Determining the supply and uptake of K nutrient and the dynamic equilibrium (adsorption-desorption) reactions among the K forms in the soils are not commonly addressed in the highlands of Ethiopia. A study was therefore initiated to determine the adsorption capacity of the exchangeable K and the release kinetics of the non-exchangeable K in the soils of the Qenberenaweti Sub-watershed. Twelve disturbed surface (0-20 cm) soil sub-samples were collected from every farmland which was representative of each pre-identified soil type (Vertic Cambisols, Pellic Vertisols, Pisoplinthic Luvisols, Relictistagnic Cambisols, Pisoplinthic Cambisols, and Plinthofractic Cambisols). A composite sample was made in duplicate for the determination of K adsorption capacity and desorption kinetics per soil type. The mean maximum (69.47 ± 4.31 %) and minimum (56.16 ± 6.04 %) K adsorption rates were obtained from the Plinthofractic Cambisols and Vertic Cambisols, respectively. Among the tested isotherm models, the goodness of the Freundlich was better fit the data of all experimental soils; hence, a modified equation of this model (qe = aCeb/a) could be used to describe the theoretical doses of K fertilizers required to develop K levels in soil solutions. The highest constant K releases from the Plinthofractic Cambisols (47 mg kg-1), Pisiopllintic Cambisols (46 mg kg-1), and Pisoplinthic Luvisols (44 mg kg-1) were attained at the 9th extraction. In comparison, it was noticed at the 7th and 11th extractions of the Relictistagnic Cambisols (45 mg kg-1) and both Pellic Vertisols (48 mg kg-1) and Vertic Cambisols (42 mg kg-1), respectively. The equation of power function was the best to successfully describe the released K+ from all the experimental soils. Eventually, determining the adsorption capacity and release kinetics of K at a site-specific level helps to know the relative potential of the soils to supply K and also plan for an effective K fertilization strategy.

Heavy metals significantly impact the environment due to their non-biodegradable, toxic, and carcinogenic behaviors. Lead contaminants impose severe health impacts on humans and the water environment. Therefore, eco-friendly and efficient lead ion removal practices such as nanotechnology are an urgent requirement for the abatement of lead pollution. In the present study, nanocellulose was synthesized from the cotton straw residue using chemical methods and modified with titanium dioxide to form a nanocomposite. The nanocomposite synthesized was characterized by using FTIR, XRD, FESEM, and BET. FTIR results noticed peaks at 1648.43 and 1443.57 cm-1 for cellulose and Ti-O-Ti bonding at 505.02 cm-1. The nanocomposite was noticed to be disordered and irregular in shape. The nanocomposite has particle sizes of 83 nm. The nanocomposite crystalline particle had 65% anatase and 32% rutile phases observed from the XRD result. BET results show that the surface area of nanocellulose increases after surface modification from 25.692 to 42.510 m2/g. The adsorption capacity of the nanocomposite was 0.552 mg/g was noticed. The Elovich kinetic and Baudu isotherms are the best-fitted models for lead ion adsorption. Thermodynamic parameters resulted in Gibbs free energy decreasing with temperature. This study revealed that modified cellulosic adsorbents efficiently absorbed lead ions derived from cotton straws.

Heavy metals are one of the most dangerous environmental pollutions, and their elimination is one of the health system\'s priorities. Microorganisms have been introduced as a safe absorber of such pollution and this ability is related to the characteristics of their surface layers. There are reports about some bacteria\'s increment of cell envelope thickness in space conditions. Therefore, this study investigated SMG effect on heavy metals biosorption using Saccharomyces (S.) cerevisiae. Furthermore, the stability of complex, isotherm, and kinetic absorption models has been investigated. The results showed that the SMG positively affected the biosorption of mercury (Hg) 97% and lead (Pb) 72.5% by S. cerevisiae. In contrast, it did not affect cadmium (Cd) and arsenic (As) biosorption. In gastrointestinal conditions, Hg, Cd, and As-yeast complexes were stable, and their biosorption increased. In the case of the Pb-yeast complex, in simulated gastric exposure, the binding decreased at first but increased again in simulated intestinal exposure in both SMG and normal gravity (NG). The metals\' biosorption by yeast followed the pseudo-second-order kinetic and the Langmuir isotherm models for all metals (As) matched with Langmuir and Freundlich. The current research results demonstrate that microgravity provides desirable conditions for heavy metal biosorption by S. cerevisiae. Furthermore, the biosorbent-heavy metal complex remains stable after simulated gastrointestinal conditions. Altogether, the results of this study could be considered in detoxifying food and beverage industries and maintaining astronauts\' health.

