Heterogeneous iron-based catalysts have drawn increasing attention in the advanced oxidation of persulfates due to their abundance in nature, the lack of secondary pollution to the environment, and their low cost over the last a few years. In this paper, the latest progress in the research on the activation of persulfate by heterogeneous iron-based catalysts is reviewed from two aspects, in terms of synthesized catalysts (Fe0, Fe2O3, Fe3O4, FeOOH) and natural iron ore catalysts (pyrite, magnetite, hematite, siderite, goethite, ferrohydrite, ilmenite and lepidocrocite) focusing on efforts made to improve the performance of catalysts. The advantages and disadvantages of the synthesized catalysts and natural iron ore were summarized. Particular interests were paid to the activation mechanisms in the catalyst/PS/pollutant system for removal of organic pollutants. Future research challenges in the context of field application were also discussed.

The spread of heavy metals throughout the ecosystem has extremely endangered human health, animals, plants, and natural resources. Hydrochar has emerged as a promising adsorbent for removal of heavy metals from water and wastewater. Hydrochar, obtained from hydrothermal carbonization of biomass, owns unique physical and chemical properties that are highly potent in capturing heavy metals via surface complexation, electrostatic interactions, and ion exchange mechanisms. This review focuses on removing heavy metals by hydrochar adsorbents from water bodies. The article discusses factors affecting the adsorption capacity of hydrochars, such as contact time, pH, initial metal concentration, temperature, and competing ions. Literature on optimization approaches such as surface modification, composite development, and hybrid systems are reviewed to enlighten mechanisms undertaking the efficiency of hydrochars in heavy metals removal from wastewater. The review also addresses challenges such as hydrochar regeneration and reusability, alongside potential issues related to its disposal and metal leaching. Integration with current water purification methods and the significance of ongoing research and initiatives promoting hydrochar-based technologies were also outlined. The article concludes that combining hydrochar with modern technologies such as nanotechnology and advanced oxidation techniques holds promise for improving heavy metal remediation. Overall, this comprehensive analysis provides valuable insights to guide future studies and foster the development of effective, affordable, and environmentally friendly heavy metal removal technologies to ensure the attainment of safer drinking water for communities worldwide.

Biological degradation method, as an environmentally friendly, low-carbon, and clean pollution treatment technology, is widely used for the harmless disposal of oily sludge. The biodegradability of oily sludge with stable emulsification system, high oil, and water content is poor. Therefore, it is necessary to pre-treat the oily sludge to improve its biodegradability, including recover the petroleum resources and remove heavy metals and bio-toxic organic matters. This review systematically summarizes five oily sludge treatment methods and their influences on sludge biodegradability, including pyrolysis, chemical hot washing, solvent extraction, chemical oxidation, and hydrothermal. Pyrolysis at temperatures above 750 °C produces high molecular weight polycyclic aromatic hydrocarbons, chemical hot washing and chemical oxidation would cause secondary pollution, solvent extraction method could not be applied due to the high cost and high toxicity of the extractant, and the oil removal of hydrothermal method is inefficient. Additionally, the principles, advantages, and disadvantages of those treatments and the factors affecting microbial degradation were analyzed, which provide the development direction of pretreatment technology to improve the biodegradability of oily sludge.

Plastic products, despite their undeniable utility in modern life, pose significant environmental challenges, particularly when it comes to recycling. A crucial concern is the pervasive introduction of microplastics (MPs) into aquatic ecosystems, with deleterious effects on marine organisms. This review presents a detailed examination of the methodologies developed for MPs removal in water treatment systems. Initially, investigating the most common types of MPs in wastewater, subsequently presenting methodologies for their precise identification and quantification in aquatic environments. Instruments such as scanning electron microscopy, dynamic light scattering, Fourier transform infrared spectroscopy, Raman spectroscopy, surface-enhanced Raman spectroscopy, and Raman tweezers stand out as powerful tools for studying MPs. The discussion then transitions to the exploration of both existing and emergent techniques for MPs removal in wastewater treatment plants and drinking water treatment plants. This includes a description of the core mechanisms that drive these techniques, with an emphasis on the latest research developments in MPs degradation. Present MPs removal methodologies, ranging from physical separation to chemical and biological adsorption and degradation, offer varied advantages and constraints. Addressing the MPs contamination problem in its entirety remains a significant challenge. In conclusion, the review offers a succinct overview of each technique and forwards recommendations for future research, highlighting the pressing nature of this environmental dilemma.

