metal 3D printing

金属 3D 打印
  • 文章类型: Journal Article
    材料成型和连接是两个基本过程,位于许多形式的金属制造技术的核心,包括增材制造。当前的金属增材制造工艺(诸如激光/电子束粉末床熔合和定向能量沉积)主要使用热和随后的熔融熔合和固化来实现成形和连接。这些方法的能量效率受到严重限制,因为在熔融点输送能量以进行成型和连接之前,能量转换损失。以及由于热量传递到周围环境而造成的损失。该手稿表明,通过使用降低金属屈服应力的物理现象和在低振幅高频振荡应变的存在下增强扩散,金属成型和连接可以以节能的方式进行。两者同时执行,使金属增材制造过程成为可能,即共振辅助沉积(RAD),有几个独特的功能,例如,能够从Al6061等难以焊接的合金中打印网状组件,以及能够以非常高的纵横比打印组件。在这项研究中,我们通过使用铝基金属合金打印固体组件来展示这个过程的能力。
    Material shaping and joining are the two fundamental processes that lie at the core of many forms of metal manufacturing techniques, including additive manufacturing. Current metal additive manufacturing processes such as laser/e-beam powder bed fusion and Directed Energy Deposition predominantly use heat and subsequent melt-fusion and solidification to achieve shaping and joining. The energy efficiency of these processes is severely limited due to energy conversion losses before energy is delivered at the point of melt-fusion for shaping and joining, and due to losses through heat transfer to the surrounding environment. This manuscript demonstrates that by using the physical phenomenon of lowered yield stress of metals and enhanced diffusion in the presence of low amplitude high frequency oscillatory strain, metal shaping and joining can be performed in an energy-efficient way. The two performed simultaneously enable a metal additive manufacturing process, namely Resonance-Assisted Deposition (RAD), that has several unique capabilities, like the ability to print net-shape components from hard-to-weld alloys like Al6061 and the ability to print components with a very high aspect ratio. In this study, we show this process\'s capabilities by printing solid components using aluminum-based metal alloys.
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  • 文章类型: Journal Article
    三维打印是一种非常规的增材制造工艺。它不同于传统的减法制造工艺。它提供了卓越的快速原型制造能力和结果,传统的减法制造方法无法达到,特别是在涉及弯曲或复杂形状的组件的应用中。尽管有其优势,金属3D打印将面临孔隙,翘曲,和表面粗糙度问题。这些问题将间接影响零件今后的实际应用,例如,通过影响结构强度和零件的装配能力。因此,这项研究比较了翘曲的质量,体重,以及轧制钢和3D打印钢之间相同材料(316L不锈钢)的铣削和磨削过程后的表面粗糙度。实验结果表明,3D打印的零件比轧钢轻约13%至14%。经过铣削或磨削加工后,3D打印钢的表面粗糙度性能优于相同材料的轧制钢。3D打印钢的硬度优于轧制钢。该研究验证了3D增材制造可以使用表面处理来优化表面性能并实现亮度和硬度的功能。
    Three-dimensional printing is a non-conventional additive manufacturing process. It is different from the conventional subtractive manufacturing process. It offers exceptional rapid prototyping capabilities and results that conventional subtractive manufacturing methods cannot attain, especially in applications involving curved or intricately shaped components. Despite its advantages, metal 3D printing will face porosity, warpage, and surface roughness issues. These issues will affect the future practical application of the parts indirectly, for example, by affecting the structural strength and the parts\' assembly capability. Therefore, this study compares the qualities of the warpage, weight, and surface roughness after milling and grinding processes for the same material (316L stainless steel) between rolled steel and 3D-printed steel. The experimental results show that 3D-printed parts are approximately 13% to 14% lighter than rolled steel. The surface roughness performance of 3D-printed steel is better than that of rolled steel for the same material after milling or grinding processing. The hardness of the 3D-printed steel is better than that of the rolled steel. This research verifies that 3D additive manufacturing can use surface processing to optimize surface performance and achieve the functions of lightness and hardness.
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  • 文章类型: Journal Article
    背景:下颌骨的节段性骨缺损导致受影响区域的完全丧失。我们已将减压装置(PRD)设计纳入定制的下颌骨假体(CMP)中,并进行了临床试验以评估这种方法。
    方法:本研究纳入7例患者。我们检查了放疗史之间的关联,CMP区域的数量,涉及的下巴区域的数量,和CMP曝光。
    结果:我们包括5名男性和2名女性,平均年龄为55岁。我们切除了平均重量为147.8g的肿瘤,CMP的平均重量为68.5g。注意到两种重量之间没有显著差异(p=0.3882)。三名患者接受了临时假牙,所有患者的CMP保持稳定。
    结论:在CMP中使用PRD可能会解决与CMP相关的先前挑战,但需要进一步的研究。
    Segmental bone defects of the mandible result in the complete loss of the affected region. We had incorporated the pressure-reducing device (PRD) designs into the customized mandible prostheses (CMP) and conducted a clinical trial to evaluate this approach.
