Titanium dioxide (TiO2) based photocatalysts have been widely used as a photocatalyst for the degradation of various persistent organic compounds in water and air. The degradation mechanism involves the generation of highly reactive oxygen species, such as hydroxyl radicals, which react with organic compounds to break down their chemical bonds and ultimately mineralize them into harmless products. In the case of pharmaceutical and pesticide molecules, TiO2and modified TiO2photocatalysis effectively degrade a wide range of compounds, including antibiotics, pesticides, and herbicides. The main downside is the production of dangerous intermediate products, which are not frequently addressed in the literature that is currently available. The degradation rate of these compounds by TiO2photocatalysis depends on factors such as the chemical structure of the compounds, the concentration of the TiO2catalyst, the intensity, the light source, and the presence of other organic or inorganic species in the solution. The comprehension of the degradation mechanism is explored to gain insights into the intermediates. Additionally, the utilization of response surface methodology is addressed, offering a potential avenue for enhancing the scalability of the reactors. Overall, TiO2photocatalysis is a promising technology for the treatment of pharmaceutical and agrochemical wastewater, but further research is needed to optimize the process conditions and to understand the fate and toxicity of the degradation products.

There have been ever-growing demands for disinfection of water and air in recent years. Efficient, eco-friendly, and cost-effective methods of disinfection for pathogens are vital to the health of human beings. The photocatalysis route has attracted worldwide attention due to its highly efficient oxidative capabilities and sustainable recycling, which can be used to realize the disinfection purposes without secondary pollution. Though many studies have comprehensively reviewed the work about photocatalytic disinfection, including design and fabrication of photocatalytic coatings, inactivation mechanisms, or practical applications, systematic reviews about the disinfection photocatalysis coatings from fabrication to effort for practical use are still rare. Among different ways of fabricating photocatalytic materials, thermal spray is a versatile surface coating technique and competitive in constructing large-scale functional coatings, which is a most promising way for the future environmental purification, biomedical and life health applications. In this review, we briefly introduced various photocatalytic materials and corresponding inactivation mechanisms for virus, bacteria and fungus. We summarized the thermal-sprayed photocatalysts and their antimicrobial performances. Finally, we discussed the future perspectives of the photocatalytic disinfection coatings for potential applications. This review would shed light on the development and implementation of sustainable disinfection strategies that is applicable for extensive use for controlling pathogens in the near future.

The development of novel photocatalysts, both visible and UV-responsive, for water decomposition reactions is of great importance. Here we focused on the application of the borates as photocatalysts in water decomposition reactions, including water splitting reaction, hydrogen evolution half-reaction, and oxygen evolution half-reaction. In addition, the rates of photocatalytic hydrogen evolution and oxygen evolution by these borate photocatalysts in different water decomposition reactions were summarized. Further, the review summarized the synthetic chemistry and structural features of existing borate photocatalysts for water decomposition reactions. Synthetic chemistry mainly includes high-temperature solid-state method, sol-gel method, precipitation method, hydrothermal method, boric acid flux method, and high-pressure method. Next, we summarized the crystal structures of the borate photocatalysts, with a particular focus on the form of the B-O unit and metal-oxygen polyhedral in the borates, and used this to classify borate photocatalysts, which are rarely mentioned in the current photocatalysis literature. Finally, we analyzed the relationship between the structural features of the borate photocatalysts and photocatalytic performance to discuss the further challenges faced by the borate photocatalysts for water decomposition reactions.

