Pollutants

污染物
  • 文章类型: Journal Article
    水产养殖是解决全球食物圣洁的主要途径。随着全球人口的增加,对水产养殖的需求增加。鱼饲料,药物和化学品,水生生物的代谢废物或死亡率也增加,最终导致生产大量的水产养殖废水。这些水产养殖排放物含有多种污染物,如常规污染物,有机化合物,重金属,和生物污染物,诱发职业危害和风险,粮食安全,环境污染。需要适当的废水处理技术来去除有害污染物,以最大程度地减少其对环境和人类健康的影响。循环水产养殖系统,一些生物和物理化学方法已经被用来去除水产养殖废水中的一些污染物,但是它们在去除污染物方面的效率仍然需要进一步提高,以实现零废物排放和确保水产养殖的可持续发展。同时,需要建立健全的法规和立法,以确保水产养殖业的正常运行和废水的标准排放。本综述旨在为研究者提供水产养殖废水的全面信息,促进水产养殖健康发展。
    Aquaculture is the major way to solve the global food sacrcity. As the global population increases, the demand for aquaculture increases. Fish feed, drugs and chemicals, and metabolic waste or mortalities of aquatic organisms also increase, eventually resulting in the production of a large amount of aquaculture wastewater. These aquaculture discharges contain a variety of pollutants, such as conventional pollutants, organic compounds, heavy metals, and biological contaminants, inducing occupational hazards and risks, food security, the environment pollution. Proper wastewater treatment technologies are required to remove hazardous pollutants for minimizing their impacts on environmental and human health. Recirculating aquaculture systems, some biological and physicochemical methods have been applied to remove some pollutants from the aquaculture wastewater, but their efficiency in removing pollutants still requires to be further improved for achieving zero-waste discharge and ensuring sustainable aquaculture development. Meanwhile, sound regulation and legislation needs to be established for ensuring the normal operation of aquaculture industries and the standard discharge of wastewater. This review aims to provide comprehensive information of aquaculture wastewater for the researchers and promote the healthy development of aquaculture.
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  • 文章类型: Journal Article
    二氧化钛(TiO2)基光催化剂已被广泛用作降解水和空气中各种持久性有机化合物(POC)的光催化剂。降解机理涉及高活性氧的产生,如羟基自由基,它们与有机化合物反应,分解它们的化学键,最终将它们矿化成无害的产物。在药物和农药分子的情况下,TiO2和改性TiO2光催化能有效降解多种化合物,包括抗生素,杀虫剂,和除草剂。主要的缺点是生产危险的中间产品,这在目前可用的文献中并不经常提到。TiO2光催化对这些化合物的降解速率取决于化合物的化学结构等因素,TiO2催化剂的浓度,强度,光源,以及溶液中其他有机或无机物质的存在。探索降解机制的理解,以获得对中间体的见解。此外,解决了响应面方法(RSM)的利用,为增强反应堆的可扩展性提供了潜在的途径。总的来说,TiO2光催化是一种很有前途的制药和农药废水处理技术,但是需要进一步的研究来优化工艺条件并了解降解产物的命运和毒性。 .
    Titanium dioxide (TiO2) based photocatalysts have been widely used as a photocatalyst for the degradation of various persistent organic compounds in water and air. The degradation mechanism involves the generation of highly reactive oxygen species, such as hydroxyl radicals, which react with organic compounds to break down their chemical bonds and ultimately mineralize them into harmless products. In the case of pharmaceutical and pesticide molecules, TiO2and modified TiO2photocatalysis effectively degrade a wide range of compounds, including antibiotics, pesticides, and herbicides. The main downside is the production of dangerous intermediate products, which are not frequently addressed in the literature that is currently available. The degradation rate of these compounds by TiO2photocatalysis depends on factors such as the chemical structure of the compounds, the concentration of the TiO2catalyst, the intensity, the light source, and the presence of other organic or inorganic species in the solution. The comprehension of the degradation mechanism is explored to gain insights into the intermediates. Additionally, the utilization of response surface methodology is addressed, offering a potential avenue for enhancing the scalability of the reactors. Overall, TiO2photocatalysis is a promising technology for the treatment of pharmaceutical and agrochemical wastewater, but further research is needed to optimize the process conditions and to understand the fate and toxicity of the degradation products.