    Seven patients were enrolled in this study. We examined the association among the history of radiotherapy, the number of CMP regions, the number of chin regions involved, and CMP exposure.
    We included five men and two women with an average age of 55 years. We excised tumors with an average weight of 147.8 g and the average weight of the CMP was 68.5 g. No significant difference between the two weights was noted (p = 0.3882). Three patients received temporary dentures and the CMP remained stable in all patients.
    The use of PRD in CMP may address the previous challenges associated with CMP, but further research is necessary.
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  • 文章类型: Journal Article
    金属增材制造(AM)是一种逐层工艺,可以直接制造各种工业零件。这种方法有利于复杂工业的设计和制造,先进,以及用于不同行业的精细零件,比如航空航天,医学,涡轮机,和珠宝,其中使用其他制造技术是困难的或不可能的。该方法在尺寸精度和制造速度方面是有利的。然而,用这种方法制造的零件可能会出现各向异性等缺陷,微孔,和有缺陷的关节。像钛这样的金属,铝,不锈钢,超合金,等。,已经以粉末或金属丝的形式用作各种零件的增材制造中的进料。区分不同增材制造工艺的主要标准是沉积方法。关于这个标准,AM过程可以分为四类:局部熔化,烧结,薄板成形,和电化学方法。影响增材制造部件的性质和与AM工艺相关的缺陷的参数决定了应当制造某个部件的方法。这项研究是对不同增材制造工艺的调查,他们的机制,能力,缺点,以及它们制造的零件的一般特性。
    Metal additive manufacturing (AM) is a layer-by-layer process that makes the direct manufacturing of various industrial parts possible. This method facilitates the design and fabrication of complex industrial, advanced, and fine parts that are used in different industry sectors, such as aerospace, medicine, turbines, and jewelry, where the utilization of other fabrication techniques is difficult or impossible. This method is advantageous in terms of dimensional accuracy and fabrication speed. However, the parts fabricated by this method may suffer from faults such as anisotropy, micro-porosity, and defective joints. Metals like titanium, aluminum, stainless steels, superalloys, etc., have been used-in the form of powder or wire-as feed materials in the additive manufacturing of various parts. The main criterion that distinguishes different additive manufacturing processes from each other is the deposition method. With regard to this criterion, AM processes can be divided into four classes: local melting, sintering, sheet forming, and electrochemical methods. Parameters affecting the properties of the additive-manufactured part and the defects associated with an AM process determine the method by which a certain part should be manufactured. This study is a survey of different additive manufacturing processes, their mechanisms, capabilities, shortcomings, and the general properties of the parts manufactured by them.
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  • 文章类型: Journal Article
    金属有机框架(MOFs)在其他材料表面的精确定位为开发多功能设备开辟了新的可能性。我们在这里提出了一种基于MOFs的三维(3D)打印金属催化流动反应器的后功能化方法。将铜基反应器浸入含有有机连接体的酸溶液中,用于合成MOFs,其中原位溶解的Cu2离子被组装以在反应器表面上形成MOF晶体。所得MOF层用作有希望的界面,其使得能够沉积催化活性金属纳米颗粒(NP)。它还作为一个有效的平台,通过在惰性气体条件下的简单热解提供碳层,这进一步实现了用有机改性剂和金属NP的官能化。使用具有四种不同单元密度的圆柱形催化流动反应器来研究反应器结构对从液相储氢材料催化生产H2的影响。活性随着内表面积的增加而增加,但在具有最小泡孔尺寸的反应器中,尽管其具有高内表面积,但活性降低。流体动力学研究的结果表明,随着孔径的减小,压力损失的影响变得更加明显。
    The accurate positioning of metal-organic frameworks (MOFs) on the surface of other materials has opened up new possibilities for the development of multifunctional devices. We propose here a postfunctionalization approach for three-dimensional (3D)-printed metallic catalytic flow reactors based on MOFs. The Cu-based reactors were immersed into an acid solution containing an organic linker for the synthesis of MOFs, where Cu2+ ions dissolved in situ were assembled to form MOF crystals on the surface of the reactor. The resultant MOF layer served as a promising interface that enabled the deposition of catalytically active metal nanoparticles (NPs). It also acted as an efficient platform to provide carbonous layers via simple pyrolysis under inert gas conditions, which further enabled functionalization with organic modifiers and metal NPs. Cylindrical-shaped catalytic flow reactors with four different cell densities were used to investigate the effect of the structure of the reactors on the catalytic production of H2 from a liquid-phase hydrogen storage material. The activity increased with an increasing internal surface area but decreased in the reactor with the smallest cell size despite its high internal surface area. The results of fluid dynamics studies indicated that the effect of pressure loss becomes more pronounced as the pore size decreases.
