ozone (O3)

臭氧 (O3)
  • 文章类型: Journal Article
    目前的证据表明,空气中的污染物通过出现小于胎龄(SGA)或足月低出生体重(TLBW)对胎儿生长产生不利影响。该研究的目的是批判性地评估有关环境污染与SGA或TLBW发生率之间关联的现有文献。在Pubmed/MEDLINE进行了全面的文献检索,WebofScience,科克伦图书馆,EMBASE,和谷歌学者使用预定义的纳入和排除标准。该方法符合PRISMA准则。系统评价方案在PROSPERO注册,ID号:CRD42022329624。因此,69篇选定的论文描述了环境污染物对SGA和TLBW发生的影响,颗粒物≤10μm(PM10)的赔率(ORs)为1.138,颗粒物≤2.5μm(PM2.5)为1.338,1.173代表臭氧(O3),1.287二氧化硫(SO2),一氧化碳(CO)为1.226。分析的所有8项研究都验证了暴露于挥发性有机化合物(VOCs)是SGA或TLBW的危险因素。SGA发生的高危人群中的孕妇,即,那些生活在城市地区或接近污染源的人,并发症的风险增加。了解孕妇的确切暴露时间有助于改善产前护理和对SGA胎儿的及时干预。然而,我们的研究结果中强调的普遍空气污染表明,迫切需要在日常生活中采取适应性措施来减轻全球环境污染。
    Current evidence suggests that airborne pollutants have a detrimental effect on fetal growth through the emergence of small for gestational age (SGA) or term low birth weight (TLBW). The study\'s objective was to critically evaluate the available literature on the association between environmental pollution and the incidence of SGA or TLBW occurrence. A comprehensive literature search was conducted across Pubmed/MEDLINE, Web of Science, Cochrane Library, EMBASE, and Google Scholar using predefined inclusion and exclusion criteria. The methodology adhered to the PRISMA guidelines. The systematic review protocol was registered in PROSPERO with ID number: CRD42022329624. As a result, 69 selected papers described the influence of environmental pollutants on SGA and TLBW occurrence with an Odds Ratios (ORs) of 1.138 for particulate matter ≤ 10 μm (PM10), 1.338 for particulate matter ≤ 2.5 μm (PM2.5), 1.173 for ozone (O3), 1.287 for sulfur dioxide (SO2), and 1.226 for carbon monoxide (CO). All eight studies analyzed validated that exposure to volatile organic compounds (VOCs) is a risk factor for SGA or TLBW. Pregnant women in the high-risk group of SGA occurrence, i.e., those living in urban areas or close to sources of pollution, are at an increased risk of complications. Understanding the exact exposure time of pregnant women could help improve prenatal care and timely intervention for fetuses with SGA. Nevertheless, the pervasive air pollution underscored in our findings suggests a pressing need for adaptive measures in everyday life to mitigate worldwide environmental pollution.
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  • 文章类型: Systematic Review
    越来越多的证据表明间质性肺病(ILD)与空气污染之间存在因果关系,都是为了疾病的发展,并推动疾病进展。我们的目标是提供关于空气污染之间关联的全面文献综述,ILD,包括特发性肺纤维化(IPF)。
    我们从六个在线数据库中进行了系统搜索。两名独立作者(DL和CF)选择了研究,并使用纽卡斯尔-渥太华量表(NOS)严格评估了偏倚的风险。研究结果通过叙事综合和荟萃分析呈现。当至少有三项研究检查相同的污染物-健康结果对时,仅进行荟萃分析。所有评估污染物浓度的等效增量,使用随机效应模型。
    确定了在13个国家或地区进行的24项观察性研究。正在调查的污染物包括臭氧(O3),二氧化氮(NO2),直径为10微米或更小(PM10)和2.5微米或更小(PM2.5)的颗粒物,二氧化硫(SO2),一氧化碳(CO),一氧化氮(NO)和氮氧化物(NOx)。我们进行了荟萃分析,以评估急性加重(AE)-IPF的估计风险比(RR)与暴露于空气污染物浓度每增加10μg/m3有关。包括O3、NO2、PM10和PM2.5。荟萃分析显示,PM2.5中AE-IPF的风险增加之间存在显着关联,RR为1.94(95%CI1.30-2.90;p=0.001)。所有纳入研究的结果表明,暴露于空气污染物的增加可能与ILD患者的一系列健康问题有关。
    关于空气污染物和ILD关系的现有研究的匮乏强调了在该领域进行进一步全面研究的必要性。现有数据表明,降低大气中PM2.5的水平可能会降低ILD患者的AE频率和严重程度。
    UNASSIGNED: There is a growing body of evidence suggesting a causal relationship between interstitial lung disease (ILD) and air pollution, both for the development of the disease, and driving disease progression. We aim to provide a comprehensive literature review of the association between air pollution, and ILD, including idiopathic pulmonary fibrosis (IPF).
