thermal diffusion

热扩散
  • 文章类型: Journal Article
    非Hermitian光子学中的高阶拓扑相位彻底改变了对波传播和调制的理解,这导致开放系统中的分层状态。然而,光子晶体的晶格对称性所认可的固有绝缘特性从根本上限制了仅在明确的系统边界处的鲁棒传输,更不用说在任意位置的分层状态下的灵活重新配置了。这里,我们报告了一个动态拓扑平台,用于在热传输系统中创建可重构的分层束联状态,并观察了实值和虚值带中的鲁棒和非局部化高阶状态。我们的实验表明,零维角和非平凡边缘模式的分层特征发生在系统本体状态中的定制位置,而不是明确的系统边界。我们的发现揭示了非局部分层非平凡拓扑状态的机制,并为扩散传输场管理提供了不同的范例。
    Higher-order topological phases in non-Hermitian photonics revolutionize the understanding of wave propagation and modulation, which lead to hierarchical states in open systems. However, intrinsic insulating properties endorsed by the lattice symmetry of photonic crystals fundamentally confine the robust transport only at explicit system boundaries, letting alone the flexible reconfiguration in hierarchical states at arbitrary positions. Here, we report a dynamic topological platform for creating the reconfigurable hierarchical bound states in heat transport systems and observe the robust and nonlocalized higher-order states in both the real- and imaginary-valued bands. Our experiments showcase that the hierarchical features of zero-dimension corner and nontrivial edge modes occur at tailored positions within the system bulk states instead of the explicit system boundaries. Our findings uncover the mechanism of non-localized hierarchical non-trivial topological states and offer distinct paradigms for diffusive transport field management.
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  • 文章类型: Journal Article
    在光声(PA)技术中,时域中的激光照射(即,激光脉冲持续时间)控制PA成像的特性-它在光声相互作用中起着至关重要的作用,PA信号的产生,和PA成像性能。
    我们旨在全面分析激光脉冲持续时间对PA成像各个方面的影响,包括信噪比,PA成像的空间分辨率,声波的声波频谱,特定物理现象的开始,和光热-PA(PT-PA)相互作用/转化。
    通过调查和审查最先进的调查,在生物医学PA成像的背景下,我们讨论了激光脉冲持续时间对PA信号生成的影响。
    首先,我们讨论了激光脉冲持续时间对PA信号幅度的影响及其与PA成像横向分辨率的相关性。随后,考虑声频谱,分析了PA成像的轴向分辨率与激光脉冲持续时间之间的关系。此外,我们研究了脉冲持续时间的操纵来触发物理现象及其相关应用。此外,我们详细阐述了脉冲持续时间的调整,以操纵从PT到PA效应的转换过程和比率。
    我们有助于理解与脉冲宽度相关的PA技术的物理机制。通过深入了解激光脉冲影响背后的机制,我们可以针对特定的PA应用触发与脉冲相关的物理现象,增强生物医学成像场景中的PA成像性能,并通过精确调整脉冲持续时间来调制PT-PA转换。
    UNASSIGNED: In the photoacoustic (PA) technique, the laser irradiation in the time domain (i.e., laser pulse duration) governs the characteristics of PA imaging-it plays a crucial role in the optical-acoustic interaction, the generation of PA signals, and the PA imaging performance.
    UNASSIGNED: We aim to provide a comprehensive analysis of the impact of laser pulse duration on various aspects of PA imaging, encompassing the signal-to-noise ratio, the spatial resolution of PA imaging, the acoustic frequency spectrum of the acoustic wave, the initiation of specific physical phenomena, and the photothermal-PA (PT-PA) interaction/conversion.
    UNASSIGNED: By surveying and reviewing the state-of-the-art investigations, we discuss the effects of laser pulse duration on the generation of PA signals in the context of biomedical PA imaging with respect to the aforementioned aspects.
    UNASSIGNED: First, we discuss the impact of laser pulse duration on the PA signal amplitude and its correlation with the lateral resolution of PA imaging. Subsequently, the relationship between the axial resolution of PA imaging and the laser pulse duration is analyzed with consideration of the acoustic frequency spectrum. Furthermore, we examine the manipulation of the pulse duration to trigger physical phenomena and its relevant applications. In addition, we elaborate on the tuning of the pulse duration to manipulate the conversion process and ratio from the PT to PA effect.
