Metal matrix composites

金属基复合材料
  • 文章类型: Journal Article
    这些天,金属基复合材料(MMC)作为传统材料的重要替代品被广泛用于汽车和航空航天工业。由于它们的强度重量比提高,特殊的断裂韧性,和轻量级的设计,它们可以用于各种应用。MMC进行广泛的加工,同时制造零件和组件。整体材料的加工,如金属和合金,是在不同行业中广泛使用和建立的过程,比如航空航天,生物医学,和汽车行业。由于金属基体的特性和坚固的增强,MMC提供了独特的挑战。已经发现现代加工工艺在克服挑战和实现MMC的改进的可加工性方面是优越的。本文提供了用现代方法进行MMC加工的概述。本文首先概述了MMC,并解决了与其加工相关的需求和困难。接下来,它回顾了以前对采用放电加工等现代方法加工MMC的研究,激光加工,磨料加工,和混合加工。生产力和表面完整性问题,包括分层和粗糙度,等。,正在讨论。在发表评论时,还考虑了现代工艺的优缺点。
    These days, metal matrix composites (MMCs) are being widely utilized in automotive and aerospace industries as prominent alternatives to traditional materials. Owing to their elevated strength-to-weight proportion, exceptional fracture toughness, and lightweight design, they can be used in a variety of applications. MMCs undergo extensive machining while making parts and components out of them. The machining of monolithic materials, such as metals and alloys, is a widely used and established process in different industries, such as the aerospace, bio-medical, and automotive sectors. Because of the properties of the metal matrix and the strong reinforcement, MMCs provide unique challenges. Modern machining processes have been found to be superior in overcoming challenges and achieving improved machinability of MMCs. An overview of MMC machining with modern methods is provided in this article. This article first outlines MMCs and addresses the need for and difficulties associated with their machining. Next, it reviews previous investigations on the machining of MMCs employing modern methods like electrical discharge machining, laser machining, abrasive machining, and hybrid machining. Productivity and surface integrity issues, including delamination and roughness, etc., are discussed. When presenting the review, the benefits and drawbacks of modern processes are also taken into account.
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  • 文章类型: Journal Article
    在这项研究中,碳添加量为0.2、1、1.5和2wt的NiCoCrMoCu合金在H2SO4和HCl溶液中的球-盘滑动磨损和摩擦腐蚀行为。以Al2O3球作为对应物,系统地研究了%。在两种水溶液中磨损后都发现了明显的摩擦腐蚀拮抗作用。与干滑动磨损条件相比,水溶液的润滑作用大大降低了合金的磨损率,在H2SO4水溶液中的还原效果比在HCl中的还原效果更明显。0.2C和1C合金的拮抗作用随载荷和滑动速率而降低,而1.5C和2C合金的增加。使用响应面分析(RSM)方法分析了不同载荷和滑动速率下的(摩擦系数)COF和磨损率。发现COF主要表现出对滑动率的依赖性,而磨损率表现出依赖于载荷和滑动速度。
    In this study, the ball-on-disk sliding wear and tribocorrosion behavior in the H2SO4 and HCl solution of NiCoCrMoCu alloys with carbon additions of 0.2, 1, 1.5, and 2 wt.% with the Al2O3 ball as a counterpart was investigated systematically. Obvious tribocorrosion antagonistic effects were found after wear in both aqueous solutions. Compared with dry sliding wear conditions, the lubrication effect of the aqueous solution significantly reduces the wear rate of the alloy, and the reduction effect in the H2SO4 aqueous solution was more obvious than that in HCl. The antagonistic effects of the 0.2C and 1C alloys decrease with the load and sliding rate, while those of the 1.5C and 2C alloys increase. The (coefficient of friction) COF and wear rate under different loads and sliding rates were analyzed using the response surface analysis (RSM) method. It was found that the COF mainly showed dependence on the sliding rate, while the wear rate showed dependence on load and sliding speed.
