It is of great significance to grasp the role of surface topography in de-icing, which however remains unclear yet. Herein, four textured surfaces are developed by regulating surface topography while keeping surface chemistry and material constituents same. Specifically, nano-textures are maintained and micro-textures are gradually enlarged. The resultant ice adhesion strength is proportional to a topography parameter, i.e. areal fraction of the micro-textures, owing to the localized bonding strengthening, which is verified by ice detachment simulation using finite element method. Moreover, the decisive topography parameter is demonstrated to be determined by the interfacial strength distribution between ice and test surface. Such parameters vary from paper to paper due to different interfacial strength distributions corresponding to respective situations. Furthermore, since hydrophobic and de-icing performance may rely on different topography parameters, there is no certain relationship between hydrophobicity and de-icing.
The role of surface topography in de-icing is verified to be determined by the interfacial strength distribution between ice and surface experimentally and numerically, unveiling the relationship between hydrophobicity and de-icing.

High population and a wide range of activities in a megacity lead to large-scale ecological consequences which require the assessment with respect to distinct characteristics of climate, location, fuel consumption, and emission sources. In-depth study of aerosol characteristics was carried out in Moscow, the largest megacity in Europe, during the cold period (autumn and winter) and in spring. PM10 chemical speciation based on carbonaceous matter, water-soluble ions, and elements was carried out to reconstruct the PM mass and evaluate the primary and secondary aerosol contribution. For the whole study period organic matter, mineral dust, and secondary inorganic/organic accounted for 34, 24, and 16 % of PM10 mass, respectively. PM10, OC, and EC approached a maximum in spring and decreased in winter. Mineral dust seasonal fraction increased from spring (17 %) to autumn (32 %), and then decreased in winter (22 %). Secondary inorganic aerosols (SIA) in opposite showed the maximum 27 % in winter. K+ marked the residential biomass burning in the region surrounding a megacity in spring and autumn, agriculture fires in spring. In winter primary aerosol contribution dropped down 56 % while secondary approached practically equal 44 %. Source factors with the relative contributions are quantified, namely city dust (26 %), traffic (23 %), industrial (20 %), biomass burning (12 %), secondary (12 %), and de-icing salt (7 %); they were significantly varying between the cold heating period and springtime. The relevance of sources to meteorological parameters and mass transportation is investigated by using both bivariate polar plots and Lagrangian integrated trajectory (HYSPLIT) model. Trajectory clustering demonstrates regional sources being crucial contributors to PM10 pollution. Aerosol speciation and source apportion factors identify the differences of the Moscow urban background among large European and Asian cities due to northern climate conditions, fast construction, long-range transport from industrial-developing area surrounding a city, regional biomass burning preferably in spring and autumn, and winter road management.

In parts of Europe and North America, cycling volumes decrease in winter due to a reduction in subjective safety. To counter this, high-quality winter maintenance is required on cycle paths. At the moment, grit and sodium chloride are considered state-of-the-art gritting/de-icing materials in Germany. However, grit has to be removed after winter because it poses a serious injury risk on dry streets, and, in various German cities, using sodium chloride is prohibited on segregated bike paths due to the harmful impact on surrounding trees. Therefore, there is a need for alternative gritting/de-icing materials.
We used a mixed-methods approach consisting of qualitative and quantitative surveys together with laboratory investigations and a life cycle assessment to find suitable alternatives to sodium chloride and grit for use on segregated bike paths, and tested four de-icing materials (sodium chloride as a reference, sodium formate, calcium magnesium acetate or CMA, and potassium acetate) at two sites in Hamburg, Germany. The tests were accompanied by on-site cyclist surveys.
The results show that the use of alternative (non-sodium chloride) de-icing materials either reduces or eliminates negative impacts on the environment at a local level, for example on trees along the cycle path. However, this reduction goes hand in hand with increasing negative environmental impacts at a global level due to higher overall emissions associated with the tested alternative de-icing materials. Regarding cyclists\' safety, sodium formate was the only de-icing material which delivered comparable results to sodium chloride and should therefore be tested in extended conditions.
Further research is needed on the large-scale application of the investigated de-icing agents on cycle paths in different cities, along with a survey of a larger number of cyclists. A final evaluation of the environmental aspects can only be made when the supply and production conditions for large-scale use are clear.
Basically there are two options for the practical application of de-icing materials: The usage of the costlier alternatives with better properties at a local level in the hope of fast development towards a better global GHG footprint in their manufacturing processes, or sticking to the use of grit and sodium chloride (where it is possible) while committing to improving clean-up after the snow and ice melt to prevent unsafe road conditions in spring.

