金属有机框架(MOFs)的进展已经从基础化学发展到工程工艺和应用,带来新的产业机遇。MOFs的独特功能,比如它们的永久孔隙度,高表面积,和结构的灵活性,继续吸引传统MOF领域之外的工业兴趣,既要解决现有的挑战,又要创造新的业务。在这种情况下,多样化的研究一直致力于将MOF商业化,但是这样的研究是根据各种个人目标进行的。因此,分享挑战的机会有限,目标,以及大部分MOF领域的发现。在这次审查中,我们研究了MOF商业化的问题和要求,并调查了MOF工艺工程和应用的最新进展。具体来说,我们从稳定性的角度讨论了MOF商业化的标准,可生产性,法规,和生产成本。这篇综述涵盖了MOF的批量生产和形成方面的进展,以及目前尚不为人所知但在MOF商业化新领域具有很高潜力的未来应用。
Progress in metal-organic frameworks (MOFs) has advanced from fundamental chemistry to engineering processes and applications, resulting in new industrial opportunities. The unique features of MOFs, such as their permanent porosity, high surface area, and structural flexibility, continue to draw industrial interest outside the traditional MOF field, both to solve existing challenges and to create new businesses. In this context, diverse research has been directed toward commercializing MOFs, but such studies have been performed according to a variety of individual goals. Therefore, there have been limited opportunities to share the challenges, goals, and findings with most of the MOF field. In this review, we examine the issues and demands for MOF commercialization and investigate recent advances in MOF process engineering and applications. Specifically, we discuss the criteria for MOF commercialization from the views of stability, producibility, regulations, and production cost. This review covers progress in the mass production and formation of MOFs along with future applications that are not currently well known but have high potential for new areas of MOF commercialization.