    UNASSIGNED: We systematically searched from six online database. Two independent authors (DL and CF) selected studies and critically appraised the risk of bias using the Newcastle-Ottawa Scale (NOS). Findings are presented through a narrative synthesis and meta-analysis. Meta-analyses were performed exclusively when there was a minimum of three studies examining identical pollutant-health outcome pairs, all evaluating equivalent increments in pollutant concentration, using a random effects model.
    UNASSIGNED: 24 observational studies conducted in 13 countries or regions were identified. Pollutants under investigation encompassed ozone (O3), nitrogen dioxide (NO2), Particulate matter with diameters of 10 micrometers or less (PM10) and 2.5 micrometers or less (PM2.5), sulfur dioxide (SO2), carbon monoxide (CO), nitric oxide (NO) and nitrogen oxides (NOx). We conducted meta-analyses to assess the estimated Risk Ratios (RRs) for acute exacerbations (AE)-IPF in relation to exposure to every 10 μg/m3 increment in air pollutant concentrations, including O3, NO2, PM10, and PM2.5. The meta-analysis revealed a significant association between the increased risk of AE-IPF in PM2.5, yielding RR 1.94 (95% CI 1.30-2.90; p = 0.001). Findings across all the included studies suggest that increased exposure to air pollutants may be linked to a range of health issues in individuals with ILDs.
    UNASSIGNED: A scarcity of available studies on the air pollutants and ILD relationship underscores the imperative for further comprehensive research in this domain. The available data suggest that reducing levels of PM2.5 in the atmosphere could potentially reduce AE frequency and severity in ILD patients.
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  • 文章类型: Journal Article
    采用在大气压空间化学气相沉积(AP-SCVD)条件下操作的大气压空间原子层沉积(AP-SALD)系统,使用三甲基铝和不同的氧化剂沉积氧化铝(AlOx)薄膜,包括水(H2O),过氧化氢(H2O2),臭氧(O3)研究了氧前驱体对薄膜结构性能及其防潮性能的影响。O3-AlOx薄膜,其次是H2O2-AlOx,表现出更高的折射率,较低浓度的OH-基团,与使用水(H2O-AlOx)沉积的薄膜相比,水蒸气透过率更低。然后,AlOx薄膜作为薄膜封装层在130ºC下快速沉积在钙钛矿太阳能电池上,而不会损坏对温度敏感的钙钛矿和有机材料。封装层显著提高了p-i-n甲脒铵甲基碘化铅太阳能电池在标准ISOS-D-3测试条件(65ºC和85%相对湿度)下的稳定性。具体来说,与未包封的细胞相比,O3-AlOx和H2O2-AlOx层导致细胞降解至其原始效率的80%所需的时间增加六倍。
    An atmospheric-pressure spatial atomic layer deposition system operated in atmospheric-pressure spatial chemical vapor deposition conditions is employed to deposit alumina (AlOx) thin films using trimethylaluminum and different oxidants, including water (H2O), hydrogen peroxide (H2O2), and ozone (O3). The impact of the oxygen precursor on the structural properties of the films and their moisture-barrier performance is investigated. The O3-AlOxfilms, followed by H2O2-AlOx, exhibit higher refractive indexes, lower concentrations of OH- groups, and lower water-vapor-transmission rates compared to the films deposited using water (H2O-AlOx). The AlOxfilms are then rapidly deposited as thin-film-encapsulation layers on perovskite solar cells at 130 °C without damaging the temperature-sensitive perovskite and organic materials. The stability of thep-i-nformamidinium methylammonium lead iodide solar cells under standard ISOS-D-3 testing conditions (65 °C and 85% relative humidity) is significantly enhanced by the encapsulation layers. Specifically, the O3-AlOxand H2O2-AlOxlayers result in a six-fold increase in the time required for the cells to degrade to 80% of their original efficiency compared to un-encapsulated cells.
