wear resistance

耐磨性
  • 文章类型: Journal Article
    已知铜(Cu)的导电性使其成为工业中使用的理想材料。由于硬度等性能差,热膨胀,和耐腐蚀性,它的应用是有限的。该手稿解决了这些问题,同时保持导电性没有击穿。在这项研究中,高强度陶瓷(SiC纳米颗粒和石墨烯纳米片)被用作增强材料,使用粉末冶金技术制造铜基杂化纳米复合材料。X射线衍射分析(XRD)用于研究研磨粉末的相组成和晶体尺寸。透射电子显微镜(TEM)和场发射扫描电子显微镜(FESEM),分别检查了制备的粉末粉末和烧结纳米复合材料的微观结构。然后,测量烧结样品的各种性能,包括身体,电气和热性能和耐磨性。获得的XRD技术和TEM图像显示研磨样品的晶体和粒径减小,达到14.08和28.30nm,分别为样品含有8体积。%SiC+0.8vol.%石墨烯(SG8)。显微硬度高达809.15、341.84MPa和336.56GPa的机械性能令人惊讶的改善,含有最高增强材料的样品的强度和纵向模量,与Cu基体相比,实现了高达122、61.37和41%的改进。此外,通过增加所检查的烧结纳米复合材料样品中混合增强材料的百分比,样品的热膨胀系数(CTE)和磨损率值显着改善。样本SG8记录的最低值,与SG1样本相比,下降了约50.2%和76.5%。最后,向Cu基体中添加增强材料对相对密度和电导率有负面影响,最低值为92.94%和8.59×106S/m,分别为SG样本。
    It is known that Copper\'s (Cu) electrical conductivity makes it a desirable material for use in industry. Due to poor properties such as hardness, thermal expansion, and corrosion resistance, its applications are limited. This manuscript solves these problems while maintaining no breakdown in electrical conductivity. In this study, high-strength ceramics (SiC nanoparticles and graphene nanosheets) were used as reinforcements in the manufacture of Cu-based hybrid nanocomposites using powder metallurgy technique. X-ray diffraction analysis (XRD) was used to investigate phase composition and crystal size of the milled powders. Transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM), respectively examined the microstructure of the prepared powder powders and sintered nanocomposites. Then, various properties of the sintered samples are measured, including physical, electrical and thermal properties and wear resistance. The obtained XRD technique and TEM images showed decreases in the crystal and particle size of milled samples reaching up to 14.08 and 28.30 nm, respectively for the sample contained 8 vol. % SiC + 0.8 vol. % graphene (SG8). A surprising improvement in the mechanical properties of up to 809.15, 341.84 MPa and 336.56 GPa for microhardness, strength and longitudinal modulus for the sample containing the highest reinforcements, achieving an improvement of up to 122, 61.37 and 41 percent compared to the Cu matrix. Moreover, there was a noticeable improvement in the coefficient of thermal expansion (CTE) and wear rate values of the samples by increasing the percentages of hybrid reinforcements in the examined sintered nanocomposite samples. The Sample SG8 recorded the lowest value, decreasing by about 50.2 and 76.5% compared to the SG1 sample. Finally, adding reinforcements to the Cu matrix had a negative effect on the relative density and electrical conductivity, and the lowest values was 92.94% and8.59 × 106 S/m, respectively for the SG sample.
