upcycling

提升循环
  • 文章类型: Journal Article
    The aim of the research problem of the article was to try to popularize the upcycling trend in the production of sustainable cosmetics and to confirm their effectiveness. The development of recycled raw materials is a new discovery in the chemical industry. Manufacturers emphasize the production of more environmentally friendly raw materials. Conscious consumers choose cosmetics whose production is based on sustainable development. Instead of throwing away waste from various industries, let us use it to produce active substances used in hair cosmetics. The production of the collagen series was created in accordance with the principles of upcycling, which involves obtaining collagen water, which is waste generated during the production of supplements. The main goal of the work was to learn cosmetic recipes for styling, washing and conditioning hair based on collagen waste, as well as to compare the results of people using the product in question. The aim of the study was also to demonstrate the effectiveness of the treatment in preventing split ends and hair breakage, usually caused by mechanical stress (brushing), as well as to confirm the effectiveness of other tests. The article presents procedures and parameters confirming the effectiveness of treatment with the tested hair products. The following tests were carried out: hair thickness and density, colour uniformity, shine factor and scalp hydration. All parameters numerically confirmed the beneficial effects of products containing collagen water used in hair care.
    L\'objectif Synthèse: de l\'article était de vulgariser la tendance de l\'upcycling dans la production de cosmétiques durables et de confirmer leur efficacité. Le développement de matières premières recyclées est une nouvelle découverte dans l\'industrie chimique. Les fabricants mettent l\'accent sur la production de matières premières plus respectueuses de l\'environnement. Les consommateurs responsables vont choisir des cosmétiques dont la production s\'appuie sur des principes de développement durable. Les déchets provenant de diverses industries peuvent servir à la fabrication de substances actives utilisées dans les produits de soins des cheveux. La fabrication de produits à base de collagène reposait sur le principe de l\'upcycling, qui consistait à obtenir de l\'eau de collagène issue des déchets générés lors de la production de compléments alimentaires. Le but principal était d\'apprendre des recettes de cosmétiques pour le coiffage, le lavage et le soin des cheveux à partir de déchets de collagène, et de comparer les résultats avec des personnes utilisant le produit en question. L\'objectif de l\'étude était de démontrer l\'efficacité des soins dans la prévention des fourches et de la casse, généralement causés par un stress mécanique tel que le brossage, et de confirmer l\'efficacité d\'autres tests. L\'article présente les procédures et paramètres confirmant l\'efficacité du traitement avec les soins capillaires testés. Les tests suivant ont été menés : épaisseur et densité des cheveux, uniformité de la couleur, brillance et hydratation du cuir chevelu. Les chiffres ont parlé et tous les paramètres ont confirmé les effets bénéfiques des produits contenant de l\'eau de collagène dans les soins capillaires.
