multifunctional composite materials

  • 文章类型: Journal Article
    细菌疗法被认为是几种疾病的具有成本效益的治疗方法。然而,它的发展受到有限功能的阻碍,弱的固有治疗效果,以及对恶劣微环境条件的脆弱性,导致次优的治疗活动。增强细菌活性和治疗结果是一个关键的挑战。纳米酶由于其酶模拟活性和高稳定性而引起了极大的关注。它们使细菌能够模拟表达相同功能酶的基因编辑细菌的功能,从而提高细菌活性和治疗功效。这篇综述描述了细菌和纳米酶的治疗机制,其次是制备细菌/纳米酶复合材料的策略总结。此外,强调了这种复合材料在生物医学应用如胃肠道疾病和肿瘤中的协同作用。最后,讨论了细菌/纳米酶复合材料的挑战,并提出了潜在的解决方案。本研究旨在提供有价值的见解,为纳米材料辅助细菌治疗的发展提供理论指导。
    Bacterial therapy is recognized as a cost-effective treatment for several diseases. However, its development is hindered by limited functionality, weak inherent therapeutic effects, and vulnerability to harsh microenvironmental conditions, leading to suboptimal treatment activity. Enhancing bacterial activity and therapeutic outcomes emerges as a pivotal challenge. Nanozymes have garnered significant attention due to their enzyme-mimic activities and high stability. They enable bacteria to mimic the functions of gene-edited bacteria expressing the same functional enzymes, thereby improving bacterial activity and therapeutic efficacy. This review delineates the therapeutic mechanisms of bacteria and nanozymes, followed by a summary of strategies for preparing bacteria/nanozyme composites. Additionally, the synergistic effects of such composites in biomedical applications such as gastrointestinal diseases and tumors are highlighted. Finally, the challenges of bacteria/nanozyme composites are discussed and propose potential solutions. This study aims to provide valuable insights to offer theoretical guidance for the advancement of nanomaterial-assisted bacterial therapy.
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  • 文章类型: Journal Article
    石墨烯纳米片(GNP)的作用,浓度为1、5和10重量%时,通过差示扫描量热法(DSC)和实时X射线衍射实验研究了聚醚醚酮(PEEK)复合材料的熔体结晶和冷结晶过程。DSC结果揭示了GNP的双重作用:(a)在较高温度下从熔体开始结晶的成核作用和(b)由于聚合物链移动性的限制而导致的较长的整体结晶时间。纳米复合材料的流变行为证明了这种受阻的流动性,因为复杂粘度的增加,G\',具有GNP含量的G″,以及在高GNP含量的复合材料中发现的非牛顿行为。最后,实时宽角度小角度同步加速器X射线辐射(WAXS/SAXS)X射线测量表明,GNP没有影响PEEK的正交相,也没有影响结晶过程中晶相的演变。然而,通过WAXS获得的晶体的相关长度和通过SAXS获得的长周期(L)根据GNP含量而变化。
    The effect of the graphene nanoplateletets (GNP), at concentration of 1, 5 and 10 wt %, in Poly ether ether ketone (PEEK) composite crystallization from melt and during cold crystallization were investigated by differential scanning calorimetry (DSC) and real time X-ray diffraction experiments. DSC results revealed a double effect of GNP: (a) nucleating effect crystallization from melt started at higher temperatures and (b) longer global crystallization time due to the restriction in the polymer chain mobility. This hindered mobility were proved by rheological behavior of nanocomposites, because to the increase of complex viscosity, G\', G″ with the GNP content, as well as the non-Newtonian behavior found in composites with high GNP content. Finally, real time wide and small angle synchrotron X-ray radiation (WAXS/SAXS) X-ray measurements showed that GNP has not affected the orthorhombic phase of PEEK nor the evolution of the crystal phase during the crystallization processes. However, the correlation length of the crystal obtained by WAXS and the long period (L) by SAXS varied depending on the GNP content.
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  • 文章类型: Journal Article
    Nowadays, many types of materials are elaborated for microwave absorption applications. Carbon-based nanoparticles belong to these types of materials. Among these, graphene presents some distinctive features for electromagnetic radiation absorption and thus microwave isolation applications. In this paper, the dielectric characteristics and microwave absorption properties of epoxy resin loaded with graphene particles are presented from 2 GHz to 18 GHz. The influence of various parameters such as particle size (3 µm, 6-8 µm, and 15 µm) and weight ratio (from 5% to 25%) are presented, studied, and discussed. The sample loaded with the smallest graphene size (3 µm) and the highest weight ratio (25%) exhibits high loss tangent (tanδ = 0.36) and a middle dielectric constant ε\' = 12-14 in the 8-10 GHz frequency range. As expected, this sample also provides the highest absorption level: from 5 dB/cm at 4 GHz to 16 dB/cm at 18 GHz.
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