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  • 文章类型: Journal Article
    增强铝基复合材料中原位TiB2颗粒的宽尺寸范围和高团聚趋势给其尺寸表征带来了很大困难。为了使用纳米颗粒粒度分析仪(NSA)获得TiB2颗粒的精确粒度分布,已经探索了一个可控的尺寸表征过程。首先,优化了TiB2颗粒的提取和干燥工艺。在提取过程中,磁力搅拌和常规超声处理的交替应用被证明可以加速Al基质在HCl溶液中的溶解。此外,发现冷冻干燥可以最大程度地减少TiB2颗粒之间的团聚趋势,促进纯粉的收购。将这些粉末定量地制成初始TiB2悬浮液。第二,TiB2初始悬浮液中涉及的化学和物理分散技术受到关注。化学上,在初始悬浮液中以mPEI/mTiB2=1/30的比例加入PEI(M.W.10000)可以大大提高TiB2的分散程度。身体上,高能超声实现TiB2分散的最佳持续时间为10分钟。总的来说,详细讨论了相应的潜在分散机制。结合这些TiB2悬浮液的化学和物理分散规范,TiB2的双峰粒度分布首次被NSA表征,其数均直径为111±6nm,比最初的暂停减少了59.8%。的确,以NSA为特征的TiB2颗粒的小尺寸和大尺寸峰大多与透射电子显微镜和扫描电子显微镜获得的结果相匹配,分别。
    The wide size range and high tendency to agglomerate of in-situ TiB2 particles in reinforced Al matrix composites introduce great difficulties in their size characterization. In order to use a nanoparticle size analyzer (NSA) to obtain the precise size distribution of TiB2 particles, a controlled size characterization process has been explored. First, the extraction and drying processes for TiB2 particles were optimized. In the extraction process, alternated applications of magnetic stirring and normal ultrasound treatments were proven to accelerate the dissolution of the Al matrix in HCl solution. Furthermore, freeze-drying was found to minimize the agglomeration tendency among TiB2 particles, facilitating the acquisition of pure powders. Such powders were quantitatively made into an initial TiB2 suspension. Second, the chemical and physical dispersion technologies involved in initial TiB2 suspension were put into focus. Chemically, adding PEI (M.W. 10000) at a ratio of mPEI/mTiB2 = 1/30 into the initial suspension can greatly improve the degree of TiB2 dispersion. Physically, the optimum duration for high-energy ultrasound application to achieve TiB2 dispersion was 10 min. Overall, the corresponding underlying dispersion mechanisms were discussed in detail. With the combination of these chemical and physical dispersion specifications for TiB2 suspension, the bimodal size distribution of TiB2 was able to be characterized by NSA for the first time, and its number-average diameter was 111 ± 6 nm, which was reduced by 59.8% over the initial suspension. Indeed, the small-sized and large-sized peaks of the TiB2 particles characterized by NSA mostly match the results obtained from transmission electron microscopy and scanning electron microscopy, respectively.
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  • 文章类型: Journal Article
    探索合金中增强物浓度较高的高强度材料被证明是一项具有挑战性的任务。这项研究探索了具有碳化钨增强剂的镁基复合材料(AZ31B合金),通过联赛冠军优化来增强医疗关节置换的实力。主要目标是使用镁基复合材料增强医疗关节置换生物材料,强调含碳化钨增强剂的AZ31B合金。搅拌铸造方法用于制造镁基复合材料(MMC),包括不同百分比的碳化钨(WC)。机械特性,如显微硬度,抗拉强度,和屈服强度,已经进行了评估,并与计算模拟进行了比较。已经进行了磨损研究以分析复合材料的摩擦学行为。此外,这项研究调查了骨和关节结构内部的应力和力分布的预测,因此,为生物医学研究领域做出了重大贡献。这项研究考虑使用镁基MMC来发现适用于医疗关节置换的生物材料。研究重点是镁合金AZ31B,颗粒的大小范围从40到60微米用作基质材料。此外,结果表明,当与基于AZ31B-镁基质的MMC结合使用时,WC颗粒成为轻质制造的高效增强材料,高强度生物医学复合材料。本研究使用联赛冠军优化(LCO)方法来确定影响AZ31B基镁合金MgMMCs合成的关键变量。仔细分析了扫描电子显微镜(SEM)图像,以描绘WC颗粒的分散以及镁(Mg)基体和WC增强体之间的界面。SEM分析探索了粒子拔出的潜在机制,粒子间区域的特征,和AZ31B基体对增强复合材料力学特性的影响。正在使用有限元分析(FEA)的应用来预测髋关节模型中的应力分布和力的相互作用。这项研究比较了WC的物理力学和摩擦学特征与0%的不同组合,5%,10%和15%,及其对性能改进的影响。SEM分析证实了这一发现,提高了强度和硬度,特别是当加入10%-15%的WC时。在镁合金基体中掺入10%的WC颗粒后,研究结果表明,强度和硬度都有所提高,此外,通过利用SEM分析已经很明显。使用ANSYS,预测结构变形和应力水平,连同强度特性,如71HRC的附加硬度,拉伸强度为140-150MPa,和屈服强度接近100-110兆帕。这些模拟对关节在各种载荷条件下的行为产生了重要的见解,从而增强了这项研究在生物医学环境中的意义。
