Thermal Conductivity

导热系数
  • 文章类型: Journal Article
    这篇简短的评论涵盖了一维材料的热电性能,如纳米线和纳米管。这些纳米结构材料的费米能级附近的电子态密度的高度局部化峰改善了塞贝克系数。此外,量子限制导致离散的能级和修改的态密度,潜在地增强导电性。这些电子效应,再加上Umklapp声子散射的优势,这降低了一维材料的热导率,可以实现前所未有的热电效率,在二维或散装材料。值得注意的进步包括碳和硅纳米管和Bi3Te2,Bi,ZnO,SiC,和Si1-xGex纳米线具有显著降低的热导率和增加的ZT。在所有这些纳米线和纳米管中,效率作为直径的函数进行了探索。在这些纳米材料中,碳纳米管提供机械灵活性和改进的热电性能。尽管碳纳米管理论上具有很高的导热性,由于其低维结构而导致的塞贝克系数的提高可以弥补这一点。关于灵活性,经济标准,易于制造,和体重,碳纳米管可能是热电发电的有希望的候选者。
    This brief review covers the thermoelectric properties of one-dimensional materials, such as nanowires and nanotubes. The highly localised peaks of the electronic density of states near the Fermi levels of these nanostructured materials improve the Seebeck coefficient. Moreover, quantum confinement leads to discrete energy levels and a modified density of states, potentially enhancing electrical conductivity. These electronic effects, coupled with the dominance of Umklapp phonon scattering, which reduces thermal conductivity in one-dimensional materials, can achieve unprecedented thermoelectric efficiency not seen in two-dimensional or bulk materials. Notable advancements include carbon and silicon nanotubes and Bi3Te2, Bi, ZnO, SiC, and Si1-xGex nanowires with significantly reduced thermal conductivity and increased ZT. In all these nanowires and nanotubes, efficiency is explored as a function of the diameter. Among these nanomaterials, carbon nanotubes offer mechanical flexibility and improved thermoelectric performance. Although carbon nanotubes theoretically have high thermal conductivity, the improvement of their Seebeck coefficient due to their low-dimensional structure can compensate for it. Regarding flexibility, economic criteria, ease of fabrication, and weight, carbon nanotubes could be a promising candidate for thermoelectric power generation.
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  • 文章类型: Journal Article
    由于传统气凝胶存在力学性能差等缺陷,复杂的制备过程,高能耗和不可再生,木质气凝胶作为新一代气凝胶显示出独特的优势。有了天然纤维素框架,木气凝胶是一种新型的纳米多孔材料,具有优异的性能,如重量轻,高孔隙率,大的比表面积,和低热导率。此外,其对进一步功能化的适应性使多功能应用在不同的领域。在可持续发展势在必行的推动下,木气凝胶作为一种可再生和环保的材料,引起了研究人员的极大关注。本文介绍了基于自上而下策略的木材气凝胶的制备方法,并分析了影响其关键性能的因素,以期获得具有理想性能的木材气凝胶。还探索了实现其功能的途径,并对各个领域的研究进展进行了调查,包括油水分离,电导率和能量储存,以及光热转换。最后,解决了与木材气凝胶开发和利用相关的潜在挑战,并讨论了未来的前景和研究方向。结果强调了木材气凝胶的广泛研究价值和未来前景,有望推动木材的高价值利用,促进绿色多功能气凝胶的发展。
    As the traditional aerogel has defects such as poor mechanical properties, complicated preparation process, high energy consumption and non-renewable, wood aerogel as a new generation of aerogel shows unique advantages. With a natural cellulose framework, wood aerogel is a novel nano-porous material exhibiting exceptional properties such as light weight, high porosity, large specific surface area, and low thermal conductivity. Furthermore, its adaptability to further functionalization enables versatile applications across diverse fields. Driven by the imperative for sustainable development, wood aerogel as a renewable and eco-friendly material, has garnered significant attention from researchers. This review introduces preparation methods of wood aerogel based on the top-down strategy and analyzes the factors influencing their key properties intending to obtain wood aerogels with desirable properties. Avenues for realizing its functionality are also explored, and research progress across various domains are surveyed, including oil-water separation, conductivity and energy storage, as well as photothermal conversion. Finally, potential challenges associated with wood aerogel exploitation and utilization are addressed, alongside discussions on future prospects and research directions. The results emphasize the broad research value and future prospects of wood aerogels, which are poised to drive high-value utilization of wood and foster the development of green multifunctional aerogels.