During the years, adsorption has garnered considerable attention being one of the most cost-effective and efficient methods for separating contaminants out of liquid phase. A comprehensive understanding of adsorption mechanisms entails several crucial steps, including adsorbent characterization, batch and column adsorption tests, fitting of predefined kinetic and isotherm models, and meticulous thermodynamic analysis. These combined efforts serve to provide clarity and insights into the intricate workings of adsorption phenomena. However, the vast amount of literature published in the field each year is riddled with ill-considered model selections and incorrect parameter analyses. Therefore, the aim of this paper is to establish guidelines for the proper employment of these numerous kinetic, isotherm, and fixed-bed models in various applications. A thorough review has been undertaken, encompassing more than 45 kinetic models, 70 isotherm models, and 45 fixed bed models available hitherto, with their classification determined based on the adsorption mechanisms expounded within each of them. Moreover, five general approaches for modifying fixed-bed models were provided. The physical meanings, assumptions, and interconversion relationships of the models were discussed in detail, along with the information criterion used to evaluate their validity. In addition to commonly used activation energy and Gibbs energy analysis, the methods for calculating site energy distribution were also summarized.

The characteristics of water vapor adsorption depend on the structure, porosity, and functional groups of the material. Metal-organic framework (MOF)-derived carbon (MDC) is a novel material that exhibits a high specific area and tunable pore sizes by exploiting the stable structure and porosity of pure MOF materials. Herein, two types of aluminum-based MOFs were used as precursors to synthesize hydrophobic microporous C-MDC and micro-mesoporous A-MDC via carbonization and activation depending on the type of ligands in the precursors. C-MDC and A-MDC have different pore characteristics and exhibit distinct water adsorption properties. C-MDC with hydrophobic properties and micropores exhibited negligible water adsorption (108.54 mgg-1) at relatively low pressures (P/P0~0.3) but showed a rapid increase in water adsorption ability (475.7 mgg-1) at relative pressures of about 0.6. A comparison with the isotherm model indicated that the results were consistent with the theories, which include site filling at low relative pressure and pore filling at high relative pressure. In particular, the Do-Do model specialized for type 5 showed excellent agreement.

In this paper, a natural Moroccan material from the Nador area in the north east of Morocco was studied as an adsorbent to remove methyl violet 2B dye from aqueous solutions. This material has never been studied before in this region, and it will be used in its raw state. It was collected and characterized by X-ray diffraction, FTIR spectroscopy, scanning electron microscopy, X-ray fluorescence, thermal analysis, N2 gas adsorption-desorption, pHPZC, and Brunauer-Emmett-Teller (BET). The studies are realized with a 500-µm grain size and 182m2/g BET surface area. XRD showed the presence of significant peaks belonging to natural zeolite type clinoptilolite-Ca and minor phases. Several parameters were studied such as contact time, adsorbent mass, initial dye concentration, initial pH solution, the particle size of the material, and temperature. Out of the three isotherm models investigated after 60 min of contact time in the experiments, the Langmuir model gave the best fit to the experimental data (R2 = 0.99). The results of kinetic and thermodynamic studies revealed that the adsorption process obeyed pseudo-second-order, spontaneous (ΔG° < 0), endothermic (ΔS° > 0). The adsorption of methyl violet 2B dye is chemisorptions and physisorption. The maximum theoretical adsorption capacity was 30.30 mg·g-1 at 23 °C for a particle diameter of 500 µm. The desorption study shows that the material can be desorbed using solvents. The reuse study indicates that the same amount of natural zeolite can be used several times which makes the process efficient and sustainable. The obtained results indicate that the country of Morocco has natural zeolite among its resources and that it can be used as an efficient adsorbent for the removal of dyes.