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  • 文章类型: Journal Article
    为了提高激光重熔后铜的表面质量,本文取激光频率,脉冲宽度,和能量密度为研究对象,采用扫描电子显微镜(SEM),激光共焦三维测量仪,硬度计,和摩擦磨损测量仪来研究表面形貌,表面粗糙度,显微硬度,和铜的耐磨性,分别。结果表明,频率,脉冲宽度,激光重熔的能量密度直接影响样品的表面质量,但频率和脉冲宽度的影响更为显著。当激光重熔频率为10Hz时,脉冲宽度为10ms,能量密度为132.69J/mm2,样品表面形貌良好,粗糙度,和耐磨性。本文的相关研究可以为铜基材料的激光表面处理提供很好的参考。
    In order to improve the surface quality of copper after laser remelting, this article took laser frequency, pulse width, and energy density as the research objects and used scanning electron microscopy (SEM), a laser confocal three-dimensional measurement instrument, hardness tester, and friction and wear measurement instrument to study the surface morphology, surface roughness, microhardness, and wear resistance of copper, respectively. The results indicate that the frequency, pulse width, and energy density of laser remelting could directly affect the surface quality of the sample, but the influence of frequency and pulse width was more significant. When the laser remelting frequency was 10 Hz, the pulse width was 10 ms, and the energy density was 132.69 J/mm2, the sample exhibited good surface morphology, roughness, and wear resistance. The relevant research in this article can provide a good reference for the laser surface treatment of copper-based materials.
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  • 文章类型: Journal Article
    这项研究考察了不同添加水平的钨(W)含量对微观结构的影响,耐腐蚀性,耐磨性,显微硬度,以及使用激光熔覆技术由FeCoCrNiAl高熵合金(HEA)制成的涂层的相组成。使用预设的粉末方法,FeCoCrNiAlWx(其中x表示W的摩尔分数,x=0.0、0.2、0.4、0.6、0.8)将HEA涂层包覆在45钢的表面上。采用往复式摩擦磨损试验机对不同覆层材料进行干摩擦试验。随后,微观结构的详细分析,相组成,耐腐蚀性,磨损痕迹,使用扫描电子显微镜(SEM)进行硬度特性,X射线衍射仪(XRD),电化学工作站,和显微硬度计。结果表明,随着W含量的增加,FeCoCrNiAlWxHEA包层涂层的宏观形貌劣化;FeCoCrNiAlWxHEA包层涂层的微观结构,由μ相和面心立方固溶体组成,经历了从树枝状晶体到细胞晶体的进化过程。值得注意的是,随着W含量的增加,熔覆层的平均显微硬度呈现显著上升趋势,FeCoCrNiAlW0.8的平均硬度达到756.83HV0.2,是45钢基体的2.97倍。同时,包覆层的摩擦系数逐渐减小,表明增强的耐磨性。具体来说,FeCoCrNiAlW0.6和FeCoCrNiAlW0.8的摩擦系数相似,大约0.527摩擦磨损机理主要为粘着磨损和磨料磨损。在3.5wt。%NaCl溶液,W含量的增加导致包层涂层的腐蚀电位发生正变化。FeCoCrNiAlW0.8的腐蚀电位比FeCoCrNiAl的腐蚀电位高约403mV。腐蚀电流密度从5.43×10-6A/cm2显着降低到5.26×10-9A/cm2,这表明包层涂层的耐腐蚀性显着提高。
    This study examines the effects of different addition levels of tungsten (W) content on the microstructure, corrosion resistance, wear resistance, microhardness, and phase composition of coatings made from FeCoCrNiAl high-entropy alloy (HEA) using the laser cladding technique. Using a preset powder method, FeCoCrNiAlWx (where x represents the molar fraction of W, x = 0.0, 0.2, 0.4, 0.6, 0.8) HEA coatings were cladded onto the surface of 45 steel. The different cladding materials were tested for dry friction by using a reciprocating friction and wear testing machine. Subsequently, the detailed analysis of the microstructure, phase composition, corrosion resistance, wear traces, and hardness characteristics were carried out using a scanning electron microscope (SEM), X-ray diffractometer (XRD), electrochemical workstation, and microhardness tester. The results reveal that as the W content increases, the macro-morphology of the FeCoCrNiAlWx HEA cladding coating deteriorates; the microstructure of the FeCoCrNiAlWx HEA cladding coating, composed of μ phase and face-centered cubic solid solution, undergoes an evolution process from dendritic crystals to cellular crystals. Notably, with the increase in W content, the average microhardness of the cladding coating shows a significant upward trend, with FeCoCrNiAlW0.8 reaching an average hardness of 756.83 HV0.2, which is 2.97 times higher than the 45 steel substrate. At the same time, the friction coefficient of the cladding coating gradually decreases, indicating enhanced wear resistance. Specifically, the friction coefficients of FeCoCrNiAlW0.6 and FeCoCrNiAlW0.8 are similar, approximately 0.527. The friction and wear mechanisms are mainly adhesive and abrasive wear. In a 3.5 wt.% NaCl solution, the increase in W content results in a positive shift in the corrosion potential of the cladding coating. The FeCoCrNiAlW0.8 exhibits a corrosion potential approximately 403 mV higher than that of FeCoCrNiAl. The corrosion current density significantly decreases from 5.43 × 10-6 A/cm2 to 5.26 × 10-9 A/cm2, which suggests a significant enhancement in the corrosion resistance of the cladding coating.
