Thermal Conductivity

导热系数
  • 文章类型: Journal Article
    废物管理不当正在引起全球环境问题。废弃玻璃可能会对生态系统产生不利影响。虽然大量的钠钙玻璃瓶(SGB)经过回收以制造新的玻璃制品,大量的垃圾最终仍被填埋。因此,这项研究的目的是探索SGB在泡沫混凝土(FC)生产中作为骨料替代品的潜在用途。SGB代替了不同重量分数的沙子,从5%到50%不等。新鲜的状态,机械,热,孔隙结构,并检查了传输特性。研究结果表明,当SGB替代20%的沙子时,FC的机械性能显着提高。压缩,弯曲,劈裂抗拉强度分别提高了17.7%、39.4%和43.8%,分别。研究结果还表明,SGB的加入提高了热导率,吸着性,吸水,和孔隙度。扫描电子显微镜分析表明,包含20%的SGB会导致空隙直径显着降低并增强其均匀性。使用各种国际标准模型对实验数据和机械性能的预测进行了比较,如IS456、ACI318、NZS-3101、EC-02、AS3600和CEB-FIB,以及文献中的一些参考文献。这些发现暗示了强度特性之间的强相关性。这项研究的结果为在FC中使用SGB的可能优势和限制提供了有价值的见解。此外,这项广泛的实验室调查可以作为未来研究的指南,并有助于开发更绿色,更环保的FC替代品。
    Improper waste management is causing global environmental problems. Waste glass may have adverse impacts on the ecosystem. While a substantial amount of soda-lime glass bottle (SGB) undergoes recycling to create new glass items, a significant volume still ends up in landfills. Therefore, the aim of this study was to explore the potential use of SGB in foamed concrete (FC) production as an aggregate replacement. SGB was substituted for sand in different weight fractions, ranging from 5 to 50%. The fresh state, mechanical, thermal, pore structure, and transport properties were examined. The findings showed a significant enhancement in the FC\'s mechanical properties when SGB replaced 20% of sand. The compressive, flexural, and splitting tensile strengths exhibited a rise of up to 17.7, 39.4, and 43.8%, respectively. The findings also demonstrated that the addition of SGB improved the thermal conductivity, sorptivity, water absorption, and porosity. The scanning electron microscopy analysis indicated that the inclusion of 20% SGB caused a substantial decrease in void diameter and enhanced its uniformity. A comparison was made between the experimental data and predictions of the mechanical properties using various models of international standards, such as IS 456, ACI 318, NZS-3101, EC-02, AS 3600, and CEB-FIB, along with several references in the literature. The findings implied a strong correlation between the strength properties. The outcomes of this research offer valuable insights into both the possible advantages and constraints of using SGB in FC. Furthermore, this extensive laboratory investigation may serve as a guideline for future study and aid in the advancement of greener and more environmentally friendly FC alternatives.
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  • 文章类型: Journal Article
    低共熔溶剂(DESs)是由两种或三种成分组成的复杂物质,其中氢键供体和受体参与氢键网络内的复杂相互作用。它们由于易于合成而引起了研究者的广泛关注,成本效益,广泛的液体范围,稳定性好,绿色无毒。然而,关于DES物理性质的研究仍然很少,许多理论还不够完善,这限制了DES在工程实践中的应用。在这项研究中,以氯化胆碱和甜菜碱为HBA合成了12种DES,和乙二醇,聚乙二醇600,邻甲酚,甘油,和乳酸作为HBDs。系统研究了其热导率和粘度随大气压力温度的变化规律。实验结果表明,1:4氯化胆碱/甘油溶剂的热导率在294K时最大,达到0.2456W·m-1·K-1,可以满足传热工件对高效传热的需求。使用Arrhenius模型拟合了DES的温度-粘度关系,最大平均绝对偏差为6.77%。
    Deep eutectic solvents (DESs) are complex substances composed of two or three components, wherein hydrogen bond donors and acceptors engage in intricate interactions within a hydrogen bond network. They have attracted extensive attention from researchers due to their easy synthesis, cost-effectiveness, broad liquid range, good stability, and for being green and non-toxic. However, studies on the physical properties of DESs are still scarce and many theories are not perfect enough, which limits the application of DESs in engineering practice. In this study, twelve DESs were synthesized by using choline chloride and betaine as HBAs, and ethylene glycol, polyethylene glycol 600, o-cresol, glycerol, and lactic acid as HBDs. The variation rules of their thermal conductivity and viscosity with temperature at atmospheric pressure were systematically investigated. The experimental results showed that the thermal conductivity of the 1:4 choline chloride/glycerol solvent was the largest at 294 K, reaching 0.2456 W·m-1·K-1, which could satisfy the demand for high efficiency heat transfer by heat-transferring workpieces. The temperature-viscosity relationship of the DESs was fitted using the Arrhenius model, and the maximum average absolute deviation was 6.77%.
