laser sintering

激光烧结
  • 文章类型: Journal Article
    在航空航天等不同行业,对具有优化机械性能的增材制造聚合物复合材料的需求不断增加,生物医学,和汽车。激光烧结(LS)是一种增材制造方法,具有生产增强聚合物的潜力,能满足这些行业的严格要求。为了开发商业上可行的LS尼龙基复合材料,以前的研究全球都集中在添加玻璃珠的粉末材料的目标,以生产完全致密的部件的性能更具代表性的注射成型(IM)热塑性复合材料。这导致开发了市售玻璃珠填充的聚酰胺12(PA12)粉末。虽然这种粉末已经上市一段时间了,缺乏对激光烧结与IM玻璃珠填充的PA12的机械行为的深入比较。在这项研究中,激光烧结玻璃珠填充的PA12样品以不同的方向构建,并与IM对应物进行比较。样品制作后,对生产的LS和IM零件的机械性能进行了测试和比较,以评估不同载荷水平下的准静态和动态机械性能以及失效机理。此外,还将玻璃珠填充的PA12性能与标准(未填充)LSPA12性能进行了比较,以评估玻璃珠是否实际上改善了最终LS样品的机械性能和疲劳寿命,正如文学中所建议的那样。这项工作的结果显示并解释了LS和IM制造的玻璃珠填充聚酰胺零件的刚度增加但疲劳寿命降低。这项研究可以被视为一项“基准”研究,其中样品是从商业上可获得的,填充和未填充,比较了LS和常规生产技术的PA12粉末等级。
    An increasing demand for additively manufactured polymer composites with optimized mechanical properties is manifesting in different industries such as aerospace, biomedical, and automotive. Laser sintering (LS) is an additive manufacturing method that has the potential to produce reinforced polymers, which can meet the stringent requirements of these industries. For the development of a commercially viable LS nylon-based composite material, previous research studies worldwide have focused on adding glass beads to the powder material with the goal to produce fully dense parts with properties more representative of injection molded (IM) thermoplastic composites. This led to the development of a commercially available glass bead-filled polyamide 12 (PA12) powder. Although this powder has been on the market for quite a while, an in-depth comparison of the mechanical behavior of laser sintered versus IM glass bead-filled PA12 is lacking. In this study, laser-sintered glass bead-filled PA12 samples were built in different orientations and compared to IM counterparts. After sample production, the mechanical performance of the produced LS and IM parts was tested and compared to evaluate the quasistatic and dynamic mechanical performance and failure mechanisms at different load levels. In addition, the glass bead-filled PA12 properties were also compared to those of standard (unfilled) LS PA12 to assess whether glass beads actually improve the mechanical performance and fatigue lifetime of the final LS samples, as suggested in literature. Results in this work present and explain the increased stiffness but decreased fatigue life of glass bead-filled polyamide parts made by LS and IM. This research can be regarded as a \"benchmark\" study, in which samples produced from commercially available, filled and unfilled, PA12 powder grades are compared for both LS and conventional production techniques.
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  • 文章类型: Journal Article
    激光烧结,称为粉末床熔化激光束(PBF-LB),为制造患者特异性药物提供了有希望的潜力。本研究的目的是提供有关工艺参数的PBF-LB工艺的见解,特别是激光孵化距离,及其对酒石酸唑吡坦(ZT)片性能的影响。使用PHARMACOAT®603作为聚合物,同时添加了Candurin®GoldSheen和AEROSIL®200以促进3D打印。粉末混合物的粒度分布表明,层高应设置为100µm,虽然激光孵化距离在五个不同的步骤(50、100、150、200和250μm)中变化,保持温度和激光扫描速度恒定。增加激光影线距离和减少激光能量输入导致颜色强度降低,质量,ZT片剂的密度和硬度,而由于颗粒之间的键更脆弱,崩解和溶解速率更快。激光孵化距离也影响了ZT剂量,表明该工艺参数在预处理药物生产中的重要性。证实了不存在药物-聚合物相互作用和ZT的非晶化。
    Laser sintering, known as powder bed fusion-laser beam (PBF-LB), offers promising potential for the fabrication of patient-specific drugs. The aim of this study was to provide an insight into the PBF-LB process with regard to the process parameters, in particular the laser hatching distance, and its influence on the properties of zolpidem tartrate (ZT) tablets. PHARMACOAT® 603 was used as the polymer, while Candurin® Gold Sheen and AEROSIL® 200 were added to facilitate 3D printing. The particle size distribution of the powder blend showed that the layer height should be set to 100 µm, while the laser hatching distance was varied in five different steps (50, 100, 150, 200 and 250 µm), keeping the temperature and laser scanning speed constant. Increasing the laser hatching distance and decreasing the laser energy input led to a decrease in the colour intensity, mass, density and hardness of the ZT tablets, while the disintegration and dissolution rate were faster due to the more fragile bonds between the particles. The laser hatching distance also influenced the ZT dosage, indicating the importance of this process parameter in the production of presonalized drugs. The absence of drug-polymer interactions and the amorphization of the ZT were confirmed.