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  • 文章类型: Journal Article
    为了提高工程机械叶片材料的耐磨性,这项研究的重点是微观结构特征,机械性能,使用优化的热处理系统开发的HB500级耐磨钢的磨损行为。为了提高热处理炉的温度均匀性,采用循环加热的方法对部件进行加热。精心设计淬火设备,例如使用十字形压力机,用于增强淬火效果并减少钢板的变形。晶体取向分析显示出均匀且细晶的微观结构,主要特征是板状回火马氏体,这表明了良好的淬透性。显微组织观察表明,马氏体的宽度约为200nm,有明显的位错和碳化物的存在。拉伸试验和多温度梯度冲击试验表明,与类似等级的耐磨钢相比,机械性能优异。包括洛氏硬度为53,抗拉强度为1610兆帕,1404MPa的屈服强度,和总伸长率约12.7%。摩擦磨损实验结果表明,随着载荷从100N增加到300N,磨损率降低,在大载荷下表现出优异的耐磨性。对磨损表面的观察表明,磨损主要涉及粘着磨损,疲劳磨损,和氧化磨损。性能的改善归因于微观结构的细化和沉淀强化。研究表明,设计一种控制温度均匀性和稳定性的热处理系统是可行的。
    To improve the wear resistance of the materials used for blades in engineering machinery, this study focused on the microstructural characteristics, mechanical properties, and wear behavior of HB500 grade wear-resistant steel developed using an optimized heat treatment system. To improve the temperature uniformity of the heat treatment furnace, the method of cyclic heating was used to heat the components. Carefully designing the quenching equipment, such as using a cross-shaped press, was employed to enhance the quenching effect and reduce the deformation of the steel plates. The crystal orientation analysis revealed a uniform and fine-grained microstructure, primarily characterized by plate-type tempered martensite, which indicated a good hardenability. The microstructure observations showed that the width of martensite is approximately 200 nm, with a significant presence of dislocations and carbides. Tensile tests and multi-temperature gradient impact tests indicated superior mechanical properties compared to similar grade wear-resistant steels, including a Rockwell hardness of 53, tensile strength of 1610 MPa, yield strength of 1404 MPa, and total elongation around 12.7%. The results of friction and wear experiments indicate that the wear rate decreases as the load increases from 100 N to 300 N, demonstrating an excellent wear resistance under a large load. Observations of the worn surfaces indicated that the wear mainly involved adhesive wear, fatigue wear, and oxidative wear. The properties\' improvements were attributed to microstructure refinement and precipitation strengthening. This study indicates that designing a heat treatment system to control temperature uniformity and stability is feasible.
