Water Purification

水净化
  • 文章类型: Journal Article
    许多水传播疾病与病毒有关,而全球范围内的COVID-19将水中病毒安全的担忧提升到了公众的视野。与其他常规水处理工艺相比,膜技术可以用更少的化学品实现令人满意的病毒去除,并最大限度地防止病毒的爆发。研究人员开发了新的改性方法来改善膜性能。这篇综述集中在提高病毒去除性能的膜修饰上。简要概述了病毒的特性及其通过膜过滤的去除,通过不同的病毒去除机制,系统地讨论了膜修饰,包括尺寸排除,亲水和疏水相互作用,电子相互作用,和失活。根据其性质,总结了用于膜改性的先进功能材料。此外,建议主要根据其孔径等级,通过不同的机制增强膜。当前的评论提供了有关膜修饰以增强病毒去除和实际应用途径的理论支持。
    Many waterborne diseases are related with viruses, and COVID-19 worldwide has raised the concern of virus security in water into the public horizon. Compared to other conventional water treatment processes, membrane technology can achieve satisfactory virus removal with fewer chemicals, and prevent the outbreaks of viruses to a maximal extent. Researchers developed new modification methods to improve membrane performance. This review focused on the membrane modifications that enhance the performance in virus removal. The characteristics of viruses and their removal by membrane filtration were briefly generalized, and membrane modifications were systematically discussed through different virus removal mechanisms, including size exclusion, hydrophilic and hydrophobic interactions, electronic interactions, and inactivation. Advanced functional materials for membrane modification were summarized based on their nature. Furthermore, it is suggested that membranes should be enhanced through different mechanisms mainly based on their ranks of pore size. The current review provided theoretical support regarding membrane modifications in the enhancement of virus removal and avenues for practical application.
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  • 文章类型: Journal Article
    环境污染构成了严峻的全球挑战,传统的废水处理方法往往不足以解决这一问题的复杂性和规模。另一方面,微藻表现出不同的代谢能力,使它们能够修复各种污染物,包括重金属,有机污染物,和多余的营养。通过利用微藻独特的代谢途径,可以开发创新策略来有效地修复污染环境。因此,这篇综述论文强调了微藻介导的生物修复作为传统方法的可持续且具有成本效益的替代方法的潜力。它还突出了利用微藻和藻类-细菌共培养物进行大规模生物修复应用的优势,展示了令人印象深刻的生物质生产率和提高的污染物去除效率。强调了微藻介导的生物修复的有前途的潜力,在应对环境污染的全球挑战方面,为传统处理方法提供了可行和创新的替代方案。这篇综述确定了基于微藻的技术的机遇和挑战,并为未来的研究提出了应对挑战的建议。这篇综述的发现促进了我们对基于微藻的技术废水处理潜力的理解。
    Environmental pollution poses a critical global challenge, and traditional wastewater treatment methods often prove inadequate in addressing the complexity and scale of this issue. On the other hand, microalgae exhibit diverse metabolic capabilities that enable them to remediate a wide range of pollutants, including heavy metals, organic contaminants, and excess nutrients. By leveraging the unique metabolic pathways of microalgae, innovative strategies can be developed to effectively remediate polluted environments. Therefore, this review paper highlights the potential of microalgae-mediated bioremediation as a sustainable and cost-effective alternative to conventional methods. It also highlights the advantages of utilizing microalgae and algae-bacteria co-cultures for large-scale bioremediation applications, demonstrating impressive biomass production rates and enhanced pollutant removal efficiency. The promising potential of microalgae-mediated bioremediation is emphasized, presenting a viable and innovative alternative to traditional treatment methods in addressing the global challenge of environmental pollution. This review identifies the opportunities and challenges for microalgae-based technology and proposed suggestions for future studies to tackle challenges. The findings of this review advance our understanding of the potential of microalgae-based technology wastewater treatment.