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  • 文章类型: English Abstract
    近年来,我国臭氧污染形势日益严峻,PM2.5是几个城市大气环境中的主要污染物。气象条件,特别是温度和湿度,对臭氧的形成有很大的影响。因此,了解和量化温湿度变化对臭氧水平的影响,可以有效地为政府防治臭氧污染提供理论依据。通过分析日最高气温(Tmax)之间的关系,相对湿度(RH),从2015年1月1日至2022年7月31日测得的最大8小时运行平均臭氧(O3-8h),在臭氧污染严重的七个地区观察到O3-8h与Tmax之间呈线性正相关,温度惩罚因子范围为2.1-6.0μg·(m3·℃)-1;还观察到O3-8h与RH之间存在非线性相关性,相对湿度为55%时O3-8h最高。不同区域对Tmax和RH的敏感性略有不同;一般来说,臭氧形成的最适宜气象条件为29℃≤Tmax<38℃,40%≤RH<70%。在长江三角洲,江苏-安徽-山东-河南,和长江中游,在极端高温条件下(Tmax≥35℃),O3-8h随着温度的升高而停止增加,甚至下降;同时,它通常伴随着颗粒物的少量增加。这可能与某些具有较高水蒸气含量的前体的非均相反应和臭氧非均相汇的增加有关。
    In recent years, the situation of ozone pollution in China has become increasingly severe, with PM2.5 being the main pollutant in the atmospheric environment of several cities. Meteorological conditions, particularly temperature and humidity, have a great influence on ozone formation. Therefore, understanding and quantifying the impact of the variation in temperature and humidity on ozone level can effectively provide the theoretical basis for the government to prevent and control ozone pollution. By analyzing the relationship among the daily maximum temperature (Tmax), relative humidity (RH), and the maximum 8-h running average ozone (O3-8h) measured from January 1, 2015 to July 31, 2022, a linear positive correlation between O3-8h and Tmax was observed in the seven regions with serious ozone pollution, and the temperature penalty factor ranged from 2.1-6.0 μg·(m3·℃)-1; a nonlinear correlation between O3-8h and RH was also observed, and O3-8h was the highest when RH was 55%. The sensitivity of different regions to Tmax and RH was slightly different; generally, the most suitable meteorological conditions for ozone formation were 29℃ ≤ Tmax< 38℃ and 40% ≤ RH<70%. In the Yangtze River Delta, Jiangsu-Anhui-Shandong-Henan, and the middle reaches of the Yangtze River, under extreme high temperature conditions (Tmax ≥ 35℃), O3-8h stopped increasing with the increase in temperature and even dropped; simultaneously, it was often accompanied with a small increase in particulate matter. It may be related to the heterogeneous reaction of some precursors with higher water vapor content and the increase in ozone heterogeneous sink.
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  • 文章类型: English Abstract
    基于OMI遥感卫星数据,对流层臭氧(O3)的时空特征,二氧化氮(NO2),分析了2005-2021年华东地区甲醛(HCHO)浓度,并使用后向轨迹(HYSPLIT)模型来探索它们的来源。结果表明:①在这17年间,对流层O3浓度稳步增加,在2010年达到最大值,然后呈现波动和起伏状态。NO2从2005年到2012年呈增加趋势,从2012年到2021年呈缓慢下降趋势。HCHO的平均浓度从2005年的1.15×1016mol·cm-2增加到2021年的1.8×1016mol·cm-2。②在空间特征方面,这三种污染物的浓度总体上呈北部高浓度,南部低浓度的模式,在北方浓度很高,不寻常的集中在中间,南方的浓度很低。③O3的灵敏度为:春季η<2.3,属于VOCs控制区;夏季η<4.2,结果表明,大部分地区是NOx-VOCs协调控制区,少数地区是VOCs控制区;秋季η<4.2,主要由挥发性有机化合物控制,其中一些是NOx-VOC协同控制区;冬季η<2.3,这是VOCs控制区域。VOCs主要在山东省得到控制。④由于2005-2021年山东省O3浓度较高,济南,2021年,山东省省会城市被选作臭氧源分析。2021年济南市O3浓度上升有两个方面。首先,长途航空运输主要起源于江苏省连云港市和河北省沧州市。第二,近距离的气团运输源于济南附近城市和黄渤海经济区的污染,并且聚合分析结果与潜在源贡献因子算法(PSCF)和加权轨迹分析(CWT)的结果一致。
    Based on OMI remote sensing satellite data, the temporal and spatial characteristics of tropospheric ozone (O3), nitrogen dioxide (NO2), and formaldehyde (HCHO) concentrations in East China from 2005 to 2021 were analyzed, and the backward trajectory (HYSPLIT) model was used to explore their sources. The results showed that ① during the 17 years, the tropospheric O3 concentration steadily increased, reached the maximum value in 2010, and then showed a fluctuating and undulating state. NO2 showed an increasing trend from 2005 to 2012 and slowly decreased from 2012 to 2021. The average HCHO