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  • 文章类型: Journal Article
    在惰性橡胶和塑料表面上润滑水凝胶涂层显着减少摩擦和磨损,从而提高材料的耐久性和寿命。然而,实现最佳水合润滑通常需要多孔聚合物网络,不幸的是,这降低了它们的机械强度,并限制了它们在坚固的耐用性和耐磨性至关重要的地方的适用性。在研究中,通过与聚合物基材在界面处形成半互穿聚合物网络,开发了具有显着的耐磨性和表面稳定性的水凝胶涂层。通过采用良好的溶剂溶胀法,单体,和光引发剂嵌入在基底表面下,然后在紫外光下进行原位聚合,创造了一个强大的半互穿和纠缠的网络结构。这种方法,提供更厚的能量耗散层,在保持抗疲劳的同时,在耐磨性方面优于传统的表面改性,亲水性,疏油性,和其他属性。通过使用合适的溶剂适应各种橡胶和塑料基材,此方法为创建持久的,润滑表面,扩大在多个行业的潜在应用。
    Lubricating hydrogel coatings on inert rubber and plastic surfaces significantly reduce friction and wear, thus enhancing material durability and lifespan. However, achieving optimal hydration lubrication typically requires a porous polymer network, which unfortunately reduces their mechanical strength and limits their applicability where robust durability and wear-resistance are essential. In the research, a hydrogel coating with remarkable wear resistance and surface stability is developed by forming a semi-interpenetrating polymer network with polymer substrate at the interface. By employing a good solvent swelling method, monomers, and photoinitiators are embedded within the substrates\' subsurface, followed by in situ polymerization under ultraviolet light, creating a robust semi-interpenetrating and entangled network structure. This approach, offering a thicker energy-dissipating layer, outperforms traditional surface modifications in wear resistance while preserving anti-fatigue, hydrophilicity, oleophobicity, and other properties. Adaptable to various rubber and plastic substrates by using suitable solvents, this method provides an efficient solution for creating durable, lubricating surfaces, broadening the potential applications in multiple industries.
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  • 文章类型: Journal Article
    旋转的杯子,纺织设备的重要组成部分,严重依赖2A12铝合金作为其主要原材料。通常,采用电镀和化学镀镍-磷(Ni-P)来改善物体的表面特性。然而,由于人们对铝合金性能的期望越来越高,Ni-P涂层的硬度和耐磨性不再足以满足工业标准。本研究主要集中在Ni-B-PTFE纳米复合化学镀的合成及其应用于2A12铝合金表面时的有效性。我们检查了镀液成分的影响,工艺参数,以及涂层沉积速度的各种其他因素,表面的硬度,和其他指标的涂层。研究结果表明,当满足以下条件时,复合共沉积涂层达到最佳的表面形貌:氯化镍浓度为30g/L,乙二胺浓度为70毫升,硼氢化钠浓度为0.6g/L,氢氧化钠浓度为90g/L,硝酸铅浓度为30毫升,pH值为12,温度为90°C,PTFE浓度为10mL/L涂层表现出一致性,密度,光滑的表面,没有明显的毛孔或裂缝。复合共沉积涂层的表面硬度为1109HV0.1,显著超过基材的232.38HV0.1硬度。Ni-B-PTFE复合涂层的平均摩擦系数约为0.12。它的划痕宽度为855.18μm,磨损质量为0.05mg。当与Ni-B涂层相比时,该涂层表现出优异的耐磨性。Ni-B-PTFE复合涂层试样的自腐蚀电位为-6.195V,腐蚀电流密度为7.81×10-7A/cm2,是最低记录。与Ni-B涂层相比,这增强了其耐腐蚀性。
    The spinning cup, a crucial component of textile equipment, relies heavily on 2A12 aluminum alloy as its primary raw material. Commonly, electroplating and chemical nickel-phosphorus (Ni-P) plating are employed to improve the surface characteristics of the object. Nevertheless, due to the growing expectations for the performance of aluminum alloys, the hardness and wear resistance of Ni-P coatings are no longer sufficient to fulfill industry standards. This study primarily focuses on the synthesis of Ni-B-PTFE nanocomposite chemical plating and its effectiveness when applied to the surface of 2A12 aluminum alloy. We examine the impact of the composition of the plating solution, process parameters, and various other factors on the pace at which the coating is deposited, the hardness of the surface, and other indicators of the coating. The research findings indicate that the composite co-deposited coating achieves its optimal surface morphology when the following conditions are met: a nickel chloride concentration of 30 g/L, an ethylenediamine concentration of 70 mL, a sodium borohydride concentration of 0.6 g/L, a sodium hydroxide concentration of 90 g/L, a lead nitrate concentration of 30 mL, a pH value of 12, a temperature of 90 °C, and a PTFE concentration of 10 mL/L. The coating exhibits consistency, density, a smooth surface, and an absence of noticeable pores or fissures. The composite co-deposited coating exhibits a surface hardness of 1109 HV0.1, which significantly surpasses the substrate\'s hardness of 232.38 HV0.1. The Ni-B-PTFE composite coating exhibits an average friction coefficient of around 0.12. It has a scratch width of 855.18 μm and a wear mass of 0.05 mg. This coating demonstrates superior wear resistance when compared to Ni-B coatings. The Ni-B-PTFE composite coating specimen exhibits a self-corrosion potential of -6.195 V and a corrosion current density of 7.81 × 10-7 A/cm2, which is the lowest recorded. This enhances its corrosion resistance compared to Ni-B coatings.