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  • 文章类型: Journal Article
    这项研究调查了在三层胶合板技术中利用榛子壳(HS)作为创新填料的潜力,满足日益增长的可持续发展需求,高性能材料。传统的胶合板生产依赖于用各种填料增强的粘合剂来改善物理,机械,和操作特点。这项研究探索了使用原生,化学改性,和由榛子壳衍生的活性炭作为脲甲醛(UF)树脂中的填料。生产的胶合板的机械性能,吸水,和甲醛排放进行了彻底的分析。关键发现表明,掺入10重量份(pbw)天然榛子壳粉可显着提高断裂模量(MOR)至138.6Nmm-2,弹性模量(MOE)至13,311Nmm-2。化学改性榛子壳粉在5pbw时达到最佳效果,而来自榛子壳的活性炭,即使在1pbw,显著提高了结合强度(2.79Nmm-2指没有添加填料的参考样品的0.81Nmm-2)。值得注意的是,活性炭有效地减少甲醛排放(2.72mg100g-1烘箱干面板指3.32mg100g-1烘箱干面板,用于具有10pbw填料的参考样品)并提高耐水性,表明更好的尺寸稳定性和更低的环境影响。研究还表明,过量的填料含量会对强度参数产生负面影响,确认优化填料浓度的重要性。这些结果突出了榛子壳作为胶合板生产中环保替代填料的潜力,促进废物价值化和环境可持续性。这项研究支持榛子壳填料的实际应用,促进循环经济,减少对传统的依赖,不可持续的材料,从而为木材复合材料行业提供了有价值的解决方案。
    This study investigates the potential of utilizing hazelnut shells (HS) as an innovative filler in three-layer plywood technology, addressing the growing need for sustainable, high-performance materials. Traditional plywood production relies on adhesives enhanced with various fillers to improve physical, mechanical, and operational characteristics. This research explores using native, chemically modified, and activated carbon derived from hazelnut shells as fillers in urea-formaldehyde (UF) resin. The produced plywood\'s mechanical properties, water absorption, and formaldehyde emissions were thoroughly analyzed. Key findings demonstrate that incorporating 10 part by weight (pbw) native hazelnut shell flour significantly enhances the modulus of rupture (MOR) to 138.6 N mm-2 and modulus of elasticity (MOE) to 13,311 N mm-2. Chemically modified hazelnut shell flour achieves optimal results at 5 pbw, while activated carbon from hazelnut shells, even at 1 pbw, markedly improves bonding strength (2.79 N mm-2 referred to 0.81 N mm-2 for reference sample without filler added). Notably, activated carbon effectively reduces formaldehyde emissions (2.72 mg 100 g-1 oven dry panel referred to 3.32 mg 100 g-1 oven dry panel for reference samples with 10 pbw filler) and improves water resistance, indicating better further dimensional stability and lower environmental impact. The study also shows that excessive filler content negatively affects strength parameters, confirming the importance of optimizing filler concentration. These results highlight the potential of hazelnut shells as an eco-friendly alternative filler in plywood production, contributing to waste valorization and environmental sustainability. This study supports the practical application of hazelnut shell fillers, promoting a circular economy and reducing reliance on traditional, less sustainable materials, thus providing a valuable solution for the wood composite industry.
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  • 文章类型: Journal Article
    非织造装饰织物是一种废品,主要是在软垫家具生产过程中产生的。聚酯组合物使得该产品的回收和再利用成为问题。这项研究检查了无纺布增强胶合板复合材料的制造过程及其选定的机械和物理性能。将非织造织物整合在与脲醛树脂结合的单板之间,以改善标准的层状复合材料的机械和物理性能。生产了几种板变体,在复合结构中非织造层的位置不同。评估复合材料的断裂模量(MOR),弹性模量(MOE),内部债券,和螺钉拔出阻力,在其他人中。结果表明,非织造布的加入显著改善了部分性能,如内键和螺钉拔出阻力。具有策略性放置的非织造层的变体显示出最高的性能增加。结果强调了非织造织物作为有效增强材料的潜力,为开发适合苛刻应用的高性能胶合板复合材料提供了一条途径。另一个环境优势是,测试胶合板生产中使用的无纺布废料没有经过燃烧或填埋,但是,通过将其纳入胶合板结构,为碳捕集与封存(CCS)政策做出了积极贡献。调查结果倡导循环经济方法,其中工业废物被有效地重新利用,促进绿色材料在木质复合材料行业的发展。
    Nonwoven upholstery fabric is a waste product which is mainly generated during upholstered furniture production. The polyester composition makes it problematic to recycle and reuse this product. This study examined the manufacturing process of nonwoven fabric-reinforced plywood composites and their selected mechanical and physical properties. Nonwoven fabric was integrated between veneers bound with urea-formaldehyde resin to improve standard layered composites\' mechanical and physical properties. Several board variants were produced, differing in the position of the nonwoven layers in the composite structure. The composites were evaluated for modulus of rupture (MOR), modulus of elasticity (MOE), internal bond, and screw withdrawal resistance, among others. The results showed that the addition of nonwoven fabric significantly improved some properties, like internal bond and screw withdrawal resistance. Variants with strategically placed nonwoven layers showed the highest performance increases. The results underscore the potential of nonwoven fabric as an effective reinforcing material, offering a path to developing high-performance plywood composites suitable for demanding applications. Another environmental advantage is that the nonwoven fabric waste used in the tested plywood production has not been subjected to burning or landfilling but, through its incorporation into plywood structure, has positively contributed to the Carbon Capture and Storage (CCS) policy. The findings advocate for a circular economy approach, in which industrial waste is effectively repurposed, contributing to the development of green materials in the wood-based composite industry.
