Among bee species, the western honey bee (Apis mellifera) is preferred in monitoring studies performed in the agricultural landscape, while bee matrices, pollen, and honey are mostly a subject of these studies due to their unique composition. A justified question about the relevance of other bee matrices, like larvae, foragers, beebread, and/or wax, has been raised. The ability of different bee matrices (wax, pollen grains, bee bread, foragers, larvae, nectar, and honey) to absorb pesticide residues is subjected in this study. All samples were collected during a crop flowering season (oilseed rape) on intensively managed agricultural land in Slovakia and Germany. The observed high variability in residue levels, profile, and number of detections among studied matrices from Germany, west, and east Slovakia gave us an assumption of the use of different agricultural practices between these two countries. Fungicides clearly dominated across all samples in all sampling regions. The increased pesticide profile positively correlated with the oilseed rape pollen grains in pollen pellets and/or bee bread. Bee wax, pollen, and bee bread showed a high number of detected active substances and total residue concentrations among matrices, indicating their high ability to absorb pesticide residues in the surrounding hive environment.

In Afghanistan, groundwater is widely used for drinking water, but its quality poses a health threat. This study investigates the physical, chemical, and bacteriological characteristics of groundwater in the Upper Kabul Sub-basin. Fifteen samples were collected and analyzed from different parts of the study area. The qualitative determination of parameters such as pH, Electrical conductivity (EC), Total dissolved solids (TDS), Salinity, Total hardness, Calcium, Magnesium, Sodium, Chloride, Fluoride, Sulfate, Phosphate, Potassium, Nitrite, Nitrate, Ammonia, Iron, Manganese, Copper, Aluminum, Arsenic, Total coliform, and Fecal coliform bacteria was carried out. The results were compared with WHO and ANSA standards to assess their suitability for drinking purposes. The analyzed samples indicate that physical parameters generally fall within permissible limits according to WHO and ANSA standards. However, certain wells exhibited elevated levels of chemical and bacteriological contaminants. Specifically, Magnesium concentrations exceeded the WHO guideline of 30 mg/L in all of the samples, and Calcium levels surpassed the recommended limit of 75 mg/L in 53% of the samples. Total coliform bacteria were detected in 33.33% of the samples, while fecal coliform bacteria were within the WHO and ANSA permissible limit for drinking water. The Pearson\'s correlation coefficient (R) suggested significant correlations between EC, TDS, and total hardness with other physical and chemical parameters. For instance, EC showed a strong positive correlation (R = 1.00) with TDS, EC and Salinity (R = 0.981), EC and Fluoride (R = 0.838) EC and Sulfate (R = 0.853), TDS and Salinity (R = 0. 981), TDS and Fluoride (R = 0.838), TDS and Sulfate (R = 0.853). The findings demonstrate that correlation coefficient analyses of water quality parameters provide a valuable means for monitoring water quality. These results offer critical insights for ensuring a safe water supply in the region.

Microplastics are a global environmental problem, polluting both aquatic and terrestrial environments. Terrestrial lizards are suitable model organisms to study human-induced pollution in these areas, as they can live in urbanized areas where microplastics are most abundant. Therefore, we analyzed the prevalence of microplastics (MPs) in a common Lacertid lizard, the snake-eyed lizard, Ophisops elegans. We detected MPs in the gastrointestinal tract (GIT) of 33 of 152 specimens from 18 populations. The detected MPs had six distinct polymer compositions, namely Polyethylene terephthalate, Polyacrylonitrile, Polypropylene, Polyethylene, Poly methyl methacrylate and Polyamide. The majority of these MPs were fiber-type and the dominant color was navy blue. The lengths of MPs varied from 37 to 563 μm, with an average length of 175 μm. MPs were detected in the GITs of 43% of juveniles (n = 7), 30% of males (n = 105), and 18% of females (n = 40), with a mean of 0.27 per specimen. Furthermore, we found that microplastic densities varied with habitat distance from human settlements, supporting the theory that high levels of microplastic contamination are associated with extensive anthropogenic activity.