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  • 文章类型: Journal Article
    在低收入和中等收入国家(LMICs),腹泻病对5岁以下儿童的影响不成比例。引起腹泻的病原体通常通过粪便污染的饮用水传播。在过去的十年中,救生杆家庭使用的水过滤器一直是干预研究的主题,并且是世界卫生组织在其水处理评估计划中评估的第一个过滤器,以提供针对许多引起腹泻的病原体的全面保护。这项系统评价旨在:1)报告与物理环境和实施有关的方面,以及2)根据随访≥12个月的研究,对救生筏家庭过滤器对儿童腹泻的有效性进行更新的荟萃分析。
    我们在2022年11月使用MEDLINE进行了文献检索,Embase,科克伦,和CINAHL数据库。纳入标准为:1)随机对照试验,群集RCT,准实验,或针对2)LifetrawFamily1.0或2.0过滤器的匹配队列研究3)在LMICs中进行的4)评估了对<5和5)儿童腹泻的过滤器有效性的评估,分析了≥12个月的腹泻临床有效性的随访数据,分别为6)从2010年开始发表,并提供7)英文全文。使用改良的纽卡斯尔-渥太华量表评估偏倚风险。提取相对风险(RR)和95%置信区间(CIs)并使用随机效应荟萃分析进行分析。
    我们纳入了6项LMIC研究,涉及4740名儿童<5。在四种临床有效的干预措施中,共同特征是获得改善的水源(75%),2.0版本的过滤器或1.0版本的额外储水(100%),使用行为改变理论,社区参与,和健康信息(75%),局部过滤器维修和更换机制(75%),和受过专门训练的当地干预人员(100%)。荟萃分析显示干预组腹泻风险降低30%(RR=0.69;95%CI=0.52-0.91,P=0.01)。
    生活稻草家庭滤水器可以有效干预措施,以减少至少一年的弱势儿科人群的腹泻,尽管与物理环境和实施有关的某些方面可能会增加其对公共卫生的影响。这项研究的结果表明,在实现普遍获得安全饮用水之前,可以在需要长期临时解决方案的环境中应用扩大规模的考虑因素。
    UNASSIGNED: Diarrhoeal disease disproportionately affects children <5 years in low- and middle-income countries (LMICs). The pathogens responsible for diarrhoea are commonly transmitted through faecally-contaminated drinking water. Lifestraw Family point-of-use water filters have been the subject of intervention studies for over a decade and were the first filters evaluated by the World Health Organization in its water treatment evaluation scheme to provide comprehensive protection against many diarrhoea-causing pathogens. This systematic review aimed to: 1) report on aspects related to physical environment and implementation and 2) conduct an updated meta-analysis on Lifestraw Family filter effectiveness against childhood diarrhoea based on studies with ≥12 months of follow-up.
    UNASSIGNED: We conducted a literature search in November 2022 using MEDLINE, Embase, Cochrane, and CINAHL databases. Inclusion criteria were: 1) RCTs, cluster-RCTs, quasi-experimental, or matched cohort studies on 2) Lifestraw Family 1.0 or 2.0 filters 3) conducted in LMICs 4) that evaluated filter effectiveness against diarrhoea in children <5 and 5) analysed ≥12 months of follow-up data on clinical effectiveness against diarrhoea and were 6) published from 2010 with 7) full-text availability in English. A modified Newcastle-Ottawa Scale was used to assess risk of bias. Relative risk (RR) and 95% confidence intervals (CIs) were extracted and analysed using a random-effects meta-analysis.
    UNASSIGNED: We included 6 studies in LMICs involving 4740 children <5. Of the four clinically-effective interventions, common characteristics were access to improved water sources (75%), the 2.0 version of the filter or the 1.0 version with additional water storage (100%), use of behaviour change theory, community engagement, and health messaging (75%), local filter repair-and-replace mechanisms (75%), and specially-trained local interventionists (100%). The meta-analysis showed a 30% reduction in diarrhoea risk in the intervention group (RR = 0.69; 95% CI = 0.52-0.91, P = 0.01).
