Environmental protection

环境保护
  • 文章类型: Journal Article
    肼(N2H4)是化工生产中广泛使用的重要化工原料。然而,由于它的波动性,水溶性,和高毒性,N2H4的气体形式和水溶液都会造成严重的污染,从而对植物产生不利影响,从而造成重大的环境风险。微生物,和人类健康。因此,准确检测环境中的N2H4对于维护公众健康至关重要。在这项研究中,我们合成了一种基于咔唑和半鸟嘌呤基团的比例荧光探针(BCaz-Cy2)。该探针显示出简单的合成程序,快速响应时间,高灵敏度和选择性以及显着的检测信号。它能够有效检测各种基质中的N2H4,例如水,食物,土壤和植物样品,从而显着扩大N2H4探针的应用范围。
    Hydrazine (N2H4) is a crucial chemical raw material extensively utilized in chemical production. However, due to its volatility, water solubility, and high toxicity, both the gaseous form and aqueous solution of N2H4 pose significant environmental risks by causing severe pollution that can adversely impact plants, microorganisms, and human health. Therefore, accurate detection of N2H4 in the environment is imperative for safeguarding public health. In this study, we synthesized a ratiometric fluorescent probe (BCaz-Cy2) based on Carbazole and Hemicyanine groups. This probe exhibits simple synthesis procedure, rapid response time, high sensitivity and selectivity as well as remarkable detection signals. It enables effective detection of N2H4 in various matrices such as water, food, soil and plant samples thereby significantly expanding the scope of applications for N2H4 probes.
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  • 文章类型: Journal Article
    对电子技术的日益依赖提高了有效的电磁干扰(EMI)屏蔽材料的紧迫性。这篇综述探讨了磁铁矿掺入的一维(1D)碳纳米结构杂化物的发展和潜力,专注于其独特的性质和合成方法。通过将磁铁矿的磁性能与碳纳米管(CNT)和碳纤维(CFs)等碳纳米结构的导电性和机械强度相结合,这些混合提供优越的EMI屏蔽性能。各种合成技术,包括溶剂热合成,原位生长,和静电自组装,进行了详细的讨论,突出它们对所得复合材料的结构和性能的影响。这篇综述还讨论了实现纳米填料均匀分散的挑战以及大规模生产的环境和经济考虑。混合材料的多功能性,包括增强的机械强度,热稳定性,和环境抗性,强调了它们在航空航天领域的先进应用的适用性,电子,和环境保护。未来的研究方向集中在优化合成工艺和探索新的混合构型,以进一步提高电磁性能和实际适用性。
    The increasing reliance on electronic technologies has elevated the urgency of effective electromagnetic interference (EMI) shielding materials. This review explores the development and potential of magnetite-incorporated one-dimensional (1D) carbon nanostructure hybrids, focusing on their unique properties and synthesis methods. By combining magnetite\'s magnetic properties with the electrical conductivity and mechanical strength of carbon nanostructures such as carbon nanotubes (CNTs) and carbon fibers (CFs), these hybrids offer superior EMI shielding performance. Various synthesis techniques, including solvothermal synthesis, in situ growth, and electrostatic self-assembly, are discussed in detail, highlighting their impact on the structure and properties of the resulting composites. This review also addresses the challenges in achieving homogeneous dispersion of nanofillers and the environmental and economic considerations of large-scale production. The hybrid materials\' multifunctionality, including enhanced mechanical strength, thermal stability, and environmental resistance, underscores their suitability for advanced applications in aerospace, electronics, and environmental protection. Future research directions focus on optimizing synthesis processes and exploring new hybrid configurations to further improve electromagnetic properties and practical applicability.