concentration showed an increasing trend from 1.15×1016molec·cm-2 in 2005 to 1.8×1016 molec·cm-2 in 2021. ② In terms of spatial characteristics, the concentrations of the three pollutants generally showed a pattern of high concentration in the north and low concentration in the south, with a high concentration in the north, uncharacteristic concentration in the middle, and low concentration in the south. ③ The sensitivity of O3 was as follows:η<2.3 in spring, which belonged to the VOCs control area; η<4.2 in summer, showing that most areas were NOx-VOCs coordinated control areas and a few areas were VOCs control areas; η<4.2 in autumn, which was primarily controlled by VOCs, with a few of them being NOx-VOC synergistic control areas; and η<2.3 in winter, which was a VOCs-controlled area. VOCs were primarily controlled in Shandong Province. ④ Owing to the high concentration of O3 in Shandong Province from 2005 to 2021, Jinan, the capital city of Shandong Province in 2021, was selected for ozone source analysis. The O3 concentration increased in Jinan in 2021 owing to two aspects. First, the long-distance air transportation primarily originated from Lianyungang City in Jiangsu Province and Cangzhou City in Hebei Province. Second, the close air mass transport originated from the pollution of cities near Jinan and the economic zones of the Yellow Sea and Bohai Sea, and the aggregation analysis results corresponded with those of the potential source contribution factor algorithm (PSCF) and the weighted trajectory analysis (CWT).
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  • 文章类型: English Abstract
    根据环境空气质量数据,气象观测资料,和卫星遥感数据,臭氧(O3)污染的时空变化,分析了O3的敏感性及其与海南岛气象因子的关系。结果表明,海南岛西部和北部城市的最大日8-h移动平均值(O3-8h)高于中部,东方,和南方城市。2015年O3-8h最高,2019年O3-8h超标比例最大。此外,O3-8h与平均气温呈正相关(P<0.1),日照时数(P<0.01),太阳总辐射(P<0.01),大气压力,平均风速与降水量(P<0.05)、相对湿度呈负相关。卫星遥感数据显示,2015-2020年海南岛对流层NO2柱浓度(NO2-OMI)和HCHO柱浓度(HCHO-OMI)呈现相反趋势。与2015年相比,2020年NO2-OMI增长了7.74%,HCHO-OMI下降了10.2%。此外,海南岛属于氮氧化物控制区,FNR值在过去6年呈现波动下降趋势,趋势系数和气候趋势率分别为-0.514和-0.123a-1。气象因子与海南岛的FNR值之间存在很强的相关性。
    Based on ambient air quality data, meteorological observation data, and satellite remote sensing data, the temporal and spatial variations in ozone (O3) pollution, the sensitivity of O3, and its relationship with meteorological factors in Hainan Island were analyzed in this study. The results showed that the maximum daily 8-h moving mean (O3-8h) in western and northern cities in Hainan Island was higher than that in the central, eastern, and southern cities. O3-8h was the highest in 2015, and O3-8h exceeding the standard proportion was the largest in 2019. In addition, O3-8h was positively correlated with average temperature (P<0.1), sunshine duration (P<0.01), total solar radiation (P<0.01), atmospheric pressure, and average wind speed and was negatively correlated with precipitation (P<0.05) and relative humidity. The satellite remote sensing data showed that the tropospheric NO2 column concentration (NO2-OMI) and HCHO column concentration (HCHO-OMI) displayed opposite trends in Hainan Island from 2015 to 2020. Compared with those in 2015, NO2-OMI increased by 7.74% and HCHO-OMI decreased by 10.2% in 2020. Moreover, Hainan Island belongs to the NOx control area, and the FNR value exhibited a fluctuating downward trend in the past 6 years, with a trend coefficient and climatic trend rate of -0.514 and -0.123 a-1, respectively. A strong correlation was observed between meteorological factors and the FNR value of Hainan Island.