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  • 文章类型: Journal Article
    供应链废物在处置方面带来了重大挑战,使再循环成为从副产品中回收生物活性化合物的有希望和可持续的替代方案。木质纤维素副产品,如STF231,来自药用植物提取物行业,提供有价值的化合物,如多酚和环烯醚萜类,可以通过再循环回收。在一项前所未有的研究中,我们探索和比较了传统的乙醇提取,超声乙醇提取,和天然的低共熔溶剂-超声提取方法在STF231上获得具有抗氧化活性的提取物。使用Folin-Ciocalteu测试测量总多酚(TPC)的提取曲线,并使用FRAP和DPPH测定法测试提取物的抗氧化能力。HPLC-UV用于定量提取物中的酚类和环烯醚萜类标志物。此外,使用绿色分析程序指数(GAPI)评估工艺的可持续性概况,AGREEPREP,和分析性绿色度量方法(AGREE)框架。我们的发现表明,氯化胆碱和乳酸的混合物比例为1:5,在最佳提取条件下,与常规乙醇提取物相比,提取物具有更高的TPC和相似的抗氧化活性。本研究的创新方面在于可持续升级循环协议对先前未经检查的矩阵的潜在应用,产生具有潜在健康应用的提取物。
    Supply chain waste gives rise to significant challenges in terms of disposal, making upcycling a promising and sustainable alternative for the recovery of bioactive compounds from by-products. Lignocellulosic by-products like STF231, which are derived from the medicinal plant extract industry, offer valuable compounds such as polyphenols and iridoids that can be recovered through upcycling. In an unprecedented study, we explored and compared conventional hydroethanolic extraction, ultrasound hydroethanolic extraction, and natural deep eutectic solvents-ultrasound extraction methods on STF231 to obtain extracts with antioxidant activity. The extraction profile of total polyphenols (TPCs) was measured using the Folin-Ciocalteu test and the antioxidant capacity of the extracts was tested with FRAP and DPPH assays. HPLC-UV was employed to quantify the phenolic and iridoid markers in the extracts. Additionally, the sustainability profile of the process was assessed using the green analytical procedure index (GAPI), AGREEprep, and analytical GREEnness metric approach (AGREE) frameworks. Our findings indicate that a choline chloride and lactic acid mixture at a 1:5 ratio, under optimal extraction conditions, resulted in extracts with higher TPC and similar antioxidant activity compared with conventional hydroethanolic extracts. The innovative aspect of this study lies in the potential application of sustainable upcycling protocols to a previously unexamined matrix, resulting in extracts with potential health applications.