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  • 文章类型: Journal Article
    工业来源的重金属污染是全球范围内的主要环境和健康危害。本研究介绍了一种使用基于废物的工业废物的固化/稳定方法,来自钢包渣和石膏的富含钙矾石的固体粘合剂,用于固定具有极高含量的几种重金属的工业废料。研究了硫酸盐和水含量对固定化效率的重要性以及使用柠檬酸来增加粘合剂的处理时间。铅的浸出,Hg,Se,As,Cd,Cu,并测量了镍,和X射线粉末衍射,场发射扫描电子显微镜,和场发射电子探针显微分析结合波长色散X射线光谱法用于分析硬化粘结剂的结构和重金属的位置。研究表明,钢包渣/石膏粘结剂适用于富重金属固体工业废料的固化/稳定化。Hg,As,Cd,Cu,Ni在研究涵盖的所有情况下都完全固定,而Pb和Se表现出更复杂的行为。主要的固定化方法是封装,观察到部分硒掺入钙矾石。柠檬酸的存在增加了粘合剂的加工时间,而不会损害固定,除非结合低硫酸盐含量。
    Heavy metal pollution from industrial sources is a major environmental and health hazard on a global scale. This study introduces a solidification/stabilization method of industrial waste using a waste-based, ettringite-rich solid binder from ladle slag and gypsum for the immobilization of an industrial waste material with extremely high contents of several heavy metals. The importance of sulfate and water content on the immobilization efficiency and the use of citric acid to increase the processing time of the binder were studied. The leaching of Pb, Hg, Se, As, Cd, Cu, and Ni was measured, and X-ray powder diffraction, field-emission scanning electron microscopy, and field-emission electron probe microanalysis combined with wavelength-dispersive X-ray spectroscopy were used to analyze the structure of the hardened binder and the location of the heavy metals within. The study shows that the ladle slag/gypsum binder is suitable for the solidification/stabilization of heavy-metal-rich solid industrial waste. Hg, As, Cd, Cu, and Ni were fully immobilized in all scenarios covered in the study, whereas Pb and Se showed more complicated behaviors. The main immobilization method was encapsulation, and partial Se incorporation into ettringite was observed. The presence of citric acid increased the processing time of the binder without harming the immobilization, unless combined with low sulfate content.
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  • 文章类型: Journal Article
    为了研究环境伦理之间的关系,精神健康,和护理专业学生的环境行为。
    在这项横断面研究中,使用简单的随机抽样方法从Chabahar护理学校中选择了200名伊朗学生。数据收集工具包括一份关于人口统计信息的问卷,知识,对环境的态度和行为,环境伦理,和精神健康。本研究利用偏最小二乘结构方程模型(PLS-SEM)来评估概念框架。
    护理专业学生的环境伦理平均得分为65.73±10.61(满分100分)。大多数学生(47%)具有理想的环境道德。知识结构(β=0.46)预测态度。态度结构还预测了环境行为(β=0.28)和精神健康(β=0.31)。最终,结果表明,精神健康和环境伦理直接和间接预测环境行为(p<0.001)。
    精神健康和环境伦理是环境行为的有力预测因子。因此,将来促进环境保护行为不仅要考虑学生的精神健康,还要考虑他们的道德行为。
    UNASSIGNED: To investigate the relationship between environmental ethics, spiritual health, and environmental behavior among nursing students.
    UNASSIGNED: In this cross-sectional study, 200 iranian students from the Chabahar Nursing School were selected using a simple random sampling method. The data collection tool included a questionnaire on demographic information, knowledge, attitudes and behaviors towards the environment, environmental ethics, and spiritual health. Partial least squares structural equation modeling (PLS-SEM) was utilized to evaluate the conceptual framework in this study.
    UNASSIGNED: The mean score for environmental ethics among nursing students was 65.73±10.61 out of 100. Most of the students (47%) had desirable environmental ethics. The knowledge structure (β=0.46) predicted attitude. The attitude structure also predicted environmental behavior (β=0.28) and spiritual health (β=0.31). Ultimately, the results showed that spiritual health and environmental ethics predict environmental behavior directly and indirectly (p<0.001).
    UNASSIGNED: Spiritual health and environmental ethics were strong predictors of environmental behavior. Therefore, it is necessary to take into account not only students\' spiritual health but also their ethical behaviors to promote environmental protection behaviors in the future.