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  • 文章类型: Journal Article
    微型化的快速发展,高频,和高度集成的微电子器件在电磁兼容和热管理方面带来了关键问题。近年来,人们对提供电磁干扰(EMI)屏蔽和导热性的轻质聚合物基复合材料产生了极大的兴趣。一种有前景的方法涉及使用聚合物基质中的功能性填料构建三维(3D)互连网络。这些网络已被证明在增强复合材料的导热性和导电性方面是有效的。这篇小型综述重点介绍了3D网络增强聚合物复合材料的制备和性能,特别是那些含有金属的,碳,陶瓷,和混合网络。通过比较不同填料种类和分布对复合材料的影响,强调了3D互连导电网络在聚合物复合材料中的优势。此外,这篇综述解决了多功能热管理和电磁防护材料领域面临的挑战,并提供了对3D结构复合材料未来发展趋势和应用前景的见解。
    The rapid development of miniaturized, high-frequency, and highly integrated microelectronic devices has brought about critical issues in electromagnetic compatibility and thermal management. In recent years, there has been significant interest in lightweight polymer-based composites that offer both electromagnetic interference (EMI) shielding and thermal conductivity. One promising approach involves constructing three-dimensional (3D) interconnection networks using functional fillers in the polymer matrix. These networks have been proven effective in enhancing the thermal and electrical conductivity of the composites. This mini-review focuses on the preparation and properties of 3D network-reinforced polymer composites, specifically those incorporating metal, carbon, ceramic, and hybrid networks. By comparing the effects of different filler types and distribution on the composite materials, the advantages of 3D interconnected conductive networks in polymer composites are highlighted. Additionally, this review addresses the challenges faced in the field of multifunctional thermal management and electromagnetic protection materials and provides insights into future development trends and application prospects of 3D structured composites.
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  • 文章类型: Journal Article
    这项研究批判性地回顾了纳米粒子的关键方面及其对集中式太阳能(CSP)中热能存储(TES)的熔盐(MS)的影响。然后对MS纳米流体进行全面分析,专注于确定盐和纳米颗粒的最佳组合,以有效增加比热容(SHC)。解释了合成这些纳米流体的各种方法和途径。本文介绍了用于表征纳米流体的不同实验技术,包括测量SHC和热导率以及分析颗粒分散。它还讨论了与表征这些纳米流体相关的挑战。该研究旨在研究MS纳米流体中SHC增加背后的潜在机制。最后,它总结了未来研究的潜在领域,突出了进一步调查和推进的关键领域。
    This study critically reviews the key aspects of nanoparticles and their impact on molten salts (MSs) for thermal energy storage (TES) in concentrated solar power (CSP). It then conducts a comprehensive analysis of MS nanofluids, focusing on identifying the best combinations of salts and nanoparticles to increase the specific heat capacity (SHC) efficiently. Various methods and approaches for the synthesis of these nanofluids are explained. The article presents different experimental techniques used to characterize nanofluids, including measuring the SHC and thermal conductivity and analyzing particle dispersion. It also discusses the challenges associated with characterizing these nanofluids. The study aims to investigate the underlying mechanisms behind the observed increase in SHC in MS nanofluids. Finally, it summarizes potential areas for future research, highlighting crucial domains for further investigation and advancement.