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  • 文章类型: Journal Article
    聚酰胺12(PA12)的激光烧结(LS)越来越多地用于最终用途零件的工业生产,然而,这个过程的复杂性加上缺乏有组织的,严谨,公开可用的过程-结构-物理特性数据集使制造商和客户面临不可接受的不良零件质量和高成本的风险。尽管已经开发了大量的科学文献来解决其中的一些问题,结果分布在基于不同机器的众多报告中,材料,工艺参数,和用户。在这项研究中,单个商业上重要的LSPA12原料已经沿着现代生产LS机器的四个构建尺寸进行了处理,以广泛的物理技术为特征,并与通过常规熔融加工形成的相同材料进行比较。结果在文献中讨论,提供新颖的见解,包括粒度和形状的分布,由于LS加工而导致的半晶相变化的局部化,化学老化对熔体粘度的影响,相对于LS构建轴的孔隙度取向,以及微观结构对拉伸性能和破坏机理的影响。由此产生的数据集将公开提供给建模者和从业者,以提高LS制造的最终使用零件的可验证性和可重复性。
    Laser sintering (LS) of polyamide 12 (PA12) is increasingly being adopted for industrial production of end-use parts, yet the complexity of this process coupled with the lack of organized, rigorous, publicly available process-structure-physical property datasets exposes manufacturers and customers to risks of unacceptably poor part quality and high costs. Although an extensive scientific literature has been developed to address some of these concerns, results are distributed among numerous reports based on different machines, materials, process parameters, and users. In this study, a single commercially important LS PA12 feedstock has been processed along four build dimensions of a modern production LS machine, characterized by a wide range of physical techniques, and compared to the same material formed by conventional melt processing. Results are discussed in the context of the literature, offering novel insights including distributions of particle size and shape, localization of semicrystalline phase changes due to LS processing, effect of chemical aging on melt viscosity, porosity orientation relative to LS build axes, and microstructural effects on tensile properties and failure mechanisms. The resulting datasets will be made publicly available to modelers and practitioners for the purpose of improving certifiability and repeatability of end-use parts manufactured by LS.
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  • 文章类型: Case Reports
    数字化转型彻底改变了各个部门,包括牙科。牙科已经成为拥抱数字技术的先驱,导致外科和假肢口腔保健的进步。全弓无牙牙种植体的即时装载,一旦辩论,现在被广泛接受。此病例报告描述了一名74岁的牙齿活动度和严重的骨质流失患者,该患者使用多伦多桥协议对四个牙齿植入物进行了立即加载的修复。数字化规划,手术指南,3D打印,采用了精密技术。手术涉及植入物放置和假体程序。患者报告了轻微的术后不适,四个月后,最终的假体成功放置。这个案例证明了在复杂的牙科场景中立即加载数字创新的有效性,改善患者预后。完整的数字化工作流程,包括3D打印和现代材料的使用,提高口腔康复的效率和可预测性,标志着牙科护理的变革性时代。将数字技术融入治疗的各个阶段,从诊断到最终确定,使这种方法更安全,可靠,高效,从而使患者和临床医生都受益。
    The digital transformation has revolutionized various sectors, including dentistry. Dentistry has emerged as a pioneer in embracing digital technologies, leading to advancements in surgical and prosthetic oral healthcare. Immediate loading for full-arch edentulous dental implants, once debated, is now widely accepted. This case report describes a 74-year-old patient with dental mobility and significant bone loss who was rehabilitated using a Toronto Bridge protocol on four dental implants with immediate loading. Digital planning, surgical guides, 3D printing, and precision techniques were employed. The surgery involved implant placement and prosthetic procedures. The patient reported minimal post-operative discomfort, and after four months, the definitive prosthesis was successfully placed. This case demonstrates the efficacy of immediate loading in complex dental scenarios with digital innovation, resulting in improved patient outcomes. The full digital workflow, including 3D printing and the use of modern materials, enhances the efficiency and predictability of oral rehabilitation, marking a transformative era in dental care. The integration of digital technology in all phases of treatment, from diagnosis to finalization, makes this approach safer, reliable, and efficient, thereby benefiting both patients and clinicians.
