The binding between water components (dissolved organic matters, anions and cations) and pharmaceuticals influences the migration and transformation of pollutants. Herein, the impact of water matrices on drug degradation, as well as the electrical energy demands during UV, UV/catalysts, UV/O3, UV/H2O2-based, UV/persulfate and UV/chlorine processes were systemically evaluated. The enhancement effects of water constituents are due to the powerful reactive species formation, the recombination reduction of electrons and holes of catalyst and the catalyst regeneration; the inhibition results from the light attenuation, quenching effects of the excited states of target pollutants and reactive species, the stable complexations generation and the catalyst deactivation. The transformation pathways of the same pollutant in various AOPs have high similarities. At the same time, each oxidant also can act as a special nucleophile or electrophile, depending on the functional groups of the target compound. The electrical energy per order (EEO) of drugs degradation may follow the order of EEOUV > EEOUV/catalyst > EEOUV/H2O2 > EEOUV/PS > EEOUV/chlorine or EEOUV/O3. Meanwhile, it is crucial to balance the cost-benefit assessment and toxic by-products formation, and the comparison of the contaminant degradation pathways and productions in the presence of different water matrices is still lacking.

Anthocyanins are colored valuable biocompounds, of which extraction increases globally, although functional applications are restrained by their limited environmental stability. Temperature is a critical parameter of food industrial processing that impacts on the food matrix, particularly affecting heat-sensitive compounds such as anthocyanins. Due to the notable scientific progress in the field of thermal stability of anthocyanins, an analytical and synthetic integration of published data is required. This review focuses on the molecular mechanisms and the kinetic parameters of anthocyanin degradation during heating, both in extracts and real food matrices. Several kinetic models (Arrhenius, Eyring, Ball) of anthocyanin degradation were studied. Crude extracts deliver more thermally stable anthocyanins than purified ones. A different anthocyanin behavior pattern within real food products subjected to thermal processing has been observed due to interactions with some nutrients (proteins, polysaccharides). The most recent studies on the stabilization of anthocyanins by linkages to other molecules using classical and innovative methods are summarized. Ensuring appropriate thermal conditions for processing anthocyanin-rich food will allow a rational design for the future development of stable functional products, which retain these bioactive molecules and their functionalities to a great extent.

High levels of toxic organic pollutants commonly detected during domestic/industrial wastewater treatment have been attracting research attention globally because they seriously threaten human health. Sulfate-radical-based advanced oxidation processes (SR-AOPs) have been successfully used in wastewater treatment, such as that containing antibiotics, pesticides, and persistent organic pollutants, for refractory contaminant degradation. This review summarizes activation methods, including physical, chemical, and other coupling approaches, for efficient generation of sulfate radicals and evaluates their applications and economic feasibility. The degradation behavior as well as the efficiency of the generated sulfate radicals of typical domestic and industrial wastewater treatment is investigated. The categories and characteristics of the intermediates are also evaluated. The role of sulfate radicals, their kinetic characteristics, and possible mechanisms for organic elimination are assessed. In the last section, current difficulties and future perspectives of SR-AOPs for wastewater treatment are summarized.