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  • 文章类型: Journal Article
    在这项研究中,微观结构特性,耐磨性,H111热轧AA5754合金热处理前的腐蚀行为,均质化后,并在老化后进行了检查。微观结构主要由基体上黑色和灰色对比颗粒的分散形式组成,在晶粒边界处观察到沉淀。轧制后的材料表现出致密的薄饼状晶粒结构,这是典型的轧制材料。沿L方向的观察没有在晶粒之间产生明显的分界,并且分布不均匀。晶界有沉淀物。当他们变老时,该区域中细而巨大的黑色和灰色对比颗粒平行增加。因此,可以说,由于均匀化过程的增加,细晶粒的数量增加了。发现具有晶粒取向的轧制母材平行于轧制方向。另一方面,在时效热处理条件下清楚地观察到粗晶粒。晶粒具有与热处理过程之前金属的轧制过程一致的细长形态。时效合金的硬度最高,为86.83HB;热处理前的合金硬度最低,为68.67HB。该材料在10,000m末的重量损失和磨损率为,分别,1.01×10-3g和5.07×10-9g/Nm。观察到该合金在热处理之前具有最高的重量损失和最差的耐磨性。10,000m末的重量损失和磨损率为,分别,3.42×10-3g和17.08×10-9g/Nm。根据这些结果,磨损时的摩擦系数是平行的,老化后摩擦系数最低的材料为0.045。虽然老化后腐蚀的合金显示出更多的重量损失,热处理前腐蚀的合金表现出更好的腐蚀行为。在合金中,在热处理前腐蚀的合金中观察到24小时后的最小重量损失,该值为0.69×10-3mg/dm2。在时效合金中观察到最高的重量损失,值为1.37×10-3mg/dm2。热处理前的合金,铸造后腐蚀,在72h后显示出最低的腐蚀速率,值为0.39×10-3mg/(dm2·day)。热处理前腐蚀的合金在-586±0.04μA/cm2的电流密度下产生1.04±1.5V的腐蚀电位,表现出最佳的腐蚀行为。然而,老化后,腐蚀的合金在-880±0.01μA/cm2的电流密度下表现出最差的腐蚀行为,腐蚀电位为5.16±3.3V。
    In this study, the microstructural properties, wear resistance, and corrosion behavior of H111 hot-rolled AA5754 alloy before heat treatment, after homogenization, and after aging were examined. The microstructure was mainly composed of the scattered forms of black and gray contrast particles on the matrix and precipitations were observed at the boundaries of the grain. The as-rolled material exhibited a dense pancake-shaped grain structure, which is typical of as-rolled material. Observation along the L-direction did not yield distinct demarcations among the grains and was not uniformly distributed, with precipitates at the grain boundary. When they aged, there was a parallel increase in fine and huge black and gray contrast particles in the zone. Therefore, it could be stated that the amount of fine grains increased due to the rise in the homogenization process. The rolled base metal with the grain orientation was found to be parallel to the rolling direction. On the other hand, the coarse grains were clearly observed in the aging heat-treatment condition. The grains had an elongated morphology consistent with the rolling process of the metal before the heat-treatment process. The aged alloy had the highest hardness with a value of 86.83 HB; the lowest hardness was seen in the alloy before heat treatment with a value of 68.67 HB. The weight loss and wear rate of this material at the end of 10,000 m were, respectively, 1.01 × 10-3 g and 5.07 × 10-9 g/Nm. It was observed that the alloy had the highest weight loss and worst wear resistance before heat treatment. Weight loss and wear rates at the end of 10,000 m were, respectively, 3.42 × 10-3 g and 17.08 × 10-9 g/Nm. According to