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  • 文章类型: Journal Article
    背景:探索3D打印技术在空间维护器(SM)制造中的集成可以为增强SM提供创新的解决方案和见解。
    目的:为了比较临床成功,保留,传统带环(TBL)SM与3D打印SM的牙周效应。
    方法:将70名儿童(平均年龄:6.99±1.18)分为两组。激光烧结(LS)组(n=34):用口内扫描仪扫描患者。SM是通过LS3D打印方法由钛基金属粉末生产的。T组(n=36):用藻酸盐进行印象。SM是通过调整带并将电线焊接在模型上来生产的。在第六个月评估SM的保留和对口腔卫生的影响。通过五个问题的调查评估了对印模技术的偏好。
    结果:38%的TSM和66%的LSSM失败(p=.007)。T组的平均生存时间显著高于对照组(p=0.035)。两组的初始和对照全口牙龈指数(GI)和菌斑指数(PI)值之间无差异。两组基牙的GI/PI值都增加。LS组的患者更积极地解释他们的印象体验。
    结论:在应用固定SM之前提供口腔卫生教育很重要,并在儿科牙科中利用更多的数字工作流程。
    BACKGROUND: Exploring the integration of 3D-printing technology in space maintainer (SM) manufacturing could offer innovative solutions and insights for enhancing SMs.
    OBJECTIVE: To compare the clinical success, retention, and periodontal effect of traditional band-loop (TBL) SMs with 3D-printed SMs.
    METHODS: Seventy children (mean age: 6.99 ± 1.18) were divided into two groups. Laser sintering (LS) group (n = 34): Patients were scanned with an intraoral scanner. SMs were produced with LS 3D-printing method from a titanium-based metal powder. T group (n = 36): Impressions were taken with alginate. SMs were produced by adjusting the bands and soldering the wires on the model. The retention and effects on oral hygiene of the SMs were evaluated at the sixth month. Preference for impression technique was assessed by a five-question survey.
    RESULTS: Thirty-eight percent of T SMs and 66% of LS SMs failed (p = .007). The mean survival time was significantly higher in the T group (p = .035). No difference was found between the initial and control full-mouth Gingival Index (GI) and Plaque Index (PI) values of the two groups. Both groups had increased GI/PI values in abutment teeth. Patients in the LS group interpreted their impression experience more positively.
    CONCLUSIONS: It is important to provide oral hygiene education before applying fixed SMs and utilize more digital workflow in paediatric dentistry.
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  • 文章类型: Journal Article
    基于激光的材料加工和增材制造之间的联系根深蒂固。事实上,开始增材制造领域的火花是两个相交的激光束可以选择性地固化一桶树脂的想法。从那以后,激光一直伴随着增材制造领域,其功能从只加工光敏树脂扩展到几乎任何材料,允许释放可定制性。因此,增材制造有望在未来几年在全球供应链中发挥更加突出的作用。在这里,从各个方面介绍了基于激光的选择性材料加工的概述:激光-材料相互作用的物理学,目前用于增材制造工艺的材料,实现基于激光的增材制造的系统配置,以及下一代增材制造的各种功能应用。此外,讨论了基于激光增材制造的当前挑战和前景。本文受版权保护。保留所有权利。
    The connection between laser-based material processing and additive manufacturing is quite deeply rooted. In fact, the spark that started the field of additive manufacturing is the idea that two intersecting laser beams can selectively solidify a vat of resin. Ever since, laser has been accompanying the field of additive manufacturing, with its repertoire expanded from processing only photopolymer resin to virtually any material, allowing liberating customizability. As a result, additive manufacturing is expected to take an even more prominent role in the global supply chain in years to come. Herein, an overview of laser-based selective material processing is presented from various aspects: the physics of laser-material interactions, the materials currently used in additive manufacturing processes, the system configurations that enable laser-based additive manufacturing, and various functional applications of next-generation additive manufacturing. Additionally, current challenges and prospects of laser-based additive manufacturing are discussed.