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  • 文章类型: Journal Article
    建筑物利用无机和有机绝缘材料来节约能源并防止热损失。然而,同时表现出优异的隔热性能,有机隔热材料由于在发生火灾时散发强烈的热量和有毒烟雾而增加了火灾的风险。相反,无机保温材料的特点是保温性能较低,导致建筑物的重量增加,广泛使用。因此,研究解决现有绝缘材料缺点的新绝缘材料的必要性,包括减轻体重,增强耐火性,提高隔热性能,已被认可。这项研究的重点是评估与传统建筑材料相比,使用新型建筑材料的隔热性能的增强。研究方法涉及将多孔气凝胶粉末掺入纸基纤维素绝缘材料中以改善其绝缘性能。以标准的100×100mm2面板形式制备样品。使用了两个对照组:一个纯对照组,样本是用100%回收纸板包装的,和一个混合对照组,其中使用30重量%陶瓷粘合剂和40重量%可膨胀石墨的混合比生产样品。通过在混合后在对照组(纯的和混合的)的每种条件下将气凝胶含量从200增加到1000mL来制备实验组样本。根据ISO22007-2(对于固体,粘贴,和粉末)。通过这项研究,结果发现,纯对照组和实验组的保温性能提高了16.66%,而混合的对照组和实验组在添加气凝胶的情况下,保温性能提高了17.06%。
    Buildings utilize both inorganic and organic insulation materials to conserve energy and prevent heat loss. However, while exhibiting excellent thermal insulation performance, organic insulation materials increase the risk of fire due to the emission of intense heat and toxic smoke in the event of a fire. Conversely, inorganic insulation materials are characterized by a lower thermal insulation performance, leading to an increase in the weight of the building with extensive use. Therefore, the necessity for research into new insulation materials that address the drawbacks of existing ones, including reducing weight, enhancing fire resistance, and improving thermal insulation performance, has been recognized. This study focuses on evaluating the enhancement of the thermal insulation performance using novel building materials compared to conventional ones. The research methodology involved the incorporation of porous aerogel powders into paper-based cellulose insulation to improve its insulating properties. Samples were prepared in standard 100 × 100 mm2 panel forms. Two control groups were utilized: a pure control group, where specimens were fabricated using 100% recycled cardboard for packaging, and a mixed control group, where specimens were produced using a mixture ratio of 30 wt% ceramic binder and 40 wt% expandable graphite. Experimental group specimens were prepared by increasing the aerogel content from 200 to 1000 mL under each condition of the control groups (pure and mixed) after mixing. The thermal insulation performance of the specimens was evaluated in terms of thermal conductivity and thermal diffusivity according to ISO 22007-2 (for solids, paste, and powders). Through this study, it was found that the thermal insulation performances of the pure control and experimental groups improved by 16.66%, while the mixed control and experimental groups demonstrated a 17.06% enhancement in thermal insulation performance with the addition of aerogel.
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  • 文章类型: Journal Article
    目的:目的是通过用1重量%的二氧化钛(TiO2)和1重量%的二氧化锆(ZrO2)纳米粒子渗透的热活化聚甲基丙烯酸甲酯(PMMA)来测定热传导,并与常规PMMA进行比较。
    方法:体外实验研究。
    方法:18个圆盘形试样,厚度为5毫米,直径为50毫米,根据所使用的材料制造和分组:B1组(用1重量%TiO2渗透的树脂),B2组(用1重量%ZrO2渗透的树脂),和对照组B3(热活化常规PMMA树脂)。在印度空间研究组织的热实验室中,使用“改良的防护热板设备”分析了圆盘形试样的热导率。
    方法:使用单向方差分析和Tukey的事后检验来比较所有三组的算术平均值。
    结果:在所有三组中观察到统计学上的显著差异。B2组的热导率最大,其次是B1组。组B3的热导率最小。事后比较显示,B2组和B3组之间的差异显着。
    结论:在PMMA中添加纳米ZrO2提高了其热导率。有证据表明它也改善了其机械性能。因此,高度推荐在PMMA中添加纳米ZrO2。在PMMA中添加纳米TiO2在热导率方面没有提供任何显著的优势,但它在PMMA中的添加是合理的,因为它的机械和抗菌性能。
    OBJECTIVE: The aim is to determine thermal conduction by heat-activated polymethylmethacrylate (PMMA) infiltrated with 1 weight% Titanium Dioxide (TiO2) and 1 weight% Zirconium Dioxide (ZrO2) nanoparticles and to compare with that of conventional PMMA.
