The goal of taking out As(III) from water is to reduce the detriment that poisonous metals can do to people and nature. A substance that can absorb As(III), TFPOTDB-SO3H, was made by combining 2,5-diaminobenzenesulfonic acid and 2,4,6-tris-(4-formylphenoxy)-1,3,5-triazine in a reaction that joins molecules together. This substance can adsorb As(III) very well and has excellent qualities like being easy to use again, separate substances, and filter out liquids. At pH = 8 and at room temperature, TFPOTDB-SO3H adsorbed a lot of As(III). It achieved a removal rate of 97.1 % within 10 min and could adsorb up to 344.8 mg/g. A research was conducted to investigate the effect of co-existing anions on the elimination of arsenic. The findings indicated that the presence of anions had a minimal adverse impact, reducing As(III) uptake by approximately 1-7 %. The kinetics of the uptake process were found to be controlled by the quasi-second order kinetic model, while the Langmuir isotherm model validated that the mechanism for As(III) removal was monolayer chemisorption. According to the thermodynamic analysis, the adsorption process was endothermic and occurred spontaneously. Moreover, even after 4 successive adsorption-desorption cycles, the adsorbent preserved a substantial uptake productivity of 88.86 % for As(III). The results collectively indicate that TFPOTDB-SO3H holds considerable promise for the efficient adsorption and elimination of As(III) ions from wastewater.

Rice can accumulate more organic and inorganic arsenic (iAs) than other crop plants. In this study, the localization of As in rice grains was investigated using High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry (HPLC-ICP-MS) based on 26 rice varieties collected from two provinces. In all the samples, the total As contents in polished rice were 0.03-0.37 mg/kg, with average values of 0.28 and 0.21 mg/kg for two sample sets. The results of the determination of arsenic speciation in different components of rice grain showed that in the polished and brown rice the mean value of arsenite (As(III)) was nearly twice than that of arsenate (As(V)). The regional difference was observed in both total As contents and As speciation. The reason may be that As(III) is more mobile than As(V) in a dissociated form and because of soil properties, rice varieties, and the growing environment. The proportion of iAs and the total As in rice bran was higher than that in polished rice, and this is because As tends accumulate between the husk and the endosperm. In our study, selenium could alleviate the risk of arsenic toxicity at the primary stage of rice growth. Co-exposure to As and Se in germinated rice indicated that the reduction in As accumulation in polished rice reached 73.8%, 76.8%, and 78.3% for total As, As(III), and As(V) when compared with rice treated with As alone. The addition of Se (0.3 mg/kg) along with As significantly reduced the As amount in different parts of germinated rice. Our results indicated that Se biofortification could alleviate the As accumulation and toxicity in rice crops.

Although the removal ability of potassium ferrate (K2FeO4) on aqueous heavy metals has been confirmed by many researchers, little information focuses on the difference between the individual and simultaneous treatment of elements from the same family of the periodic table. In this project, two heavy metals, arsenic (As) and antimony (Sb) were chosen as the target pollutants to investigate the removal ability of K2FeO4 and the influence of humic acid (HA) in simulated water and spiked lake water samples. The results showed that the removal efficiencies of both pollutants gradually increased along the Fe/As or Sb mass ratios. The maximum removal rate of As(III) reached 99.5% at a pH of 5.6 and a Fe/As mass ratio of 4.6 when the initial As(III) concentration was 0.5 mg/L; while the maximum was 99.61% for Sb(III) at a pH of 4.5 and Fe/Sb of 22.6 when the initial Sb(III) concentration was 0.5 mg/L. It was found that HA inhibited the removal of individual As or Sb slightly and the removal efficiency of Sb was significantly higher than that of As with or without the addition of K2FeO4. For the co-existence system of As and Sb, the removal of As was improved sharply after the addition of K2FeO4, higher than Sb; while the latter was slightly better than that of As without K2FeO4, probably due to the stronger complexing ability of HA and Sb. X-ray energy dispersive spectroscopy (EDS), X-ray diffractometer (XRD), and X-ray photoelectron spectroscopy (XPS) were used to characterize the precipitated products to reveal the potential removal mechanisms based on the experimental results.