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  • 文章类型: Journal Article
    由于阴极材料和Al集电器之间的强粘附性,Al杂质是最可能进入废锂离子电池(LIB)阴极粉末的组分之一。然而,在传统湿法冶金工艺中,深度去除Al杂质以获得高纯度金属盐产品的过程中,高价值金属元素往往会流失。在这项工作中,通过将稳健的Al-O共价键结合到由Ti改性辅助的阴极的主体中,将有害的Al杂质设计为向上循环高电压LiCoO2的有益成分。受益于主体中牢固的Al-O和Ti-O键,上循环的R-LCO-AT的不可逆相变在高电压下被显著抑制,如原位XRD所示。此外,通过在晶界上钉扎缓慢扩散的Ti,在R-LCO-AT的表面上构造了Li导电的Li2TiO3保护层,导致改善的Li+扩散动力学和抑制界面副反应。因此,在4.6V的高截止电压下,R-LCO-AT的循环稳定性和倍率性能显着增强,1C时的放电容量为189.5mAhg-1,4.6V时100次循环的容量保持率为92.9%。本研究通过精心设计的体/表面结构设计,利用有害杂质元素对高压LCO阴极进行上循环。提供了一种高价值利用废旧LIB的策略。
    Al impurity is among the most likely components to enter the spent lithium-ion battery (LIB) cathode powder due to the strong adhesion between the cathode material and the Al current collector. However, high-value metal elements tend to be lost during the deep removal of Al impurities to obtain high-purity metal salt products in the conventional hydrometallurgical process. In this work, the harmful Al impurity is designed as a beneficial ingredient to upcycle high-voltage LiCoO2 by incorporating robust Al-O covalent bonds into the bulk of the cathode assisted with Ti modification. Benefiting from the strong Al-O and Ti-O bonds in the bulk, the irreversible phase transitions of the upcycled R-LCO-AT have been significantly suppressed at high voltages, as revealed by in situ XRD. Moreover, a Li+-conductive Li2TiO3 protective layer is constructed on the surface of R-LCO-AT by pinning slow-diffusion Ti on the grain boundaries, resulting in improved Li+ diffusion kinetics and restrained interface side reactions. Consequently, the cycle stability and rate performance of R-LCO-AT were significantly enhanced at a high cutoff voltage of 4.6 V, with a discharge capacity of 189.5 mAhg-1 at 1 C and capacity retention of 92.9% over 100 cycles at 4.6 V. This study utilizes the detrimental impurity element to upcycle high-voltage LCO cathodes through an elaborate bulk/surface structural design, offering a strategy for the high-value utilization of spent LIBs.
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  • 文章类型: Journal Article
    有机气凝胶由于其多功能特性而成为有前途的材料,使它们成为隔热领域各种应用的优秀候选人,储能,制药,化学吸附,和催化。然而,目前的气凝胶设计依赖于交联聚合物网络,缺乏有效的最终使用解决方案,从而阻碍其整体可持续性。在这项研究中,介绍了具有亚胺和氰尿酸酯部分的独特组合的有机气凝胶的容易合成,导致高性能,轻质绝缘材料。气凝胶结构,确保机械坚固性,热电阻,和疏水性没有额外的处理,对长期业绩至关重要。此外,为了应对目前不可持续使用的交联聚合物材料,分子设计提供了多种化学回收途径。这些包括完全解聚回到原始单体中,部分网络碎片产生可溶性低聚物,可迅速用于制造新的气凝胶,并将气凝胶废物再循环成有用的积木。这项工作开创了一种新颖的材料设计方法,强调可回收性作为核心特征,同时保持卓越的高性能。
    Organic aerogels are emerging as promising materials due to their versatile properties, rendering them excellent candidates for a variety of applications in the fields of thermal insulation, energy storage, pharmaceuticals, chemical adsorption, and catalysis. However, current aerogel designs rely on cross-linked polymer networks, which lack efficient end-of-use solutions, thereby hindering their overall sustainability. In this study, a facile synthesis of organic aerogels with a unique combination of imine and cyanurate moieties is presented, resulting in high-performance, lightweight insulating materials. The aerogels\' structure, ensures mechanical robustness, thermal resistance, and hydrophobicity without additional treatments, crucial for long-term performance. Additionally, in response to the currently unsustainable use of cross-linked polymer materials, the molecular design offers diverse avenues of chemical recycling. These include full depolymerization back into the original monomers, partial network fragmentation producing soluble oligomers that can be promptly employed to fabricate new aerogels, and upcycling of aerogel waste into useful building blocks. This work pioneers a novel approach to material design, emphasizing recyclability as a core feature while maintaining high-performance excellence.