    METHODS: In vitro experimental study.
    METHODS: Eighteen disc shaped specimens with a thickness of 5 mm and diameter of 50 mm, were fabricated and grouped according to the material used: Group B1 (resin infiltrated with 1 weight% TiO2), Group B2 (resin infiltrated with 1 weight% ZrO2), and Control Group B3 (heat-activated conventional PMMA resin). Disc-shaped specimens were analyzed for thermal conductivity using \"modified guarded hot plate apparatus\" in the thermal lab of the Indian Space Research Organisation.
    METHODS: One-way ANOVA followed by Tukey\'s post hoc test was used to compare the arithmetic means of all three groups.
    RESULTS: A statistically significant difference was noted among all three groups. Group B2 had the maximum thermal conductivity, followed by Group B1. Thermal conductivity was the least for Group B3. A post hoc comparison revealed that the difference was significant between Group B2 and Group B3.
    CONCLUSIONS: Nano ZrO2 addition in PMMA increased its thermal conductivity. There is evidence that it improves its mechanical properties as well. Hence, Nano ZrO2 addition in PMMA is highly recommended. Nano TiO2 addition in PMMA did not provide any significant advantage in terms of thermal conductivity, but its addition in PMMA is justified because of its mechanical and antimicrobial properties.
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  • 文章类型: Journal Article
    高温聚合物对极端温度下的应用具有吸引力,在那里他们保持他们的机械灵活性和电绝缘性能。然而,它们的散热能力是有限的,由于其固有的低热导率。六方氮化硼(hBN)是一种化学惰性,热稳定,和具有高导热性的电绝缘化合物,使其成为高温聚合物基质中填料的理想候选物,以增加热导率。这项研究通过使用溶剂混合和共振声混合(RAM)的组合生产均匀的复合材料样品,评估了填料尺寸和分散对热导率的影响。我们仔细表征了我们的样品,包括大小分布的分布,并观察到以5μm为中心的较小尺寸的hBN能够更无缝地集成到粒度在15μm范围内的聚四氟乙烯(PTFE)基体中,因此优于30μm,与传统智慧相反,它断言较大的填充物普遍比较小的填充物表现更好。我们的hBN/PTFE复合材料在30wt%时的热导率比文献值高2倍。值得注意的是,我们在40重量%时达到了3.5W/mK的创纪录的高值,在20重量%时开始渗滤,归因于优化的hBN分散,有助于形成热渗滤。我们的研究结果提供了一般准则,以提高聚合物复合材料的热导率,用于热管理,从电力传输到微电子冷却。
    High-temperature polymers are attractive for applications in extreme temperatures, where they maintain their mechanical flexibility and electrical insulating properties. However, their heat dissipation capability is limited due to their intrinsically low thermal conductivities. Hexagonal boron nitride (hBN) is a chemically inert, thermally stable, and electrically insulative compound with a high thermal conductivity, making it an ideal candidate as a filler within a high-temperature polymer matrix to increase the thermal conductivity. This study evaluates the effect of filler size and dispersion on thermal conductivity by producing homogeneous composite samples using a combination of solvent mixing and resonant acoustic mixing (RAM). We carefully characterized our samples, including the spread of the size distribution, and observed that the smaller sized hBN centered around 5 μm was able to integrate more seamlessly into the polytetrafluoroethylene (PTFE) matrix with particle size in the 15 μm range and hence outperformed 30 μm, in contrast to the conventional wisdom, which asserts that larger fillers universally perform better than smaller ones. Our thermal conductivity of hBN/PTFE composites at 30 wt % is 2× higher than the literature values. Notably, we reached the record-high value of 3.5 W/m K at 40 wt % with an onset of percolation at 20 wt %, attributed to optimized hBN dispersion that facilitates the formation of thermal percolation. Our findings provide general guidelines to enhance the thermal conductivity of polymer composites for thermal management, ranging from power transmission to microelectronics cooling.
