Over the past couple of decades, additive manufacturing and the use of root-analogue-printed titanium dental implants have been developed. Not all powder particles are sintered into the final product during the additive manufacturing process. Reuse of the remaining powder could reduce the overall implant manufacturing cost. However, Ti-6Al-4V powder particles are affected by heat, mechanical factors, and oxidization during the powder bed fusion manufacturing process. Degradation of the powder may harm the final surface composition and decrease the biocompatibility and survival of the implant. The uncertainty of the recycled powder properties prevents implant fabrication facilities from reusing the powder. This study investigates the chemical composition of controlled, clean, and recycled titanium alloy powder and root-analogue implants (RAI) manufactured from these powders at three different depths. The change in titanium\'s quantity, oxidization state, and chemical composition in powder and RAI implants have been demonstrated and analyzed. While not identical, the surface chemical composition of the recycled powder implant and the implant manufactured from unused powder are similar. The results also indicate the presence of TiO2 on all surfaces. Many studies confirmed that titanium dioxide on the implant\'s surface correlates with better osteointegration, reduced bacterial infection, and increased corrosion resistance. Considering economic and environmental aspects, surface chemical composition comparison of clean and reused powder is crucial for the future manufacturing of cost-effective and biocompatible implants.

Additive manufacturing (AM) of polymeric materials offers many benefits, from rapid prototyping to the production of end-use material parts. Powder bed fusion (PBF), more specifically selective laser sintering (SLS), is a very promising AM technology. However, up until now, most SLS research has been directed toward polyamide powders. In addition, only basic models have been put forward that are less directed to the identification of the most suited operating conditions in a sustainable production context. In the present combined experimental and theoretical study, the impacts of several SLS processing parameters (e.g., laser power, part bed temperature, and layer thickness) are investigated for a thermoplastic elastomer polyester by means of colorimetric, morphological, physical, and mechanical analysis of the printed parts. It is shown that an optimal SLS processing window exists in which the printed polyester material presents a higher density and better mechanical properties as well as a low yellowing index, specifically upon using a laser power of 17-20 W. It is further highlighted that the current models are not accurate enough at predicting the laser power at which thermal degradation occurs. Updated and more fundamental equations are therefore proposed, and guidelines are formulated to better assess the laser power for degradation and the maximal temperature achieved during sintering. This is performed by employing the reflection and absorbance of the laser light and taking into account the particle size distribution of the powder material.

In recent years, the application field of laser powder bed fusion of metals and polymers extends through an increasing variability of powder compositions in the market. New powder formulations such as nanoparticle (NP) additivated powder feedstocks are available today. Interestingly, they behave differently along with the entire laser powder bed fusion (PBF-LB) process chain, from flowability over absorbance and microstructure formation to processability and final part properties. Recent studies show that supporting NPs on metal and polymer powder feedstocks enhances processability, avoids crack formation, refines grain size, increases functionality, and improves as-built part properties. Although several inter-laboratory studies (ILSs) on metal and polymer PBF-LB exist, they mainly focus on mechanical properties and primarily ignore nano-additivated feedstocks or standardized assessment of powder feedstock properties. However, those studies must obtain reliable data to validate each property metric\'s repeatability and reproducibility limits related to the PBF-LB process chain. We herein propose the design of a large-scale ILS to quantify the effect of nanoparticle additivation on powder characteristics, process behavior, microstructure, and part properties in PBF-LB. Besides the work and sample flow to organize the ILS, the test methods to measure the NP-additivated metal and polymer powder feedstock properties and resulting part properties are defined. A research data management (RDM) plan is designed to extract scientific results from the vast amount of material, process, and part data. The RDM focuses not only on the repeatability and reproducibility of a metric but also on the FAIR principle to include findable, accessible, interoperable, and reusable data/meta-data in additive manufacturing. The proposed ILS design gives access to principal component analysis (PCA) to compute the correlations between the material-process-microstructure-part properties.

OBJECTIVE: To compare the marginal and internal fit of cobalt-chromium (Co-Cr) alloy copings fabricated by with lost wax technique (LW), computer-aided design and computer-aided manufacturing (CAD/CAM), and direct metal laser sintering (DMLS).
METHODS: Thirty-six tissue level, straight titanium abutments were screwed onto implant replicas. All specimens were embedded in acrylic resin and randomly divided into 3 subgroups according to the fabrication of metal coping: LW, CAD/CAM, and DMLS. In total, 36 (n = 12/group) Co-Cr implant-supported metal copings were prepared. Marginal, intermarginal, axial, and occlusal fits of each coping were measured using the silicone replica technique. The data were evaluated statistically using one-way ANOVA and Bonferioni post-hoc test (α = 0.05).
RESULTS: The CAD/CAM group showed significantly lower marginal fit than the LW group and DMLS groups (p < 0.001). The marginal fit of the LW group was not significantly different from the DMLS group (p = 0.721). No significant difference found among the fabrication methods in terms of intermarginal fit (p = 0.913). The CAD/CAM group showed lower axial fit than the LW group (p = 0.026), but there was no statistical difference between the DMLS group and the LW (p = 0.999) and CAD/CAM groups (p = 0.247). No significant differences found among the fabrication methods in terms of occlusal fit (p = 0.158).
CONCLUSIONS: The LW and DMLS groups showed better marginal fit compared to the CAD/CAM group; however, the CAD/CAM group was better than the LW group in terms of axial fit. All fabrication methods demonstrated similar intermarginal and occlusal fit.