Magnetic nanocomposites have received immense interest as adsorbents for water decontamination. This paper presents adsorptive properties of nitrogen-doped graphene oxide (N-GO) with magnesium ferrite (MgFe2O4) magnetic nanocomposite for removing lead(II) (Pb(II)and arsenite As(III) ions. Transmission electron microscope (TEM) image of synthesized nanocomposite revealed the wrinkled sheets of N-GO containing MgFe2O4 nanoparticles (NPs) with particle size of 5-15 nm distributed over its surface. This nanocomposite displayed higher BET surface area (72.2 m2g-1) than that of pristine MgFe2O4 NPs (38.4 m2g-1). Adsorption on the nanocomposite could be described by the Langmuir isotherm with the maximum adsorption capacities were 930 mg/g, and 64.1 mg/g for Pb(II) and As(III), respectively. Whereas, maximum removal efficiencies were observed to be 99.7 [Formula: see text] 0.2% and 93.5 [Formula: see text] 0.1% for Pb(II) and As(III), respectively. The study on the effect of coexisting anions on the adsorption of metal ions showed that the phosphate ions were potential competitors of Pb(II) and As(III) ions to adsorb on the nanocomposite. Significantly, the investigation on adsorption of metal ion in the presence of coexisting heavy metal ions indicated the preferential adsorption of Pb(II) ions as compared to Cd(II), Zn(II) and Ni(II) ions. The effectiveness of the nanocomposite to remove the metal ions in electroplating wastewater was demonstrated.

A portable and simple method was developed for on-site selective determination of As(III) based on the SERS signal of As(III)-O vibration. The method relies on the synergistic effect of nanoparticles aggregation and analyte adsorption. Experimental results demonstrated that phosphate replaced the ligands of HH@Ag NPs, which in turn facilitated the adsorption of As(III) on the surface of HH@Ag NPs. The phosphate was introduced as an agglomerating agent to improve the detection ability of the method for As(III). The method shows good selectivity and linear relationship between 5 × 10-8 and 0.8 × 10-6 M, with the detection limit of 1.8 × 10-9 M. The method was applied to actual water samples and successfully detected As(III), indicating that the method could have application potential in actual detection scenarios.

This study demonstrated that As(III) was appreciably removed by ferrate in the presence of straw biochar. Removal efficiency of As in ferrate/biochar system was over 91%, increased by 34% compared with ferrate alone ([biochar]0 = 10 mg/L, [ferrate]0 = 6 mg/L, [As(III)]0 = 200 μg/L). In the reaction process, As(III) was oxidized to As(V) mainly by ferrate, while ferrate was reduced into ferric (hydr)oxides and coated on the biochar. Biochar was oxidized in the reaction and its surface area, pore volume and the amount of Lewis acid functional groups were substantially improved, which provided interaction sites for As adsorption. Analysis of hydrodynamic diameter and zeta potential revealed that biochar interacted with the ferrate resulted ferric oxides and enlarged the Fe-C-As particle/floc, which promoted their settlement and thus the liquid-solid separation of As. As(V) was adsorbed on the surface of biochar and ferric (hydr)oxides through hydrogen bond, electrostatic attraction and As-(OFe) bond. Ferrate/biochar was not only effective for As removal, but removed 73.31% of As, 50.38% of Cd, and 75.27% of Tl when these hazardous species synchronously existed in polluted water (initial content: As, 100 μg/L; Cd, 50 μg/L; Tl, 1 μg/L). The combination of ferrate with biochar has potential for the remediation of hazardous species polluted water.

Fe-Mn binary oxide has received increasing interest in treating As(III)-containing polluted groundwater due to its low cost and environmental friendliness. Although the stability of Fe-Mn binary oxide is as important as its adsorption ability, little is known about whether and why Fe-Mn binary oxide is stable during As(III) removal. In this study, five successive cycles were conducted to evaluate the stability of Fe-Mn binary oxide for As(III) removal. As(III) oxidation/adsorption kinetics and the speciation distribution of the released Fe and Mn elements within single Fe oxide, Mn oxide, and Fe-Mn binary oxide were investigated by using characterization techniques of TEM-EDS mapping, selected area electron diffraction (SAED), and XPS combined with a binary component reactor, where Fe and Mn oxides were separated by a semipermeable membrane. The results revealed that Fe-Mn binary oxide could maintain excellent stability, although As(III) oxidation/adsorption behavior was coupled with the release of Fe and Mn ions from its surface. The great stability of Fe-Mn binary oxide for As(III) removal was attributed to the rapid return of aqueous Fe(II) and Mn(II) to the solid surface, which subsequently formed new mineral phases mediated by Fe and Mn oxides, thus considerably decreasing the loss of released Mn(II) and Fe(II).