Modern society pays further and further attention to environmental protection and the promotion of sustainable energy solutions. Heterogeneous photocatalysis is widely recognized as one of the most economically viable and ecologically sound technologies to combat environmental pollution and the global energy crisis. One challenge is finding a suitable photocatalytic material for an efficient process. Inorganic nanotubes have garnered attention as potential candidates due to their optoelectronic properties, which differ from their bulk equivalents. Among them, clay nanotubes (halloysite, imogolite, and chrysotile) are attracting renewed interest for photocatalysis applications thanks to their low production costs, their unique physical and chemical properties, and the possibility to functionalize or dope their structure to enhance charge-carriers separation into their structure. In this review, we provide new insights into the potential of these inorganic nanotubes in photocatalysis. We first discuss the structural and morphological features of clay nanotubes. Applications of photocatalysts based on clay nanotubes across a range of photocatalytic reactions, including the decomposition of organic pollutants, elimination of NOx, production of hydrogen, and disinfection of bacteria, are discussed. Finally, we highlight the obstacles and outline potential avenues for advancing the current photocatalytic system based on clay nanotubes. Our aim is that this review can offer researchers new opportunities to advance further research in the field of clay nanotubes-based photocatalysis with other vital applications in the future.

With the increasing popularity of photocatalytic technology and the highly growing issues of energy scarcity and environmental pollution, there is an increasing interest in extremely efficient photocatalytic systems. The widespread immense attention and applicability of Nb2O5 photocatalysts can be attributed to their multiple benefits, including strong redox potentials, non-toxicity, earth abundance, corrosion resistance, and efficient thermal and chemical stability. However, the large-scale application of Nb2O5 is currently impeded by the barriers of rapid recombination loss of photo-activated electron/hole pairs and the inadequacy of visible light absorption. To overcome these constraints, plentiful design strategies have been directed at modulating the morphology, electronic band structure, and optical properties of Nb2O5. The current review offers an extensive analysis of Nb2O5-based photocatalysts, with a particular emphasis on crystallography, synthetic methods, design strategies, and photocatalytic mechanisms. Finally, an outline of future research directions and challenges in developing Nb2O5-based materials with excellent photocatalytic performance is presented.

As society progresses and industrializes, the issue of water pollution, caused by a wide array of organic and inorganic pollutants, poses significant risks to both human well-being and the environment. Given its distinctive characteristics, water pollution has become a paramount concern for society, necessitating immediate attention. Numerous studies have been conducted on wastewater treatment, primarily focusing on two key approaches: adsorption and photocatalytic degradation. Adsorption offers unparalleled advantages, including its simplicity, high removal efficiency, and cost-effectiveness. Conversely, photocatalysis harnesses abundant, clean, and non-polluting sunlight, addressing the critical issue of energy scarcity. Porphyrins, which are macrocyclic tetrapyrrole derivatives found widely in nature, have attracted growing interest in recent years. These lipophilic pigments exhibit remarkable chemical stability and have retained their major structural features for up to 1.1 billion years. As such, they are considered vital indicators of life and have been extensively studied, from the remnants of extinct organisms to gain insights into the principles of evolution. Porphyrins are often associated with a central metal ion within their ring system and can be modified through various substituents, including additional rings or ring opening, resulting in a wide range of functionalities. This comprehensive review summarizes recent advancements in the field of porphyrins. It begins by introducing the structures and preparation methods of porphyrins. Subsequently, it delves into notable applications of porphyrins in the context of pollutant adsorption in water and their environmentally friendly photocatalytic degradation.

Over the last few decades, the global rise in energy demand has prompted researchers to investigate the energy requirements from alternative green fuels apart from the conventional fossil fuels, due to the surge in CO2 emission levels. In this context, the global demand for hydrogen is anticipated to extend by 4-5% in the next 5 years. Different production technologies like gasification of coal, partial oxidation of hydrocarbons, and reforming of natural gas are used to obtain high yields of hydrogen. In present time, 96% of hydrogen is produced by the conventional methods, and the remaining 4% is produced by the electrolysis of water. Photo-electrochemical (PEC) water splitting is a promising and progressive solar-to-hydrogen pathway with high conversion efficiency at low operating temperatures with substrate electrodes such as fluorine-doped tin oxide (FTO), incorporated with photocatalytic nanomaterials. Several semiconducting nanomaterials such as carbon nanotubes, TiO2, ZnO, graphene, alpha-Fe2O3, WO3, metal nitrides, metal phosphides, cadmium-based quantum dots, and rods have been reported for PEC water splitting. The design of photocatalytic electrodes plays a crucial role for efficient PEC water splitting process. By modifying the composition and morphology of photocatalytic nanomaterials, the overall solar-to-hydrogen (STH) energy conversion efficiency can be improved by optimizing their opto-electronic properties. The present article highlights the recent advancements in cleaner and effective photocatalysts for producing high yields of hydrogen via PEC water splitting.