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  • 文章类型: Journal Article
    目的:这项研究的目的是评估直接金属激光烧结(DMLS)桩和核的打印方向对牙髓治疗的下颌前磨牙的抗断裂性和失效模式的影响。
    方法:对60个完整的人下颌前磨牙进行了牙髓治疗。然后将牙齿随机分为四组(n=15)。钴铬(Co-Cr)金属柱通过传统铸造(C组)制造,和0-中的DMLS方法,45-和,90度打印方向(组DMLS0、组DMLS45和组DMLS90)。用复合树脂水泥粘结柱和芯,并以1mm/min的十字头速度进行压缩试验。通过使用方差分析的单向方差分析和多重比较事后Tukey检验(α=.05)来分析数据。在具有X20放大倍数的立体显微镜下观察样本以评估骨折类型。
    结果:在骨折阻力方面,测试组之间没有发现显着差异(P>0.05)。C组和DMLS0组表现出相似的骨折模式。
    结论:可以使用DMLS技术生产桩和核心修复体,并将其用于临床。印刷取向不影响抗断裂性。然而,断裂模式不同。C组在断裂模式方面优于所有DMLS组。本文受版权保护。保留所有权利。
    OBJECTIVE: The aim of this study was to evaluate the impact of the print orientation of direct metal laser sintering (DMLS) posts and cores on the fracture resistance and failure patterns of endodontically treated mandibular premolar teeth.
    METHODS: Sixty intact human mandibular premolars were endodontically treated. The teeth were then randomly divided into four groups (n = 15). Cobalt-chromium (Co-Cr) metal posts were fabricated by traditional casting (Group C), and DMLS method in 0-, 45-, and 90-degree print orientations (Group DMLS 0, Group DMLS 45, and Group DMLS 90). The posts and cores were cemented with composite resin cement and subjected to compression test at a crosshead speed of 1 mm/min. Data was analyzed by using one-way analysis of variance ANOVA and multiple comparison post hoc Tukey tests (α = 0.05). Specimens were viewed under a stereo microscope with x20 magnification to evaluate the fracture types.
    RESULTS: No significant differences were found among the groups tested in terms of fracture resistance (p > 0.05). Group C and Group DMLS 0 group exhibited similar fracture patterns.
    CONCLUSIONS: It is possible to produce post and core restorations with the DMLS technique and use them clinically.  Print orientation did not influence the fracture resistance. However, fracture patterns were different. Group C outperformed all DMLS groups in terms of fracture patterns.
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  • 文章类型: Journal Article
    在激光烧结(LS)打印过程中,通过在粉末床上逐层烧结形成打印部件。因此,必须将激光烧结粉末床的尺寸精度作为重要的评价指标。在本文中,提出了一种非结晶热塑性聚合物材料的广义粉末床尺寸精度补偿模型。以聚醚砜(PES)材料为例,本研究对LS打印过程中影响粉末床尺寸精度的主要因素进行了建模和实验分析,包括四个重要因素:激光参考偏差,温度偏差,密度偏差,和二次烧结偏差。在这项研究中,CX_A200LS设备用于原型设计和验证,3D扫描方法用于测量打印部件,并对测量结果进行了数字化对比分析。在此基础上,通过实验确定了所提出的补偿模型中各个影响因素的关系,实验结果表明,所提出的补偿模型在校正粉末床尺寸精度偏差方面的有效性约为95%。
    In the laser sintering (LS) printing process, a printed part is formed by sintering layer-by-layer on the powder bed. Thus, it is necessary to consider the dimensional accuracy of the laser-sintered powder bed as an important evaluation index. In this paper, a generalized powder bed-size accuracy compensation model is proposed for non-crystalline thermoplastic polymer materials. Taking polyethersulfone (PES) material as an example, the main factors influencing powder bed dimensional accuracy during LS printing are modeled and analyzed experimentally in this study, including four important factors: laser reference deviation, temperature deviation, density deviation, and secondary sintering deviation. In this study, CX_A200 LS equipment is used for prototyping and verification, a 3D scanning method is used to measure the printed parts, and the measurement results are digitally compared and analyzed. On this basis, the relationship of each influencing factor in the proposed compensation model is determined experimentally, and the experimental results demonstrate that the proposed compensation model is approximately 95% effective in terms of correcting the deviation of powder bed dimensional accuracy.
