Carbon materials technology provides the possibility of synthesizing low-cost, outstanding performance replacements to noble-metal catalysts for long-term use. Graphdiyne (GDY) is a carbon allotrope with an extremely thin atomic thickness. It consists of carbon elements, that are hybridized with both sp. and sp2, resulting in a multilayered two-dimensional (2D) configuration. Several functional models suggest, that GDY contains spontaneously existing band structure with Dirac poles. This is due to the non-uniform interaction among carbon atoms, which results from various fusions and overlapping of the 2pz subshell. Unlike other carbon allotropes, GDY has Dirac cone arrangements, that in turn give it inimitable physiochemical characteristics. These properties include an adjustable intrinsic energy gap, high speeds charging transport modulation efficiency, and exceptional conductance. Many scientists are interested in such novel, linear, stacked materials, including GDY. As a result, organized synthesis of GDY has been pursued, making it one of the first synthesized GDY materials. There are several methods to manipulate the band structure of GDY, including applying stresses, introducing boron/nitrogen loading, utilizing nanowires, and hydrogenations. The flexibility of GDY can be effectively demonstrated through the formation of nano walls, nanostructures, nanotube patterns, nanorods, or structured striped clusters. GDY, being a carbon material, has a wide range of applications owing to its remarkable structural and electrical characteristics. According to subsequent research, the GDY can be utilized in numerous energy generation processes, such as electrochemical water splitting (ECWS), photoelectrochemical water splitting (PEC WS), nitrogen reduction reaction (NRR), overall water splitting (OWS), oxygen reduction reaction (ORR), energy storage materials, lithium-Ion batteries (LiBs) and solar cell applications. These studies suggested that the use of GDY holds significant potential for the development and implementation of efficient, multimodal, and intelligent catalysts with realistic applications. However, the limitation of GDY and GDY-based composites for forthcoming studies are similarly acknowledged. The objective of these studies is to deliver a comprehensive knowledge of GDY and inspire further advancement and utilization of these unique carbon materials.

Graphdiyne is a two-dimensional carbon nanomaterial synthesized artificially in 2010. Its outstanding performance is considered to have great potential in different fields. This article summarizes the work of graphdiyne in the sensing field by literature summary and bibliometrics analysis. The development of graphdiyne in the field of sensing has gone through a process from theoretical calculation to experimental verification. Especially in the last three years, there has been very rapid development. The theoretical calculations suggest that graphdiyne is an excellent gas sensing material, but there is little experimental evidence in this direction. On the contrary, graphdiyne has been widely reported in the field of electrochemical sensing. At the same time, graphdiyne can also be used as a molecular switch for DNA sequencing. Fluorescent sensors based on graphdiyne have also been reported. In general, the potential of graphdiyne in sensing still needs to be explored. Current research results do not show that graphdiyne has irreplaceable advantages in sensing. The bibliometric analysis used in this review also provides cooperative network analysis and co-citation analysis on this topic. This provides a reference for the audience wishing to undertake research on the topic. In addition, according to the analysis, we also listed the direction that which this field deserves attention in the future.

The development of carbon materials brings a new two-dimensional catalyst support, graphdiyne (GDY), which is attracting increasing interest in the field of catalysis. This article presents a systematical review of recent studies about the characteristics, design strategies, and applications of GDY-supported catalysts. The sp- and sp2-hybridized carbon, high electrical conductivity, direct band gap, and high intrinsic carrier mobility are key characteristics for GDY to serve as a competitive catalyst support. Hydrothermal method (or solvothermal method), GDY in-situ growth, and electrochemical deposition are commonly used to load catalysts on GDY support. In the applications of GDY-supported photocatalysts, GDY mainly serves as an electron or hole transfer material. For the electrocatalytic hydrogen production, the unique electronic structure and high electrical conductivity of GDY can promote the electron transfer and water splitting kinetics. This review is expected to provide meaningful insight and guidance for the design of GDY-supported catalysts and their applications.

Graphdiyne (GDY), a two-dimensional artificial-synthesis carbon material, has aroused tremendous interest because of its unique physical properties. The very high activity affords the possibility to chemically dope GDY with metal atoms or lightweight elements such as hydrogen and halogen and so on. Chemical doping has been confirmed to be an effective method to lead to various GDY derivatives with useful physical properties. Thus, this review is intended to provide an overview of the electronic, optical, and magnetic properties of pristine GDY and its derivatives reported from theories to experiments. Because of the importance of pristine GDY and its derivatives in real applications, we also summarize the main physical applications of GDY and its derivatives reported in recent years in this review. We believe that the review will be valuable to all those interested in GDY.