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  • 文章类型: Journal Article
    这篇综述研究了将农业残留物升级为有价值的药物化合物的创新策略。农业残留物的不当处置导致了重大的环境问题,包括温室气体排放增加和生态系统退化。Upcycle提供了一个可持续的解决方案,将这些残留物转化为高价值的生物产品(抗氧化剂,抗肿瘤剂,抗糖尿病化合物,抗炎药,和抗病毒药物)。纳米技术和微生物生物技术在提高生物利用度和生物活性化合物的靶向递送方面具有至关重要的作用。先进的技术,如酶解,绿色溶剂,微波加工,热解,超声波处理,酸和碱水解,臭氧分解,探索了有机溶剂工艺在分解农业废物和提取有价值化合物方面的有效性。尽管潜力巨大,挑战,如残留物成分的可变性,可扩展性,高成本持续存在。审查强调需要对具有成本效益的提取技术和强大的监管框架进行未来研究,以确保安全,功效,和生物产品的质量。农业残留物的再循环是实现可持续废物管理和药物化合物生产的可行途径,促进环境保护和改善公众健康。这篇综述提供了对当前文献的分析,并确定了知识差距,为未来的研究提供建议,以优化药品行业中农业残留物的使用。
    This review investigates innovative strategies for upcycling agricultural residues into valuable pharmaceutical compounds. The improper disposal of agricultural residues contributes to significant environmental issues, including increased greenhouse gas emissions and ecosystem degradation. Upcycling offers a sustainable solution, transforming these residues into high-value bioproducts (antioxidants, antitumor agents, antidiabetic compounds, anti-inflammatory agents, and antiviral drugs). Nanotechnology and microbial biotechnology have a crucial role in enhancing bioavailability and targeted delivery of bioactive compounds. Advanced techniques like enzymatic hydrolysis, green solvents, microwave processing, pyrolysis, ultrasonic processing, acid and alkaline hydrolysis, ozonolysis, and organosolv processes are explored for their effectiveness in breaking down agricultural waste and extracting valuable compounds. Despite the promising potential, challenges such as variability in residue composition, scalability, and high costs persist. The review emphasizes the need for future research on cost-effective extraction techniques and robust regulatory frameworks to ensure the safety, efficacy, and quality of bioproducts. The upcycling of agricultural residues represents a viable path towards sustainable waste management and production of pharmaceutical compounds, contributing to environmental conservation and public health improvements. This review provides an analysis of the current literature and identifies knowledge gaps, offering recommendations for future studies to optimize the use of agricultural residues in the drug industry.
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  • 文章类型: Journal Article
    “白色污染”被认为是自然环境中最严重的问题之一。因此,塑料废物的绿色回收在最近的研究中吸引了大量的努力。在这项研究中,用一块石头杀死两只鸟,从塑料废物的热解合成了一系列多孔碳纳米块(PCNs)(聚对苯二甲酸乙二醇酯,PET)和无机盐(包括NaHCO3,Na2CO3,NaCl,和ZnCl2)用于通过过氧单硫酸盐(PMS)活化降解磺胺嘧啶(SDZ)。PCNs-1(从PET和NaHCO3共煅烧)具有大量的CO和COOH活性位点,这有利于催化过程中的PMS活化和电子转移,对SDZ的降解表现出最好的催化活性。重要的是,PCNs-1表现出优异的普适性,适应性,和稳定性。通过总有机碳(TOC)含量确定SDZ的降解途径,和高分辨率质谱(HR-MS)。根据阴离子效应提出了可能的机理,淬火实验,电子顺磁共振(EPR),和电化学分析,表明自由基(OH,SO4-,O2-)和非自由基(1O2和e)物种是PCNs-1/PMS系统中SDZ分解的催化活性物种。此外,生态结构-活动-关系模型(ECOSAR)程序和小麦种子栽培实验清楚地表明,PCNs-1/PMS系统可以有效降低SDZ的生物毒性。在这里,我们成功地将塑料废物循环成高价值的材料,以实现高效的水净化。
