient rheological modifiers in WBDFs. Moreover, the nano-size dimension and facilely tunable surface chemistry of CNMs make them suitable as effective fluid loss reducers as well as shale inhibitors as they have the ability to penetrate, absorb, and plug the nanopores within the exposed formation and prevent further penetration of water into the formation. This review provides an overview of recent progress in the application of cellulose derivatives, including CMC, PAC, HEC, CNFs, and CNCs, as additives in WBDFs. It begins with a discussion of the structure and synthesis of cellulose derivatives, followed by their specific application as rheological, fluid loss reducer, and shale inhibition additives in WBDFs. Finally, the challenges and future perspectives are outlined to guide further research and development in the effective utilization of cellulose derivatives as additives in WBDFs.
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  • 文章类型: Journal Article
    了解炎症的程度对于早期疾病检测至关重要,监测疾病进展,并评估治疗反应。在过去的十年里,研究人员已经证明有必要通过使用不同技术对组织粘弹性进行定性或定量表征来了解炎症的程度.在这篇科学评论中,对疾病中弹性和粘度之间关联的研究的检查,特别是随着组织炎症的发展,是进行的。还对利用机械流变模型表征正常和发炎组织的定量粘弹性参数进行了回顾。根据纳入和排除标准,在2000年1月至2024年1月发表的290篇文章中,我们确定了14篇全文研究适合进行综述.我们使用PRISMA指南进行系统评价。在审查中,三项研究证明了研究人员在确定最佳流变模型时使用的标准。11项研究显示了流变模型在定量正常和病理组织的粘弹性中的临床应用。该评价量化了各种软组织中正常和病理组织的粘弹性参数。它评估了每种粘弹性在区分正常和病理组织硬度方面的有效性。此外,该综述概述了其他粘弹性相关参数,供研究人员在未来的刚度分类研究中考虑.
    Understanding the extent of inflammation is crucial for early disease detection, monitoring disease progression, and evaluating treatment responses. Over the past decade, researchers have demonstrated the need to understand the extent of inflammation through qualitative or quantitative characterization of tissue viscoelasticity using different techniques. In this scientific review, an examination of research on the association between elasticity and Viscosity in diseases, particularly as tissue inflammation progresses, is conducted. A review of utilizing mechanical rheological models to characterize quantitative viscoelastic parameters of normal and inflamed tissues is also undertaken. Based on inclusion and exclusion criteria, we identified 14 full-text studies suitable for review out of 290 articles published from January 2000 to January 2024. We used PRISMA guidelines for the systematic review. In the review, three studies demonstrated the criterion used by the researchers in identifying the best rheological model. Eleven studies showed the clinical application of the rheological model in quantifying the viscoelastic properties of normal and pathological tissue. The review quantified viscoelastic parameters for normal and pathological tissue across various soft tissues. It evaluated the effectiveness of each viscoelastic property in distinguishing between normal and pathological tissue stiffness. Furthermore, the review outlined additional viscoelastic-related parameters for researchers to consider in future stiffness classification studies.
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  • 文章类型: Journal Article
    这篇综述利用了优化的Rouse-Zimm离散流体动力学模型和预平均Oseen张量,其中准确地考虑了流体动力学相互作用来研究模型树枝状聚合物。我们报告了先前为创建树枝状聚合物的广义分析模型而开发的分析理论。这些广义理论用于评估树枝状聚合物的构象和动力学行为。通过在键中包括刚度,对排除的体积相互作用的忽视可能会有所抵消。这至少在短间隔件的情况下是正确的。虽然树枝状聚合物中单个键向量的方向和取向的拓扑限制实现了半柔性,这些接触的强度由键的潜在几何取向决定,以及后来在树枝状聚合物中排除的体积相互作用,根据最近的非键合单体之间的有效共体积进行描述,并使用δ函数伪势进行建模。借助开发的模型,作者总结了树枝状聚合物的各种构象和动态特性,这些特性取决于它们的半柔性程度和排除体积的强度。这些分析得出的结论是,一个极限中的柔性树枝状聚合物和另一个极限中的先前描述的树枝状聚合物的自由旋转模型构成了在树枝状聚合物中开发的数学模型中捕获各种构象的高度广义的方式。
    This review utilizes an optimized Rouse-Zimm discrete hydrodynamic model and the preaveraged Oseen tensor, which accurately consider hydrodynamic interactions to study model dendrimers. We report the analytical theories that have been previously developed for the creation of generalized analytical models for dendrimers. These generalized theories were used to assess the conformational and dynamical behavior of the dendrimers. By including stiffness in the bonds, the neglect of excluded volume interactions may be somewhat offset. This is true at least in the case of short spacers. While the topological limitations on the directions and orientations of the individual bond vectors in dendrimers implement semiflexibility, the intensity of these contacts was determined by the potential geometric orientations of the bonds, and later on the excluded volume interactions in dendrimers, which were described in terms of the effective co-volume between nearest non-bonded monomers and modeled using the delta function pseudopotential. With the aid of the models developed, the authors condensed various conformational and dynamic properties of dendrimers that depend on their degree of semiflexibility and the strength of the excluded volume. These analyses came to the conclusion that the flexible dendrimer in one limit and the earlier described freely rotating model of dendrimers in the other constitute a highly generalized way of capturing a wide range of conformations in the developed mathematical model in dendrimers.