    UNASSIGNED: Lifestraw Family water filters can be effective interventions to reduce diarrhoea in vulnerable paediatric populations for at least one year, though certain aspects related to physical environment and implementation may increase their public health impact. The findings of this study suggest considerations for scale-up that can be applied in settings in need of longer-term interim solutions until universal access to safe drinking water is achieved.
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  • 文章类型: Journal Article
    多氟烷基和全氟烷基(PFAS)的流行是一个重大挑战,和各种处理技术已经取得了相当大的成功,以消除水中的PFAS,最终目标是确保废水的安全处理。本文首先介绍了最有前途的电化学氧化(EO)技术,然后分析了其基本原理。此外,本文回顾和讨论了电极材料和电化学反应器领域的研究和发展现状。此外,还研究了电极材料和电解质类型对劣化过程的影响。电极材料在环氧乙烷中的重要性已得到广泛认可,因此,当前研究的重点主要是创新电极材料的开发,优越的电极结构设计,以及高效电极制备方法的改进。为了提高电化学系统中全氟辛烷磺酸的降解效率,研究全氟辛烷磺酸在环氧乙烷存在下的氧化机理至关重要。此外,影响PFAS治疗疗效的因素,包括电流密度,能源消耗,初始浓度,和其他参数,清楚地描绘了。总之,这项研究全面概述了将EO技术与其他水处理技术相结合的潜力。电极材料的不断发展和其他水处理工艺的集成为环氧乙烷技术的广泛应用提出了有希望的未来。
    The prevalence of polyfluoroalkyls and perfluoroalkyls (PFAS) represents a significant challenge, and various treatment techniques have been employed with considerable success to eliminate PFAS from water, with the ultimate goal of ensuring safe disposal of wastewater. This paper first describes the most promising electrochemical oxidation (EO) technology and then analyses its basic principles. In addition, this paper reviews and discusses the current state of research and development in the field of electrode materials and electrochemical reactors. Furthermore, the influence of electrode materials and electrolyte types on the deterioration process is also investigated. The importance of electrode materials in ethylene oxide has been widely recognised, and therefore, the focus of current research is mainly on the development of innovative electrode materials, the design of superior electrode structures, and the improvement of efficient electrode preparation methods. In order to improve the degradation efficiency of PFOS in electrochemical systems, it is essential to study the oxidation mechanism of PFOS in the presence of ethylene oxide. Furthermore, the factors influencing the efficacy of PFAS treatment, including current density, energy consumption, initial concentration, and other parameters, are clearly delineated. In conclusion, this study offers a comprehensive overview of the potential for integrating EO technology with other water treatment technologies. The continuous development of electrode materials and the integration of other water treatment processes present a promising future for the widespread application of ethylene oxide technology.
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  • 文章类型: Journal Article
    重金属在整个生态系统中的扩散已经极大地危害了人类的健康,动物,植物,和自然资源。水煤浆已成为一种有前途的吸附剂,用于从水和废水中去除重金属。水煤浆,从生物质的水热碳化中获得,拥有独特的物理和化学性质,在通过表面络合捕获重金属方面非常有效,静电相互作用,和离子交换机制。本文综述了水炭吸附剂从水体中去除重金属的研究进展。本文讨论了影响水炭吸附能力的因素,如接触时间,pH值,初始金属浓度,温度,和竞争离子。关于表面改性等优化方法的文献,复合材料开发,并对混合系统进行了审查,以启发实现从废水中去除重金属的水炭效率的机制。该评论还解决了水煤焦再生和可重复使用等挑战,以及与其处置和金属浸出相关的潜在问题。还概述了与当前水净化方法的整合以及正在进行的研究和促进基于水炭的技术的举措的重要性。本文得出的结论是,将水炭与纳米技术和高级氧化技术等现代技术相结合,有望改善重金属修复。总的来说,这种全面的分析为指导未来的研究和促进有效的发展提供了宝贵的见解,负担得起的,和环保的重金属去除技术,以确保全球社区获得更安全的饮用水。