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  • 文章类型: Journal Article
    本文探讨了从废物中提取的相变材料(PCM)的使用,在储能系统中。它强调了这些PCM在解决与化石燃料使用和环境影响相关的问题方面的潜力。本文还强调了这些PCM的方面,包括减少对可再生资源的依赖,最大限度地减少温室气体排放和减少废物。该研究还讨论了诸如集成纳米技术以增强热导率以及利用机器学习和深度学习技术预测动态行为等方法。本文提供了对可生物降解的基于废物的PCM的研究的总体观点,以及它们如何在实现节能和可持续的储热系统中发挥有希望的作用。然而,从提出的结果中得出的具体结论没有明确概述,离开房间,在这个不断发展的领域进行调查和探索。用于热能存储设备的人工神经网络(ANN)预测模型表现不同。调整后的平均绝对误差为4%,高斯径向基函数核支持向量回归(SVR)模型捕获了与热相关的充电和放电问题。人工神经网络模型预测翅片管热和热通量优于数值模型。在某些数据集中,SVM模型的性能优于ANN和ANFIS。材料属性预测有利于梯度提升,但是线性回归和SVR模型表现更好,强调特定于应用程序和数据集的模型选择。这些预测模型提供了对建筑结构复杂热性能的见解,协助节能系统的设计和运行。可生物降解的基于废物的PCM的可持续性包括碳足迹,减少废物,生物降解性,和循环经济调整。纳米技术,机器学习,和深度学习提高热导率和预测。循环经济原则包括减少废物和减少碳足迹。没有陈述基于结果的具体结论。对当前研究进行了全面概述,突出了可生物降解的基于废物的PCM在节能和可持续储热系统方面的潜力。
    This article explores the use of phase change materials (PCMs) derived from waste, in energy storage systems. It emphasizes the potential of these PCMs in addressing concerns related to fossil fuel usage and environmental impact. This article also highlights the aspects of these PCMs including reduced reliance on renewable resources minimized greenhouse gas emissions and waste reduction. The study also discusses approaches such as integrating nanotechnology to enhance thermal conductivity and utilizing machine learning and deep learning techniques for predicting dynamic behavior. The article provides an overall view of research on biodegradable waste-based PCMs and how they can play a promising role in achieving energy-efficient and sustainable thermal storage systems. However, specific conclusions drawn from the presented results are not explicitly outlined, leaving room, for investigation and exploration in this evolving field. Artificial neural network (ANN) predictive models for thermal energy storage devices perform differently. With a 4% adjusted mean absolute error, the Gaussian radial basis function kernel Support Vector Regression (SVR) model captured heat-related charging and discharging issues. The ANN model predicted finned tube heat and heat flux better than the numerical model. SVM models outperformed ANN and ANFIS in some datasets. Material property predictions favored gradient boosting, but Linear Regression and SVR models performed better, emphasizing application- and dataset-specific model selection. These predictive models provide insights into the complex thermal performance of building structures, aiding in the design and operation of energy-efficient systems. Biodegradable waste-based PCMs\' sustainability includes carbon footprint, waste reduction, biodegradability, and circular economy alignment. Nanotechnology, machine learning, and deep learning improve thermal conductivity and prediction. Circular economy principles include waste reduction and carbon footprint reduction. Specific results-based conclusions are not stated. Presenting a comprehensive overview of current research highlights biodegradable waste-based PCMs\' potential for energy-efficient and sustainable thermal storage systems.
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  • 文章类型: Journal Article
    在过去的三十年中,对磁流变液(MRF)进行了许多研究,突出了几个突出的优点,比如快速的相变,容易控制屈服应力,等等。特别是,在过去的二十年里,已经报道了几篇关于MRF技术的评论文章,总结了MRF的发展及其应用。作为具体的例子,评论文章已经发表,包括优化颗粒和载体液体,以实现最小的关闭状态粘度和最大的屈服应力,包括Casson模型和Herschel-Bulkley(H-B)模型在内的许多本构模型的建立,使用添加剂和纳米颗粒增强沉降,用于汽车悬架和民用结构的许多类型的阻尼器,医疗和康复设备,MRF抛光技术,磁路设计的方法,以及各种控制器的合成。最近,温度和热导率对MRF和应用系统的性能的影响正在通过一些工作进行积极研究。然而,到目前为止还没有关于这个问题的评论文章,尽管热问题是开发先进的MRF和应用系统的商业产品需要认真考虑的最关键因素之一。在这项工作中,综述了MRF本身的热导率和温度及其与温度相关的应用系统的研究,分别,并总结了主要结果,强调以下几点:如何减少温度对MRF场相关特性的影响,以及如何设计一个最小化热效应的应用系统。这里要注意的是,使用表格以时间顺序的格式组织综述摘要。
    Many studies on magnetorheological fluid (MRF) have been carried out over the last three decades, highlighting several salient advantages, such as a fast phase change, easy control of the yield stress, and so forth. In particular, several review articles of MRF technology have been reported over the last two decades, summarizing the development of MRFs and their applications. As specific examples, review articles have been published that include the optimization of the particles and carrier liquid to achieve minimum off-state viscosity and maximum yield stress at on-state, the formulation of many constitutive models including the Casson model and the Herschel-Bulkley (H-B) model, sedimentation enhancement using additives and nanosized particles, many types of dampers for automotive suspension and civil structures, medical and rehabilitation devices, MRF polishing technology, the methods of magnetic circuit design, and the synthesis of various controllers. More recently, the effect of the temperature and thermal conductivity on the properties of MRFs and application systems are actively being investigated by several works. However, there is no review article on this issue so far, despite the fact that the thermal problem is one of the most crucial factors to be seriously considered for the development of advanced MRFs and commercial products of application systems. In this work, studies on the thermal conductivity and temperature in MRFs themselves and their temperature-dependent application systems are reviewed, respectively, and principal results are summarized, emphasizing the following: how to reduce the temperature effect on the field-dependent properties of MRFs and how to design an application system that minimizes the thermal effect. It is noted here that the review summary is organized in a chronological format using tables.
