films and coatings

  • 文章类型: Journal Article
    居住空间的能源效率是保持能源充足的关键主题,减少气候影响,促进经济储蓄;因此,迫切需要解决这一问题的解决方案。一种可行的方法包括用无功率或被动冷却方法补充主动冷却方法。此外,基于可持续材料的无源辐射冷却解决方案的开发仍有相当大的范围。纤维素,以其丰富为特征,可再生性,和生物降解性,由于其利用中红外(MIR)大气传输窗口(8-13μm)的显着辐射冷却潜力,因此成为有前途的材料。在这项工作中,我们建议将热致变色(TC)材料与纤维素纳米原纤维(CNF)结合使用,以赋予混合CNF膜的温度依赖性适应性。我们采用高反射的概念,加上加热状态下的MIR发射,有利于冷却,而在冷态下的高可见光吸收允许加热,从而实现自适应热调节。CNF薄膜掺杂有黑色到隐色TC颗粒,并且将薄的银层任选地施加到膜上。这些薄膜在~22°C时的光学性能表现出快速转变(在1s内),在转变温度以上变得透明。所有样品的可见透射率范围为60-90%,在8-13μm范围内具有明显的吸收。在没有任何Ag层的1-4°C和有Ag层的~10°C下测量膜的冷却电势。在户外现场测试中,在明亮的阳光下达到12°C的峰值冷却值,相当于商业太阳能膜。根据实验结果建立了仿真模型。本研究中提出的概念超出了作为独立薄膜的应用范围,但也适用于玻璃涂层。总的来说,这项工作为绿色纤维素基材料的新应用机会打开了大门。
    Energy efficiency in habitation spaces is a pivotal topic for maintaining energy sufficiency, cutting climate impact, and facilitating economic savings; thus, there is a critical need for solutions aimed at tackling this problem. One viable approach involves complementing active cooling methods with powerless or passive cooling ones. Moreover, considerable scope remains for the development of passive radiative cooling solutions based on sustainable materials. Cellulose, characterized by its abundance, renewability, and biodegradability, emerges as a promising material for this purpose due to its notable radiative cooling potential exploiting the mid-infrared (MIR) atmospheric transmission window (8-13 μm). In this work, we propose the utilization of thermochromic (TC) materials in conjunction with cellulose nanofibrils (CNF) to confer temperature-dependent adaptivity to hybrid CNF films. We employ a concept where high reflection, coupled with MIR emission in the heated state, facilitates cooling, while high visible light absorption in the cold state allows heating, thus enabling adaptive thermal regulation. CNF films were doped with black-to-leuco TC particles, and a thin silver layer was optionally applied to the films. The films exhibited a rapid transition (within 1 s) in their optical properties at ∼22 °C, becoming transparent above the transition temperature. Visible range transmittance of all samples ranged from 60 to 90%, with pronounced absorption in the 8-13 μm range. The cooling potential of the films was measured at 1-4 °C without any Ag layer and ∼10 °C with a Ag layer. In outdoor field testing, a peak cooling value of 12 °C was achieved during bright sunshine, which is comparable to a commercial solar film. A simulation model was also built based on the experimental results. The concept presented in this study extends beyond applications as standalone films but has applicability also in glass coatings. Overall, this work opens the door for a novel application opportunity for green cellulose-based materials.
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  • 文章类型: Journal Article
    生物聚合物在眼睑和泪道系统后层重建中的应用标志着生物材料科学与临床进步的重要融合。这篇综述吸收了2015年至2023年的研究,以详细研究生物聚合物在重建眼睑后层和泪道系统中的作用。它涵盖了眼睑结构的解剖学和病理生理学,重建的挑战,以及手术干预的细微差别。本文进展到评估当前的黄金标准,替代选项,以及这些复杂程序中使用的生物聚合物的理想特性。它强调了该领域的进步,从脱细胞移植物和无细胞基质到创新的天然和合成聚合物,并探讨了它们在泪腺组织工程中的应用,包括3D生物打印技术的承诺。这篇综述强调了材料科学家和临床医生之间的多学科合作在提高手术结果和患者生活质量方面的重要性。强调这种合作对于将台式研究转化为床边应用至关重要。这种协作努力对于恢复患有眼睑疾病的患者的美学和功能至关重要,最终旨在弥合创新材料与其临床翻译之间的差距。
    The application of biopolymers in the reconstruction of the posterior lamella of the eyelid and the lacrimal system marks a significant fusion of biomaterial science with clinical advancements. This review assimilates research spanning 2015 to 2023 to provide a detailed examination of the role of biopolymers in reconstructing the posterior lamella of the eyelid and the lacrimal system. It covers the anatomy and pathophysiology of eyelid structures, the challenges of reconstruction, and the nuances of surgical intervention. This article progresses to evaluate the current gold standards, alternative options, and the desirable properties of biopolymers used in these intricate procedures. It underscores the advancements in the field, from decellularized grafts and acellular matrices to innovative natural and synthetic polymers, and explores their applications in lacrimal gland tissue engineering, including the promise of 3D bioprinting technologies. This review highlights the importance of multidisciplinary collaboration between material scientists and clinicians in enhancing surgical outcomes and patient quality of life, emphasizing that such cooperation is pivotal for translating benchtop research into bedside applications. This collaborative effort is vital for restoring aesthetics and functionality for patients afflicted with disfiguring eyelid diseases, ultimately aiming to bridge the gap between innovative materials and their clinical translation.