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  • 文章类型: Journal Article
    利用卫星数据分析了平朔矿区和市区粉尘浓度的时空分布规律。结果表明,卫星反演的朔州市PM2.5和PM10平均浓度的相关系数分别为0.88和0.63,卫星反演数据可靠性高。平朔矿区冬季和春季粉尘浓度的空间分布升高,冬季有大量的灰尘积累。平朔矿区的污染现象在1-3月份明显,空气质量严重恶化。城市与矿区之间粉尘浓度的相关性分析揭示了城市与矿区边界处明显的空间不连续性,说明矿区不是市区粉尘浓度升高的主要原因,矿区内粉尘浓度的变化对市区没有显著影响。研究结果对矿区和城市地区的粉尘控制具有重要意义。
    The spatial and temporal distribution patterns of dust concentration in the Pingshuo mining area and urban area were analyzed utilizing satellite data. The results indicate that the correlation coefficients of the average PM2.5 and PM10 concentration retrieved by satellite in Shuozhou City are 0.88 and 0.63, respectively, and the satellite inversion data demonstrate high reliability. The spatial distribution of dust concentration in the Pingshuo Mine area is elevated during winter and spring, with significant dust accumulation in winter. The pollution phenomenon in the Pingshuo mining area was pronounced from January to March, and the air quality deteriorated significantly. The correlation analysis of dust concentration between the city and the mining area reveals a marked spatial discontinuity at the boundary between the city and the mining area, indicating that the mining area is not the primary cause of the increase of dust concentration in the urban area, and changes in dust concentration within the mining area exert no significant impact on the urban area. The research results possess significant implications for dust control in both the mining and urban areas.
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  • 文章类型: Journal Article
    公司内部采取环境保护政策的决定面临着对业绩产生负面影响的担忧。本文的目的是分析采取环境保护措施对喀麦隆第三产业VSE绩效的影响。线性模型和匹配方法的使用,如倾向得分匹配(PSM)和多变量距离匹配(MDM)揭示了对性能的积极影响。然而,并非所有的环境保护措施都会产生这样的效果。当检查影响通道时,路径分析类型的结构方程模型表明,成本是不可忽略的传输渠道。然而,根据所采用的设备,在作用机制的差异被发现。对采取环保措施效果的异质性分析表明,根据企业经营年限和公司规模的不同,效果并不相同。建立应用于IV方法的区域部门工具的结果证明了我们结果的稳健性。该研究鼓励公司以环保的方式行事,并确认公共当局需要在不强迫他们这样做的情况下支持他们。
    The decision to adopt environmental protection policies within companies is faced with the fear of negative repercussions on performance. The aim of this paper is to analyse the effect of adopting environmental protection measures on the performance of VSEs in the tertiary sector in Cameroon. The use of linear models and matching methods such as Propensity Score Matching (PSM) and Multivariate Distance Matching (MDM) reveals a positive influence on performance. However, not all environmental protection measures produce such an effect. When the channel of influence is checked, structural equation models of the path analysis type show that costs are a non-negligible transmission channel. However, a difference in the mechanism of action depending on the device adopted is found. An analysis of the heterogeneity of the effect of adopting environmental protection measures shows that the effect is not identical according to the number of years in business and the size of the company. The results of building a region-sectoral instrument applied to the IV method attest to the robustness of our results. The study encourages companies to behave in an environmentally friendly way and confirms the need for public authorities to support them without forcing them to do so.
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  • 文章类型: Journal Article
    化石燃料,尤其是煤炭,在过去的一个世纪中,在推动技术和经济进步方面发挥了关键作用,尽管伴随着许多环境挑战。绿色和可持续能源的快速发展,包括潮汐,风,和太阳能,加上日益增长的环境问题,传统煤炭行业的规模和财务生存能力都在持续下降。这种情况迫切需要采用先进的煤炭利用方法。除了作为能源,煤炭及其副产品,被称为煤炭废物,可以作为开发先进材料的宝贵资源,包括光催化剂。来自煤炭和煤炭废物的光催化材料的进步可以利用这些天然碳和矿物来源,为众多环境挑战提供可行的解决方案。目前,这一领域的研究仍处于早期阶段,现有的研究主要集中在特定类型的光催化剂或制造过程的特定方面。因此,系统检查了可用的煤基和煤渣基光催化材料,并根据其组成和尺寸/结构特征将其分为六种类型。介绍了各种类型的光催化材料,以及常见的制造和表征技术。详细讨论了代表性作品,以突出不同类型的煤基和煤渣基光催化材料的独特特性。此外,总结了这些材料在环境保护和污染治理中的应用前景,同时也解决了这一研究领域的挑战和前景。这篇综述全面概述了煤和煤废料中光催化材料的基本知识和最新进展,目的是促进下一代光催化剂的发展,并为传统煤炭行业的转型做出贡献。