    Exploring high strength materials with a higher concentration of reinforcements in the alloy proves to be a challenging task. This research has explored magnesium-based composites (AZ31B alloy) with tungsten carbide reinforcements, enhancing strength for medical joint replacements via league championship optimisation. The primary objective is to enhance medical joint replacement biomaterials employing magnesium-based composites, emphasising the AZ31B alloy with tungsten carbide reinforcements. The stir casting method is utilised in the manufacture of magnesium matrix composites (MMCs), including varied percentages of tungsten carbide (WC). The mechanical characteristics, such as micro-hardness, tensile strength, and yield strength, have been assessed and compared with computational simulations. The wear studies have been carried out to analyse the tribological behaviour of the composites. Additionally, this study investigates the prediction of stress and the distribution of forces inside bone and joint structures, therefore offering significant contributions to the field of biomedical research. This research contemplates the use of magnesium-based MMCs for the discovery of biomaterials suitable for medical joint replacement. The study focuses on the magnesium alloy AZ31B, with particles ranging in size from 40 to 60 microns used as the matrix material. Moreover, the outcomes have revealed that when combined with MMCs based on AZ31B-magnesium matrix, the WC particle emerges as highly effective reinforcements for the fabrication of lightweight, high-strength biomedical composites. This study uses the league championship optimisation (LCO) approach to identify critical variables impacting the synthesis of Mg MMCs from an AZ31B-based magnesium alloy. The scanning electron microscopy (SEM) images are meticulously analysed to depict the dispersion of WC particulates and the interface among the magnesium (Mg) matrix and WC reinforcement. The SEM analysis has explored the mechanisms underlying particle pull-out, the characteristics of inter-particle zones, and the influence of the AZ31B matrix on the enhancement of the mechanical characteristics of the composites. The application of finite element analysis (FEA) is being used in order to make predictions regarding the distribution of stress and the interactions of forces within the model of the hip joint. This study has compared the physico-mechanical and tribological characteristics of WC to distinct combinations of 0%, 5%, 10% and 15%, and its impact on the performance improvements. SEM analysis has confirmed the findings\' improved strength and hardness, particularly when 10%-15% of WC was incorporated. Following the incorporation of 10% of WC particles within Mg-alloy matrix, the outcomes of the study has exhibited enhanced strength and hardness, which furthermore has been evident by utilising SEM analysis. Using ANSYS, structural deformation and stress levels are predicted, along with strength characteristics such as additional hardness of 71 HRC, tensile strength of 140-150 MPa, and yield strength closer to 100-110 MPa. The simulations yield significant insights into the behaviour of the joint under various loading conditions, thus enhancing the study\'s significance in biomedical environments.
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  • 文章类型: Journal Article
    颗粒吞噬在铸锭冶金制备的颗粒增强金属基复合材料的应用中起着至关重要的作用。在凝固过程中,尽管如此,粒子还是被前进的前沿所推动。作为一个模型系统,TiB2p/Al复合材料用于研究声空化促进的颗粒吞噬。气泡的内爆驱动颗粒向固体/液体界面下降,这增加了吞噬的可能性。由于TiB2颗粒的强制移动,二次枝晶臂从271.2μm细化到98.0μm。由于粒子吞噬和枝晶细化,超声振动处理的复合材料显示出更快的加工硬化速率和更高的强度。
    Particle engulfment plays a vital role in the application of particulate reinforced metal matrix composites fabricated by ingot metallurgy. During solidification, particles are nevertheless pushed by an advancing front. As a model system, TiB2p/Al composites were used to investigate the particle engulfment facilitated by acoustic cavitation. The implosion of bubbles drives the particles plunging towards the solid/liquid interface, which increases the engulfment probability. The secondary dendrite arms are refined from 271.2 μm to 98.0 μm as a result of the forced movements of TiB2 particles. Owing to the particle engulfment and dendrite refinement, the composite with ultrasound vibration treatment shows a more rapid work-hardening rate and higher strength.
