Rare earth elements (REEs) are a group consisting of the following 17 metals: Ce, Dy, Er, Eu, Gd, Ho, La, Lu, Nd, Pr, Pm, Sc, Sm, Tb, Tm, Y and Yb. In the current century, the number of applications of REEs has significantly increased. They are being used as components in high technology devices of great importance industrial/economic. However, information on the risk of human exposure to REEs, as well as the potential toxic effects of these elements is still limited. In general terms, dietary intake is the main route of exposure to metals for non-occupationally exposed individuals, which should be also expected for REEs. The current paper aimed at reviewing the studies -conducted over the world- that focused on determining the levels of REEs in foods, as well as the dietary intake of these elements. Most studies do not suggest potential health risk for consumers of freshwater and marine species of higher consumption, or derived from the intake of a number of vegetables, fruits, mushrooms, as well as other various foodstuffs (honey, tea, rice, etc.). The current estimated daily intake (EDI) of REEs does not seem to be of concern. However, considering the expected wide use of these elements in the next years, it seems to be clearly recommendable to assess periodically the potential health risk of the dietary exposure to REEs. This is already being done with well-known toxic elements such as As, Cd, Pb and Hg, among other potentially toxic metals.

The growing utilization of rare earth elements (REEs) in industrial and technological applications has captured global interest, leading to the development of high-performance technologies in medical diagnosis, agriculture, and other electronic industries. This accelerated utilization has also raised human exposure levels, resulting in both favourable and unfavourable impacts. However, the effects of REEs are dependent on their concentration and molecular species. Therefore, scientific interest has increased in investigating the molecular interactions of REEs with biomolecules. In this current review, particular attention was paid to the molecular mechanism of interactions of Lanthanum (La), Cerium (Ce), and Gadolinium (Gd) with biomolecules, and the biological consequences were broadly interpreted. The review involved gathering and evaluating a vast scientific collection which primarily focused on the impact associated with REEs, ranging from earlier reports to recent discoveries, including studies in human and animal models. Thus, understanding the molecular interactions of each element with biomolecules will be highly beneficial in elucidating the consequences of REEs accumulation in the living organisms.

Phytomining is a promising method that employs hyperaccumulators to concentrate metals from various substrates. Many studies on phytomining have been reported in the literature, while how to recover metals from hyperaccumulators has not been well resolved, which is critical for developing a complete phytomining-based metal recovery process. The most straightforward approach is to combust hyperaccumulators and recover metals from the combustion residue. However, the combustion process results in significant waste and carbon emissions. In contrast to combustion, thermochemical treatments can convert the biomass of hyperaccumulators to valuable products, such as biochar, hydrochar, biocrudes, and biogas. Therefore, it is more sustainable to develop a process that combines thermochemical treatments for metal recovery from hyperaccumulators. To achieve this objective, a systematic and comprehensive understanding of product characteristics and metal fate during thermochemical processing is required. In this article, three emerging thermochemical technologies, i.e., microwave-assisted pyrolysis, hydrothermal processing, and microwave-assisted hydrothermal treatment, are systematically reviewed in terms of conversion mechanisms, merits, demerits, product characteristics, and metal fate. Significant findings reported in the literature on the effects of operating parameters on product characteristics and metal fate during thermochemical treatment of waste biomass, especially those from hyperaccumulators, were summarized. Due to limited studies on thermochemical treatments of rare earth element hyperaccumulators, this review is expanded to include hyperaccumulators of any metal species. Based on comparisons among the three emerging thermochemical treatment technologies, microwave-assisted hydrothermal pyrolysis is identified as the most promising approach that favors carbon product obtainment and REE recovery from hyperaccumulators.

How mine tailings storage facilities (TSF) are managed reflects the history, regulatory framework, and environment of a country and locale of the mine. Despite many attempts to find an environmentally friendly strategy for tailings management and governance that balances the needs of society and the ecosystem, there is no worldwide agreement regarding the best practices for tailings management and governance. This article reviews the evolution of copper tailings management and governance in Chile, current practices, and changes that could be or may need to be made to improve practices in response to local environmental conditions and local tolerance for risk. The progress to date in developing a holistic tailings management strategy is summarized. This article also describes recent proposals for the best available technologies (BATs), case histories of Chilean TSF using conventional technology, thickened tailings, paste tailings, filtered tailings, water use reduction, tailings reprocessing to obtain rare earth elements (REEs), circular economy, submarine deep-sea tailings disposal, and ways to avoid failure in a seismic region. Finally, the Chilean tailings industry\'s pending issues and future challenges in reducing the socioenvironmental impacts of tailings are presented, including advances made and lessons learned in developing more environmentally friendly solutions.