    UNASSIGNED: We contribute to the understanding of the physical mechanisms governing pulse-width-dependent PA techniques. By gaining insight into the mechanism behind the influence of the laser pulse, we can trigger the pulse-with-dependent physical phenomena for specific PA applications, enhance PA imaging performance in biomedical imaging scenarios, and modulate PT-PA conversion by tuning the pulse duration precisely.
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  • 文章类型: Journal Article
    由温度梯度引起的胶体颗粒的迁移通常称为热扩散,热扩散,或者(路德维希)索雷特效应。驱动热扩散的胶体粒子所经历的热泳力由两个不同的贡献组成:由单个胶体粒子的内部自由度产生的贡献,以及由于胶体之间的相互作用而产生的贡献。我们提出了一种基于不可逆热力学的理论,用于后者对热泳力的集体贡献。目前的理论导致了一种新的“热泳相互作用力”(对于不带电的胶体),在早期的方法中还没有发现。此外,提出了一个包含温度梯度的N粒子Smoluchowski方程,这符合不可逆热力学方法。给出了在大浓度和温度范围内具有温度依赖性吸引相互作用势的胶体实验的比较。比较表明,新颖的热泳相互作用力对于描述Soret系数和热扩散系数的数据至关重要。
    Migration of colloidal particles induced by temperature gradients is commonly referred to as thermodiffusion, thermal diffusion, or the (Ludwig-)Soret effect. The thermophoretic force experienced by a colloidal particle that drives thermodiffusion consists of two distinct contributions: a contribution resulting from internal degrees of freedom of single colloidal particles, and a contribution due to the interactions between the colloids. We present an irreversible thermodynamics based theory for the latter collective contribution to the thermophoretic force. The present theory leads to a novel \"thermophoretic interaction force\" (for uncharged colloids), which has not been identified in earlier approaches. In addition, an N-particle Smoluchowski equation including temperature gradients is proposed, which complies with the irreversible thermodynamics approach. A comparison with experiments on colloids with a temperature dependent attractive interaction potential over a large concentration and temperature range is presented. The comparison shows that the novel thermophoretic interaction force is essential to describe data on the Soret coefficient and the thermodiffusion coefficient.
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  • 文章类型: Journal Article
    传统的钛基植入物易受术后感染的影响,在不影响成骨能力的前提下提高抗菌效率是骨植入物设计的关键问题之一。虽然在Ti衬底上水热生长的氧化锌(ZnO)纳米棒可以提高抗菌性能,但不能满足骨植入物的严格要求,因为ZnO的快速降解和Zn2+的不受控制的浸出对植入物周围的细胞和组织是有害的。为了解决这些问题,采用无晶格损伤的方法,用薄磷酸钙(CaP)壳修饰ZnO纳米棒。来自CaP壳的Ca和P离子热扩散到ZnO晶格中以防止ZnO纳米棒快速降解并确保Zn2离子的持续释放。此外,设计的异质结构纳米棒不仅诱导了MC3T3-E1细胞的成骨性能,而且通过物理渗透对金黄色葡萄球菌和大肠杆菌细菌表现出优异的抗菌能力。体内研究还表明,杂化Ti-ZnO@CaP5不仅能根除接触细菌,而且还提供了足够的生物相容性而不会引起过度的炎症反应。我们的研究提供了有关用于骨植入物的多功能生物材料设计的见解。重要声明:•采用无晶格损伤的方法对具有磷酸钙(CaP)薄壳的ZnO纳米棒进行修饰•通过实验验证和理论计算分析了Ca和P扩散到ZnO晶格中的动态过程•CaP沉积后ZnO纳米棒的降解速率显着降低•CaP沉积后的ZnO纳米棒不仅可以通过物理渗透对接触细菌进行杀菌,而且还提供足够的生物相容性和成骨能力,而不会引起过度的炎症反应。
    Conventional Ti-based implants are vulnerable to postsurgical infection and improving the antibacterial efficiency without compromising the osteogenic ability is one of the key issues in bone implant design. Although zinc oxide (ZnO) nanorods grown on Ti substrates hydrothermally can improve the antibacterial properties, but cannot meet the stringent requirements of bone implants, as rapid degradation of ZnO and uncontrolled leaching of Zn2+ are detrimental to peri-implant cells and tissues. To solve these problems, a lattice-damage-free method is adopted to modify the ZnO nanorods with thin calcium phosphate (CaP) shells. The Ca and P ions from the CaP shells diffuse thermally into the ZnO lattice to prevent the ZnO nanorods from rapid degradation and ensure the sustained release of Zn2+ ions as well. Furthermore, the designed heterostructural nanorods not only induce the osteogenic performances of MC3T3-E1 cells but also exhibit excellent antibacterial ability against S. aureus and E. coli bacteria via physical penetration. In vivo studies also reveal that hybrid Ti-ZnO@CaP5 can not only eradicates bacteria in contact, but also provides sufficient biocompatibility without causing excessive inflammation response. Our study provides insights into the design of multifunctional biomaterials for bone implants. STATEMENT OF SIGNIFICANCE: • A lattice-damage-free method is adopted to modify the ZnO nanorods with thin calcium phosphate (CaP) shells. • The dynamic process of Ca and P diffusion into the ZnO lattice is analyzed by experimental verification and theoretical calculation. • The degradation rate of ZnO nanorods is significantly decreased after CaP deposition. • The ZnO nanorods after CaP deposition can not only sterilize bacteria in contact via physical penetration, but also provide sufficient biocompatibility and osteogenic capability without causing excessive inflammation response..