Human existence and societal growth are both dependent on the availability of clean and fresh water. Photocatalysis is a type of artificial photosynthesis that uses environmentally friendly, long-lasting materials to address energy and environmental issues. There is currently a considerable demand for low-cost, high-performance wastewater treatment equipment. By changing the structure, size, and characteristics of nanomaterials, the use of nanotechnology in the field of water filtration has evolved dramatically. Semiconductor-assisted photocatalysis has recently advanced to become among the most promising techniques in the fields of sustainable energy generation and ecological cleanup. It is environmentally beneficial, cost-effective, and strictly linked to the zero waste discharge principle used in industrial effluent treatment. Owing to the reduction or removal of created unwanted byproducts, the green synthesis of photoactive nanomaterial is more beneficial than chemical synthesis approaches. Furthermore, unlike chemical synthesis methods, the green synthesis method does not require the use of expensive, dangerous, or poisonous ingredients, making it a less costly, easy, and environmental method for photocatalyst synthesis. This work focuses on distinct greener synthesis techniques utilized for the production of new photocatalysts, including metals, metal doped-metal oxides, metal oxides, and plasmonic nanostructures, including the application of artificial intelligence and machine learning to the design and selection of an innovative photocatalyst in the context of energy and environmental challenges. A brief overview of the industrial and environmental applications of photocatalysts is also presented. Finally, an overview and recommendations for future research are given to create photocatalytic systems with greatly improved stability and efficiency.

Over the past few decades, acetaminophen (ACT), a typical nonsteroidal anti-inflammatory drug (NSAID), has gained global usage, positioning itself as one of the most extensively consumed medications. However, the incomplete metabolism of ACT leads to a substantial discharge into the environment, classifying it as an environmental contaminant with detrimental effects on non-target organisms. Various wastewater treatment technologies have been developed for ACT removal to mitigate its potential environmental risk. Particularly, photocatalytic technology has garnered significant attention as it exhibits high efficiency in oxidizing and degrading a wide range of organic pollutants. This comprehensive review aims to systematically examine and discuss the application of photocatalytic technology for the removal of ACT from aqueous environments. Additionally, the study provides a detailed overview of the limitations associated with the photocatalytic degradation of ACT in practical applications, along with effective strategies to address these challenges.

Photocatalysis utilizing semiconductors offer a cost-effective and promising solution for the removal of pollutants. MXene and perovskites, which possess desirable properties such as a suitable bandgap, stability, and affordability, have emerged as a highly promising material for photocatalytic activity. However, the efficiency of MXene and perovskites is limited by their fast recombination rates and inadequate light harvesting abilities. Nonetheless, several additional modifications have been shown to enhance their performance, thereby warranting further exploration. This study delves into the fundamental principles of reactive species for MXene-perovskites. Various methods of modification of MXene-perovskite-based photocatalysts, including Schottky junction, Z-scheme and S-scheme are analyzed with regard to their operation, differences, identification techniques and reusability. The assemblance of heterojunctions is demonstrated to enhance photocatalytic activity while also suppressing charge carrier recombination. Furthermore, the separation of photocatalysts through magnetic-based methods is also investigated. Consequently, MXene-perovskite-based photocatalysts are seen as an exciting emerging technology that necessitates further research and development.