    \"White pollution\" is regarded as one of the most serious problems in the natural environment. Thus greener recycling of plastic waste has attracted significant efforts in recent research. In this study, to kill two birds with one stone, a series of porous carbon nanobulks (PCNs) were synthesized from the pyrolysis of plastic waste (polyethylene terephthalate, PET) and inorganic salt (including NaHCO3, Na2CO3, NaCl, and ZnCl2) for sulfadiazine (SDZ) degradation via peroxymonosulfate (PMS) activation. PCNs-1 (co-calcinated from PET and NaHCO3) with a large number of CO and COOH active sites, which were in favor of PMS activation and electron transfer during the catalytic process, had shown the best catalytic activity for SDZ degradation. Significantly, PCNs-1 exhibited excellent universality, adaptability, and stability. The degradation pathways of SDZ were identified by the total content of organic carbon (TOC), and high-resolution mass spectrometry (HR-MS). The possible mechanism was proposed according to the anion effect, quenching experiments, electron paramagnetic resonance (EPR), and electrochemical analysis, indicating that radical (OH, SO4-, O2-) and non-radical (1O2 and e) species were the catalytically active species for SDZ decomposition in the PCNs-1/PMS system. Moreover, Ecological Structure-Activity-Relationship Model (ECOSAR) program and wheat seed cultivation experiments clearly demonstrated that the biotoxicity of SDZ could be effectively reduced by the PCNs-1/PMS system. Here we successfully upcycled plastic waste into high-value materials for efficient water decontamination.
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  • 文章类型: Journal Article
    简介:塑料废物在环境中的积累是一个严重的全球性问题。为了解决这个问题,需要改进和更有效的塑料废物回收方法。一种方法是使用热解或化学解构来解聚塑料,然后将单体微生物向上循环为更有价值的产物。微生物聚生体可能能够增加响应过程扰动的稳定性,并适应不同的碳源,但可能更有可能形成污染工艺设备的生物膜,增加了收获细胞生物量的挑战。方法:为了更好地了解生物过程条件之间的关系,生物膜的形成,生物反应器内的生态,在这项研究中,以前富集的微生物联盟(LS1_Calumet)生长在(1)氢氧化铵解聚聚对苯二甲酸乙二醇酯(PET)单体和(2)聚乙烯(PE)和聚丙烯(PP)的热解产物。生物反应器温度,pH值,搅拌速度,改变曝气以确定导致浮游生物量产量最高和生物膜形成最少的条件。使用16SrRNA基因扩增子测序评估了浮游和生物膜状态的群落组成和多样性。结果:结果表明,在所有发酵条件下,热解的液体产品上几乎没有微生物生长。当在化学解构的PET上生长时,在30°C下产生最高的细胞密度(0.69g/L),生物膜形成最少。pH7,100rpm搅拌,和10升/小时的气流。16SrRNA测序结果表明,浮游期具有比生物膜更高的多样性,还有红球菌,Paracocus,和螯合球菌是所有工艺条件下最丰富的属。红球菌的生物膜形成。和Paracocussp。分离物通常低于全部微生物群落,并且基于碳源而变化。讨论:最终,结果表明,生物反应器内的生物膜形成可以通过优化工艺条件和使用纯培养物或较少多样化的群落显著减少,同时保持较高的生物量生产率。这项研究的结果提供了对塑料废物进行再循环的方法以及如何使用工艺条件来控制生物反应器中生物膜的形成的见解。
    Introduction: Accumulation of plastic waste in the environment is a serious global issue. To deal with this, there is a need for improved and more efficient methods for plastic waste recycling. One approach is to depolymerize plastic using pyrolysis or chemical deconstruction followed by microbial-upcycling of the monomers into more valuable products. Microbial consortia may be able to increase stability in response to process perturbations and adapt to diverse carbon sources, but may be more likely to form biofilms that foul process equipment, increasing the challenge of harvesting the cell biomass. Methods: To better understand the relationship between bioprocess conditions, biofilm formation, and ecology within the bioreactor, in this study a previously-enriched microbial consortium (LS1_Calumet) was grown on (1) ammonium hydroxide-depolymerized polyethylene terephthalate (PET) monomers and (2) the pyrolysis products of polyethylene (PE) and polypropylene (PP). Bioreactor temperature, pH, agitation speed, and aeration were varied to determine the conditions that led to the highest production of planktonic