Valorization

Valorization
  • 文章类型: Journal Article
    废弃电气和电子设备(WEEE)被定义为“城市矿山”,因为它们含有各种可回收矿物。然而,目前的WEEE分类方法大多局限于其物理特征,注重收藏,运输,和治疗目的,而不是价值化。在本研究中,我们的目标是提出一种适用于低收入国家的替代分类方法,以回收WEEE,突出其贵金属和有价金属的含量。WEEE的类型是基于瓦加杜古(布基纳法索)产生的WEEE创建的。主成分分析(PCA)和移动中心技术(K-means)用于分类方法。最终,我们发现,为了提高WEEE的回收率,它们可以分为三大类:(i)一组含WEEE的电池,(ii)一组含WEEE的贵重和贵金属,最后,(iii)一组由阴极射线管电视(CRT-TV)废料组成的WEEE。属于第二组的WEEE是可以产生更高的经济价值的WEEE。这种替代分类方法将帮助投资者和运营商更好地将其价值化活动定位为呈现最佳贵金属回收潜力的WEEE类型。最大化他们的利润。另一方面,决策者会发现这种分类对重组WEEE价值链很有用。
    Waste electrical and electronic equipment (WEEE) is defined as \"urban mines\" due to the various recoverable minerals they contain. However, current WEEE classification methods are mostly limited to their physical characteristics, focusing on collection, transport, and treatment purposes rather than on valorization. In the present study, our aim is to propose an alternative classification approach adapted for low-income countries for WEEE recovery that highlights their content of precious and valuable metals. A typology of WEEE was created based on WEEE generated in Ouagadougou (Burkina Faso). Principal component analysis (PCA) and the moving center technique (K-means) were used for the classification method. Ultimately, we have found that to improve the recovery of WEEE, they can be classified into three main groups: (i) a group of WEEE-containing batteries, (ii) a group of WEEE-containing valuable and precious metals, and finally, (iii) a group of WEEE made up of cathode ray tube televisions (CRT-TV) waste. The WEEE belonging to the second group are the ones that could generate higher economical values. This alternative classification approach will help investors and operators to better orient their valorization activities towards WEEE types that present the best precious metals recovery potential, maximizing their profits. On the other hand, decision-makers will find this classification useful for reorganizing the WEEE value chain.
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  • 文章类型: Journal Article
    为了追求可持续性,有效管理农业工业和食品加工残留物(AFR)至关重要。这项研究提出了一种通过固态发酵(SSF)将AFR转化为有价值的产品的系统方法。以真菌酶生产为例,这种适应性强的方法适合任何SSF生物过程。最初,评估了AFR的理化性质,以评估其作为SSF碳源和固体基质的可行性。然后,筛选了5个菌株产生酶的能力(木聚糖酶,X;果胶酶,P;纤维素酶,C).苹果渣(AP)和带有曲霉的啤酒厂废谷物(BSG)。选择(菌株G5)。随后的步骤涉及两阶段统计方法,确定关键因素并优化它们。使用Plackett-Burman设计筛选工艺条件,将关键变量缩小到三个(BSG/AP,pH值,湿度)。响应面法(中心复合设计)进一步优化了这些因素,用于X的共合成,P,和C。湿度对这三个响应的影响最显著。最佳条件取决于每种酶,并进一步验证以最大化X,将获得的提取物用于从橙皮中提取果胶。主要含有木聚糖酶的提取物(X=582.39,P=22.86,C=26.10UmL-1)显示出主要的果胶产率恢复(12.33±0.53%),并且使用BSG/AP的最佳设置(81/19)获得,湿度(50.40%),和pH(4.58)。该发现将能够调整工艺条件以获得具有用于特定应用的定制组合物的酶混合物。
    In the pursuit of sustainability, managing agro-industrial and food processing residues (AFR) efficiently is crucial. This study proposes a systematic approach to convert AFR into valuable products via solid-state fermentation (SSF). Using fungal enzyme production as a case study, this adaptable methodology suits any SSF bioprocess. Initially, AFR\'s physicochemical properties were evaluated to assess their feasible use as carbon sources and solid matrices for SSF. Then, five strains were screened for their capability to produce enzymes (Xylanase, X; pectinase, P; cellulase, C). Apple pomace (AP) and brewery spent grain (BSG) with Aspergillus sp. (strain G5) were selected. Subsequent steps involved a two-phase statistical approach, identifying critical factors and optimizing them. Process conditions were screened using a Plackett-Burman design, narrowing critical variables to three (BSG/AP, pH, humidity). Response Surface Methodology (Central Composite Design) further optimized these factors for co-synthesis of X, P, and C. The humidity had the most significant effect on the three responses. The optimum conditions depended on each enzyme and were further validated to maximize either X, P or C. The obtained extracts were used for pectin extraction from orange peels. The extract containing primarily xylanase (X = 582.39, P = 22.86, C = 26.10 U mL-1) showed major pectin yield recovery (12.33 ± 0.53%) and it was obtained using the optimal settings of BSG/AP (81/19), humidity (50.40%), and pH (4.58). The findings will enable adjusting process conditions to obtain enzymatic cocktails with a tailored composition for specific applications.