    The spread of heavy metals throughout the ecosystem has extremely endangered human health, animals, plants, and natural resources. Hydrochar has emerged as a promising adsorbent for removal of heavy metals from water and wastewater. Hydrochar, obtained from hydrothermal carbonization of biomass, owns unique physical and chemical properties that are highly potent in capturing heavy metals via surface complexation, electrostatic interactions, and ion exchange mechanisms. This review focuses on removing heavy metals by hydrochar adsorbents from water bodies. The article discusses factors affecting the adsorption capacity of hydrochars, such as contact time, pH, initial metal concentration, temperature, and competing ions. Literature on optimization approaches such as surface modification, composite development, and hybrid systems are reviewed to enlighten mechanisms undertaking the efficiency of hydrochars in heavy metals removal from wastewater. The review also addresses challenges such as hydrochar regeneration and reusability, alongside potential issues related to its disposal and metal leaching. Integration with current water purification methods and the significance of ongoing research and initiatives promoting hydrochar-based technologies were also outlined. The article concludes that combining hydrochar with modern technologies such as nanotechnology and advanced oxidation techniques holds promise for improving heavy metal remediation. Overall, this comprehensive analysis provides valuable insights to guide future studies and foster the development of effective, affordable, and environmentally friendly heavy metal removal technologies to ensure the attainment of safer drinking water for communities worldwide.
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  • 文章类型: Journal Article
    地下水砷中毒是地球上最严重的环境危害之一。因此,对水中砷的实际和适当处理需要更多的关注,以确保安全的饮用水。世界卫生组织(WHO)制定了饮用水中10μg/L砷的准则,直接长期暴露于超过该值的饮用水中的砷会对个人造成严重的健康危害。大量研究证实了长期消耗砷污染水后砷的不利影响。这里,强调了从水中修复砷的技术,以了解对处理As(III)污染水的单点解决方案的需求。由于(III)物种在中性pH下是中性的;该溶液需要转化技术才能完全去除。在这次重要的审查中,重点放在具有多种功能的单步技术上,以从水中修复砷。
    Arsenic poisoning of groundwater is one of the most critical environmental hazards on Earth. Therefore, the practical and proper treatment of arsenic in water requires more attention to ensure safe drinking water. The World Health Organization (WHO) sets guidelines for 10 μg/L of arsenic in drinking water, and direct long-term exposure to arsenic in drinking water beyond this value causes severe health hazards to individuals. Numerous studies have confirmed the adverse effects of arsenic after long-term consumption of arsenic-contaminated water. Here, technologies for the remediation of arsenic from water are highlighted for the purpose of understanding the need for a single-point solution for the treatment of As(III)-contaminated water. As(III) species are neutral at neutral pH; the solution requires transformation technology for its complete removal. In this critical review, emphasis was placed on single-step technologies with multiple functions to remediate arsenic from water.
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  • 文章类型: Journal Article
    有机磷酸酯(OPEs)是广泛使用的商业添加剂,但是它们的环境持久性和毒性引起了人们的严重关注,需要相关的修复策略。尽管有各种现有的OPE去除技术,迫切需要对它们进行全面筛查,以指导进一步的研究。这篇综述全面概述了用于从土壤和水中去除OPEs的技术,包括它们的相关影响因素,去除机制/降解途径,和实际应用。在对最新文献进行分析的基础上,我们得出的结论是(1)用于净化OPEs的方法包括吸附,水解,光解,高级氧化工艺(AOPs),活性污泥法,和微生物降解;(2)催化剂/添加剂的数量/特性等因素,pH值,无机离子浓度,和天然有机物(NOM)影响OPE的去除;(3)主要降解机制涉及活性氧(ROS)(包括•OH和SO4•-)诱导的氧化,降解途径包括水解,羟基化,氧化,脱氯,脱烷基化;(5)pH值的干扰,无机离子和NOM的存在可能会限制处理过程中的完全矿化,影响OPE去除技术的实际应用。这篇综述为现有和潜在的OPE去除方法提供了指导,为开发更有效,更环保的技术来处理土壤和水中的OPEs提供了理论基础和创新思路。