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  • 文章类型: Journal Article
    认识到有必要解决工业副产品管理不善的问题,因为它们的积累严重威胁着环境。工业废物的有效再利用是实现环境友好型可持续发展的必要条件。为此,监督采用受控低强度材料(CLSM)可以是一种解决方案。CLSM是环境安全的水泥基材料,具有自调平和自固结特性。CLSM的长期可持续应用完全取决于其在施工阶段期间和之后的地质环境特性。这篇全面的综述探讨了地质环境特性对用于CLSM创建的工业副产品的塑料和在役特性的影响。它严格地检查了CLSM的各种地质环境特性,包括化学成分的交错方面,矿物学组成,浸出行为,pH值,和导热性。结果表明,CLSM的地质环境特性主要由原材料的特性和含量决定。废物,以及最终混合物中使用的水量。Further,该审查强调了地质环境属性对CLSM塑料和在役属性的不利影响。全面审查可以帮助有效利用CLSM减少对环境的关注,同时实现可持续发展。
    There is a recognized need to address the mismanagement of industrial by-products, as their accumulation severely threatens the environment. Efficient reutilizing of industrial waste is indispensable in realizing environment-friendly sustainable development. Towards this end, supervised adoption of controlled low-strength materials (CLSM) can be a solution. CLSM are cement-based materials which are environmentally safe, with self-levelling and self-consolidating properties. CLSM\'s long-term sustainable applications exclusively depend on its geo-environmental properties during and after the construction phase. This comprehensive review explores the impact of geo-environmental properties on the plastic and in-service properties of industrial by-products used for CLSM creation. It critically examines various geo-environmental properties of CLSM comprising interlaced aspects of chemical composition, mineralogical composition, leaching behavior, pH value, and thermal conductivity. It is shown that the geo-environmental properties of CLSM are determined mainly by the characteristics and content of raw materials, wastes, and the quantity of water used in the final blend. Further, the review accentuates the geo-environmental properties\' detrimental effects on the plastic and in-service properties of CLSM. The comprehensive review can aid in effectively utilizing CLSM to reduce environmental concerns while achieving sustainable development.
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  • 文章类型: Journal Article
    在污染带来的全球挑战中,不断升级的能源费用,以及全球变暖的迫在眉睫的威胁,追求可持续能源解决方案已变得越来越必要。热电,一种有希望的绿色能源,可以利用废热并直接将其转化为电能。由于其环保特性,这项技术几个世纪以来一直备受关注,机械稳定性,尺寸和基材的多功能性,没有移动的组件。它的应用跨越了不同的领域,包括热回收,冷却,传感,在低温和高温下运行。然而,开发具有高性能效率的热电材料面临诸如高成本,毒性,对稀土元素的依赖。为了应对这些挑战,这份全面的审查涵盖了热电的关键方面,包括它的历史背景,基本操作原则,尖端材料,创新战略。特别是,一维纳米结构的潜力被探索为推进热电技术的有希望的途径。一维纳米结构的概念被广泛研究,包括各种配置及其对材料的热电性能的影响。还彻底讨论了一维纳米结构对热电参数的深远影响。综述还全面综述了一维热电材料的大规模合成方法,深入研究这种材料特有的热电性能的测量。最后,审查最后概述了前景,并确定了该领域进一步发展的潜在方向。
    Amidst the global challenges posed by pollution, escalating energy expenses, and the imminent threat of global warming, the pursuit of sustainable energy solutions has become increasingly imperative. Thermoelectricity, a promising form of green energy, can harness waste heat and directly convert it into electricity. This technology has captivated attention for centuries due to its environmentally friendly characteristics, mechanical stability, versatility in size and substrate, and absence of moving components. Its applications span diverse domains, encompassing heat recovery, cooling, sensing, and operating at low and high temperatures. However, developing thermoelectric materials with high-performance efficiency faces obstacles such as high cost, toxicity, and reliance on rare-earth elements. To address these challenges, this comprehensive review encompasses pivotal aspects of thermoelectricity, including its historical context, fundamental operating principles, cutting-edge materials, and innovative strategies. In particular, the potential of one-dimensional nanostructuring is explored as a promising avenue for advancing thermoelectric technology. The concept of one-dimensional nanostructuring is extensively examined, encompassing various configurations and their impact on the thermoelectric properties of materials. The profound influence of one-dimensional nanostructuring on thermoelectric parameters is also thoroughly discussed. The review also provides a comprehensive overview of large-scale synthesis methods for one-dimensional thermoelectric materials, delving into the measurement of thermoelectric properties specific to such materials. Finally, the review concludes by outlining prospects and identifying potential directions for further advancements in the field.