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  • 文章类型: English Abstract
    “十四五”期间是河北南部城市的关键阶段(石家庄,邢台,和邯郸)将从空气质量综合指数的倒数前十名中删除。2020年4-10月河北省南部城市15个国控监测站的小时臭氧(O3)数据,3种挥发性有机物(VOCs)超、小时数据,并利用同期的气象资料进行分析,结合时空演替,O3形成电位(OFP),反向轨迹建模,和空间统计建模。结果表明:首先,4月至10月河北省南部城市O3的时间变化呈倒“U”形,空间分布南高北低。六月份O3污染最严重,邢台(233.8μg·m-3)>邯郸(225.2μg·m-3)>石家庄(224.8μg·m-3)。O3与温度和风速呈正相关,与湿度和VOCs呈负相关;4月至10月的ρ(TVOC)顺序为邢台(274μg·m-3)>石家庄(266μg·m-3)>邯郸(218μg·m-3)。烯烃和芳烃的总OFP占一半以上;此外,河北省南部城市O3污染轨迹表现出空间方向性和相关性。O3的最高质量浓度(198.92μg·m-3)在石家庄至邢台的轨迹中,O3污染频率最高的是邯郸到邢台的轨迹。此外,邢台对石家庄城市群的O3传播贡献较高(27.39%),邯郸在O3对邢台的传输贡献中发挥了重要作用(32.76%)。
    The \"14th Five-Year Plan\" period is the key stage for southern Hebei cities (Shijiazhuang, Xingtai, and Handan) to be removed from the bottom ten of the Air Quality Composite Index. The hourly ozone (O3) data of 15 country-controlled monitoring stations in the southern cities of Hebei Province from April to October 2020, hourly data of three volatile organic compound (VOCs) supersites, and the meteorological data of the same period were used for analysis, combined with the spatiotemporal succession, O3 formation potential (OFP), backward trajectory modeling, and spatial statistical modeling. The results showed the following:firstly, the temporal variations in O3 in southern cities of Hebei Province from April to October presented an inverted \"U\" shape, and the spatial distribution was high in the south and low in the north. O3 pollution was the most serious in June, with Xingtai (233.8 μg·m-3)>Handan (225.2 μg·m-3)>Shijiazhuang (224.8 μg·m-3). O3 was positively correlated with temperature and wind speed and negatively correlated with humidity and VOCs; furthermore, the ρ(TVOC) from April to October followed the order of Xingtai (274 μg·m-3)>Shijiazhuang (266 μg·m-3)>Handan (218 μg·m-3). The total OFP of alkenes and aromatics accounted for more than half; moreover, the trajectory of O3 pollution in southern cities of Hebei Province showed spatial directionality and relevance. The highest mass concentration of O3 (198.92 μg·m-3) was in the trajectory from Shijiazhuang to Xingtai, and the highest frequency of O3 pollution was in the trajectory from Handan to Xingtai. Moreover, the transmission contributions of O3from Xingtai to Shijiazhuang agglomerations were high (27.39%), and Handan played a significant role in the transmission contribution of O3 to Xingtai (32.76%).
