Micro/nanostructures have garnered significant attention and widespread applications in areas such as photocatalysis, coated fabrics, microchips, and sensors. However, high-resolution and multifunctional micro/nanostructures fabrication remains a great challenge. In this work, a novel self-assembly-femtosecond laser processing for the regular micro squares and nano bumps surface on steel substrates is proposed, and a great potential in the field of anti-icing/de-icing and self-cleaning is demonstrated. The surface tension gradient-driven liquid-air self-assembly provides a silica microsphere monolayer, while the post-femtosecond laser process can give precise micro/nano decoration. We systematically explore the impact of laser repetition frequency, scanning speed, and laser incident power on the size and shape of micro/nano decorations that have been studied. The different performances of self-cleaning effects, ice adhesion, and the photothermal de-icing capability due to the change in surface wettability have been demonstrated. This research shows a new pathway for the creation of smart micro/nanostructures surface which possess stable super hydrophilic and highly adhesive superhydrophobic properties, as well as high abrasion resistance. The discovery achieves a suitable blend of multiple functions on the surface of a single material, which can be applied to various surface engineering fields.

Photothermal materials have gained considerable attention in the field of anti-/de-icing due to its environmental friendliness and energy saving. However, it is always significantly challenging to obtain solar thermal materials with hierarchical structure and simultaneously demonstrate both the ultra-long icing delay ability and the superior photothermal de-icing ability. Here, a photothermal icephobic MOF-based micro and nanostructure surface (MOF-MNS) is presented, which consists of micron groove structure and fluorinated MOF nanowhiskers. The optimal MOF-M250 NS can achieve solar absorption of over 98% and produce a high temperature increment of 65.5 °C under 1-sun illumination. Such superior photothermal-conversion mechanism of MOF-M250 NS is elucidated in depth. In addition, the MOF-M250 NS generates an ultra-long icing delay time of ≈3960 s at -18 °C without solar illumination, achieving the longest delay time, which isn\'t reported before. Due to its excellent solar-to-heat conversation ability, accumulated ice and frost on MOF-M250 NS can be rapidly melted within 720 s under 1-sun illumination and it also holds a high de-icing rate of 5.8 kg m-2 h-1 . MOF-M250 NS possesses the versatility of mechanical robustness, chemical stability, and low temperature self-cleaning, which can synergistically reinforce the usage of icephobic surfaces in harsh conditions.

Ice protection techniques have attracted significant interest, notably in aerospace and wind energy applications. However, the current solutions are mostly costly and inconvenient due to energy-intensive and environmental concerns. One of the appealing strategies is the use of passive icephobicity, in the form of coatings, which is induced by means of several material strategies, such as hydrophobicity, surface texturing, surface elasticity, and the physical infusion of ice-depressing liquids, etc. In this review, surface-roughness-related icephobicity is critically discussed to understand the challenges and the role of roughness, especially on superhydrophobic surfaces. Surface roughness as an intrinsic, independent surface property for anti-icing and de-icing performance is also debated, and their interdependence is explained using the related physical mechanisms and thermodynamics of ice nucleation. Furthermore, the role of surface roughness in the case of elastomeric or low-modulus polymeric coatings, which typically instigate an easy release of ice, is examined. In addition to material-centric approaches, the influence of surface roughness in de-icing evaluation is also explored, and a comparative assessment is conducted to understand the testing sensitivity to various surface characteristics. This review exemplifies that surface roughness plays a crucial role in incorporating and maintaining icephobic performance and is intrinsically interlinked with other surface-induced icephobicity strategies, including superhydrophobicity and elastomeric surfaces. Furthermore, the de-icing evaluation methods also appear to be roughness sensitive in a certain range, indicating a dominant role of mechanically interlocked ice.