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  • 文章类型: Journal Article
    近年来,使用卧式旋转盘式反应器(SDR)作为光催化反应器降解水溶液中的各种污染物的增加。本研究是基于PRISMA方法进行搜索的。两名自主研究人员使用Scopus进行了相关研究,WebofScience(WOS),和科学直接数据库。搜索词扩展,重点关注水平旋转盘式光催化反应器(SDPR)的性能。在这篇评论文章中,随着光源类型(可见光和紫外线辐射范围)的变化,操作因素对污染物降解效率的影响的主要目标,光盘转速,流量,污染物的初始浓度,pH值,考虑了圆盘结构的类型和流态。SDPR当前的挑战包括诸如有限的传质,不均匀的光分布,和扩大规模的困难。为了克服这些挑战,改进可以通过优化反应器设计来实现更好的传质,通过先进的光源或反应堆配置增强光分布,并开发可扩展的模型,以在更大的规模上保持效率。此外,创新材料和涂料的使用可以提高SDPR的整体性能。
    In recent years, the use of a horizontal spinning disc reactor (SDR) as a photocatalytic reactor for the degradation of various pollutants in aqueous solutions has increased. This study was searched based on the PRISMA method. Two autonomous researchers carried out for the relevant studies using Scopus, Web of Science (WOS), and Science Direct databases. The search terms expanded focusing on the performance of horizontal spinning disc photocatalytic reactor (SDPR). In this review article, the main objective of the effect of operational factors on the efficiency of the degradation of pollutants with changes in the type of light source (range of visible light and UV radiation), disc rotational speed, flow rate, initial concentration of pollutants, pH, type of disc structure and flow regime are considered. Current challenges in SDPR include issues such as limited mass transfer, uneven light distribution, and difficulties in scaling up. To overcome these challenges, improvements can be made by optimizing reactor design for better mass transfer, enhancing light distribution through advanced light sources or reactor configurations, and developing scalable models that maintain efficiency at larger scales. Additionally, the use of innovative materials and coatings could improve the overall performance of SDPR.
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  • 文章类型: Journal Article
    藻类在增值产品和生物精炼应用中的应用,由于其显著的光合能力,近年来在研究人员中引起了极大的关注,适应性,和积累脂质和碳水化合物的能力。藻类生物量,基于其低制造成本,是相对可再生的,可持续,与其他物种相比,环境友好和经济。藻类的高生产率为其转化为具有优异物理化学性质的生物炭提供了独特的机会,viz.高表面积和孔体积,高吸附能力,表面上有丰富的官能团,等。尽管有几种潜在的藻类生物炭,对其应用于去除废水中新兴污染物的详细研究是有限的。因此,正在进行这项技术审查,以评估废水中无机和有机污染物的具体消除,以评估从各种藻类中获得的生物炭的吸附性能。本文讨论了废水中新兴污染物的物种特异性吸附。有前途的方法,如热解,气化,重点介绍了用于生产藻类生物炭的干法和湿法烘焙。在当前工作中也考虑了包括藻类生物炭的化学和结构修饰以去除有毒污染物的策略。这篇综述的总体目标是讨论合成,技术进步,藻类生物炭处理废水的划定和应用。
    The use of algae for value-added product and biorefining applications is enchanting attention among researchers in recent years due to its remarkable photosynthetic ability, adaptability, and capacity to accumulate lipids and carbohydrates. Algae biomass, based on its low manufacturing costs, is relatively renewable, sustainable, environmentally friendly and economical in comparison with other species. High production rate of algae provides a unique opportunity for its conversion to biochar with excellent physicochemical properties, viz. high surface area and pore volume, high adsorption capacity, abundant functional groups over surface, etc. Despite several potential algal-biochar, a detailed study on its application for removal of emerging contaminants from wastewater is limited. Therefore, this technical review is being carried out to evaluate the specific elimination of inorganic and organic pollutants from wastewater, with a view to assessing adsorption performances of biochar obtained from various algae species. Species-specific adsorption of emerging pollutants from wastewater have been discussed in the present review. The promising methods like pyrolysis, gasification, dry and wet torrefaction for the production of algae biochar are highlighted. The strategies include chemical and structural modifications of algae biochar for the removal of toxic contaminants have also been considered in the current work. The overall aim of this review is to confer about the synthesis, technological advancements, delineation and application of algae biochar for the treatment of wastewater.