    Organophosphate esters (OPEs) are widely used commercial additives, but their environmental persistence and toxicity raise serious concerns necessitating associated remediation strategies. Although there are various existing technologies for OPE removal, comprehensive screening for them is urgently needed to guide further research. This review provides a comprehensive overview of the techniques used to remove OPEs from soil and water, including their related influencing factors, removal mechanisms/degradation pathways, and practical applications. Based on an analysis of the latest literature, we concluded that (1) methods used to decontaminate OPEs include adsorption, hydrolysis, photolysis, advanced oxidation processes (AOPs), activated sludge processes, and microbial degradation; (2) factors such as the quantity/characteristics of the catalysts/additives, pH value, inorganic ion concentration, and natural organic matter (NOM) affect OPE removal; (3) primary degradation mechanisms involve oxidation induced by reactive oxygen species (ROS) (including •OH and SO4•-) and degradation pathways include hydrolysis, hydroxylation, oxidation, dechlorination, and dealkylation; (5) interference from the pH value, inorganic ion and the presence of NOM may limit complete mineralization during the treatment, impacting practical application of OPE removal techniques. This review provides guidance on existing and potential OPE removal methods, providing a theoretical basis and innovative ideas for developing more efficient and environmentally friendly techniques to treat OPEs in soil and water.
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  • 文章类型: Journal Article
    由于工业和农业部门的快速发展,水污染是严重的环境问题之一,清洁水资源越来越受到重视。最近,越来越多的研究见证了催化剂(金属氧化物,金属硫化物,金属有机框架,零价金属,等。)用于废水处理和水净化。固定在壳聚糖基材料(Cat@CSbMs)中的可持续和清洁催化剂由于其高催化活性而被认为是功能材料中最吸引人的子类之一。高吸附能力,无毒性和相对稳定性。这篇综述总结了各种升级可再生Cat@CSbM(如助催化剂,光催化剂,和类似芬顿的试剂,等。).至于工程应用,Cat@CSbMs的进一步研究应集中在处理同时含有重金属和有机污染物的复杂废水上,以及使用Cat@CSbMs开发工业废水的连续流处理方法。总之,这篇评论缩小了升级可再生和清洁Cat@CSbM的不同方法及其未来应用之间的差距。这将有助于开发用于废水处理和水净化的更清洁和可持续的Cat@CSbM。
    Water pollution is one of serious environmental issues due to the rapid development of industrial and agricultural sectors, and clean water resources have been receiving increasing attention. Recently, more and more studies have witnessed significant development of catalysts (metal oxides, metal sulfides, metal-organic frameworks, zero-valent metal, etc.) for wastewater treatment and water purification. Sustainable and clean catalysts immobilized into chitosan-based materials (Cat@CSbMs) are considered one of the most appealing subclasses of functional materials due to their high catalytic activity, high adsorption capacities, non-toxicity and relative stability. This review provides a summary of various upgrading renewable Cat@CSbMs (such as cocatalyst, photocatalyst, and Fenton-like reagent, etc.). As for engineering applications, further researches of Cat@CSbMs should focus on treating complex wastewater containing both heavy metals and organic pollutants, as well as developing continuous flow treatment methods for industrial wastewater using Cat@CSbMs. In conclusion, this review abridges the gap between different approaches for upgrading renewable and clean Cat@CSbMs and their future applications. This will contribute to the development of cleaner and sustainable Cat@CSbMs for wastewater treatment and water purification.