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  • 文章类型: English Abstract
    环境空气中高浓度的细颗粒物(PM2.5)和臭氧(O3)影响气候变化,也危害人类健康和生态系统。自2013年实施《大气污染防治行动计划》以来,南京市空气污染状况一直在改善。然而,南京仍面临PM2.5和O3污染。评估污染物浓度对前体排放减少的响应有助于获得有效的减排策略以提高污染水平。大气化学模型中对排放扰动的敏感模拟直接表明了污染对排放减少的响应。然而,这些敏感的模拟是有限的计算时间和资源。利用2015年大气化学输运模型(GEOS-Chem)的仿真结果对随机森林算法进行训练。在人为减排的不同情景下,有效预测了2019年南京市PM2.5日变化和每日最大八小时O3(MDA8O3)浓度变化。模拟结果表明,南京市的ρ(PM2.5)的季节性平均值将减少2-4μg·m-3,2019年中国人为排放量减少10%。在南京只控制局部排放的情况下,在没有当地人为排放的情况下,南京市PM2.5浓度显着下降。此外,模拟结果表明,当2019年中国人为减排量高于20%时,南京市的ρ(PM2.5)年平均值可能低于国家二级限值(35μg·m-3)。对于臭氧,中国O3前体的氮氧化物(NOx)和挥发性有机污染物(VOCs)的等比例减排可能导致南京O3的季节性平均浓度增加。对于中国人为排放量按比例减少10%-50%,2019年南京市春季ρ(MDA8O3)的季节平均值将增加1-3μg·m-3,秋季1-4μg·m-3,冬季为3-11μg·m-3,分别,与基础模拟相比。随着人为NOx排放量减少10%,VOCs减少20%,南京市ρ(MDA8O3)的季节平均值将减少3-6μg·m-3。在此基础上,进一步提高VOCs减排比例(30%)可使南京市ρ(MDA8O3)年均减少7μg·m-3。然而,2019年南京市ρ(MDA8O3)年均增加1μg·m-3,NOx减排10%,VOCs减排30%。因此,这表明,合理控制臭氧前体排放比例和实施区域联防联控是缓解南京市臭氧污染的关键。为了有效减少南京市的O3污染,我国NOx和VOCs的减排比例应小于1:2。通过随机森林算法和GEOS-Chem模型有效地获得了污染物浓度对前体排放减少的响应。模拟将为缓解空气污染的排放控制策略提供科学依据。
    High levels of fine particulate matter (PM2.5) and ozone (O3) in ambient air affect climate change and also endanger human health and ecosystems. Air pollution in Nanjing has been improving since the implementation of the \"Air Pollution Prevention and Control Action Plan\" in 2013. However, Nanjing still faces PM2.5 and O3 pollution. Evaluating the response of pollutant concentrations to the reductions in precursor emissions is helpful to obtain effective strategies of emission reduction to improve pollution levels. The sensitive simulations of emission perturbation in atmospheric chemistry models directly demonstrate the response of pollution to the reductions in emissions. Nevertheless, these sensitive simulations are limited in computing time and resources. The random forest algorithm was trained by using the simulation results of the atmospheric chemical transport model (GEOS-Chem) in 2015. The changes in daily PM2.5 and daily maximum eight-hour O3 (MDA8 O3) concentrations in Nanjing in 2019 were efficiently predicted under different reduction scenarios of anthropogenic emissions. The simulations showed that the seasonal average of ρ(PM2.5) in Nanjing would decrease by 2-4 μg·m-3 with the reduction in anthropogenic emissions of 10% in 2019 in China. In the case of controlling only local emissions in Nanjing, the concentrations of PM2.5 in Nanjing decreased significantly without local anthropogenic emissions. Additionally, the simulations showed that the annual average of ρ(PM2.5) in Nanjing could be lower than the national secondary limit (35 μg·m-3) when the anthropogenic emission reduction in China was higher than 20% in 2019. For ozone, the equal proportional emission reductions in nitrogen oxides (NOx) and volatile organic pollutants (VOCs) of O3 precursors in China likely led to the increase in seasonal average concentrations of O3 in Nanjing. For the proportional reduction of anthropogenic emissions by 10%-50% in China, the seasonal average of ρ(MDA8 O3) in Nanjing in 2019 would increase by 1-3 μg·m-3 in spring, 1-4 μg·m-3 in autumn, and 3-11 μg·m-3 in winter, respectively, compared with that in the base simulation. With the reduction in anthropogenic NOx emission by 10% and VOCs by 20%, the seasonal average of ρ(MDA8 O3) in Nanjing would decrease by 3-6 μg·m-3. On this basis, further increasing the proportion (30%) of VOCs emission reduction could reduce the annual average of ρ(MDA8 O3) in Nanjing by 7 μg·m-3. However, the annual average of ρ(MDA8 O3) of Nanjing in 2019 increased by 1 μg·m-3, with the local emission reduction of NOx by 10% and VOCs by 30%. Therefore, this showed that the key to alleviate ozone pollution in Nanjing is a reasonable control ratio of ozone precursor emissions and the implementation of regional joint prevention and control. In order to effectively reduce the O3 pollution in Nanjing, the emission reduction ratio of NOx and VOCs in China should be less than 1:2. The response of pollutant concentrations to reductions in precursor emissions were efficiently obtained by the random forest algorithm and GEOS-Chem model. The simulations would provide the scientific basis for the emission control strategy to alleviate air pollution.