Bimetallic nanoparticles (BMNPs) have gained considerable attention due to their remarkable catalytic properties, making them invaluable in wastewater treatment applications. One of these challenges lies in the propensity of BMNPs to aggregate due to Van der Waals interactions, which can reduce their overall performance. Additionally, retrieving exhausted NPs from the treated solution for subsequent reuse remains a significant hurdle. Moreover, the leaching of NPs into the discharged wastewater can have harmful effects on humans as well as aquatic life. To overcome these issues, various substrates have been researched to maximize the efficiency and stability of the NPs. This review paper delves into the pivotal role of various substrates in immobilizing BMNPs, providing a comprehensive analysis of their performances, advantages, and drawbacks. The substrates encompass a diverse range of materials, including organic, inorganic, organic-inorganic, beads, fibers, and membranes. Each substrate type offers unique attributes, influencing the stability, efficiency, and recyclability of BMNPs. This review paper aims to provide an up-to-date and detailed analysis and comparison of the substrates used for the immobilization of BMNPs. This work further reviews the underlying mechanisms of the composites involved in treating pollutants from wastewater and how these mechanisms are enhanced by the synergistic effects produced by the substrate and BMNPs. Furthermore, the reusability and sustainability of these composites are discussed. Also, high-performing substrates are highlighted to give direction to future research focusing on the immobilization of BMNPs in the application of wastewater treatment.

Sewage sludge, a complex mixture of contaminants and pathogenic agents, necessitates treatment or stabilization like anaerobic digestion (AD) before safe disposal. AD-derived products (solid digestate and liquid fraction) can be used as fertilizers. During AD, biogas is also produced, and used for energy purposes. All these fractions can be contaminated with various compounds, whose amount depends on the feedstocks used in AD (and their mutual proportions). This paper reviews studies on the distribution of organic contaminants across AD fractions (solid digestate, liquid fraction, and biogas), delving into the mechanisms behind contaminant dissipation and proposing future research directions. AD proves to be a relatively effective method for removing polychlorinated biphenyls, polycyclic aromatic hydrocarbons, pharmaceuticals, antibiotic resistance genes and hydrocarbons. Contaminants are predominantly removed through biodegradation, but many compounds, especially hydrophobic (e.g. per- and polyfluoroalkyl substances), are also sorbed onto digestate particles. The process of sorption is suggested to reduce the bioavailability of contaminants. As a result of sorption, contaminants accumulate in the largest amount in the solid digestate, whereas in smaller amounts in the other AD products. Polar pharmaceuticals (e.g. metformin) are particularly leached, while volatile methylsiloxanes and polycyclic aromatic hydrocarbons, characterized by a high Henry\'s law constant, are volatilized into the biogas. The removal of compounds can be affected by AD operational parameters, the type of sludge, physicochemical properties of contaminants, and the sludge pretreatment used.

In the global effort to reduce CO2 emissions, the concurrent enhancement of pollutant degradation and reductions in fossil fuel consumption are pivotal aspects of microalgae-mediated wastewater treatment. Clarifying the degradation mechanisms of bacteria and microalgae during pollutant treatment, as well as regulatory biolipid production, could enhance process sustainability. The synergistic and inhibitory relationships between microalgae and bacteria are introduced in this paper. The different stimulators that can regulate microalgal biolipid accumulation are also reviewed. Wastewater treatment technologies that utilize microalgae and bacteria in laboratories and open ponds are described to outline their application in treating heavy metal-containing wastewater, animal husbandry wastewater, pharmaceutical wastewater, and textile dye wastewater. Finally, the major requirements to scale up the cascade utilization of biomass and energy recovery are summarized to improve the development of biological wastewater treatment.