    Fossil fuels, especially coal, have played a pivotal role in driving technological and economic advancements over the past century, though accompanied by numerous environmental challenges. Rapid progress in green and sustainable energy sources, including tidal, wind, and solar energy, coupled with growing environmental concerns, the conventional coal industry is experiencing a sustained decline in both size and financial viability. This situation necessitates the urgent adoption of advanced approaches to coal utilization. Beyond serving as an energy source, coal and its by-products, known as coal waste, can serve as valuable resources for the development of advanced materials, including photocatalysts. The advancement of photocatalytic materials derived from coal and coal waste can capitalize on these natural carbon and mineral sources, providing a viable solution to numerous environmental challenges. Currently, research in this domain remains in its early stages, with existing studies primarily focusing on specific types of photocatalysts or particular aspects of the fabrication process. Therefore, available coal-based and coal waste-based photocatalytic materials were systematically examined and categorized into six types according to their composition and dimensional/structural characteristics. Each type of photocatalytic material was introduced, along with common fabrication and characterization technologies. Representative works were discussed in detail to highlight the unique features of different types of coal-based and coal waste-based photocatalytic materials. Furthermore, the promising applications of these materials in environmental protection and pollution treatment were summarized, while also addressing the challenges and prospects in this research field. This review comprehensively overviews the fundamental knowledge and recent advancements in photocatalytic materials derived from coal and coal waste, with the goal of catalyzing the development of next generation photocatalysts and contributing to the transformation of the conventional coal industry.
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  • 文章类型: Journal Article
    这项研究的目的是评估铜(Cu)和锌(Zn)的迁移率及其对膨润土性能和未冻结水含量的影响。该领域的有限研究需要进一步分析以防止金属相互作用对膨润土有效性的负面影响。测试涉及具有Zn或Cu离子交换的美国(SWy-3,Stx-1b)和斯洛伐克(BSvk)膨润土样品。使用社区参考局(BCR)方法进行顺序提取。通过电感耦合等离子体发射光谱法(ICP-OES)分析元素含量。使用核磁共振(1H-NMR)和差示扫描量热法(DSC)测量未冷冻水含量。结果表明,主要阳离子(Zn或Cu)对离子迁移率有显着影响,有毒金属浓度增加了迁移率,降低了残留分数。移动Zn分数随着粒径的增加而增加,较低的粘土含量,和较短的平面间距,而铜则相反。锌可能积聚在较大的粘土孔隙中,而Cu固定在膨润土络合物中。Zn或Cu离子的稳定性随粘土含量或比表面积的增加而增加。在未污染的膨润土中,残留的Zn或Cu含量最高,未冻结水含量较高,表明在零度以下的温度下可能形成浓缩溶液,对粘土-水环境构成威胁,尤其是在寒冷地区。
    The aim of this study was to evaluate the mobility of copper (Cu) and zinc (Zn) and their impact on the properties of bentonites and unfrozen water content. Limited research in this area necessitates further analysis to prevent the negative effects of metal interactions on bentonite effectiveness. Tests involved American (SWy-3, Stx-1b) and Slovak (BSvk) bentonite samples with Zn or Cu ion exchange. Sequential extraction was performed using the Community Bureau of Reference (BCR) method. Elemental content was analyzed via inductively coupled plasma optical emission spectrometry (ICP-OES). Unfrozen water content was measured using nuclear magnetic resonance (1H-NMR) and differential scanning calorimetry (DSC). Results showed a significant influence of the main cation (Zn or Cu) on ion mobility, with toxic metal concentrations increasing mobility and decreasing residual fractions. Mobile Zn fractions increased with larger particle diameters, lower clay content, and shorter interplanar spacing, while the opposite was observed for Cu. Zn likely accumulated in larger clay pores, while Cu was immobilized in the bentonite complex. The stability of Zn or Cu ions increased with higher clay content or specific surface area. Residual Zn or Cu fractions were highest in uncontaminated bentonites with higher unfrozen water content, suggesting the potential formation of concentrated solutions in sub-zero temperatures, posing a threat to the clay-water environment, especially in cold regions.