UNASSIGNED: The purpose of this study was to compare the marginal and internal adaptation of cobalt-chromium (Co-Cr) copings fabricated from conventional wax pattern, three-dimensional (3D)-printed resin pattern, and laser sintering technique.
UNASSIGNED: A total of thirty copings were made, out of which ten copings were made from 3D-printed resin pattern (Group A), ten from inlay wax pattern (Group B), and ten copings were obtained from direct metal laser sintering (DMLS) technique (Group C). All the thirty samples were seated on their respective dies and sectioned carefully using a laser jet cutter and were evaluated for marginal and internal gaps at the predetermined areas using a stereomicroscope. The values were then analyzed using one-way ANOVA test and post hoc Bonferroni test.
UNASSIGNED: One-way ANOVA showed lowest mean marginal discrepancy for DMLS and highest value for copings fabricated from inlay wax. The values for internal discrepancy were highest for DMLS (169.38) and lowest for 3D-printed resin pattern fabricated copings (133.87). Post hoc Bonferroni test for both marginal and internal discrepancies showed nonsignificant difference when Group A was compared to Group B (P > 0.05) and significant when Group A was compared with Group C (P < 0.05). Group B showed significant difference (P < 0.05) when compared with Group C.
UNASSIGNED: Marginal and internal discrepancies of all the three casting techniques were within clinically acceptable values. Marginal fit of DMLS was superior as compared to other two techniques, whereas when internal fit was evaluated, conventional technique showed the best internal fit.

OBJECTIVE: This study aimed to compare the marginal fit and microleakage of metal laser sintered Co-Cr alloy copings and conventional cast Ni-Cr alloy copings using a stereomicroscope.
METHODS: Forty extracted maxillary premolars were randomly divided into two groups. One group was subjected to coping fabrication using conventional lost wax (LW) technique while the other group was subjected to coping fabrication using metal laser sintering (MLS) technology. The marginal fit of these copings were compared before and after ceramic addition using images obtained with a steromicroscope and an ImageJ analysis software. All the specimens were cemented using Type 1 glass ionomer cement and were subjected to thermocycling. The specimens were evaluated for microleakage using stereomicroscope and 2% methylene blue die used as a tracer. The data were subjected to statistical analysis using paired t-test, Mann-Whitney test and Chi-Square test.
RESULTS: The mean marginal fit of copings before and after ceramic addition in Group B (MLS) was better than the copings in Group A (LW) and was statistically significant (P<0.05). The influence of ceramic firing had a significant (P<0.05) increase in mean marginal gap in Group A (LW) but not in Group B (MLS). And the difference in mean microleakage between the groups was not statistically significant (P≥0.05).
CONCLUSIONS: The copings fabricated using MLS technique had a better marginal fit and an observable decrease in microleakage when compared to the copings fabricated using the conventional lost wax (LW) technique.

OBJECTIVE: It was the aim of this study to analyze osseointegrative properties of porous additive manufactured titanium implants made by direct metal laser sintering in a sheep model after an implantation period of 2 and 8 weeks.
METHODS: Three different types of implants were placed in the pelvis of six sheep. In each sheep were placed three standard machined (M), three sandblasted and etched (SE), and three porous additive manufactured (AM) implants. Of these three implants (one per type) were examined histologically and six implants were tested biomechanically. Additionally a semiquantitative histomorphometrical and qualitative fluorescent microscopic analysis were performed.
RESULTS: After 2 and 8 weeks bone-to-implant-contact (BIC) values of the AM surface (2w: 20.49% ± 5.18%; 8w: 43.91% ± 9.69%) revealed no statistical significant differences in comparison to the M (2w: 20.33% ± 11.50%; 8w: 25.33% ± 4.61%) and SE (2w: 43.67 ± 12.22%; 8w: 53.33 ± 8.96%) surfaces. AM surface showed the highest increase of the BIC between the two observation time points. Considering the same implantation period histomorphometry and fluorescent labelling disclosed no significant differences in the bone surrounding the three implants groups. In contrast Removal-torque-test showed a significant improve in fixation strength (P ≤ 0.001) for the AM (1891.82 ± 308, 44 Nmm) surface after eight weeks in comparison to the M (198.93±88,04 Nmm) and SE (730.08 ± 151,89 Nmm) surfaces.
CONCLUSIONS: All three surfaces (M, SE, and AM) showed sound osseointegration. AM implants may offer a possible treatment option in clinics for patients with compromised bone situations.