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  • 文章类型: Journal Article
    消费者对新鲜口味的无添加剂产品越来越感兴趣,导致高压处理(HPP)作为热加工的替代品的增长趋势。这篇综述探讨了HPP对果汁性能的影响,冰沙,和果泥,以及它在食品工业中的实际应用。研究结果表明,与热加工相比,HPP是最有前途的技术,在两个方面,即,确保微生物安全和最大限度地保留微观和宏观营养素和功能成分。HPP保留了自然颜色,消除了对人工着色的需要。该评论还强调了其在饮料行业中增强风味的潜力。该综述还讨论了HPP如何间接影响导致异味的植物酶,并根据研究调查提出了酶失活的潜在障碍方法。关于改善有关营养保留的商业操作高压机制的质量见解的科学研究为扩大规模铺平了道路,并提高了对HPP设备的市场需求。在未来的研究中,明确的重点应该是与消费者可接受性和感知相关的科学参数和感官属性,以更好地澄清HPP对果汁和冰沙/果泥的影响。
    Consumers are increasingly interested in additive-free products with a fresh taste, leading to a growing trend in high pressure processing (HPP) as an alternative to thermal processing. This review explores the impact of HPP on the properties of juices, smoothies, and purees, as well as its practical applications in the food industry. Research findings have explained that HPP is a most promising technology in comparison to thermal processing, in two ways i.e., for ensuring microbial safety and maximum retention of micro and macro nutrients and functional components. HPP preserves natural color and eliminates the need for artificial coloring. The review also emphasizes its potential for enhancing flavor in the beverage industry. The review also discusses how HPP indirectly affects plant enzymes that cause off-flavors and suggests potential hurdle approaches for enzyme inactivation based on research investigations. Scientific studies regarding the improved quality insights on commercially operated high pressure mechanisms concerning nutrient retention have paved the way for upscaling and boosted the market demand for HPP equipment. In future research, the clear focus should be on scientific parameters and sensory attributes related to consumer acceptability and perception for better clarity of the HPP effect on juice and smoothies/purees.
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  • 文章类型: Journal Article
    在过去的十年里,由蛋白质颗粒稳定的皮克林乳液(PE)一直是研究的重点。油-水界面处的蛋白质颗粒的特性对于稳定PE至关重要。蛋白质颗粒独特的吸附行为和各种改性方法使油水界面表现出可控的调节策略。然而,从接口的角度来看,关于蛋白质颗粒在油-水界面的吸附行为对PEs的调控研究有限。因此,本文对蛋白质颗粒的油水界面吸附及其对PEs的调控进行了深入的研究。具体来说,阐述了界面层的形成及其界面特性对蛋白质颗粒稳定的PE的影响。特别是,复杂的行为,包括吸附,蛋白质颗粒在油水界面的排列和变形是影响界面层形成的前提。此外,颗粒大小,表面电荷,形态和润湿性对蛋白质颗粒的界面吸附行为有很大影响。重要的是,基于蛋白质颗粒的PE的稳定性也取决于界面层的性质,包括界面层厚度和界面流变性。这篇综述为基于界面设计的蛋白质颗粒稳定的PE的开发提供了有用的见解。
    Over the past decade, Pickering emulsions (PEs) stabilized by protein particles have been the focus of researches. The characteristics of protein particles at the oil-water interface are crucial for stabilizing PEs. The unique adsorption behaviors of protein particles and various modification methods enable oil-water interface to exhibit controllable regulation strategies. However, from the perspective of the interface, studies on the regulation of PEs by the adsorption behaviors of protein particles at oil-water interface are limited. Therefore, this review provides an in-depth study on oil-water interfacial adsorption of protein particles and their regulation on PEs. Specifically, the formation of interfacial layer and effects of their interfacial characteristics on PEs stabilized by protein particles are elaborated. Particularly, complicated behaviors, including adsorption, arrangement and deformation of protein particles at the oil-water interface are the premise of affecting the formation of interfacial layer. Moreover, the particle size, surface charge, shape and wettability greatly affect interfacial adsorption behaviors of protein particles. Importantly, stabilities of protein particles-based PEs also depend on properties of interfacial layers, including interfacial layer thickness and interfacial rheology. This review provides useful insights for the development of PEs stabilized by protein particles based on interfacial design.