Micro/nanostructures have garnered significant attention and widespread applications in areas such as photocatalysis, coated fabrics, microchips, and sensors. However, high-resolution and multifunctional micro/nanostructures fabrication remains a great challenge. In this work, a novel self-assembly-femtosecond laser processing for the regular micro squares and nano bumps surface on steel substrates is proposed, and a great potential in the field of anti-icing/de-icing and self-cleaning is demonstrated. The surface tension gradient-driven liquid-air self-assembly provides a silica microsphere monolayer, while the post-femtosecond laser process can give precise micro/nano decoration. We systematically explore the impact of laser repetition frequency, scanning speed, and laser incident power on the size and shape of micro/nano decorations that have been studied. The different performances of self-cleaning effects, ice adhesion, and the photothermal de-icing capability due to the change in surface wettability have been demonstrated. This research shows a new pathway for the creation of smart micro/nanostructures surface which possess stable super hydrophilic and highly adhesive superhydrophobic properties, as well as high abrasion resistance. The discovery achieves a suitable blend of multiple functions on the surface of a single material, which can be applied to various surface engineering fields.

Photothermal materials have gained considerable attention in the field of anti-/de-icing due to its environmental friendliness and energy saving. However, it is always significantly challenging to obtain solar thermal materials with hierarchical structure and simultaneously demonstrate both the ultra-long icing delay ability and the superior photothermal de-icing ability. Here, a photothermal icephobic MOF-based micro and nanostructure surface (MOF-MNS) is presented, which consists of micron groove structure and fluorinated MOF nanowhiskers. The optimal MOF-M250 NS can achieve solar absorption of over 98% and produce a high temperature increment of 65.5 °C under 1-sun illumination. Such superior photothermal-conversion mechanism of MOF-M250 NS is elucidated in depth. In addition, the MOF-M250 NS generates an ultra-long icing delay time of ≈3960 s at -18 °C without solar illumination, achieving the longest delay time, which isn\'t reported before. Due to its excellent solar-to-heat conversation ability, accumulated ice and frost on MOF-M250 NS can be rapidly melted within 720 s under 1-sun illumination and it also holds a high de-icing rate of 5.8 kg m-2 h-1 . MOF-M250 NS possesses the versatility of mechanical robustness, chemical stability, and low temperature self-cleaning, which can synergistically reinforce the usage of icephobic surfaces in harsh conditions.

Traffic accidents caused by road icing are a serious global problem, and conventional de-icing methods like spraying chemicals have several limitations, including excessive manpower management, road damage, and environmental pollution. In this study, the carbon nanotubes reinforced de-icing coating for the road system with a self-heating function was developed as part of the development of a new system to prevent accidents caused by road icing. The electrical characteristics of the fabricated coating were analyzed, and the carbon nanotube coating heating performance experiment was conducted to measure the temperature increments by applying a voltage to the coating at a sub-zero temperature using an environmental chamber. In addition, the coating was installed on the road pavement and the applicability was investigated through a heating test in winter. As a result of the experiment, the coating made with the higher carbon nanotube concentration presented higher heating owing to its higher electrical conductivity. In addition, the coating showed sufficient heating performance, although the maximum temperature by Joule heating decreased for the entire coating at sub-zero temperatures. Finally, field tests demonstrated the potential of electrically conductive coatings for de-icing applications.