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  • 文章类型: Journal Article
    Al-SiC金属基复合材料(MMC)的微观结构和载荷损伤的定量评估对于优化其设计具有重要意义。绩效评价和结构-属性相关性。X射线相衬显微层析成像可能用于评估以空隙形式表现的三维微结构,裂缝,嵌入粒子,和负载引起的损坏。然而,Al基体和SiC颗粒之间的对比不足以进行清晰的形态识别和定量评估。在本研究中,我们已经提出并应用了基于单个图像的相位检索作为预处理步骤,以进行显微层析成像重建,以改善Al-SiCMMC中微结构和内聚引起的损伤的评估。在SiC颗粒的图像质量增强和形态量化中应用不同的相位恢复技术的优势,讨论了孔隙和内聚损伤。观察到,Paganin方法为测量嵌入Al基体中的SiC颗粒提供了最佳的对比度噪声比改进。
    The quantitative assessment of micro-structure and load-induced damages in Al-SiC metal matrix composites (MMC) is important for its design optimization, performance evaluation and structure-property correlation. X-ray Phase contrast micro-tomography is potentially used for evaluation of its 3 dimensional micro-structure manifested in the form of voids, cracks, embedded particles, and load-induced damages. However, the contrast between Al matrix and SiC particles is insufficient for their clear morphological identification and quantitative assessment. In the present study, we have proposed and applied single image-based phase retrieval as a pre-processing step to micro-tomography reconstruction for improved assessment of micro-structure and cohesion-induced damages in Al-SiC MMC. The advantages of applying different phase retrieval techniques in the enhancement of image quality and morphological quantification of SiC particles, pores and cohesion damages are discussed. It is observed that the Paganin method offers the best improvement in contrast to noise ratio for the measurement of SiC particles embedded in the Al matrix.
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  • 文章类型: Journal Article
    这项工作的主要目的是为纤维金属基复合材料(MMC)的均匀化过程提供不确定性传播分析。此处应用的均质化方法基于原始材料和均质化材料的代表性体积元素(RVE)的变形能的比较。本部分使用ABAQUS系统中提供的有限元方法(FEM)平面应变分析完成。概率目标是通过使用响应函数方法来实现的,通过一些FEM测试进行计算机恢复,可以近似RVE位移的多项式基,并进一步代数确定所有必要的不确定性度量。期望值,标准偏差,符号代数系统MAPLE中得出了相对熵;还对比了一些不同的熵模型,包括最流行的Kullback-Leibler测度。这些特性用于讨论MMCs有效材料张量分量中不确定性传播的影响,但可以通过量化极端响应与相应的容许值之间的距离来进行可靠性评估。
    The main aim of this work is to deliver uncertainty propagation analysis for the homogenization process of fibrous metal matrix composites (MMCs). The homogenization method applied here is based on the comparison of the deformation energy of the Representative Volume Element (RVE) for the original and for the homogenized material. This part is completed with the use of the Finite Element Method (FEM) plane strain analysis delivered in the ABAQUS system. The probabilistic goal is achieved by using the response function method, where computer recovery with a few FEM tests enables approximations of polynomial bases for the RVE displacements, and further-algebraic determination of all necessary uncertainty measures. Expected values, standard deviations, and relative entropies are derived in the symbolic algebra system MAPLE; a few different entropy models have been also contrasted including the most popular Kullback-Leibler measure. These characteristics are used to discuss the influence of the uncertainty propagation in the MMCs\' effective material tensor components, but may serve in the reliability assessment by quantification of the distance between extreme responses and the corresponding admissible values.