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  • 文章类型: Journal Article
    导电有机硅弹性体碳纳米管(CNTs)复合材料在各个领域具有潜在的应用,包括电子皮肤,可穿戴电子产品,和人体运动检测。基于聚二甲基硅氧烷(PDMS)的新型自制共价自适应网络(CAN),该网络包含动态空间位阻吡唑脲键(PDMS-CAN),采用液相吸附沉积法制备了CNTs包裹的PDMS-CANs(CNTs@PDMS-CANs)粉体,并成功用于选择性激光烧结(SLS)三维打印。SLS打印的PDMS-CANs/CNTs纳米复合材料具有较高的导电性和较低的渗滤阈值,通过使用具有特殊CNTs包裹结构的PDMS粉末,可以形成导电隔离的CNTs网络。动态吡唑脲键的引入赋予了材料在电热和光热刺激下的自修复能力。此外,由于受损和完好区域的电阻差异,裂纹诊断可以通过电力下的红外热成像来实现。在应变传感器的应用演示中,复合材料在循环压缩和弯曲时表现出规则的循环电阻变化,表明相对较高的可靠性。
    Conductive silicone elastomer carbon nanotubes (CNTs) composites possess potential applications in a variety of fields, including electronic skin, wearable electronics, and human motion detection. Based on a novel self-made covalent adaptable network (CANs) of polydimethylsiloxane (PDMS) containg dynamic steric-hindrance pyrazole urea bond (PDMS-CANs), CNTs wrapped PDMS-CANs (CNTs@PDMS-CANs) powders were prepared by a liquid phase adsorption and deposition, and were successfully used for selective laser sintering (SLS) three-dimensional printing. SLS-printed PDMS-CANs/CNTs nanocomposites possess high electrical conductivity and low percolation threshold as SLS is one kind of quasi-static processing, which leads to the formation of conductive segregated CNTs network by using the PDMS powders with special CNTs wrapped structure. The introduction of dynamic pyrazole urea bond endows the materials self-healing capability under electrothermal and photothermal stimulus. In addition, due to the resistance difference of the damaged and intact areas, crack diagnosing can be realized by infrared thermograph under electricity. In an application demonstration in strain sensor, the composite exhibits a regular cyclic electrical resistance change at cyclic compression and bending, indicating a relative high reliability.
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  • 文章类型: Journal Article
    难熔金属为高温电子产品提供了卓越的优势,包括耐高温,耐腐蚀性和优异的机械强度,而它们的高熔化温度和差的可加工性对制造提出了挑战。在这里,这项工作报告了直接墨水书写和焦油介导的激光烧结(DIW-TMLS)技术,以制造用于高温应用的三维(3D)难熔金属器件。利用煤焦油作为粘合剂,设计了高粘度和增强光吸收的金属油墨。在周围环境中使用低功率(<10W)激光将印刷图案烧结成无氧化的多孔金属结构,3D独立式架构可以一步快速制造。介绍了几种应用,包括一个基于分形图案的应变仪,在半球上形成图案的电小天线(ESA),和一个无线温度传感器,可以在高达350°C的温度下工作并承受燃烧的火焰。DIW-TMLS技术为各种金属材料的快速图案化铺平了一条可行的路线,具有广泛的适用性,高灵活性,和3D一致性,扩大恶劣环境传感器的可能性。
    Refractory metals offer exceptional benefits for high temperature electronics including high-temperature resistance, corrosion resistance and excellent mechanical strength, while their high melting temperature and poor processibility poses challenges to manufacturing. Here this work reports a direct ink writing and tar-mediated laser sintering (DIW-TMLS) technique to fabricate three-dimensional (3D) refractory metal devices for high temperature applications. Metallic inks with high viscosity and enhanced light absorbance are designed by utilizing coal tar as binder. The printed patterns are sintered into oxidation-free porous metallic structures using a low-power (<10 W) laser in ambient environment, and 3D freestanding architectures can be rapidly fabricated by one step. Several applications are presented, including a fractal pattern-based strain gauge, an electrically small antenna (ESA) patterned on a hemisphere, and a wireless temperature sensor that can work up to 350 °C and withstand burning flames. The DIW-TMLS technique paves a viable route for rapid patterning of various metal materials with wide applicability, high flexibility, and 3D conformability, expanding the possibilities of harsh environment sensors.
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