Ice protection techniques have attracted significant interest, notably in aerospace and wind energy applications. However, the current solutions are mostly costly and inconvenient due to energy-intensive and environmental concerns. One of the appealing strategies is the use of passive icephobicity, in the form of coatings, which is induced by means of several material strategies, such as hydrophobicity, surface texturing, surface elasticity, and the physical infusion of ice-depressing liquids, etc. In this review, surface-roughness-related icephobicity is critically discussed to understand the challenges and the role of roughness, especially on superhydrophobic surfaces. Surface roughness as an intrinsic, independent surface property for anti-icing and de-icing performance is also debated, and their interdependence is explained using the related physical mechanisms and thermodynamics of ice nucleation. Furthermore, the role of surface roughness in the case of elastomeric or low-modulus polymeric coatings, which typically instigate an easy release of ice, is examined. In addition to material-centric approaches, the influence of surface roughness in de-icing evaluation is also explored, and a comparative assessment is conducted to understand the testing sensitivity to various surface characteristics. This review exemplifies that surface roughness plays a crucial role in incorporating and maintaining icephobic performance and is intrinsically interlinked with other surface-induced icephobicity strategies, including superhydrophobicity and elastomeric surfaces. Furthermore, the de-icing evaluation methods also appear to be roughness sensitive in a certain range, indicating a dominant role of mechanically interlocked ice.

The aeronautical industry demands facile lightweight and low-cost solutions to address climate crisis challenges. Graphene can be a valid candidate to tackle these functionalities, although its upscalability remains difficult to achieve. Consequently, graphene-related materials (GRM) are gathering massive attention as top-down graphite exfoliation processes at the industrial scale are feasible and often employed. In this work, environmentally friendly produced partially oxidized graphene nanosheets (POGNs) reduced by green solvents such as l-Ascorbic Acid to rGNs are proposed to deliver functional coatings based on a glass fiber composite or coated Al2024 T3 for strategic R&D questions in the aeronautical industry, i.e., low energy production, de-icing, and water uptake. In detail, energy efficiency in rGNs production is assessed via response-surface modeling of the powder conductivity, hence proposing an optimized reduction window. De-Icing functionality is verified by measuring the stable electrothermal property of an rGNs based composite over 24 h, and water uptake is elucidated by evaluating electrochemical and corrosion properties. Moreover, a mathematical model is proposed to depict the relation between the layers\' sheet resistance and applied rGNs mass per area, which extends the system to other graphene-related materials, conductive two-dimensional materials, and various substrates. To conclude, the proposed system based on rGNs and epoxy paves the way for future multifunctional coatings, able to enhance the resistance of surfaces, such as airplane wings, in a flight harsh environment.

Slippery liquid-infused porous surface (SLIPS) realized on commercial materials provides various functionalities, such as corrosion resistance, condensation heat transfer, anti-fouling, de/anti-icing, and self-cleaning. In particular, perfluorinated lubricants infused in fluorocarbon-coated porous structures have showed exceptional performances with durability; however, they caused several issues in safety, due to their difficulty in degradation and bio-accumulation. Here, we introduce a new approach to create the multifunctional lubricant-impregnated surface with edible oils and fatty acid, which are also safe to human body and degradable in nature. The edible oil-impregnated anodized nanoporous stainless steel surface shows a significantly low contact angle hysteresis and sliding angle, which is similar with general surface of fluorocarbon lubricant-infused systems. The edible oil impregnated in the hydrophobic nanoporous oxide surface also inhibits the direct contact of external aqueous solution to a solid surface structure. Due to such de-wetting property caused by a lubricating effect of edible oils, the edible oil-impregnated stainless steel surface shows enhanced corrosion resistance, anti-biofouling and condensation heat transfer with reduced ice adhesion.

In this study, the de-icing performance is investigated between traditional carbon fibre-based coatings and novel MXene and poly(3,4-ethylenedioxythiophene)-coated single-walled carbon nanotube (PEDOT-CNT) nanocoatings, based on simple and scalable coating application. The thickness and morphology of the coatings are investigated using atomic force microscopy and scanning electron microscopy. Adhesion strength, as well as electrical properties, are evaluated on rough and glossy surfaces of the composite. The flexibility and electrical sensitivity of the coatings are studied under three-point bending. Additionally, the influence of ambient temperature on coating\'s electrical resistance is investigated. Finally, thermal imaging and Joule heating are analysed with high-accuracy infrared cameras. Under the same power density, the increase in average temperature is 84% higher for MXenes and 117% for PEDOT-CNT, when compared with fibre-based coatings. Furthermore, both nanocoatings result in up to three times faster de-icing. These easily processable nanocoatings offer fast and efficient de-icing for large composite structures such as wind turbine blades without adding any significant weight.