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  • 文章类型: Journal Article
    汞是一种危险的重金属,分布在全球水生生态系统中。甲基汞(MeHg)对水生生物构成重大毒性风险,主要通过生物积累和生物放大,由于其对蛋白质巯基的强亲和力,即使在低浓度下也会产生负面影响。甲基汞暴露会引起各种生理变化,氧化应激,神经毒性,代谢紊乱,遗传损伤,和免疫毒性。评估实际水生生态系统中甲基汞污染的风险,了解甲基汞如何与环境因素如温度相互作用是很重要的,pH值,溶解的有机物,盐度,和其他污染物,如微塑料和有机化合物。复杂的环境条件会导致潜在的毒性,比如协同,拮抗,和不变的效果,水生生物中的甲基汞。这篇综述的重点是展示单一甲基汞暴露的毒性效应以及甲基汞与周围环境因子或污染物对水生生物的相互作用关系。我们的综述还建议进一步研究水生生物的生物和分子反应,以更好地了解组合暴露的潜在毒性。
    Mercury is a hazardous heavy metal that is distributed worldwide in aquatic ecosystems. Methylmercury (MeHg) poses significant toxicity risks to aquatic organisms, primarily through bioaccumulation and biomagnification, due to its strong affinity for protein thiol groups, which results in negative effects even at low concentrations. MeHg exposure can cause various physiological changes, oxidative stress, neurotoxicity, metabolic disorders, genetic damage, and immunotoxicity. To assess the risks of MeHg contamination in actual aquatic ecosystems, it is important to understand how MeHg interacts with environmental factors such as temperature, pH, dissolved organic matter, salinity, and other pollutants such as microplastics and organic compounds. Complex environmental conditions can cause potential toxicity, such as synergistic, antagonistic, and unchanged effects, of MeHg in aquatic organisms. This review focuses on demonstrating the toxic effects of single MeHg exposure and the interactive relationships between MeHg and surrounding environmental factors or pollutants on aquatic organisms. Our review also recommends further research on biological and molecular responses in aquatic organisms to better understand the potential toxicity of combinational exposure.
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  • 文章类型: Journal Article
    Exposomics是一个不断扩展的领域,它捕获了化学物质的累积暴露,生物,物理,生活方式,以及与生物反应相关的社会因素。由于骨骼肌目前被认为是最大的分泌器官,并且在整个生命过程中表现出很大的可塑性,这篇评论通过回顾最先进的证据和最有趣的观点来解决暴露和骨骼肌的话题.肌肉干细胞通过磷酸化的真核起始因子2α和结节性硬化症1对应激源作出反应,并且通过沉默蛋白1对激素因子敏感。微塑料可以通过p38丝裂原激活的蛋白激酶延迟肌肉再生,并通过核因子κB诱导向脂肪细胞的转分化。Acrolein可以抑制肌分化并破坏氧化还原系统。重金属与儿童肌肉力量降低有关。对污染物和生物学特性的深入研究可以为神经肌肉病理生理学提供新的思路。来自一组感兴趣的暴露和表型的时变和动态暴露风险评分的分析是有希望的。激素因子的系统化和微生物群在调节暴露对骨骼肌反应的影响中的作用也是有希望的。全面的暴露评估及其与内源性过程的相互作用以及由此产生的生物学效应值得在整个生命周期的肌肉健康领域做出更多努力。
    Exposomics is an ever-expanding field which captures the cumulative exposures to chemical, biological, physical, lifestyle, and social factors associated with biological responses. Since skeletal muscle is currently considered as the largest secretory organ and shows substantial plasticity over the life course, this reviews addresses the topic of exposome and skeletal muscle by reviewing the state-of-the-art evidence and the most intriguing perspectives. Muscle stem cells react to stressors via phosphorylated eukaryotic initiation factor 2α and tuberous sclerosis 1, and are sensible to hormetic factors via sirtuin 1. Microplastics can delay muscle regeneration via p38 mitogen-activated protein kinases and induce transdifferentiation to adipocytes via nuclear factor kappa B. Acrolein can inhibit myogenic differentiation and disrupt redox system. Heavy metals have been associated with reduced muscle strength in children. The deep study of pollutants and biological features can shed new light on neuromuscular pathophysiology. The analysis of a time-varying and dynamic exposome risk score from a panel of exposure and phenotypes of interest is promising. The systematization of hormetic factors and the role of the microbiota in modulating the effects of exposure on skeletal muscle responses are also promising. The comprehensive exposure assessment and its interactions with endogenous processes and the resulting biological effects deserve more efforts in the field of muscle health across the lifespan.