these results, the friction coefficients during wear were parallel and the material with the lowest friction coefficient after aging was 0.045. While the alloys corroded after aging showed more weight loss, the alloys corroded before heat treatment exhibited better corrosion behavior. Among the alloys, the least weight loss after 24 h was observed in the alloy that was corroded before heat treatment and this value was 0.69 × 10-3 mg/dm2. The highest weight loss was observed in the aged alloy with a value of 1.37 × 10-3 mg/dm2. The alloy before heat treatment, which corroded after casting, showed the lowest corrosion rate with a value of 0.39 × 10-3 mg/(dm2·day) after 72 h. The alloy that was corroded before heat treatment showed the best corrosion behavior by creating a corrosion potential of 1.04 ± 1.5 V at a current density of -586 ± 0.04 μA/cm2. However, after aging, the corroded alloy showed the worst corrosion behavior with a corrosion potential of 5.16 ± 3.3 V at a current density of -880 ± 0.01 μA/cm2.
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  • 文章类型: Journal Article
    通过粉末冶金生产了ZrB2-铜-石墨复合材料,并作为新的电刷材料进行了测试。本文旨在研究ZrB2的加入对复合材料性能的影响。除了它的物理性质,如密度和电阻率,其机械性能,如硬度,抗弯强度和耐磨性,被研究过。使用扫描电子显微镜(SEM)研究了磨损表面的形貌,并使用配置的能量色散光谱仪(EDS)研究样品的化学成分。结果表明,随着ZrB2的加入,复合材料的性能,如密度,电阻率,硬度,弯曲强度明显提高。与不含ZrB2的样品相比,加入4%ZrB2的样品硬度达到87.5HRA,提高了45.8%,弯曲强度为53.1MPa,增加了近50.0%。ZrB2含量为1%的复合材料在非导电摩擦下显示出最佳的耐磨性;但是,在导电摩擦下,ZrB2含量为4%的复合材料表现出更好的耐磨性。
    A ZrB2-copper-graphite composite was produced through powder metallurgy and was tested as a new electric brush material. The aim of this paper was to study the effect of ZrB2 addition on the composite\'s properties. Besides its physical properties such as density and resistivity, its mechanical properties, such as hardness, bending strength and wear resistance, were studied. A scanning electron microscope (SEM) was used to study the morphology of the wear surface, and a configured energy-dispersive spectrometer (EDS) was used to research the chemical composition of the samples. The results showed that, with the addition of ZrB2, the composite\'s properties such as density, resistivity, hardness, and bending strength improved significantly. Compared with samples without ZrB2, samples with the addition of 4% ZrB2 achieved a hardness of 87.5 HRA, which was improved by 45.8%, and a bending strength of 53.1 MPa, which was increased by nearly 50.0%. Composites with 1% content of ZrB2 showed the best wear resistance under non-conductive friction; however, under conductive friction, composites with 4% content of ZrB2 showed better wear resistance.