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  • 文章类型: Journal Article
    基于膜的水处理已成为解决全球水挑战的有希望的解决方案。氧化石墨烯(GO)由于其可逆特性已成功用于膜过滤过程,大规模生产潜力,层层堆叠,很大的含氧官能团,和独特的物理化学特征,包括创建纳米通道。这篇综述评估了各种基于GO的膜的分离性能,通过用不同的支撑层(如聚合物)涂覆或界面聚合制造,金属,和陶瓷,用于内分泌干扰化合物(EDC)和药物活性化合物(PhAC)。在大多数研究中,GO的加入显著提高了去除效率,通量,孔隙度,亲水性,稳定性,机械强度,与原始膜相比,具有防污性能。污染物去除的关键机制包括尺寸排除,静电排除,和吸附。这些机制可以归因于化合物的物理化学性质,如分子大小和形状,亲水性,和充电状态。因此,了解基于化合物特性的去除机理并适当调整操作条件是膜分离的关键。未来的研究方向应探索GO衍生物与各种支持层结合的特点,通过定制不同的操作条件和化合物来有效去除EDC和PhAC。预期这将加速用于增强污染物去除的表面改性策略的发展。
    Membrane-based water treatment has emerged as a promising solution to address global water challenges. Graphene oxide (GO) has been successfully employed in membrane filtration processes owing to its reversible properties, large-scale production potential, layer-to-layer stacking, great oxygen-based functional groups, and unique physicochemical characteristics, including the creation of nano-channels. This review evaluates the separation performance of various GO-based membranes, manufactured by coating or interfacial polymerization with different support layers such as polymer, metal, and ceramic, for endocrine-disrupting compounds (EDCs) and pharmaceutically active compounds (PhACs). In most studies, the addition of GO significantly improved the removal efficiency, flux, porosity, hydrophilicity, stability, mechanical strength, and antifouling performance compared to pristine membranes. The key mechanisms involved in contaminant removal included size exclusion, electrostatic exclusion, and adsorption. These mechanisms could be ascribed to the physicochemical properties of compounds, such as molecular size and shape, hydrophilicity, and charge state. Therefore, understanding the removal mechanisms based on compound characteristics and appropriately adjusting the operational conditions are crucial keys to membrane separation. Future research directions should explore the characteristics of the combination of GO derivatives with various support layers, by tailoring diverse operating conditions and compounds for effective removal of EDCs and PhACs. This is expected to accelerate the development of surface modification strategies for enhanced contaminant removal.
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  • 文章类型: Journal Article
    制药,个人护理产品(PPCP),和内分泌干扰化合物(EDC)的使用最近持续增加,导致废水中的排放和积累增加。传统的水处理和消毒方法在有效解决这种微污染物问题方面有些受限。超声(美国),作为高级氧化过程,是基于超声波照射的原理,将水暴露在高频波中,诱导H2O热分解,同时使用产生的自由基氧化和分解溶解的污染物。这篇综述评估了过去五年对基于美国的有效降解水中EDC和PPCP的技术的研究,并评估了可能影响去除率的各种因素:溶液pH值,水的温度,背景常见离子的存在,天然有机物,作为启动子和清除剂的物种,和美国条件的变化(例如,频率,功率密度,和反应类型)。这篇综述还讨论了各种类型的碳/非碳催化剂,O3和紫外工艺结合US工艺可进一步提高EDC和PPCP的降解效率。此外,考虑了许多类型的EDC和PPCPs以及这些有机污染物的最新研究趋势。
    Pharmaceuticals, personal care products (PPCPs), and endocrine-disrupting compounds (EDCs) have seen a recent sustained increase in usage, leading to increasing discharge and accumulation in wastewater. Conventional water treatment and disinfection processes are somewhat limited in effectively addressing this micropollutant issue. Ultrasonication (US), which serves as an advanced oxidation process, is based on the principle of ultrasound irradiation, exposing water to high-frequency waves, inducing thermal decomposition of H2O while using the produced radicals to oxidize and break down dissolved contaminants. This review evaluates research over the past five years on US-based technologies for the effective degradation of EDCs and PPCPs in water and assesses various factors that can influence the removal rate: solution pH, temperature of water, presence of background common ions, natural organic matter, species that serve as promoters and scavengers, and variations in US conditions (e.g., frequency, power density, and reaction type). This review also discusses various types of carbon/non-carbon catalysts, O3 and ultraviolet processes that can further enhance the degradation efficiency of EDCs and PPCPs in combination with US processes. Furthermore, numerous types of EDCs and PPCPs and recent research trends for these organic contaminants are considered.
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