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  • 文章类型: Journal Article
    通过面糊涂层调节食品表面是减少油炸产品中油的存在的有前途的方法。这篇评论批判性地讨论了功能,行动机制,流变学,配方成分,过程的数学建模,烹饪方法,安全和监管方面,物理化学,面糊涂层的热微观结构表征,以及未来的研究方向。大量的成分可用于制备减油粘弹性面糊涂层,其中主要包括面粉,水胶体,和淀粉。生物活性化合物,酶,矿物,草药提取物,烘焙剂,糖醇,等。可以掺入面糊配方中以影响包衣产品的味道和质地。面糊涂层油炸食品的整体传质过程可以通过几个数学模型来表征(Fick,牛顿,Page,Henderson&Pabis,已修改的页面,阿伦尼乌斯)。表面和内部微结构表征技术,热探测,物理化学表征技术和人工智能可以表征面糊涂层的不同功能,包括减油和纹理演变。
    Food surface modulation by batter coating is a promising approach to reduce the presence of oil in fried products. This review critically discussed the functionalities, mechanism of actions, rheology, ingredients of formulation, mathematical modeling of the process, cooking method, safety and regulatory aspects, physicochemical, thermal-microstructural characterization of batter coatings, and future research directions. Enormous list of ingredients could be used in preparation of oil-reducing viscoelastic batter coating that includes mostly flours, hydrocolloids, and starches. Bioactive compounds, enzymes, minerals, herbal extracts, baking agents, sugar alcohols, etc. could be incorporated in batter formulation to affect the taste and texture of coated products. Overall mass-transfer process of batter-coated fried foods could be characterized by several mathematical models (Fick, Newton, Page, Henderson & Pabis, modified Page, Arrhenius). Surface and internal microstructural characterization techniques, thermal probing, physicochemical characterization techniques and artificial intelligence can characterize different functionalities of batter coatings including oil reduction and textural evolution.
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  • 文章类型: Journal Article
    3D打印技术可以生产出满足消费者需求的创意和个性化食品,例如有吸引力的视觉外观,强化特定的营养素,和修改的纹理。普及和多样化3D打印食品,对各种食品糊的印刷可行性的评估,包括无法本地打印的材料,是必要的。大多数动物资源,比如肉,牛奶,和鸡蛋,不是天生可打印的;因此,控制可印刷性的流变性能应该通过前/后处理或添加适当的添加剂来改善。本文综述了基于挤出的3D打印动物资源油墨的最新进展。此外,这篇综述讨论了油墨成分的影响,打印条件,并对印刷结构的印刷性能和特征进行后处理。需要进一步的研究来提高基于动物资源的印刷食品的感官质量以及营养和质地特性。
    3D printing technology enables the production of creative and personalized food products that meet consumer needs, such as an attractive visual appearance, fortification of specific nutrients, and modified textures. To popularize and diversify 3D-printed foods, an evaluation of the printing feasibility of various food pastes, including materials that cannot be printed natively, is necessary. Most animal resources, such as meat, milk, and eggs, are not inherently printable; therefore, the rheological properties governing printability should be improved through pre-/post-processing or adding appropriate additives. This review provides the latest progress in extrusion-based 3D printing of animal resource-based inks. In addition, this review discusses the effects of ink composition, printing conditions, and post-processing on the printing performance and characteristics of printed constructs. Further research is required to enhance the sensory quality and nutritional and textural properties of animal resource-based printed foods.
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