高温蠕变是指材料在高温和机械应力作用下长时间缓慢而连续的塑性变形,这可能导致组件的功能降级甚至失效。AlxCr0.2NbTiV(x=0.2、0.5或0.8)耐火高熵合金是通过电弧熔炼制造的。利用X射线衍射研究了Al含量对AlxCr0.2NbTiV合金显微组织的影响,扫描电子显微镜,和电子背散射衍射。显微硬度,压缩属性,还测试了AlxCr0.2NbTiV合金的纳米压痕蠕变性能。结果表明,AlxCr0.2NbTiV系列具有BCC单相结构。随着Al含量的增加,合金的晶格常数逐渐减小,(110)晶面衍射峰的强度增大。添加铝增强固溶强化的效果;然而,由于谷物粗化,合金的显微硬度和室温抗压强度仅略有提高。此外,因为在高温下溶液强化的效果会减弱,合金在1000°C下的抗压强度显著降低。合金的蠕变机制主要由位错蠕变控制。此外,增加Al含量有助于降低合金在蠕变过程中对加载速率的敏感性。在2.5mN/s的加载速率下,Al0.8Cr0.2NbTiV合金表现出最低的蠕变应变速率敏感指数(m),也就是0.0758。
High-temperature
creep refers to the slow and continuous plastic deformation of materials under the effects of high temperatures and mechanical stress over extended periods, which can lead to the degradation or even failure of the components\' functionality. AlxCr0.2NbTiV (x = 0.2, 0.5, or 0.8) refractory high-entropy alloys were fabricated by arc melting. The effects of Al content on the microstructure of AlxCr0.2NbTiV alloys were studied using X-ray diffraction, scanning electron microscopy, and electron backscatter diffraction. The microhardness, compression properties, and nanoindentation
creep properties of AlxCr0.2NbTiV alloys were also tested. The results show that the AlxCr0.2NbTiV series exhibits a BCC single-phase structure. As the Al content increases, the lattice constant of the alloys gradually decreases, and the intensity of the (110) crystal plane diffraction peak increases. Adding aluminum enhances the effect of solution strengthening; however, due to grain coarsening, the microhardness and room temperature compressive strength of the alloy are only slightly improved. Additionally, because the effect of solution strengthening is diminished at high temperatures, the compressive strength of the alloy at 1000 °C is significantly reduced. The
creep mechanism of the alloys is predominantly governed by dislocation
creep. Moreover, increasing the Al content helps to reduce the sensitivity of the alloy to the loading rate during the
creep process. At a loading rate of 2.5 mN/s, the Al0.8Cr0.2NbTiV alloy exhibits the lowest
creep strain rate sensitivity index (m), which is 0.0758.