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  • 文章类型: Journal Article
    由于空气和废水造成的环境污染几十年来一直是令人不安的现象。污染物,如二氧化碳(CO2),染料,制药,酚类物质,重金属以及许多有机和无机物种已被发现在不同的环境区域。研究表明它们对人类健康的负面影响,野生动物,和生态系统。因此,通过法规做出了各种努力,技术进步,和公众宣传运动,以减少污染的影响。然而,寻找合适的替代品来减轻它们的影响仍然是一个挑战。金属有机骨架(MOFs)是具有高孔隙率和稳定性等独特特性的先进材料之一。最近,他们在环境修复中发现了广泛的应用。已经发现它们与氧化钛纳米颗粒(TiO2)的复合物提供了比原始形式的潜在特征,例如集光能力和催化活性。通过使用表面积分析进行表征,证实了复合材料的集成度和性能,扫描电子/透射电子显微镜,原子力显微镜,傅里叶变换红外光谱,X射线衍射分析,X射线光电子能谱,热重分析,和其他人。因此,这项工作严格讨论了MOF@TiO2纳米材料在二氧化碳捕获和有效利用甲醇中的潜在应用,乙醇,丙酮,乙醛,和其他有用的产品,作为各种工业过程的燃料。此外,这项工作突出了材料对有机和无机污染物的光催化降解的有效性能。已经说明了所述过程的机制。因此,希望这篇文章将为开发可持续和有效的环境监测和减少污染技术做出重大贡献。
    Environmental pollution has been increasing since last decade due to increasing industrialisation and urbanisation. Various kinds ofenvironmental pollutants including carbon dioxide (CO2), dyes, pharmaceuticals, phenols, heavy metals along with many organic and inorganic species have been discovered in the various environmental compartments which possess harmful impacts tox human health, wildlife, and ecosystems. Thus, various efforts have been made through regulations, technological advancements, and public awareness campaigns to reduce the impact of the pollution. However, finding suitable alternatives to mitigate their impacts remained a challenge. Metal-organic frameworks (MOFs) are one of the advanced materials with unique features such as high porosity and stability which exhibit versatile applications in environmental remediation. Their composites with titanium oxide nanoparticles (TiO2) have been discovered to offer potential feature such as light harvesting capacity and catalytic activity. The composite integration and properties have been confirmed through characterization using surface area analysis, scanning electron/transmission electron microscopy, atomic force microscopy, fourier transformed infrared spectroscopy, X-ray diffraction analysis, X-ray photoelectron spectroscopy, thermogravimetric analysis, and others. Thus, this work rigorously discussed potential applications of the MOF@TiO2 nanomaterials for the CO2 capture and effective utilization in methanol, ethanol, acetone, acetaldehyde, and other useful products that served as fuel to various industrial processes. Additionally, the work highlights the effective performance of the materials towards photocatalytic degradation of both organic and inorganic pollutants with indepth mechanistic insights. The article will offer significant contribution for the development of sustainable and efficient technologies for the environmental monitoring and pollution mitigation.
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  • 文章类型: Journal Article
    目的:吸入空气中的污染物在自然和建筑环境中无处不在;然而,暴露在不同的生命周期中是不同的,对个人来说是独一无二的。这里,我们回顾了空气污染物暴露的精神健康结果之间的联系,生物炎症机制,并为研究人员和政策制定者提供未来的方向。讨论了心理健康结果与《清洁空气法》标准污染物之间的关联,与交通有关的空气污染物,杀虫剂,重金属,喷气燃料,烧坑。
    结果:尽管空气中的污染物与负面身体健康结果之间的关联一直是以前研究的主题,强调暴露与心理健康之间关联的工作才刚刚开始出现。关于标准污染物和精神健康结果的研究有迄今为止最有力的结果,其次是与交通有关的空气污染物,然后是杀虫剂。相比之下,对重金属的暴露进行了稀缺的心理健康研究,喷气燃料,烧坑。特定的个体群体,例如美国军事成员,反过来,退伍军人,通常有独特的曝光历史,包括与服务相关的飞机(例如喷气燃料)和燃烧坑。需要针对退伍军人和其他暴露可能性增加且更容易受到负面心理健康结果影响的个人进行研究。未来的研究将促进旨在预防和干预的知识,以改善军事人员的身心健康,退伍军人,和其他有风险的人。
    Inhalation of airborne pollutants in the natural and built environment is ubiquitous; yet, exposures are different across a lifespan and unique to individuals. Here, we reviewed the connections between mental health outcomes from airborne pollutant exposures, the biological inflammatory mechanisms, and provide future directions for researchers and policy makers. The current state of knowledge is discussed on associations between mental health outcomes and Clean Air Act criteria pollutants, traffic-related air pollutants, pesticides, heavy metals, jet fuel, and burn pits.
    Although associations between airborne pollutants and negative physical health outcomes have been a topic of previous investigations, work highlighting associations between exposures and psychological health is only starting to emerge. Research on criteria pollutants and mental health outcomes has the most robust results to date, followed by traffic-related air pollutants, and then pesticides. In contrast, scarce mental health research has been conducted on exposure to heavy metals, jet fuel, and burn pits. Specific cohorts of individuals, such as United States military members and in-turn, Veterans, often have unique histories of exposures, including service-related exposures to aircraft (e.g. jet fuels) and burn pits. Research focused on Veterans and other individuals with an increased likelihood of exposure and higher vulnerability to negative mental health outcomes is needed. Future research will facilitate knowledge aimed at both prevention and intervention to improve physical and mental health among military personnel, Veterans, and other at-risk individuals.