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  • 文章类型: Review
    橄榄副产品是酚类化合物的丰富来源,其价值化是符合联合国(UN)组织促进福祉和生产更健康产品的可持续发展目标的有利方法;同时,处理环境和经济问题,从而提高橄榄油行业的盈利能力。从这些副产物生产增值成分没有在工业规模上广泛利用。干燥是提取前的关键预处理,可直接影响橄榄副产品中可用生物活性化合物的回收率和产率。为了生产更稳定和高质量的酚类产品,使用喷雾和冷冻干燥进行封装。在这项研究中,综述了从橄榄副产品中提取生物活性化合物作为有价值的酚类化合物来源之前和之后的干燥过程的影响。此外,还研究了使用这些成分的强化及其在食品配方中的掺入。
    Olive by-products are rich sources of phenolic compounds and their valorization is a favorable approach in line with sustainable development goals of the United Nations (UN) organization to promote well-being and production of healthier products; also, to deal with the environmental and economic subjects resulting in more profitability in the olive oil industry. The production of value-added ingredients from these by-products is not extensively exploited on the industrial scale. Drying is a critical pretreatment before extraction that can have a direct impact on the recovery and yield of the available bioactive compounds in olive by-products. In order to produce more stable and high quality phenolic products, encapsulation using spray and freeze drying is used. In this study, the effect of the drying process before and after extraction of bioactive compounds from olive by-products as a valuable source of phenolic compounds is reviewed. In addition, fortification using these ingredients and their incorporation in food formulations is also investigated.
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  • 文章类型: Journal Article
    在欧洲,蔬菜食品供应链的增值潜力很大。例如,新鲜食用的西红柿偶尔会过量生产,一小部分产品不适合新鲜消费销售(不可接受的颜色,形状,成熟,病变,等。).在缺乏番茄加工设施和基础设施的国家,这些西红柿通常会被破坏,用作填埋或动物饲料,并代表生产者的经济损失和负面环境影响。同样,番茄加工业也有潜力使侧流增值并减少浪费。本文概述了欧洲的番茄生产以及番茄侧流和废物馏分的加工和增值策略。特别强调了四个番茄生产国挪威,比利时,波兰,和土耳其。这些国家非常不同,例如他们的气候条件为番茄生产和产量,代表了欧洲番茄生产国的极端情况。讨论了收获后的处理和应用,以优化收获时间和改善优质原料质量的储存,以及小说,可持续加工技术,实现废物和侧流价值最小化。番茄红素的保存和富集,主要的健康促进剂和销售论点,进行了详细的审查。欧洲番茄采后浪费量估计为每年>300万吨。一起,收获时间和预处理储存条件的优化以及可持续食品加工技术,加上加工副产品和侧流的稳定和增值,可以显着促进这种未充分利用的生物质的增值。
    There is a large potential in Europe for valorization in the vegetable food supply chain. For example, there is occasionally overproduction of tomatoes for fresh consumption, and a fraction of the production is unsuited for fresh consumption sale (unacceptable color, shape, maturity, lesions, etc.). In countries where the facilities and infrastructure for tomato processing is lacking, these tomatoes are normally destroyed, used as landfilling or animal feed, and represent an economic loss for producers and negative environmental impact. Likewise, there is also a potential in the tomato processing industry to valorize side streams and reduce waste. The present paper provides an overview of tomato production in Europe and the strategies employed for processing and valorization of tomato side streams and waste fractions. Special emphasis is put on the four tomato-producing countries Norway, Belgium, Poland, and Turkey. These countries are very different regards for example their climatic preconditions for tomato production and volumes produced, and represent the extremes among European tomato producing countries. Postharvest treatments and applications for optimized harvest time and improved storage for premium raw material quality are discussed, as well as novel, sustainable processing technologies for minimum waste and side stream valorization. Preservation and enrichment of lycopene, the primary health promoting agent and sales argument, is reviewed in detail. The European volume of tomato postharvest wastage is estimated at >3 million metric tons per year. Together, the optimization of harvesting time and preprocessing storage conditions and sustainable food processing technologies, coupled with stabilization and valorization of processing by-products and side streams, can significantly contribute to the valorization of this underutilized biomass.