Accumulation of snow and ice often causes problems and even dangerous situations for both industry and the general population. Passive de-icing technologies, e.g., hydrophobic, liquid-infused bionic surfaces, have attracted more and more attention compared with active de-icing technologies, e.g., electric heating, hot air heating, due to the passive de-icing technology\'s lower energy consumption and sustainability footprint. Using passive de-icing coatings seems to be one of the most promising solutions. However, the previously reported de-icing coatings suffer from high ice adhesion strength or short service life caused by wear. An intrinsic self-healing material based on poly-silicone-urea is developed in this work to address these problems. The material is prepared by introducing dynamic disulfide bonds into the hard phase of the polymer. Experimental results indicate that this poly-silicone-urea has a self-healing efficiency of close to 99%. More interestingly, it is found that the coating prepared from this poly-silicone-urea has a super low ice adhesion force, only 7 ± 1 kPa, which is almost the lowest value compared with previous intrinsic self-healing de-/anti-icing reports. This material can maintain low ice adhesion strength after healing. This intrinsic self-healing poly-silicone-urea can meet several practical applications, opening the door for future sustainable anti-/de-icing technologies.

The accumulation of ice in winter has brought many problems in industrial production and everyday life, and how to prevent icing or remove ice rapidly has aroused great attention from researchers in recent years. In this work, we demonstrated a strategy of using a superhydrophobic photothermal and thermal isolation macroporous xerogel (PMX) to delay icing and remove ice efficiently under faint sunlight irradiation. An oriented macroporous xerogel was prepared by an ice templating method, and multi-walled carbon nanotubes acting as the photothermal genesis component under sunlight irradiation were introduced into the xerogel. After fluorination, the PMX presented a robust water repellency and delayed icing. More importantly, numerous macropores in the PMX matrix acted as the thermal barrier that can restrict heat transmission to surroundings at maximum, which guarantees efficient anti-icing and de-icing in low temperature. Water on the PMX surface can never freeze at -30 °C under 0.25 kW/m2 (\"0.25 sun\") sunlight irradiation. The outdoor experiment also has confirmed the availability of PMX in a natural winter environment. The PMX integrated with thermogenesis and thermo-isolation functions provides a new route for highly efficient anti-icing and de-icing.

OBJECTIVE: Ice accretion is a challenging issue for various residential activities and industrial facilities. However, most of the current anti/de-icing coatings fail to maintain their properties when subject to frequent mechanical wear, and their limited functionality (either anti-icing or de-icing individually) cannot meet the requirement of all-weather utilization.
METHODS: Herein, a multifunctional superhydrophobic coating is prepared by compositing ferroferric oxide nanoparticles (Fe3O4 NPs) with fluorinated epoxy resin via an inverse infiltration process. The surface composition, morphology and wettability are systematically characterized using Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDX), laser scanning microscopy and contact angle tensiometer. The anti-icing and de-icing performances are evaluated by investigating the freezing delay and photothermal effect, respectively.
RESULTS: This coating shows outstanding water repellency (water contact angle up to 161.0°, sliding angle down to 1.4°) and can maintain superhydrophobicity within 400 cycles of tape peeling, 260 cycles of sandpaper abrasion or 25 cycles of sand impact. Besides, because the hydrophobic nano/micro hierarchical structures tremendously retard the heat transfer, the freezing process of water droplet on this coating can be apparently delayed by up to 35 min as compared to the uncoated substrate. Moreover, owing to the photothermal effect of the Fe3O4 NPs, the coating\'s surface temperature can be rapidly increased above 0 °C under infrared irradiation, which facilitates the ice melting on cold surfaces. Our work offers a versatile approach to address the icing problems in diverse weather conditions, which exhibits great prospects in various engineering applications.

Resource utilization of industrial waste is a significant global challenge. Steel slag, a typical industrial by-product in the steel-making process, pollutes the environment and causes ecological deterioration. In this study, steel slag was recycled in chip seals as the aggregate, and the functional and environmental performance of the chip seal with recycled steel slag was determined. Economic costs were also discussed and compared with conventional surface layers. The results indicated that recycling steel slag as the aggregate in chip seal has a lower pollution risk and higher environmental benefits compared with those used for landfilling and dumping. Steel slag can significantly increase the heating and de-icing efficiencies of chip seal compared with basalt, particularly for microwave heating. The self-bonded function represented by the durability of aggregate retention can be enhanced by steel slag. The cost of the chip seal containing steel slag and steel fiber is only increased by 0.14 USD/m2 than that of ordinary chip seal, indicating a remarkable economic efficiency of chip seal with de-icing and self-bonded functions.