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  • 文章类型: Journal Article
    具有接近于零热膨胀的金属基复合材料(NZTE)由于其优异的热稳定性和机械性能而在高精度工业中获得了显著的普及。Mn3Zn0.8Sn0.2N的掺入,具有突出的负热膨胀性能,有效地抑制了钛的热膨胀。通过调整制备温度,获得了高密度的Mn3Zn0.8Sn0.2N/Ti复合材料。在650°C和700°C下制造的两种复合材料均表现出NZTE。此外,采用有限元分析研究了复合材料内部热应力对其热膨胀性能的影响。
    Metal matrix composites with near-zero thermal expansion (NZTE) have gained significant popularity in high-precision industries due to their excellent thermal stability and mechanical properties. The incorporation of Mn3Zn0.8Sn0.2N, which possesses outstanding negative thermal expansion properties, effectively suppressed the thermal expansion of titanium. Highly dense Mn3Zn0.8Sn0.2N/Ti composites were obtained by adjusting the fabrication temperature. Both composites fabricated at 650 °C and 700 °C exhibited NZTE. Furthermore, finite element analysis was employed to investigate the effects of thermal stress within the composites on their thermal expansion performance.
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  • 文章类型: Journal Article
    随着半导体技术的进步,芯片冷却已成为提高电力电子系统能力的主要障碍。传统的电子封装材料已不能满足高性能芯片的散热要求。高导热率(TC),低热膨胀系数(CTE),良好的机械性能,和丰富的微加工技术基础是下一代电子封装材料的基本要求。目前,由高TC基体金属和增强相材料组成的金属基复合材料(MMC)已成为高性能包装材料开发和应用的主流方向。碳化硅(SiC)由于其高TC,是增强相的最佳选择,低CTE,和高硬度。本文综述了SiC增强铝(Al)和铜(Cu)电子封装材料的研究现状,以及影响其热力学性能的因素和改进措施。最后,总结了SiC增强MMC常规制造方法的研究现状和局限性,展望了电子封装材料未来的发展趋势。
    With the advancement of semiconductor technology, chip cooling has become a major obstacle to enhancing the capabilities of power electronic systems. Traditional electronic packaging materials are no longer able to meet the heat dissipation requirements of high-performance chips. High thermal conductivity (TC), low coefficient of thermal expansion (CTE), good mechanical properties, and a rich foundation in microfabrication techniques are the fundamental requirements for the next generation of electronic packaging materials. Currently, metal matrix composites (MMCs) composed of high TC matrix metals and reinforcing phase materials have become the mainstream direction for the development and application of high-performance packaging materials. Silicon carbide (SiC) is the optimal choice for the reinforcing phase due to its high TC, low CTE, and high hardness. This paper reviews the research status of SiC-reinforced aluminum (Al) and copper (Cu) electronic packaging materials, along with the factors influencing their thermo-mechanical properties and improvement measures. Finally, the current research status and limitations of conventional manufacturing methods for SiC-reinforced MMCs are summarized, and an outlook on the future development trends of electronic packaging materials is provided.
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  • 文章类型: Journal Article
    粉末冶金法,特别是球磨,在调整金属基复合材料(MMC)性能方面正在崛起。这项研究使用球磨在不同的研磨时间来创建一个铝基复合材料(AMC)增强的磁铁矿纳米颗粒。优化了研磨时间,以创建具有良好机械和磁性能的AMC,以及它对磁性的影响,微观结构,和硬度进行了研究。AMC在研磨8小时后显示出11.04emu/g的最高磁饱和度。压实和烧结后,使用能量色散光谱和X射线衍射(XRD)对最终复合材料的表征表明,Al2O3和Fe3Al相的存在,导致维氏硬度的机械性能增强,达到81Hv的值,与未增强的铝相比增加了270%。
    Powder metallurgy methods, particularly ball milling, are up-and-coming in tuning metal matrix composite (MMC) properties. This study uses ball milling at various milling times to create an aluminum matrix composite (AMC) reinforced with magnetite nanoparticles. The milling time was optimized to create an AMC with favorable mechanical and magnetic properties, and its effect on magnetism, microstructure, and hardness was studied. The AMC displayed the highest magnetic saturation of 11.04 emu/g after 8 h of milling. After compaction and sintering, characterization of the final composite material using Energy Disperse Spectroscopy and X-ray diffraction (XRD) showed the presence of Al2O3 and Fe3Al phases leading to enhanced mechanical properties in terms of Vickers hardness that reached a value of 81 Hv corresponding to an increase of 270% compared to unreinforced aluminum.
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