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  • 文章类型: Journal Article
    粉煤灰(CFA),煤燃烧的副产品,是一种有害的工业固体废物。其过度的全球生产,加上不当的处置做法,利用不足和对其固有危害的认识有限,对生态环境和人类健康都构成重大威胁。根据CFA及其渗滤液的理化性质,我们阐明了CFA的形式及其进入人体的潜在途径,以及浸出行为,CFA中存在的有毒元素的最大耐受性和生物半衰期。此外,我们概述了减轻CFA中这些有害元素浸出的当前策略和方法。此外,我们系统地总结了CFA对各种复杂生物的毒性作用,分析有关CFA暴露对人类健康影响的流行病学发现,并在细胞和分子水平上深入研究CFA及其渗滤液的生物毒理学机制。这篇综述旨在提高人们对CFA潜在毒性的认识。从而提高公众对这种工业废物处置和管理的认识。
    Coal fly ash (CFA), a byproduct of coal combustion, is a hazardous industrial solid waste. Its excessive global production, coupled with improper disposal practices, insufficient utilization and limited awareness of its inherent hazards, poses a significant threat to both ecological environment and human health. Based on the physicochemical properties of CFA and its leachates, we elucidate the forms of CFA and potential pathways for its entry into the human body, as well as the leaching behavior, maximum tolerance and biological half-life of toxic elements present in CFA. Furthermore, we provide an overview of current strategies and methods for mitigating the leaching of these harmful elements from CFA. Moreover, we systemically summarize toxic effect of CFA on organisms across various tiers of complexity, analyze epidemiological findings concerning the human health implications resulting from CFA exposure, and delve into the biotoxicological mechanisms of CFA and its leachates at cellular and molecular levels. This review aims to enhance understanding of the potential toxicity of CFA, thereby promoting increased public awareness regarding the disposal and management of this industrial waste.
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  • 文章类型: Journal Article
    从环境的角度来看,发展廉价是必不可少的,环保,以及用于水和废水处理的高效材料。在这方面,水凝胶和基于水凝胶的复合材料已被广泛用于减轻全球水污染,因为这种方法简单且不含有害副产物。值得注意的是,海藻酸盐和纤维素,它们是天然的碳水化合物聚合物,它们的可用性获得了极大的关注,价格竞争力,优异的生物降解性,生物相容性,亲水性,在水处理中具有优越的物理化学性能。这篇综述概述了开发和应用基于藻酸盐和纤维素的水凝胶去除染料等各种污染物的最新进展,重金属,油,药物污染物,和废水中的农药。这篇综述还强调了各种物理或化学方法的影响,如交联,嫁接,添加填料,纳米粒子掺入,和聚合物共混,水凝胶的物理化学和吸附性能。此外,这篇综述涵盖了基于藻酸盐和纤维素的水凝胶的当前局限性,例如机械性能低和稳定性差,同时提出了改善水凝胶缺点的策略。最后,我们讨论了基于藻酸盐和纤维素的水凝胶的前景和未来的方向。我们希望这篇综述对水凝胶的有效制备和应用提供有价值的见解。
    From the environmental perspective, it is essential to develop cheap, eco-friendly, and highly efficient materials for water and wastewater treatment. In this regard, hydrogels and hydrogel-based composites have been widely employed to mitigate global water pollution as this methodology is simple and free from harmful by-products. Notably, alginate and cellulose, which are natural carbohydrate polymers, have gained great attention for their availability, price competitiveness, excellent biodegradability, biocompatibility, hydrophilicity, and superior physicochemical performance in water treatment. This review outlined the recent progress in developing and applying alginate- and cellulose-based hydrogels to remove various pollutants such as dyes, heavy metals, oils, pharmaceutical contaminants, and pesticides from wastewater streams. This review also highlighted the effects of various physical or chemical methods, such as crosslinking, grafting, the addition of fillers, nanoparticle incorporation, and polymer blending, on the physiochemical and adsorption properties of hydrogels. In addition, this review covered the alginate- and cellulose-based hydrogels\' current limitations such as low mechanical performance and poor stability, while presenting strategies to improve the drawbacks of the hydrogels. Lastly, we discussed the prospects and future directions of alginate- and cellulose-based hydrogels. We hope this review provides valuable insights into the efficient preparations and applications of hydrogels.
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