One of the major issues of modern society is water contamination with different organic, inorganic, and contaminants bacteria. Finding cost-effective and efficient materials and methods for water treatment and environment remediation is among the scientists\' most important considerations. Hollow-structured nanomaterials, including hollow fiber membranes, hollow spheres, hollow nanoboxes, etc., have shown an exciting capability for wastewater refinement approaches, including membrane technology, adsorption, and photocatalytic procedure due to their extremely high specific surface area, high porosity, unique morphology, and low density. Diverse hollow nanostructures could potentially eliminate organic contaminants, including dyes, antibiotics, oil/water emulsions, pesticides, and other phenolic compounds, inorganic pollutants, such as heavy metal ions, salts, phosphate, bromate, and other ions, and bacteria contaminations. Here, a comprehensive overview of hollow nanostructures\' fabrication and modification, water contaminant classification, and recent studies in the water treatment field using hollow-structured nanomaterials with a comparative attitude have been provided, indicating the privilege abd detriments of this class of nanomaterials. Eventually, the future outlook of employing hollow nanomaterials in water refinery systems and the upcoming challenges arising in scaling up are also propounded.

In the present study, single phase nickel based disulphide (NiS2) and diselenide (NiSe2) nanostructures were prepared hydrothermally in a short time span (4 h) under subcritical temperature (160 °C). The nanostructures grow in cubic crystal phases. Average crystallite sizes and intrinsic microstrains were determined using Williamson-Hall (W-H) plot analysis. Hollow NiS2 nanospheres and bipyramidal NiSe2 nanostructures are reported that are suitable for surface related applications. Thermal gravimetric analysis (TGA) indicated high stability of the nanostructures at elevated temperatures. Optical studies indicated visible light activeness of the nanostructures exhibiting sharp band edges. The nanostructures are mesoporous in nature with NiS2 and NiSe2 having respectively a large specific surface area of 310 m2/g and 177 m2/g. A primarily work done to determine the electrochemical nature of the nanostructures showed the materials are pseudo-capacitive in nature with specific capacitances of 1022 F/g and 480 F/g respectively for NiS2 and NiSe2. The photo-catalytic activity of the nanostructures was explored against a colourless pollutant; phenol. The nanostructures degraded most of the phenol (>90 %) under visible light illumination and the reusability experiments performed determined industrial value of the photocatalysts.

Hollow nanoreactors (HoNRs) have regarded as an attractive catalytic material for photocatalysis due to their exceptional capabilities in enhancing light harvesting, facilitating charge separation and transfer, and optimizing surface reactions. Developing novel HoNRs offers new options to realize controllable catalytic behavior. However, the catalytic mechanism of photocatalysis occurring in HoNRs has not yet been fully revealed. Against this backdrop, this review elaborates on three aspects: 1) the fundamental theoretical insights of HoNRs-driven photocatalytic kinetics; 2) structure-performance relationship of HoNRs to photocatalysis; 3) catalytic advantages of HoNRs in photocatalytic applications. Specifically, the review focuses on the fundamental theories of HoNRs for photocatalysis and their structural advantages for strengthening light scattering, promoting charge separation and transfer, and facilitating surface reaction kinetics, and the relationship between key structural parameters of HoNRs and their photocatalytic performance is in-depth discussed. Also, future prospects and challenges are proposed. It is anticipated that this review paper will pave the way for forthcoming investigations in the realm of HoNRs for photocatalysis.

Metal nanoparticles are attracting interest for their light-absorption properties, but such materials are known to dynamically evolve under the action of chemical and physical perturbations, resulting in changes in their structure and composition. Using a transmission electron microscope equipped for optical excitation of the specimen, the structural evolution of Cu-based nanoparticles under simultaneous electron beam irradiation and plasmonic excitation was investigated with high spatiotemporal resolution. These nanoparticles initially have a Cu core-Cu2O oxide shell structure, but over the course of imaging, they undergo hollowing via the nanoscale Kirkendall effect. We captured the nucleation of a void within the core, which then rapidly grows along specific crystallographic directions until the core is hollowed out. Hollowing is triggered by electron-beam irradiation; plasmonic excitation enhances the kinetics of the transformation likely by the effect of photothermal heating.

As a novel class of catalytic materials, hollow nanoreactors offer new opportunities for improving catalytic performance owing to their higher controllability on molecular kinetic behavior. Nevertheless, to achieve controllable catalysis with specific purposes, the catalytic mechanism occurring inside hollow nanoreactors remains to be further understood. In this context, this Review presents a focused discussion about the basic concept of hollow nanoreactors, the underlying theory for hollow nanoreactor-driven kinetics, and the intrinsic correlation between key structural parameters of hollow nanoreactors and molecular kinetic behaviors. We aim to provide in-depth insights into understanding kinetics occurred within typical hollow nanoreactors. The perspectives proposed in this paper may contribute to the development of the fundamental theoretical framework of hollow nanoreactor-driven catalysis.