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  • 文章类型: Journal Article
    近年来,光伏/热(PV/T)系统在降低能源消耗和环境恶化方面发挥了至关重要的作用,尽管如此,低能量转换效率对PV/T系统提出了相当大的障碍。因此,提高热转换效率是提高能源效率的关键。在本文中,提出了带有特斯拉阀的PV/T系统来解决这个问题。首先,在具有四种不同的流道结构的系统中,模拟和分析了冷却效果:半圆,矩形,三角形和特斯拉阀。结果表明,采用特斯拉阀的系统具有优越的冷却性能。随后,几个因素,包括角度,阀门编号,阀门类型,通过数值和仿真分析进一步研究了Tesla阀的管径比。结果表明,当具有以下结构参数时,特斯拉阀门表现出最佳的冷却性能:完全对称,更多的阀门,30度角和管径比为1。最后,选择四种不同类型的流体来探索特斯拉阀门。结论表明,纳米流体具有较高的密度,低比热,和高导热性也提高了冷却性能。因此,带有特斯拉阀门的PV/T系统具有良好的散热和储能效率,电效率可达16.32%,热效率达59.65%。
    In recent years, photovoltaic/thermal (PV/T) systems have played a crucial role in reducing energy consumption and environmental degradation, nonetheless, the low energy conversion efficiency presents a considerable obstacle for PV/T systems. Therefore, improving heat conversion efficiency is essential to enhance energy efficiency. In this paper, the PV/T system with the Tesla valve is proposed to solve this problem. Firstly, the cooling effect is simulated and analyzed in the system with four different flow channel structures: semicircle, rectangle, triangle and Tesla valve. The results indicate that the system with the Tesla valve exhibits superior cooling performance. Subsequently, several factors including angle, valve number, valve type, and pipe diameter ratio for the Tesla valve are further studied through numerical and simulation analysis. The results reveal that Tesla valves demonstrate optimal cooling performance when possessing the following structural parameters: complete symmetry, more valves, a 30-degree angle and a pipe diameter ratio of 1. Finally, four different types of fluid are selected to explore the Tesla valve. The conclusion shows that nanofluids with high density, low specific heat, and high thermal conductivity also improve the cooling performance. Thus, the PV/T system with the Tesla valve exhibits good heat dissipation and energy storage efficiency, electrical efficiency can reach 16.32% and thermal efficiency reach 59.65%.
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  • 文章类型: Journal Article
    本文介绍了管道绝缘导热性的实验评估结果。减少工业管道系统中的能量损失的需要使得相关且可靠的绝缘材料的可用性具有特别重要的意义。几个管道滞后样本,由不同的材料制成,包括矿棉,聚乙烯泡沫(PEF),发泡聚苯乙烯(EPS),柔性弹性泡沫(FEF)和聚氨酯泡沫(PUR),根据欧洲标准ISO8497进行测试。在宽范围的温度下测量材料的热导率。将结果与技术规范中报告的值以及文献数据进行比较。还描述了测量不确定度的评定。结果表明,在少数情况下,导热系数比制造商声明的高10%以上。
    This paper describes the results of an experimental assessment of the thermal conductivity of pipe insulation. The need for reducing energy loss in industrial piping systems makes the availability of relevant and reliable insulation materials of special importance. Several specimens of pipe laggings, made of different materials, including mineral wool, polyethylene foam (PEF), expanded polystyrene (EPS), flexible elastomeric foam (FEF) and polyurethane foam (PUR), were tested in accordance with the European standard ISO 8497. The thermal conductivity of the materials was measured for a wide range of temperatures. The results were compared with the values reported in the technical specifications as well as with the literature data. The assessment of measurement uncertainty was also described. The results showed that, in a few cases, thermal conductivity turned out to be greater than that declared by the manufacturer by as much as over 10%.