Atopic dermatitis (AD) is a complex disease characterized by dry, pruritic skin and significant atopic and psychological sequelae. Although AD has always been viewed as multifactorial, early research was dominated by overlapping genetic determinist views of either innate barrier defects leading to inflammation or innate inflammation eroding skin barrier function. However, the incidence of AD in the US has increased since 1970 at a pace that far exceeds genetic drift and thus suggests a modern, environmental etiology. Another implicated factor is Staphylococcus aureus; however, a highly contagious microorganism is unlikely to be the primary etiology of a non-communicable disease. Recently, the roles of the skin and gut microbiomes have received greater attention as potentially targetable drivers of AD. Here too however, dysbiosis on a population scale would require induction by an environmental factor. In this review, we describe the evidence supporting the environmental hypothesis of AD etiology and detail the molecular mechanisms of each AD-relevant toxins. We also outline how a pollution focused paradigm demands earnest engagement with environmental injustice if the field is to meaningfully address racial and geographic disparities. Identifying specific toxins and their mechanisms can also inform in-home and national mitigation strategies.

Sessile intertidal organisms live in a harsh environment with challenging environmental conditions and increasing anthropogenic pressure such as microplastic (MP) pollution. This study focused on effects of environmentally relevant MP concentrations on the metabolism of intertidal Pacific oyster Crassostrea gigas, and its potential MP-induced vulnerability to warming during midday low tide. Oysters experienced a simulated semidiurnal tidal cycle based on their natural habitat, and were exposed to a mixture of polystyrene microbeads (4, 7.5 and 10 µm) at two environmentally relevant concentrations (0.025 µg L-1 and 25 µg L-1) for 16 days, with tissue samplings after 3 and 12 days to address dose-dependent effects over time. On the last day of exposure, the remaining oysters were additionally exposed to low tide warming (3 °C h-1) to investigate possible MP-induced susceptibility to aerial warming. Metabolites of digestive gland and gill tissues were analysed by using untargeted 1H nuclear magnetic resonance (NMR) based metabolomics. For the digestive gland metabolite profiles were comparable to each other independent of MP concentration, exposure time, or warming. In contrast, gill metabolites were significantly affected by high MP exposure and warming irrespective of MP, initiating the same cellular stress response to counteract induced oxidative stress. The activated cascade of antioxidant defence mechanisms required energy on top of the general energy turnover to keep up homeostasis, which in turn may lead to subtle, and likely sub-lethal, effects within intertidal oyster populations. Present results underline the importance of examining the effects of environmentally relevant MP concentrations not only alone but in combination with other environmental stressors.

The platypus (Ornithorhynchus anatinus) is a semi-aquatic monotreme that occupies a high trophic position in the freshwater ecosystems of eastern mainland Australia and Tasmania. Platypuses are continuously exposed to anthropogenic contaminants including perfluorooctane sulfonate (PFOS). This study examined PFOS concentrations in the livers of deceased platypuses (eight wild; one captive) that were opportunistically collected across NSW over a two- and a half-year period. There was a large variation in PFOS concentrations, ranging from < 1 µg/kg to 1200 µg/kg. This study presents the first report of PFOS contamination in platypuses, revealing their PFOS levels are broadly similar to those found in river otters (Lutra canadensis) and lower than those in American mink (Mustela vison), both which occupy similar ecological niches in freshwater systems. This study raises concerns about the impact of PFOS on platypus health.

Sulfate (SO42-) is an essential anion in drinking water and a vital macronutrient for plant growth. However, elevated sulfate levels can impact ecosystem or human health and could be an important indicator of acid rock drainage or pollution. Therefore, monitoring SO42- sources and transport is important for water quality assessments. This study focused on exploring the sources and transformations of SO42- as well as estimating the proportional contribution of the potential SO42- pollutant sources to groundwater and surface water in a tropical river basin, the Densu River Basin. The study used major ions combined with stable sulfur and oxygen isotope compositions and a Bayesian isotope mixing model, MixSIAR. The major ion characteristics indicate that SO42- concentrations remain stable throughout the rainy and dry seasons but originate from diverse sources. The multi-isotope model (δ34SSO4, δ18OSO4) identified four potential SO42- sources: detergent, precipitation, sewage, and sulfate fertilizer. However, the δ34SSO4 and δ18OSO4 values of the fertilizer source signatures overlapped with those of precipitation and sewage. Nevertheless, the contributions from each source were disentangled using the MixSIAR model, which revealed sewage as the most dominant SO42- pollutant in the Densu Basin, accounting for ~47 % of sulfate in groundwater and ~ 56 % of sulfate in surface water. Sulfate fertilizer (~33 %) was the second most important source after sewage for groundwater, while detergent (~23 %) was the second most important source for surface water. The redox processes of bacterial sulfate reduction and sulfide oxidation were determined to have a minimal impact on the sulfur isotope fractionation within the basin. This study highlights the benefits of combining major ions, sulfur isotopes and the MixSIAR model for identifying sources of sulfate. This approach accounts for uncertainties in source contributions which allows for more robust and reliable apportionment of sulfate sources. The study emphasizes the need for effective waste management and pollution control measures to protect water quality and provides vital guidelines on how to partition sulfate sources on a large catchment scale and evidence for making pollution management decisions on water resources.