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  • 文章类型: Journal Article
    在涉及材料研磨的工业和实验室过程中,研磨介质承受长时间的高碰撞和摩擦环境,导致大量的磨损。因此,本研究采用粉末冶金热压烧结技术制备SiC增强铁基耐磨复合研磨介质,旨在提高磨损性能。为此,将具有10重量%SiC粉末的Fe研磨用于制造复合材料。然后,在炉中通过在1100°C的热压进行烧结。采用扫描电子显微镜(SEM)和X射线衍射研究了SiC增强铁基复合材料的微观结构和物相。随后,在磨损率和研磨效率方面,对新开发的研磨介质和传统的铬基介质进行了比较性能评估。耐磨性测试表明,与含铬替代品相比,SiC增强的复合介质在各种磨料中显示出明显优异的耐磨性。具体来说,复合介质在1小时内对标准砂的磨损率降低了2.9倍,砂岩和铁渣的2.3和2.4倍,分别。此外,延长3小时的研磨将这些减少进一步增加到3.1、2.4和2.7倍,分别。此外,效率评估表明,在1:1的材料比下,复合介质的研磨效率优于含铬介质7.5%,12.5%,标准砂为10.3%,砂岩,和铁渣,分别。进一步将材料比提高到3:1,效率提高了7.4%,17.5%,和11.3%,相应地。
    During industrial and laboratory processes involving material grinding, the grinding media endure prolonged high-collision and friction environments, resulting in substantial wear. Consequently, this study adopts the hot-pressing sintering technique in powder metallurgy to prepare SiC-reinforced Fe-based wear-resistant composite grinding media, aiming to increase wear performance. For this purpose, Fe with 10 wt% SiC powders were milled for the fabrication of the composite. Then, sintering was performed by hot press at 1100 °C in a furnace. Scanning electron microscopy (SEM) and X-ray diffraction were employed to investigate the microstructures and phase of SiC-reinforced Fe-based matrix composite. Subsequently, comparative performance evaluations of the newly developed grinding media and traditional chromium-based media were conducted in terms of wear rate and grinding efficiency. The wear resistance tests revealed that the SiC-reinforced composite media displayed significantly superior wear resistance across various abrasives compared to the chromium-containing alternatives. Specifically, the composite media achieved a wear rate reduction of 2.9 times against standard sand over 1 h, and 2.3 and 2.4 times against sandstone and iron slag, respectively. Moreover, extended grinding for 3 hours further enhanced these reductions to 3.1, 2.4, and 2.7 times, respectively. Additionally, efficiency assessments indicated that at a 1:1 material ratio, the composite media outperformed the chromium-containing media in grinding efficiency by 7.5%, 12.5%, and 10.3% for standard sand, sandstone, and iron slag, respectively. Further increasing the material ratio to 3:1 resulted in efficiency improvements of 7.4%, 17.5%, and 11.3%, correspondingly.
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  • 文章类型: Journal Article
    系统研究了添加Si对CoCrNi中熵合金(MEA)组织和性能的影响。当x小于0.3时,CrCoNiSixMEA具有单面心立方(FCC)相,并促进溶液强化,而当x=0.4时,晶体结构显示出向FCCσ相结构的转变,并且σ相的体积分数随着Si含量的增加而随微观结构的演变而增加。来自σ沉淀的Orowan机制有效地增强了强度,硬度,和CrCoNiSixMEA的污点硬化,在高温下也表现出优异的硬度。此外,大量的σ相降低了耐磨性,因为主要磨损机理从无σ的CrCoNiSixMEA的磨损转变为含σ的CrCoNiSixMEA的粘附磨损。这项工作有助于了解添加Si对FCC结构合金的影响,并为开发新型Si掺杂合金提供指导。
    The effects of Si addition on the microstructures and properties of CoCrNi medium-entropy alloy (MEA) were systematically investigated. The CrCoNiSix MEA possesses a single face-centered cubic (FCC) phase when x is less than 0.3 and promotes solution strengthening, while the crystal structure shows a transition to the FCC+σ phase structure when x = 0.4 and the volume fraction of the σ phase increases with a microstructure evolution as the Si content increases. The Orowan mechanism from σ precipitation effectively enhances the strength, hardness, and stain hardening of CrCoNiSix MEA, which also exhibits superior hardness at high temperatures. Furthermore, a large amount of σ phase decreases the wear resistance because of the transformation of the main wear mechanism from abrasion wear for σ-free CrCoNiSix MEA to adhesion wear for σ-contained CrCoNiSix MEA. This work contributes to the understanding of the effect of Si addition on FCC structured alloys and provides guidance for the development of novel Si-doped alloys.
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