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  • 文章类型: English Abstract
    变化趋势,关系,利用Kolmogorov-Zurbenko(KZ)滤波结合逐步多元线性回归分析,利用2013-2020年天津市PM2.5和O3时空分辨率监测数据及气象观测数据,对PM2.5和O3浓度的影响因素进行分析.结果表明,从2013年到2020年,PM2.5浓度显着下降趋势,下降了50.0%,而从2013年到2020年,O3浓度上升了25.8%。与2013年至2017年相比,2018年至2020年PM2.5浓度月差逐渐缩小,而4月以来O3浓度明显上升,O3污染的发生时间提前。O3与PM2.5的相关系数格局呈现明显的季节分布特征。相关系数在冬季呈负相关,在夏季呈正相关,夏季的相关系数普遍高于其他季节。O3和PM2.5在不同季节的相关系数与拟合斜率呈正比例关系。拟合斜率与相关系数的比值呈上升趋势,这可能反映了PM2.5对O3形成的抑制作用在PM2.5-O3相互作用机制中可能由于减排的影响而减弱。PM2.5浓度时间序列的长期趋势分量呈显著下降趋势;减排起主导作用,气象因素贡献-3至6μg·m-3。从2013-2017年到2018-2020年,天津市观察到PM2.5/CO比值与NO2/SO2之间由负向正的关系变化,这可能表明在当前的减排情景下,氮氧化物对PM2.5主要次要成分形成的贡献潜力增强,天津市PM2.5的主要次要成分逐渐由硫酸盐向硝酸盐转变。从2013年到2020年,O3浓度时间序列的长期趋势分量总体呈上升趋势,从2013年到2018年,前体排放对O3长期分量的贡献增加,2019年后开始下降。气象因子对O3长期组分的贡献呈现明显的阶段性变化,2013年至2016年呈现下降趋势,2016年至2020年呈现上升趋势。在夏季强烈的大气光化学过程期间(11:00-16:00),O3浓度与NO2呈非线性关系。与2013-2015年相比,O3和NO2的拟合曲线明显抵消了2016-2020年NO2的低值,反映了这一时期的NOx减排取得了一定的成效。与2018年相比,从2019年到2020年,O3和NO2的拟合曲线向下移动,这可能反映了现阶段NOx和VOCs的减排对O3的下降具有不可忽视的影响。
    The change trend, relationship, and influencing factors of PM2.5 and O3 concentrations were analyzed by using a Kolmogorov-Zurbenko (KZ) filter coupled with stepwise multiple linear regression analysis and the spatiotemporal resolution monitoring data of PM2.5 and O3 and meteorological data observed in Tianjin from 2013 to 2020. The results showed that a significant decreasing trend of PM2.5 concentrations by 50.0% was observed from 2013 to 2020, whereas an increasing trend for O3 concentrations by 25.8% was observed from 2013 to 2020. Compared with that in 2013 to 2017, the monthly difference in PM2.5 concentrations gradually narrowed from 2018 to 2020, whereas the concentration of O3 had increased significantly since April, and the occurrence time of O3 pollution was advanced. The correlation coefficient patterns of O3 and PM2.5 showed obvious seasonal distribution characteristics. The correlation coefficients were negatively correlated in winter and positively correlated in the summer, and the correlation coefficients in summer were generally higher than those in other seasons. The correlation coefficients between O3 and PM2.5 in different seasons were positively proportional to the fitting slope. The ratios of the fitting slope to correlation coefficients showed an increasing trend, which might reflect that the inhibitory effect of PM2.5 on O3 formation in the PM2.5-O3 interaction mechanism might have been weakened due to the impact of emission reduction. A significant decreasing trend was observed for the long-term trend components of the PM2.5 concentration time series; emission reduction played a leading role, and meteorological factors contributed -3 to 6 μg·m-3. The changes in the relationship between the PM2.5/CO ratio versus NO2/SO2 from negative to positive were observed from 2013-2017 to 2018-2020 in Tianjin, which could indicate the enhanced contribution potential of nitrogen oxides to the main secondary component formation of PM2.5 under the current emission reduction scenarios, and the main secondary components of PM2.5in Tianjin gradually changed from sulfate to nitrate. An overall upward trend was observed for the long-term trend components of the O3 concentration time series from 2013 to 2020, and the contribution of precursor emissions to the long-term component of O3 increased from 2013 to 2018 and began to decrease after 2019. The contribution of meteorological factors to the long-term component of O3 presented an obvious stage change, showing a downward trend from 2013 to 2016 and an upward trend from 2016 to 2020. The O3 concentration presented a non-linear relationship with NO2 during the period of intense atmospheric photochemical processes (11:00-16:00) in summer. Compared with that in 2013-2015, the fitting curve of O3 and NO2 showed an obvious offset to the low value of NO2 from 2016 to 2020, which reflected that the NOx emission reduction in this period achieved certain results. Compared with that in 2018, the fitting curve of O3 and NO2 moved downward from 2019 to 2020, which may reflect that NOx and VOCs emission reduction had a non-negligible effect on the O3 decline at this stage.