biomass and minimal formation of biofilm. The community makeup and diversity in the planktonic and biofilm states were evaluated using 16S rRNA gene amplicon sequencing. Results: Results showed that there was very little microbial growth on the liquid product from pyrolysis under all fermentation conditions. When grown on the chemically-deconstructed PET the highest cell density (0.69 g/L) with minimal biofilm formation was produced at 30°C, pH 7, 100 rpm agitation, and 10 sL/hr airflow. Results from 16S rRNAsequencing showed that the planktonic phase had higher observed diversity than the biofilm, and that Rhodococcus, Paracoccus, and Chelatococcus were the most abundant genera for all process conditions. Biofilm formation by Rhodococcus sp. And Paracoccus sp. Isolates was typically lower than the full microbial community and varied based on the carbon source. Discussion: Ultimately, the results indicate that biofilm formation within the bioreactor can be significantly reduced by optimizing process conditions and using pure cultures or a less diverse community, while maintaining high biomass productivity. The results of this study provide insight into methods for upcycling plastic waste and how process conditions can be used to control the formation of biofilm in bioreactors.
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  • 文章类型: Journal Article
    聚对苯二甲酸乙二醇酯(PET)是年产量仅次于聚乙烯的重要聚合物。由于其生物降解性低,为了可持续发展,大量的PET被回收利用。然而,当前的PET回收策略受到附加值低或产品规模小的限制。迫切需要在PET大分子反应原理上取得突破,高效制备高附加值和广泛应用的产品。这里,报道了通过PET废物与生物基氢化二聚酸(HDA)之间的新型羧基酯酯交换反应合成生物降解塑料的无催化剂和无溶剂合成,可以用HDA单元直接取代PET链中的一些对苯二甲酸(TPA)单元。该大分子反应可以在聚酯工业的现有设备上轻松进行,无需任何额外的催化剂和溶剂。从而实现低成本和大规模生产。此外,产品半生物基共聚酯表现出优异的机械性能,可调节的柔韧性和良好的生物降解性,有望替代聚(己二酸丁二醇酯-共对苯二甲酸酯)(PBAT)塑料作为高附加值的可生物降解材料。这项工作为大规模回收PET废物提供了环保和经济的策略。
    Poly(ethylene terephthalate) (PET) is an important polymer with annual output second only to polyethylene. Due to its low biodegradability, a large amount of PET is recycled for sustainable development. However, current strategies for PET recycling are limited by low added value or small product scale. It is urgent to make a breakthrough on the principle of PET macromolecular reaction and efficiently prepare products with high added value and wide applications. Here, the catalyst- and solvent-free synthesis of biodegradable plastics are reported through novel carboxyl-ester transesterification between PET waste and bio-based hydrogenated dimer acid (HDA), which can directly substitute some terephthalic acid (TPA) units in PET chain by HDA unit. This macromolecular reaction can be facilely carried out on current equipment in the polyester industry without any additional catalyst and solvent, thus enabling low-cost and large-scale production. Furthermore, the product semi-bio-based copolyester shows excellent mechanical properties, regulable flexibility and good biodegradability, which is expected to substitute poly(butylene adipate-co-terephthalate) (PBAT) plastic as high value-added biodegradable materials. This work provides an environmental-friendly and economic strategy for the large-scale upcycling of PET waste.
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