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  • 文章类型: Journal Article
    目的:热疗质量保证的一个关键方面是定期证明设备的加热性能。现有方法根据短功率脉冲后的温度升高来估计比吸收率(SAR),当热扩散扩大了表观SAR模式时,会产生有偏差的估计。为了获得无偏估计,我们提出了一种同时识别SAR和热动力学的鲁棒频域方法。方法:我们提出了一种方法,该方法包括对FUS功率进行周期性调制,同时使用MR测温法(MRT)记录响应。该方法能够实现对热响应进行编码的空间傅里叶系数的无偏测量。这些系数在通用热模型中代入以同时估计SAR,扩散系数,和阻尼。使用圆柱形体模和3T临床MR-HIFU系统测试了该方法。选择具有不同调制策略的三个场景来挑战该方法。将结果与众所周知的功率脉冲技术进行比较。结果:六个实验之间的热扩散率估计为0.151mm2s-1,标准偏差为0.01mm2s-1。SAR估计在所有实验之间是一致的,并且与建立良好的功率脉冲方法相比,显示出出色的信噪比(SNR)。频域方法被证明对B0漂移和非稳态初始温度分布不敏感。结论:所提出的频域估计方法显示出较高的SNR,并提供了SAR和相应热扩散率的可重复估计。研究结果表明,频域工具可以非常有效地从周期性功率调制期间获取的(偏置)MRT数据中估计SAR。
    Purpose: A crucial aspect of quality assurance in thermal therapy is periodic demonstration of the heating performance of the device. Existing methods estimate the specific absorption rate (SAR) from the temperature rise after a short power pulse, which yields a biased estimate as thermal diffusion broadens the apparent SAR pattern. To obtain an unbiased estimate, we propose a robust frequency-domain method that simultaneously identifies the SAR as well as the thermal dynamics.Methods: We propose a method consisting of periodic modulation of the FUS power while recording the response with MR thermometry (MRT). This approach enables unbiased measurements of spatial Fourier coefficients that encode the thermal response. These coefficients are substituted in a generic thermal model to simultaneously estimate the SAR, diffusivity, and damping. The method was tested using a cylindrical phantom and a 3 T clinical MR-HIFU system. Three scenarios with varying modulation strategies are chosen to challenge the method. The results are compared to the well-known power pulse technique.Results: The thermal diffusivity is estimated at 0.151 mm2s-1 with a standard deviation of 0.01 mm2s-1 between six experiments. The SAR estimates are consistent between all experiments and show an excellent signal-to-noise ratio (SNR) compared to the well established power pulse method. The frequency-domain method proved to be insensitive to B0-drift and non steady-state initial temperature distributions.Conclusion: The proposed frequency-domain estimation method shows a high SNR and provided reproducible estimates of the SAR and the corresponding thermal diffusivity. The findings suggest that frequency-domain tools can be highly effective at estimating the SAR from (biased) MRT data acquired during periodic power modulation.