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  • 文章类型: Journal Article
    近年来,植物性饮料的趋势继续快速增长。本研究旨在评估社会人口统计学特征和植物性饮料知识的影响。主观规范,感知价格,环境保护,动物福利,可用性,以及对这些产品的态度和购买行为的信任。这项研究是通过考虑文献编写的两部分问卷在线进行的。这项研究包括935名参与者,我们的研究结果证实,环境保护的变量会影响对这些产品的态度(β=0.095;p=0.007)。此外,性别,收入水平,乳糖不耐受,牛奶或羊奶引起的腹胀影响了实际购买行为(p<0.05;p<0.001)。这些发现表明,人们的环保意识的提高将对植物性饮料的态度产生积极影响,并且没有因牛奶或山羊奶而经历乳糖不耐受和腹胀的个体将具有较低的实际购买行为。还确定,收入较低的人购买了更多的植物性饮料。总之,植物性饮料营销人员在规划营销策略时需要考虑个人的社会人口特征和环保意识。
    In recent years, the trend toward plant-based beverages has continued to grow rapidly. This study aimed to assess the effects of sociodemographic characteristics and knowledge about plant-based beverages, subjective norms, perceived price, environmental protection, animal welfare, availability, and trust on attitudes and buying behavior toward these products. This study was conducted online using a two-part questionnaire prepared by considering the literature. This study included 935 participants, and our findings confirmed that the variable of environmental protection affects the attitude toward these products (β= 0.095; p = 0.007). Furthermore, gender, income level, lactose intolerance, and bloating due to cow\'s or sheep\'s milk influenced actual buying behavior (p < 0.05; p < 0.001). These findings indicate that people\'s increased environmental protection awareness will positively influence attitudes towards plant-based beverages and that individuals who do not experience lactose intolerance and bloating due to cow\'s or goat\'s milk will have lower actual buying behavior. It was also determined that individuals with lower incomes bought more plant-based beverages. In conclusion, plant-based beverage marketers need to take into account individuals\' sociodemographic characteristics and environmental protection awareness when planning their marketing strategies.
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  • 文章类型: Journal Article
    双子型咪唑啉季铵盐是一种新型的环保型缓蚀剂,在工程材料中得到了广泛的应用。然而,其中大多数是源自石油基产品的有害/有毒化合物,对环境有害。在这项工作中,以二聚酸工业回收的廉价脂肪酸为原料,合成了一种环境友好的双子型咪唑啉季铵盐缓蚀剂(G211)。通过失重实验研究了G211在1MHCl溶液中对Q235钢的缓蚀作用,电位极化曲线,和交流阻抗谱实验。结果表明,G211作为混合型抑制剂在25℃时的抑制率高达94.4%,浓度下降低至500ppm。G211在Q235表面的吸附符合Langmuir吸附等温曲线。通过扫描电子显微镜(SEM)和X射线光电子能谱(XPS)分析了Q235钢表面的化学成分。此外,提出了G211对Q235钢表面可能的缓蚀机理。本文不仅提出了保护Q235钢免受腐蚀的出色解决方案,而且还介绍了一种高价值利用单体酸(MA)的可行方法。
    Gemini-type imidazoline quaternary ammonium salt is a new type of environmentally friendly corrosion inhibitor has been widely used in engineering materials. However, most of them are hazardous/toxic compounds derived from petroleum-based products, which did harm to environment. In this work, an environmentally friendly Gemini-shaped imidazoline quaternary ammonium salt corrosion inhibitor (G211) was synthesized using cheap fatty acid recycled from dimer acid industry as feedstock. The corrosion inhibition effects of G211 on Q235 steel in 1 M HCl solution were investigated through weight loss experiments, potential polarization curves, and alternating current impedance spectroscopy experiments. The results show that the inhibition rate of G211 as a mixed-type inhibitor is up to 94.4% and the concentration drop as low as 500 ppm at 25 ℃. The adsorption of G211 on Q235 surface follows Langmuir adsorption isothermal curve. The chemical composition of the Q235 steel surface was analyzed through scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Furthermore, the possible corrosion inhibition mechanism of G211 on the surface of Q235 steel is proposed. This article not only presents an outstanding solution for safeguarding Q235 steel against corrosion but also introduces a feasible method for high-value utilization of monomer acid (MA).
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