Promoting charge separation, constructing active sites, and improving the utilization of metal atoms are very important for the design of efficient photocatalysts. A simultaneous loading of Ni2 P cocatalysts on the inner and outer surfaces of mesoporous P-doped carbon nitride hollow nanospheres (PCNHS) to construct a Ni2 P@PCNHS@Ni2 P photocatalyst is reported. Ni2 P cocatalysts loading provides enough active sites on both the inner and outer surfaces for proton reduction, and the formed heterojunctions simultaneously promote the migration and separation of the photogenerated charges on the inner and outer surfaces. The photocatalytic reaction proceeds simultaneously on the inner and outer surfaces of Ni2 P@PCNHS@Ni2 P, which leads to a significantly improved photocatalytic water splitting performance and enhanced atomic utilization. Notably, the hydrogen evolution rate of Ni2 P@PCNHS@Ni2 P is 2.4 times higher than that of Pt-loaded PCNHS. The findings guide the design of hollow nanostructured composites with high-boosting photocatalytic performance.

Rationally modulating the catalytic microenvironment is important for targeted induction of specific molecular behaviors to fulfill complicated catalytic purposes. Herein, a metal pre-chelating assisted assembly strategy is developed to facilely synthesize the hollow carbon spheres with ultrafine ruthenium clusters embedded in pore channels of the carbon shell (Ru@Shell-HCSs), which can be employed as nanoreactors with preferred electronic and geometric catalytic microenvironments for the efficient tandem hydrogenation of biomass-derived furfural toward 2-methylfuran. The channel-embedding structure is proved to confer the ultrafine ruthenium clusters with an electron-deficient property via a reinforced interfacial charge transfer mechanism, which prompts the hydrogenolysis of intermediate furfuryl alcohol during the tandem reaction, thus resulting in an enhanced 2-methylfuran generation. Meanwhile, lengthening the shell pore channel can offer reactant molecules with a prolonged diffusion path, and correspondingly a longer retention time in the channel, thereafter delivering an accelerated tandem hydrogenation progression. This paper aims to present a classic case that emphasizes the critical role of precisely controlling the catalytic microenvironment of the metal-loaded hollow nanoreactors in coping with the arduous challenges from multifunctional catalyst-driven complex tandem reactions.

The development of efficient and stable nanomaterial electrocatalysts for the hydrogen evolution reaction (HER) is of great significance for renewable energy conversion via water electrolysis. Herein, we have developed a novel class of bimetallic RuM (M = Ni, Co) hollow nanorods (HNRs) through a facile Fe3+ etching strategy, as electrocatalysts for enhancing the HER. Morphological physical characterization and electrochemical tests demonstrated that RuM (M = Ni, Co) HNRs with hollow structures can effectively enhance electrocatalytic activity due to their high specific surface areas. Impressively, the RuNi HNRs exhibited superior HER performance with an overpotential of merely 25.6 mV in 1 M KOH solution at 10 mA cm-2, which is significantly lower than that of commercial Pt/C (44.7 mV). Moreover, the as prepared RuNi HNRs showed excellent stability and could continuously work at a current density of 10 mA cm-2 for 40 h with a negligible increase in potential. The Ru-based HNRs also showed high HER activity in an acidic solution. This study paves a new way for the universal fabrication of bimetallic hollow structured nanomaterials as efficient electrocatalysts for boosting the HER.

The ability to detect pathogens specifically and sensitively is critical to combat infectious diseases outbreaks and pandemics. Colorimetric assays involving loop-mediated isothermal amplification (LAMP) provide simple readouts yet suffer from the intrinsic non-template amplification. Herein, a highly specific and sensitive assay relying on plasmonic sensing of LAMP amplicons via DNA hybridization, termed as plasmonic LAMP, is developed for the severe acute respiratory syndrome-related coronavirus 2 (SARS-CoV-2) RNA detection. This work has two important advances. First, gold and silver (Au-Ag) alloy nanoshells are developed as plasmonic sensors that have 4-times stronger extinction in the visible wavelengths and give a 20-times lower detection limit for oligonucleotides over Au counterparts. Second, the integrated method allows cutting the complex LAMP amplicons into short repeats that are amendable for hybridization with oligonucleotide-functionalized Au-Ag nanoshells. In the SARS-CoV-2 RNA detection, plasmonic LAMP takes ≈75 min assay time, achieves a detection limit of 10 copies per reaction, and eliminates the contamination from non-template amplification. It also shows better detection specificity and sensitivity over commercially available LAMP kits due to the additional sequence identification. This work opens a new route for LAMP amplicon detection and provides a method for virus testing at its early representation.

Potassium-selenium (K-Se) batteries attract tremendous attention because of the two-electron transfer of the selenium cathode. Nonetheless, practical K-Se cells normally display selenium underutilization and unsatisfactory rate capability. Herein, we employ a synergistic spatial confinement and architecture engineering strategy to establish selenium cathodes for probing the effect of K+ diffusion kinetics on K-Se battery performance and improving the charge transfer efficiency at ultrahigh rates. By impregnating selenium into hollow and solid carbon spheres with similar diameters and porous structures, the obtained parallel Se/C composites possess nearly identical selenium loadings, molecular structures, and heterogeneous interfaces but enormously different paths for K+ diffusion. Remarkably, as the solid-state K+ diffusion distance is significantly reduced, the K-Se cell achieves 96% of 2e- transfer capacity (647.1 mA h g-1). Reversible capacities of 283.5 and 224.1 mA h g-1 are obtained at 7.5 and 15C, respectively, corresponding to an unprecedented high power density of 8777.8 W kg-1. Quantitative kinetic analysis demonstrated a twofold higher capacitive charge storage contribution and a 1 order of magnitude higher K+ diffusion coefficient due to the short K+ diffusion path. By combining the determination of potassiation products by ex situ characterization and density functional theory (DFT) calculations, it is identified that the kinetic factor is decisive for K-Se battery performances.