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  • 文章类型: Journal Article
    铝合金已被广泛用作汽车和通信行业的耐热和散热部件,对导热系数较高的铝合金的需求越来越大。因此,本文对铝合金的导热性能进行了综述。首先,我们制定了金属热传导理论和有效介质理论,然后分析合金元素的影响,次要阶段,和温度对铝合金导热性能的影响。合金元素是最关键的因素,谁的物种,现有状态,和相互作用显著影响铝的热导率。在固溶体中的合金元素比在沉淀状态下更显著地削弱铝的热导率。第二相的特征和形态也影响热导率。温度还通过影响铝合金中电子和声子的热传导来影响热导率。此外,最近关于铸造效果的研究,热处理,并总结了AM工艺对铝合金导热性能的影响,其中过程主要通过改变合金元素的存在状态和第二相的形态来影响热导率。这些分析和总结将进一步促进高导热铝合金的工业设计和发展。
    Aluminum alloys have been extensively used as heatproof and heat-dissipation components in automotive and communication industries, and the demand for aluminum alloys with higher thermal conductivity is increasing. Therefore, this review focuses on the thermal conductivity of aluminum alloys. First, we formulate the theory of thermal conduction of metals and effective medium theory, and then analyze the effect of alloying elements, secondary phases, and temperature on the thermal conductivity of aluminum alloys. Alloying elements are the most crucial factor, whose species, existing states, and mutual interactions significantly affect the thermal conductivity of aluminum. Alloying elements in a solid solution weaken the thermal conductivity of aluminum more dramatically than those in the precipitated state. The characteristics and morphology of secondary phases also affect thermal conductivity. Temperature also affects thermal conductivity by influencing the thermal conduction of electrons and phonons in aluminum alloys. Furthermore, recent studies on the effects of casting, heat treatment, and AM processes on the thermal conductivity of aluminum alloys are summarized, in which processes mainly affect thermal conductivity by varying existing states of alloying elements and the morphology of secondary phases. These analyses and summaries will further promote the industrial design and development of aluminum alloys with high thermal conductivity.
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  • 文章类型: Journal Article
    目前,热积累严重影响电子器件的稳定性和寿命。具有高导热系数(λ)的聚酰亚胺(PI)薄膜长期以来一直被认为是散热的理想解决方案。基于热传导机理和经典热传导模型,本文提出了具有微观有序液晶结构的PI薄膜的设计思想,这对打破λ增强的极限具有重要意义,并描述了高λ填料增强PI薄膜中热传导网络的构造原理。更进一步,填料类型的影响,系统地综述了PI薄膜的热传导路径和界面热阻(ITR)对其热传导行为的影响。同时,本文对已有的研究进行了总结,并对导热PI薄膜的未来发展进行了展望。最后,希望本文的综述对今后导热PI薄膜的研究有一定的指导意义。本文受版权保护。保留所有权利。
    Currently, heat accumulation has seriously affected the stabilities and life of electronic devices. Polyimide (PI) film with high thermal conductivity coefficient (λ) has long been held up as an ideal solution for heat dissipation. Based on the thermal conduction mechanisms and classical thermal conduction models, this review presents design ideas of PI films with microscopically ordered liquid crystalline structures which are of great significance for breaking the limit of λ enhancement and describes the construction principles of thermal conduction network in high-λ filler strengthened PI films. Furthermore, the effects of filler type, thermal conduction paths, and interfacial thermal resistances on thermally conductive behavior of PI film are systematically reviewed. Meanwhile, this paper summarizes the reported research and provides an outlook on the future development of thermally conductive PI films. Finally, it is expected that this review will give some guidance to future studies in thermally conductive PI film.
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