Wastewater serves as a vital resource for sustainable fertilizer production, particularly in the recovery of nitrogen (N) and phosphorus (P). This comprehensive study explores the recovery chain, from technology to final product reuse. Biomass growth is the most cost-effective method, valorizing up to 95 % of nutrients, although facing safety concerns. Various techniques enable the recovery of 100 % P and up to 99 % N, but challenges arise during the final product crystallization due to the high solubility of ammonium salts. Among these techniques, chemical precipitation and ammonia stripping/ absorption have achieved full commercialization, with estimated recovery costs of 6.0-10.0 EUR kgP-1 and 4.4-4.8 £ kgN-1, respectively. Multiple technologies integrating biomass thermo-chemical processing and P and/or N have also reached technology readiness level TRL = 9. However, due to maturing regulatory of waste-derived products, not all of their products are commercially available. The non-homogenous nature of wastewater introduces impurities into nutrient recovery products. While calcium and iron impurities may impact product bioavailability, some full-scale P recovery technologies deliver products containing this admixture. Recovered mineral nutrient forms have shown up to 60 % higher yield biomass growth compared to synthetic fertilizers. Life cycle assessment studies confirm the positive environmental outcomes of nutrient recycling from wastewater to agricultural applications. Integration of novel technologies may increase wastewater treatment costs by a few percent, but this can be offset through renewable energy utilization and the sale of recovered products. Moreover, simultaneous nutrient recovery and energy production via bio-electrochemical processes contributes to carbon neutrality achieving. Interdisciplinary cooperation is essential to offset both energy and chemicals inputs, increase their cos-efficiency and optimize technologies and understand the nutrient release patterns of wastewater-derived products on various crops. Addressing non-technological factors, such as legal and financial support, infrastructure redesign, and market-readiness, is crucial for successfully implementation and securing the global food production.

Sludge is an inevitable waste product of sewage treatment with a high water content and large volume, it poses a significant threat of secondary pollution to both water and the atmosphere without proper disposal. In this regard, dewatering has emerged as an attractive method in sludge treatment, as it can reduce the sludge volume, enhance its transportability and calorific value, and even decrease the production of landfill leachate. In recent years, physical conditioning methods including non-chemical conditioners or energy input alone, have been extensively researched for their potential to enhance sludge dewatering efficiency, such as thermal treatment, freeze-thaw, microwave, ultrasonic, skeleton builders addition, and electro-dewatering, as well as combined methods. The main objective of this paper is to comprehensively evaluate the dewatering capacity of various physical conditioning methods, and identify key factors affecting sludge dewatering efficiency. In addition, future research anticipated directions and outlooks are proposed. This work is expected to provide valuable insights for developing efficient, eco-friendly, and low-energy consumption techniques for deep sludge dewatering.

Textile and cosmetic industries generate large amounts of dye effluents requiring treatment before discharge. This wastewater contains high levels of reactive dyes, low to none-biodegradable materials and chemical residues. Technically, dye wastewater is characterised by high chemical and biological oxygen demand. Biological, physical and pressure-driven membrane processes have been extensively used in textile wastewater treatment plants. However, these technologies are characterised by process complexity and are often costly. Also, process efficiency is not achieved in cost-effective biochemical and physical treatment processes. Membrane distillation (MD) emerged as a promising technology harnessing challenges faced by pressure-driven membrane processes. To ensure high cost-effectiveness, the MD can be operated by solar energy or low-grade waste heat. Herein, the MD purification of dye wastewater is comprehensively and yet concisely discussed. This involved research advancement in MD processes towards removal of dyes from industrial effluents. Also, challenges faced by this process with a specific focus on fouling are reviewed. Current literature mainly tested MD setups in the laboratory scale suggesting a deep need of further optimization of membrane and module designs in near future, especially for textile wastewater treatment. There is a need to deliver customized high-porosity hydrophobic membrane design with the appropriate thickness and module configuration to reduce concentration and temperature polarization (CP and TP). Also, energy loss should be minimized while increasing dye rejection and permeate flux. Although laboratory experiments remain pivotal in optimizing the MD process for treating dye wastewater, the nature of their time intensity poses a challenge. Given the multitude of parameters involved in MD process optimization, artificial intelligence (AI) methodologies present a promising avenue for assistance. Thus, AI-driven algorithms have the potential to enhance overall process efficiency, cutting down on time, fine-tuning parameters, and driving cost reductions. However, achieving an optimal balance between efficiency enhancements and financial outlays is a complex process. Finally, this paper suggests a research direction for the development of effective synthetic and natural dye removal from industrially discharged wastewater.