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  • 文章类型: Journal Article
    这项工作的重点是评估将使用过的食用油(UCO)用作城市生物精炼厂的油脂化学原料的潜力。该研究案例是为波哥大市开发的,哥伦比亚。最初,根据主要油脂分销商的数据,市场信息,和公共数据库,据估计,哥伦比亚每年的UCOs总发电量约为22.5万吨,人均为ca。5kg/人/年。相应地,波哥大的UCO产量估计至少为45,000吨/年。,主要一代人发生在家庭和霍雷卡(酒店,餐厅和餐饮)细分市场。特别是在霍雷卡,快餐店(尤其是汉堡包和鸡肉)被确定为主要的UCO发电机,为工业开发提供了合适的供应。然后,来自这部分餐馆的UCOs样品通过密度测定进行物理化学表征,挥发物含量,酸值,颜色,过氧化值,皂化值,碘值,和总极性化合物的含量。与油的降解程度相关的性质表现出很大的变化,即使是来自同一来源的样本。这种异质性表明在重复使用之前需要预处理过程。尽管样本的异质性,密度,碘值,不同餐厅的皂化值略有变化,很大程度上取决于加工食用油的性质,而不是烹饪条件。收集的UCOs显示碘值和皂化指数在80至119gI2/100g之间,和178-201毫克KOH/克,分别。这表明在适当的纯化后,UCO可以用作各种高价值油脂化学品的原料。最后,根据市场数据,并促进进一步的研究,确定了一些期许增值衍生品。
    This work is focused on assessing the potential for the exploitation of used cooking oils (UCOs) as oleochemical feedstock for urban biorefineries. The study case was developed for the city of Bogotá, Colombia. Initially, and according to data from major fats and oils distributors, market information, and public databases, it was estimated that total annual generation of UCOs in Colombia is about 225,000 t, with a per capita of ca. 5 kg/person/yr. Correspondingly, UCOs generation in Bogotá was estimated in at least 45,000 t/yr., with a major generation occurring at Household and HORECA (Hotels, Restaurants and Catering) segments. Specifically in HORECA, fast food restaurants (in particular those of hamburger and chicken) were identified as the main UCOs generators with a suitable supply for industrial exploitation. Then, UCOs samples from this segment of restaurants were subjected to physicochemical characterization by determination of density, volatile matter content, acid value, color, peroxide value, saponification value, iodine value, and content of total polar compounds. The properties associated with the degree of degradation of the oil showed a large variation, even among samples from the same origin. This heterogeneity indicates the need for a pre-treatment process before its reuse. Despite the heterogeneity of the samples, density, iodine value, and saponification value showed slight changes among the different restaurants, largely depending on the nature of the processed cooking oil rather than on the cooking conditions. The collected UCOs showed iodine values and saponification indexes ranging between 80 and 119 g I2/100 g, and 178-201 mg KOH/g, respectively. This indicates that after a suitable purification, UCOs could be used as raw material for a variety of high value oleochemicals. Finally, based upon market data, and to boost further studies, some promissory value-added derivatives are identified.
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  • 文章类型: Journal Article
    Fruit peels are a rich source of cellulose, hemicellulose, phenolic compounds, and terpenic compounds. Thus, they have the potential to be a novel renewable, sustainable, and low-cost raw material (source) for the production of several value-added products based on framework and concepts such as waste hierarchy that includes biofertilizers, dietary fiber, animal feed, industrial enzymes, substrate for the bioactive compounds production, synthesis of nanomaterials, and clean energy (from residual biomass). With a view of evaluating the environmental burden of biorefinery, a life cycle assessment (LCA) is performed for a representative citrus waste (CW) biorefinery. The functional unit used for LCA was set as 2500 kg of CW processed. The overall GWP was observed to be 937.3 kg CO2 equivalent per 2500 kg of CW processed. On further analysis of the environmental impact, it was found that different steps contributed significantly, as shown by the various environmental indicator values. Alternative advanced process intensification technologies like microwave and ultrasound-assisted steps replacing the conventional steps when implemented show considerable reduction in environmental indicator values. The variations in the contribution to environmental indicators should be considered during the design and process selection of biorefineries.
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