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  • 文章类型: Journal Article
    半面微症(HFM),最常见的先天性面部畸形之一,通常采用双侧矢状劈开截骨术(BSSO)治疗,以纠正下颌骨的不对称外观和错牙合。然而,频繁的术后复发事件会导致下颌段恢复到其术前位置和BSSO手术失败.在这项研究中,开发了一种定制的不对称固定板(CAF板),以抵抗由于半面微肌咬合力和下颌骨两侧不同的肌肉牵引力而引起的复发。对于本研究中的实际HFM案例,在拓扑优化分析中,使用带有矩形板(原始CAF板外观)的BSSO固定重建的下颌节段骨模型。利用拓扑优化技术,考虑到HFM不对称肌肉牵引力和咬合力,CAF板设计具有轻巧的外形和出色的结构强度。使用生物力学模拟,比较von-Mises应力和CAF板下颌节段移位和微型板,以评估具有优异的复发抗性。在体外生物力学测试中,250,000次循环的疲劳力和恒定的肌肉牵引力应用于HFM下颌模型,用金属3D打印(选择性激光熔化,SLM)以获得下颌节段位移作为复发评估。拓扑优化分析表明,CAF板具有最佳的特性,重量轻,结构强度30%的体积保留。生物力学分析表明,微型钢板的最大vonMises应力是CAF钢板的2.71倍。微型钢板固定的下颌段复发位移是CAF钢板固定的1.62倍。生物力学测试结果证实了CAF板抵抗复发的能力,因此在下颌段仅观察到0.29mm的复发位移。结果表明,CAF板的结构强度和抗复发能力明显优于微型板。这项研究开发了一种定制的不对称固定板,用于治疗半面微缩肌,集成拓扑优化,金属3D打印,和体外生物力学测试,以抵抗咬合力和下颌骨两侧的差异肌肉牵引,以减少复发并提高固定稳定性。
    Hemifacial microsomia (HFM), one of the most common congenital facial anomalies, was usually treated with the bilateral sagittal split osteotomy (BSSO) procedure to correct the asymmetric appearance and malocclusion of the mandible. However, the frequent post-operative relapse incidents would lead to the restoration of the mandibular segment to its preoperative position and failure of the BSSO procedure. In this study, a customized asymmetric fixed plate (CAF plate) was developed to resist relapse due to hemifacial microsomia occlusal forces and the different muscular traction forces on both sides of the mandible. For the actual HFM case in this study, the reconstructed mandibular segmental bone model was fixed using BSSO with a rectangular plate (the original CAF plate appearance) in the topology optimization analysis. With the topology optimization technique, the CAF plate was designed with a lightweight profile and excellent structural strength in consideration of the HFM asymmetrical muscle traction and occlusal force. Using biomechanical simulations, the von-Mises stress and CAF plate mandibular segment displacement and the miniplate were compared to evaluate which had superior relapse resistance. In the in-vitro biomechanical test, a fatigue force of 250,000 cycles and a constant muscle traction force were applied to the HFM mandibular model, which was fixed with the CAF plate fabricated using metal 3D printing (selective laser melting, SLM) to obtain the mandibular segment displacement as a relapse assessment. The topology optimization analysis showed that the CAF plate has the best characteristics, light weight and structural strength with 30% volume retention. The biomechanical analysis showed that the maximum von Mises stress of the mini-plate was 2.71 times higher than that of the CAF plate. The relapse displacement of the mandibular segment fixed with the mini-plate was 1.62 times higher than that fixed with the CAF plate. The CAF plate ability to resist relapse was confirmed by the biomechanical testing results so that only 0.29 mm of recurrence displacement was observed in the mandibular segment. The results indicated that the CAF plate structural strength and resistance to relapse was significantly better than that of the mini-plate. This study developed a customized asymmetric fixation plate for hemifacial microsomia, integrating topology optimization, metal 3D printing, and in vitro biomechanical testing to resist occlusal forces and differential muscle traction on both sides of the mandible to reduce relapse and improve fixation stability.