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  • 文章类型: English Abstract
    湖南省臭氧(O3)污染已成为六种常见常规污染物中最重要的因素(即,NO2,SO2,CO,大气环境中的O3,PM10和PM2.5)。进一步的调查表明,对O3的相关研究不足。因此,对于政府监管机构来说,澄清O3变化的关键驱动因素至关重要。在这项研究中,一种由广义加性模型(GAM)组成的组合方法,经验正交函数(EOF),和绝对主成分得分(APC)模型用于识别和量化气象学和局部光化学生成(局部)以及从外部(非局部)运输对2018-2020年O3变化的影响。同时,分析了长沙市2018-2019年和2019-2020年O3年值的驱动因素。结果表明,当前兆的相对贡献较高时,O3事件通常是由气象学引起的,在短期时间尺度上。总的来说,在时间尺度上,气象学和当地是2018年至2019年O3年度增加的驱动因素。此外,气象学的贡献,当地,2019年至2020年,非本地下降,导致2020年O3浓度水平较低。地理上,东方,北,长沙南部主要受气象影响,当地,和非本地的,分别。在这三年中,非本地表现出持续下降的趋势,而气象学和当地的趋势因年份和地理而异。从2018年到2019年,长沙北部的本地贡献有所增加,这可能归因于生物挥发性有机化合物排放(BVOCs)的增加,由于NOx的消耗增加,南部的水平降低了。从2018年到2019年,气象学对所有站点O3的影响都得到了加强。相比之下,从2019年到2020年,随着BVOC和NOx排放量的下降,北部地区的局部贡献减少,南部地区的贡献增加,当时对整个地区O3的气象影响变弱。
    Ozone (O3) pollution in Hunan province has become the most important factor among the six common conventional pollutants (i.e., NO2, SO2, CO, O3, PM10, and PM2.5) in the atmospheric environment. Further investigation has indicated that the relevant studies of O3 are insufficient. Therefore, it is essential to clarify the key driving factors of O3 variations for government regulators. In this study, a combined method consisting of a generalized additive model (GAM), empirical orthogonal function (EOF), and absolute principal component scores (APCs) model was employed to identify and quantify the impacts of meteorology and local photochemical generation (local) and that transported from outside (nonlocal) on O3 variations from 2018-2020. Simultaneously, the driving factors of O3 annual values from 2018 to 2019 and from 2019 to 2020 in Changsha were analyzed. The results showed that O3 episodes were commonly caused by meteorology when the relative contribution from precursors was high, on the short-term time scale. Overall, on the temporal scale, meteorology and local were the driving factors for the increasing annual O3 from 2018 to 2019. Additionally, the contribution from meteorology, local, and nonlocal decreased from 2019 to 2020, leading to a lower level of O3 concentration in 2020. Geographically, the east, north, and south of Changsha were mainly affected by meteorology, local, and nonlocal, respectively. Throughout the three years, nonlocal exhibited a sustained decreasing trend, whereas the tendencies from meteorology and local varied by year and geography. Local contribution in the north of Changsha increased from 2018 to 2019, which was likely attributed to the increasing biogenic volatile organic compound emission (BVOCs), and it became lower in the south owing to the strengthened consumption by NOx. Impacts from meteorology on O3 in all sites were enhanced from 2018 to 2019. By contrast, local contribution decreased in the north and increased in the south with the decline in BVOC and NOx emissions from 2019 to 2020, when the meteorological impacts on O3 in the whole area became weak.
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