有史以来最迷人的2D纳米材料(NMs)之一是MXene家族的各种成员。其中,钛基MXenes,超过70%的出版物相关调查,比较好的研究,为具有灵活特性的2DMXene家族成员提供基础,熟悉各种先进的新颖技术应用。尽管如此,过渡金属(TMs)中还有更多的候选者可以作为MXeneNMs,其作用方式远远超出了现在公认的范围。系统化的准备细节,特点,局限性,重大发现,以及新型M基MXenes(M-MXenes)的用途,其中M代表非TiTM(M=Sc,V,Cr,Y,Zr,Nb,Mo,Hf,Ta,W,和Lu),是给定的。2D非TiMXene的卓越品质在多种应用中优于标准Ti-MXene。MXenes家族成员的自上而下和自下而上的生产有很多进步,这允许精确控制M特性MXeneNMs以包含尖端应用。本研究对现有研究进行了系统评价,涵盖生产复杂的M-MXenes的所有内容,从主要限制到根据其新颖特征对其应用进行表征和选择。双金属组合的发展,将其他候选金属扩展到组-(III-VI)B族之外,和2DTM碳化物/TM氮化物/TM碳氮化物到2D金属硼化物家族的后续发展也包括在此概述中。非TiMXeneNMs合成方法的可能性和进一步建议将在此关键评估中详细讨论。
One of the most fascinating 2D nanomaterials (NMs) ever found is various members of MXene family. Among them, the titanium-based MXenes, with more than 70% of publication-related investigations, are comparatively well studied, producing fundamental foundation for the 2D MXene family members with flexible properties, familiar with a variety of advanced novel technological applications. Nonetheless, there are still more candidates among transitional metals (TMs) that can function as MXene NMs in ways that go well beyond those that are now recognized. Systematized details of the preparations, characteristics, limitations, significant discoveries, and uses of the novel M-based MXenes (M-MXenes), where M stands for non-Ti TMs (M = Sc, V, Cr, Y, Zr, Nb, Mo, Hf, Ta, W, and Lu), are given. The exceptional qualities of the 2D non-Ti MXene outperform standard Ti-MXene in several applications. There is many advancement in top-down as well as bottom-up production of MXenes family members, which allows for exact control of the M-characteristics MXene NMs to contain cutting-edge applications. This study offers a systematic evaluation of existing research, covering everything in producing complex M-MXenes from primary limitations to the characterization and selection of their applications in accordance with their novel features. The development of double metal combinations, extension of additional metal candidates beyond group-(III-VI)B family, and subsequent development of the 2D TM carbide/TMs nitride/TM carbonitrides to 2D metal boride family are also included in this overview. The possibilities and further recommendations for the way of non-Ti MXene NMs are in the synthesis of NMs will discuss in detail in this critical evaluation.