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  • 文章类型: Journal Article
    一种金属熔化直写工艺,采用半固态等温热处理,形成优质的半固态部件,实现了半固态成型与增材制造的集成创新。对金属熔炼直写技术的半固态等温热处理进行了实验研究,采用2A12铝合金为原料。在不同温度范围内进行了半固体等温热处理,研究了半固态熔融直写过程中半固态微观结构的四个阶段演化机理。提出了保温温度和时间对合金半固态等温热处理显微组织的影响。根据对半固体熔融直写试验结果的分析,发现了半固态微观结构与挤压成形性之间的对应关系。结果表明,当保温温度为640-650℃,保温时间为20-25min时,液相率可达40%左右,并且可以稳定地进行直接写入成形技术。
    A metal-melting direct writing process, using semi-solid isothermal heat treatment to form high-quality semi-solid components, realized the integrated innovation of semi-solid formation and additive manufacturing. An experimental study was carried out on semi-solid isothermal heat treatment for metal-melting direct-writing technology, using 2A12 aluminum alloy as raw material. The semi-solid isothermal heat treatment was carried out over different temperature ranges, and four-stages evolution mechanism of the semi-solid microstructure in the semi-solid melting direct writing process was investigated. The effects of holding temperature and time on the microstructure of the semi-solid isothermal heat treatment of the alloy were put forward. According to the analysis of the results of the semi-solid-melting direct-writing test, the corresponding relationship between semi-solid microstructure and extrusion formability was found. The results show that when the holding temperature is 640-650 °C and the holding time is 20-25 min, the liquid phase rate can reach about 40%, and the direct-writing forming technology can be carried out stably.
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  • 文章类型: Journal Article
    To evaluate the accuracy of metal 3D printed frameworks (MEP group) for removable partial dentures (RPDs) by digital superimposition, in comparison to that of frameworks produced by the conventional (CON group) and resin printing/casting (RPC group) workflows.
    A partially edentulous maxillary dentiform was prepared with rest seats and guiding planes on the right canine, left first premolar, and left second molar. Thirty master casts were prepared via repeated impressions of the dentiform. Frameworks were fabricated by three different workflows (n = 10 for each group). The internal discrepancies of the frameworks were assessed at 12 points by digital scanning with an optical triangulation principle-based tabletop scanner and superimposition using a reference best-fit alignment method. First, the master cast was scanned alone. Subsequently, a thin silicone material was applied to the framework and fitted onto the master cast, after which the framework was removed. Finally, the master cast with the silicone material attached was rescanned. The data from the two scans were matched, with the reference being the area not occupied by the silicone.
    For the CON, MEP, and RPC groups, respectively, the mean overall internal discrepancies (279.72 µm, 241.02 µm, and 331.70 µm), and the mean internal discrepancies on palate areas (292.92 µm, 250.72 µm, and 355.84 µm) and rest seat areas (240.12 µm, 211.91 µm, and 259.26 µm) did not significantly differ among the three fabrication methods (p = 0.558, 0.542, and 0.774).
    The reference best-fit alignment of scan datasets is a useful approach to evaluate the internal discrepancy of frameworks. Metal 3D printing produces RPD frameworks that are comparable to conventional frameworks and meet clinical standards.
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  • 文章类型: Journal Article
    The grain size is a determinant microstructural feature to enable the activation of deformation twinning in hexagonal close-packed (hcp) metals. Although deformation twinning is one of the most effective mechanisms for improving the strength-ductility trade-off of structural alloys, its activation is reduced with decreasing grain size. This work reports the discovery of the activation of deformation twinning in a fine-grained hcp microstructure by introducing ductile body-centered cubic (bcc) nano-layer interfaces. The fast solidification and cooling conditions of laser-based additive manufacturing are exploited to obtain a fine microstructure that, coupled with an intensified intrinsic heat treatment, permits to generate the bcc nano-layers. In situ high-energy synchrotron X-ray diffraction allows tracking the activation and evolution of mechanical twinning in real-time. The findings obtained show the potential of ductile nano-layering for the novel design of hcp damage tolerant materials with improved life spans.
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  • 文章类型: Journal Article
    Additive manufacturing technologies based on metal are evolving into an essential advanced manufacturing tool for constructing prototypes and parts that can lead to complex structures, dissimilar metal-based structures that cannot be constructed using conventional metallurgical techniques. Unlike traditional manufacturing processes, the metal AM processes are unreliable due to variable process parameters and a lack of conventionally acceptable evaluation methods. A thorough understanding of various diagnostic techniques is essential to improve the quality of additively manufactured products and provide reliable feedback on the manufacturing processes for improving the quality of the products. This review summarizes and discusses various ex-situ inspections and in-situ monitoring methods, including electron-based methods, thermal methods, acoustic methods, laser breakdown, and mechanical methods, for metal additive manufacturing.
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