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  • 文章类型: Journal Article
    气候变化迫使各国改变其建设和城市化政策,以尽量减少对环境的影响。欧盟已经设定了温室气体排放量减少55%的目标,认识到其50%的排放源于保持建筑物内的热舒适性。作为回应,欧盟制定了关于能源效率的全面立法。在这篇文章中,使用气凝胶的特殊砂浆,珍珠岩,制备和研究了蛭石作为轻质骨料,以提高砂浆的热性能。检查了它们的热性能,在高温和低温条件下使用太阳模拟器,发现这些轻质骨料的不同比例导致砂浆在温暖条件下比参考砂浆提供高达7°C的外部绝缘,在寒冷条件下高达4.5°C。
    Climate change is compelling countries to alter their construction and urbanization policies to minimize their impact on the environment. The European Union has set a goal to reduce greenhouse gas emissions by 55%, recognizing that 50% of its emissions originate from maintaining thermal comfort within buildings. As a response, the EU has developed comprehensive legislation on energy efficiency. In this article, special mortars using aerogel, perlite, and vermiculite as lightweight aggregates were prepared and studied to enhance the thermal properties of the mortar. Their thermal properties were examined and, using a solar simulator for both hot and cold conditions, it was found that varying proportions of these lightweight aggregates resulted in a mortar that provided insulation from the exterior up to 7 °C more than the reference mortar in warm conditions and up to 4.5 °C in cold conditions.
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  • 文章类型: Journal Article
    温度显著影响花岗岩的物理参数,导致岩石热导率的变化。为了考察花岗岩在不同温度下多种物理参数的变化对岩石导热系数的影响,采用主成分分析(PCA)确定不同温度下花岗岩与各种物理参数之间的相关性。包括密度(ρ),P波速度(P),热导率(KT),和热扩散系数(KD)。利用线性贡献率,得出了一个单一的指标“y”来全面表示岩石的热导率。研究结果表明,在150-450°C的温度范围内,\'y\'值相对较高,表明岩石具有良好的导热性。值得注意的是,与其他物理参数相比,纵波速度对温度变化具有更高的敏感性。
    Temperature significantly influences the physical parameters of granite, resulting in variations in the rock\'s thermal conductivity. In order to examine the impact of changes in multiple physical parameters of granite at different temperatures on the thermal conductivity of rocks, Principal Component Analysis (PCA) was employed to determine the correlation between granite at different temperatures and various physical parameters, including density (ρ), P-wave velocity (P), thermal conductivity (KT), and thermal diffusion coefficient (KD). Utilizing the linear contribution rate, a single indicator \'y\' was derived to comprehensively represent the thermal conductivity of rocks. Research findings indicate that within the temperature range of 150-450 °C, the \'y\'-value is relatively high, signifying favorable thermal conductivity of the rock. Notably, longitudinal wave velocity demonstrates higher sensitivity to temperature changes compared to other physical parameters.
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  • 文章类型: Journal Article
    尽管由无机填料和基质组成的环氧基复合材料由于其优异的绝缘性和坚固性而广泛用于“常规”电子包装应用中,它们限制了它们在需要增强导热性的“先进电子封装”中的用途。然而,用于制造环氧基复合材料的常规热固化方法不能实现足够的导热性。在这里,我们应用光诱导固化策略来制造包含氧化铝的环氧-硅氧烷复合材料,该复合材料由溶胶-凝胶衍生的硅氧烷基质和作为导热填料的双峰氧化铝颗粒组成。我们研究了固化机理(热固化或UV固化)以及改变两种不同尺寸的氧化铝颗粒的比例如何影响各种物理性质。发现光固化过程使热导率大大提高,低热膨胀,和高机械强度相比,热固化复合材料。作为结果,我们可以实现显着增强的热导率(>11W/mK)具有高热稳定性和机械鲁棒性。
    Although epoxy-based composites that consist of inorganic fillers and matrixes are widely used in \"conventional\" electronic packaging applications due to their excellent insulation and robust properties, they limit their uses in \"advanced electronic packaging\" which requires enhanced thermal conductivity. However, conventional thermal curing methods for fabrication of epoxy-based composites do not fulfill sufficient thermal conductivity. Herein, we apply photo-induced curing strategy for fabricating alumina-incorporated epoxy-siloxane composites that consist of sol-gel derived siloxane matrix and bimodal sized alumina particles as a thermally conductive filler. We investigate how curing mechanism (thermal- or UV-curing) and varying the ratios of the alumina particles of two different sizes affect the various physical properties. It is found that photo-curing process makes greatly enhanced thermal conductivity, low thermal expansion, and high mechanical robustness compared to thermally-cured composites. As the results, we can achieve significantly enhanced thermal conductivity (>11 W/m K) with high thermal stability and mechanical robustness.
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