As an important source of arsenic (As) pollution in mine drainage, arsenopyrite undergoes redox and adsorption reactions with dissolved As, which further affects the fate of As in natural waters. This study investigated the interactions between dissolved As(III) and arsenopyrite and the factors influencing the geochemical behavior of As, including initial As(III) concentration, dissolved oxygen and pH. The hydrogen peroxide (H2O2) and hydroxyl radical (OH•) generated from the interaction between Fe(II) on arsenopyrite surface and oxygen were found to facilitate the rapid oxidation of As(III), and the production of As(V) in the reaction system increased with increasing initial As(III) concentration. An increase of pH from 3.0 to 7.0 led to a gradual decrease in the oxidation rate of As(III). At pH 3.0, the presence of As(III) accelerated the oxidation rate of arsenopyrite; while at pH 5.0 and 7.0, As(III) inhibited the oxidative dissolution of arsenopyrite. This work reveals the potential environmental process of the interaction between dissolved As(III) and arsenopyrite, and provides important implications for the prevention and control of As(III) pollution in mine drainage.

Sulfate (SO4•-) and hydroxyl-based (HO•) radical are considered potential agents for As(III) removal from aquatic environments. We have reported the synergistic role of SO4•- and HO• radicals for As(III) removal via facile synthesis of biochar-supported SO4•- species. MoS2-modified biochar (MoS2/BC), iron oxide-biochar (FeOx@BC), and MoS2-modified iron oxide-biochar (MoS2/FeOx@BC) were prepared and systematically characterized to understand the underlying mechanism for arsenic removal. The MoS2/FeOx@BC displayed much higher As(III) adsorption (27 mg/g) compared to MoS2/BC (7 mg/g) and FeOx@BC (12 mg/g). Effects of kinetics, As(III) concentration, temperature, and pH were also investigated. The adsorption of As(III) by MoS2/FeOx@BC followed the Freundlich adsorption isotherm and pseudo-second-order, indicating multilayer adsorption and chemisorption, respectively. The FTIR and XPS analysis confirmed the presence of Fe-O bonds and SO4 groups in the MoS2/FeOx@BC. Electron paramagnetic resonance (EPR) and radical quenching experiments have shown the generation of SO4•- radicals as predominant species in the presence of MoS2 and FeOx in MoS2/FeOx@BC via radical transfer from HO• to SO42-. The HO• and SO4•- radicals synergistically contributed to enhanced As(III) removal. It is envisaged that As(III) initially adsorbed through electrostatic interactions and partially undergoes oxidation, which is finally adsorbed to MoS2/FeOx@BC after being oxidized to As(V). The MoS2/FeOx@BC system could be considered a novel material for effective removal of As(III) from aqueous environments owing to its cost-effective synthesis and easy scalability for actual applications.

Arsenite contaminated water is one of severe global environmental problems. It is challenging to treat As(III) pollution by a one-step technology. In this study, we developed a Fe(III)/CaO2 Fenton-like technology for the treatment of As(III). The simultaneous oxidation of arsenite and removal of arsenic were achieved with efficiencies of nearly 100% and 95.8% respectively, which outperforms conventional technologies. It worked well in pH 3 to 9, and in the presence of cationic heavy metals, anions and humic acid. Moreover, the PO43- inhibited the removal of As(III). •OH and 1O2 played the important roles in the oxidation of As(III). The Ca(II) derived from CaO2 made a significant contribution to the oxidation and removal of As(III). The SEM and XPS studies confirmed that the formation of Ca-Fe nascent colloid caused the effective removal of arsenic. Our study demonstrates that the one-step Fe(III)/CaO2 technology has a great potential for purification of the As(III)-contaminated water.