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  • 文章类型: Case Reports
    背景:皮内痣是一种常见的皮肤肿瘤,经典的切除方法有复发和瘢痕形成的风险。快速有效地治疗眉毛皮内痣是皮肤科医生面临的挑战。本研究旨在探讨剪切联合电灼术和刮宫术治疗眉毛皮内痣的疗效和安全性。
    方法:我们描述了两名通过剪切结合电灼术和刮宫治疗的成年眉毛皮内痣患者。两组患者术后均定期随访。在后续行动中,两组患者均未发现眉毛皮内痣复发,也未发现明显的疤痕或色素减退。结果表明,剪切联合电灼术和刮宫术可以去除眉毛皮内痣,无副作用,证实了这种方式治疗这些皮肤病变的有效性和安全性。
    结论:剪切联合电灼术和刮宫术具有优越的优点,包括简单的操作,良好的美容效果,患者满意度高,为治疗皮内痣提供了巨大的应用潜力。
    BACKGROUND: An intradermal nevus is a common skin tumour, and the classical method of removal has a risk of recurrence and scarring. It is a challenge for dermatologists to treat eyebrow intradermal nevi quickly and efficiently. This study focused on investigating the efficacy and safety of shearing combined with electrocautery and curettage in the treatment of eyebrow intradermal nevi.
    METHODS: We describe two adult patients with eyebrow intradermal nevi treated by shearing combined with electrocautery and curettage. Both patients were followed up regularly after surgery. At follow-up, no recurrence of eyebrow intradermal nevus and no obvious scars or hypopigmentation were found in either patient. The results indicated that shearing combined with electrocautery and curettage could remove eyebrow intradermal nevus without side effects and confirmed the efficacy and safety of this modality for treating these skin lesions.
    CONCLUSIONS: Shearing combined with electrocautery and curettage has superior merits, including simple operation, good cosmetic effects, and high patient satisfaction, presenting great application potential for treating intracutaneous nevus.
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  • 文章类型: Journal Article
    在这里,通过一种新颖的热扩散方法在聚酰亚胺(PI)衬底上制备了n型Ag2Se热电柔性薄膜,并且通过调节热扩散的压力和温度来很好地优化热电性能。所有的Ag2Se薄膜都有利于生长(013)择优取向,这有利于执行高塞贝克系数。通过提高热扩散温度,电导率可以合理调节,同时保持塞贝克系数的独立性,这主要归因于电动交通的增加。因此,制备的Ag2Se薄膜在室温下实现了18.25μWcm-1K-2的高功率因数,在393K下实现了21.7μWcm-1K-2的最大值。热扩散法导致波浪形屈曲,有限元分析(FEA)的仿真结果进一步验证了该结构具有实现较大温差的前景。此外,Ag2Se薄膜的这种独特的表面形态也表现出优异的机械性能,其弹性模量仅为0.42GPa。最后,用Sb2Te3组装的柔性圆形模块在50K的温差下显示出166nW的输出功率。这项工作不仅介绍了一种制备Ag2Se薄膜的新方法,而且提供了一种令人信服的优化微观结构以提高低等级热利用效率的策略。
    Herein, an n-type Ag2Se thermoelectric flexible thin film has been fabricated on a polyimide (PI) substrate via a novel thermal diffusion method, and the thermoelectric performance is well-optimized by adjusting the pressure and temperature of thermal diffusion. All of the Ag2Se films are beneficial to grow (013) preferred orientations, which is conducive to performing a high Seebeck coefficient. By increasing the thermal diffusion temperature, the electrical conductivity can be rationally regulated while maintaining the independence of the Seebeck coefficient, which is mainly attributed to the increased electric mobility. As a result, the fabricated Ag2Se thin film achieves a high power factor of 18.25 μW cm-1 K-2 at room temperature and a maximum value of 21.7 μW cm-1 K-2 at 393 K. Additionally, the thermal diffusion method has resulted in a wave-shaped buckling, which is further verified as a promising structure to realize a larger temperature difference by the simulation results of finite element analysis (FEA). Additionally, this unique surface morphology of the Ag2Se thin film also exhibits outstanding mechanical properties, for which the elasticity modulus is only 0.42 GPa. Finally, a flexible round-shaped module assembled with Sb2Te3 has demonstrated an output power of 166 nW at a temperature difference of 50 K. This work not only introduces a new method of preparing Ag2Se thin films but also offers a convincing strategy of optimizing the microstructure to enhance low-grade heat utilization efficiency.