Protecting rivers and lakes from pollution is crucial for maintaining the health of aquatic ecosystems and ensuring the well-being of both wildlife and humans. Present study intends to examine the water quality of the Suna River (Eastern Fennoscandia in the European North of Russia) to assess the ecological risk. Widespread methods for assessing water quality based on macrozoobenthos and phytoperiphoton were applied. It was found that in conditions of ultra-fresh waters with high humus content, biotic indicators may indicate pollution of water bodies that do not actually experience significant anthropogenic impact. Ratings ranging from \'poor\' to \'excellent\' were obtained for different stations, reflecting the influence of natural features of different sections of the river. \'Good\' water quality was noted at the river stones biotopes. In river gravel, sand and silt biotopes, as well as all lake biotopes, \'mediocre\' water quality was found. The low anthropogenic income on the river catchment allows us to conclude that most indices for assessing water quality significantly underestimate the results in the natural conditions of Eastern Fennoscandia. Biotic indices EPT, BBI and EBI are most accurate for assessing the water quality of rivers and lakes in Eastern Fennoscandia.

The presence of various contaminants in airborne dusts from metal mining sites poses obvious risks to human health and the environment. Yet, few studies have thoroughly investigated the properties of airborne particles in terms of their morphology, size distribution and chemical composition, that are associated with health effects around mining activities. This review presents the most recent knowledge on the sources, physicochemical characteristics, and health and environmental risks associated with airborne dusts from various mining and smelting operations. The literature reviewed found only one research on atmospheric dust associated with hydrometallurgical plants compared to a larger number of pyrometallurgical processes/smelters studies. In addition, there are relatively few works comparing the distribution of metals between the fine and coarse size fractions around mining sites. Our analysis suggests that (i) exposure pathways of metal(loid)s to the human body are defined by linking concentration data in human biosamples and contaminated samples such as soils, drinking water and food, and (ii) chitosan and its derivatives may serve as an environmentally friendly and cost-effective method for soil remediation, with removal rates for metal(loid)s around 70-95 % at pH 6-8, and as dust suppressants for unpaved roads around mining sites. The specific limit values for PM and metal(loid)s at mining sites are not well documented. Despite the health risks associated with fine particles around mining areas, regulations have tended to focus on coarse particles. While some air quality agencies have issued regulations for occupational health and safety, there is no global alignment or common regulatory framework for enforcement. Future research priorities should focus on investigating PM and secondary inorganic aerosols associated with hydrometallurgical processes and dust monitoring, using online metal(loid)s analysers to identify the driving parameters in the deposition and resuspension process.

Coppe and zinc are priority pollutants in city soils. Copper and zinc are the limiting factors for lawn grasses. Cell selection can increase the resistance of lawn grasses to zinc and copper. The effect of zinc on the morphogenic ability of the callus was determined. The results of this study showed that zinc is less toxic to calli than copper. The method of obtaining lawn grass resistant to zinc has been developed. The results were used to develop the cell selection technology for obtaining plants resistant to the complex effect of zinc and copper. Concentrations of Copper (75 mg/l) and zinc (150 mg/L) were selected as selective. The author developed the cell selection scheme for obtaining plants resistant to the complex effect of Cu and Zn. The regenerants showed increased resistance to copper and zinc.