Nowadays, the use of natural materials and especially \"waste\" valorization has evolved and attracted the wide attention of scientists and academia. In this regard, the use of rice husk (RH) powder as a naturally abundant and cheap byproduct material is gaining superior attention. However, improving the physicochemical properties of such RH is still under research. In the current investigation, the modification of rice husk (RH) via γ-irradiation has shown to be a promising green tool to meet such a need. Clean, prepared, powdered RH samples were subjected to various γ-radiation doses, namely 5, 10, 15 and 25 kGy, and the corresponding samples were named as RH-0, RH-5, RH-10, RH-15, RH-15 and RH-25. Then, the samples were characterized via scanning electron microscopy (SEM). After irradiation, the samples showed an increase in their surface roughness upon increasing the γ-radiation up to 15 kGy. Furthermore, the sorption capacity of the irradiated RH samples was investigated for eliminating Urolene Blue (UB) dye as a model pharmaceutical effluent stream. The highest dye uptake was recorded as 14.7 mg/g, which corresponded to the RH-15. The adsorption operating parameters were also investigated for all of the studied systems and all adsorbents showed the same trend, of a superior adsorption capacity at pH 6.6 and high temperatures. Langmuir and Freundlich isotherm models were also applied for UB adsorption and an adequate fitted isotherm model was linked with Langmuir fitting. Moreover, the pseudo-second-order kinetic model provided the best fit for the adsorption data. Experimental assays confirmed that the UB dye could be successfully eradicated feasibly from the aqueous stream via a sustainable green methodology.

Multiwalled carbon nanotubes (MWCNTs) were modified by oxidation and acidification with concentrated HNO3 and H2SO4, and the modified multiwalled carbon nanotubes (M-MWCNTs) and raw MWCNTs were characterized by several analytical techniques. Then the demanganization effects of MWCNTs and M-MWCNTs were well investigated and elucidated. The experimental data demonstrated that the adsorption efficiency of Mn(II) could be greatly promoted by M-MWCNTs from about 20% to 75%, and the optimal adsorption time was 6 h and the optimal pH was 6. The results of the kinetic model studies showed that Mn(II) removal by M-MWCNTs followed the pseudo-second-order model. Isothermal studies were conducted and the results demonstrated that the experimental data fitted well with the three models. The reliability of the experimental results was well verified by PSO-BP simulation, and the present conclusion could be used as a condition for further simulation. The research results provide a potential technology for promoting the removal of manganese from wastewater; at the same time, the application of various mathematical models also provides more scientific ideas for the research of the mechanism of adsorption of heavy metals by nanomaterials.

The quantitative description of the equilibrium data by the isotherm models is an indispensable link in adsorption studies. The previous review papers focus on the underlying assumptions, fitting methods, error functions and practical applications of the isotherm models, usually ignoring their curve characteristics, selection criteria and common controversies. The main contents of this review include: (i) effect of the model parameters on the isotherm curves; (ii) determination of the site energy distribution; (iii) selection criteria of the isotherm models; and (iv) elimination of some common controversies. It is of great significance to reveal the curve characteristics for selecting a proper isotherm model. The site energy distribution is conducive to understanding the physicochemical properties of the adsorbent surface. The complete isotherm is recommended to be correlated with the experimental data. The model parameter qmax should be cautiously adopted for comparison of the adsorbent performance. The residual plot can be used to diagnose the fitting quality of the isotherm models further. This review also addresses some common mistakes and controversies and thereby avoids their propagation in future publications.

Nonylphenol (NP) is considered to be an environmentally toxic, endocrine-disrupting chemical that affects humans and ecosystems. Adsorption is one of the most promising approaches for the removal of nonylphenol contamination from water. Herein, in order to design an adsorbent with high adsorption capacity, magnesium silicate with different Mg/Si ratios was successfully synthesized by a sol-gel method at 60 °C. Magnesium silicate with a Mg/Si ratio of 1:6 was found to possess the best adsorption performance, with maximum 4-NP sorption 30.84 mg/g under 25 °C and 0.2 g/L adsorbent dose. The adsorption was negatively affected by increasing adsorbent dose and temperature. The kinetics and isotherm of 4-NP adsorption by Mg/Si were well described by the pseudo-second-order and Sips model, respectively, and behavior was proven to be physisorption-enhanced by a chemical effect. Detailed characterization by XRD, BET, and SEM confirmed that the magnesium silicate possesses an amorphous, mesoporous structure. The study will contribute to the applicability of cheap magnesium silicate for removal of NP contamination in water.