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  • 文章类型: Journal Article
    最近,消费者越来越倾向于在食品加工和包装中使用天然抗菌剂和抗氧化剂。几种生物活性化合物起源于天然来源,其中,葡萄柚籽提取物(GSE)被广泛接受,并且在食品中使用通常是安全的。GSE是食品中非常常用的抗菌剂;最近,还发现其作为涂层材料或在可食用包装膜中非常有效。最近的许多工作报告了GSE在食品包装中的应用,以确保食品质量和安全;因此,这项工作旨在提供对基于GSE的包装的最新审查。这篇评论讨论了GSE,其提取方法,以及它们在制造食品包装薄膜/涂料中的用途。还讨论了添加GSE的薄膜的各种物理和功能特性。本文还提供了GSE掺入膜和涂层的食品保鲜应用。最后,机会,挑战,以及添加GSE的包装膜/涂层的观点也有争议。
    Recently, consumers have been increasingly inclined towards natural antimicrobials and antioxidants in food processing and packaging. Several bioactive compounds have originated from natural sources, and among them, grapefruit seed extract (GSE) is widely accepted and generally safe to use in food. GSE is a very commonly used antimicrobial in food; lately, it has also been found very effective as a coating material or in edible packaging films. A lot of recent work reports the use of GSE in food packaging applications to ensure food quality and safety; therefore, this work intended to provide an up-to-date review of GSE-based packaging. This review discusses GSE, its extraction methods, and their use in manufacturing food packaging film/coatings. Various physical and functional properties of GSE-added film were also discussed. This review also provides the food preservation application of GSE-incorporated film and coating. Lastly, the opportunities, challenges, and perspectives in the GSE-added packaging film/coating are also debated.
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  • 文章类型: Journal Article
    由于粮食短缺,粮食部门正面临问题,人口和食物需求的增加加剧了这种情况。食品通常使用聚乙烯等石油基塑料包装和包装,聚氯乙烯,和其他人。然而,过度使用这些聚合物具有环境和健康风险。因此,目前许多研究集中在使用生物基材料进行食品包装。与食品相容的生物可降解聚合物用于制造可食用包装材料。这些可以与食物一起摄入,并为消费者提供额外的健康益处。最近的研究已将重点转移到多层涂层和基于薄膜的食品包装上,这可以提供具有附加的不同特征的材料。本文旨在研究几种生物基聚合物在食品包装中的性能和应用。几种类型的可食用薄膜和包衣生产技术也分别涵盖。此外,研究了可食用薄膜和涂层在食品工业中的用途,并讨论了它们相对于传统材料的优势。
    Food sectors are facing issues as a result of food scarcity, which is exacerbated by rising populations and demand for food. Food is ordinarily wrapped and packaged using petroleum-based plastics such as polyethylene, polyvinyl chloride, and others. However, the excessive use of these polymers has environmental and health risks. As a result, much research is currently focused on the use of bio-based materials for food packaging. Biodegradable polymers that are compatible with food products are used to make edible packaging materials. These can be ingested with food and provide consumers with additional health benefits. Recent research has shifted its focus to multilayer coatings and films-based food packaging, which can provide a material with additional distinct features. The aim of this review article is to investigate the properties and applications of several bio-based polymers in food packaging. The several types of edible film and coating production technologies are also covered separately. Furthermore, the use of edible films and coatings in the food industry has been examined, and their advantages over traditional materials are also discussed.
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