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  • 文章类型: Journal Article
    熔融长丝制造是最期望的热塑性增材制造工艺之一,因为其能够制造具有高可达性的复杂物体。然而,由于基于挤压轨道的直接写入过程机制,使用这种方法构建的零件表现出各向异性的机械性能。在这项工作中,引入了一种过程中的激光加热方法,通过提高界面温度来促进聚合物的排斥并增强相邻轨道界面的结合强度,从而修复相邻沉积轨道之间的界面附着力。用激光加热诱导界面愈合,在同一层中相邻轨道之间测得的挠曲强度增加并超过沿轨道方向测试的对照样品的挠曲强度。还通过研究断裂表面的载荷-位移曲线和形貌分析,验证了激光对界面愈合的影响。
    Fused filament fabrication is one of the most desired thermal plastic additive manufacturing processes because of its ability to fabricate complex objects with high accessibility. However, due to the extrusion track-based direct write process mechanism, parts built using this method exhibit anisotropic mechanical properties. In this work, an in-process laser heating method is introduced to heal interface adhesion between adjacent deposited tracks by increasing the interface temperature to promote polymer reptation and enhance bonding strength of the interface of adjacent tracks. With the use of laser heating induced interface healing, the measured flexural strength between adjacent tracks in the same layer increased and exceeded that of the control sample tested along the track direction. The effect of laser on interface healing was also verified by investigating the load-displacement curve and morphology analysis of the fractured surface.
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  • 文章类型: Journal Article
    自1920年代以来,玻尔兹曼方程的Enskog解为预测稀薄气体混合物的传输特性提供了一条途径。在较高的密度下,预测仅限于硬球的气体。在这项工作中,我们提出了Mie流体多组分混合物的改进的Enskog理论,其中Barker-Henderson摄动理论用于计算接触时的径向分布函数。在Mie势的参数回归到平衡性质的情况下,该理论完全可以预测传输特性。提出的框架在高密度下提供了Mie潜力和传输特性之间的联系,为真实流体提供准确的预测。对于稀有气体的混合物,来自实验的扩散系数在±4%内再现。对于氢气,预测的自扩散系数在高达200MPa且温度高于171K的实验数据的10%以内。在高达14.7MPa的压力下,模拟中的CO2/CH4混合物的二元扩散系数在20%以内再现。除了临界点附近的氙气,惰性气体及其混合物的热导率在实验数据的10%内再现。对于稀有气体以外的其他分子,热导率的温度依赖性被低估了,而密度依赖性似乎是正确预测的。粘度的预测在甲烷实验数据的±10%以内,氮,和高达300巴的氩气,温度范围从233到523K。在高达500巴的压力和200到800K的温度下,预测在空气粘度最准确相关性的±15%内。将理论与一组广泛的热扩散比测量值进行比较,我们发现49%的模型预测在报告测量值的±20%以内。预测的热扩散系数与Lennard-Jones混合物的模拟结果相差不到15%,即使在密度远远超过临界密度。
    Since the 1920s, the Enskog solutions to the Boltzmann equation have provided a route to predicting the transport properties of dilute gas mixtures. At higher densities, predictions have been limited to gases of hard spheres. In this work, we present a revised Enskog theory for multicomponent mixtures of Mie fluids, where the Barker-Henderson perturbation theory is used to calculate the radial distribution function at contact. With parameters of the Mie-potentials regressed to equilibrium properties, the theory is fully predictive for transport properties. The presented framework offers a link between the Mie potential and transport properties at elevated densities, giving accurate predictions for real fluids. For mixtures of noble gases, diffusion coefficients from experiments are reproduced within ±4%. For hydrogen, the predicted self-diffusion coefficient is within 10% of experimental data up to 200 MPa and at temperatures above 171 K. Binary diffusion coefficients of the CO2/CH4 mixture from simulations are reproduced within 20% at pressures up to 14.7 MPa. Except for xenon in the vicinity of the critical point, the thermal conductivity of noble gases and their mixtures is reproduced within 10% of the experimental data. For other molecules than noble gases, the temperature dependence of the thermal conductivity is under-predicted, while the density dependence appears to be correctly predicted. Predictions of the viscosity are within ±10% of the experimental data for methane, nitrogen, and argon up to 300 bar, for temperatures ranging from 233 to 523 K. At pressures up to 500 bar and temperatures from 200 to 800 K, the predictions are within ±15% of the most accurate correlation for the viscosity of air. Comparing the theory to an extensive set of measurements of thermal diffusion ratios, we find that 49% of the model predictions are within ±20% of the reported measurements. The predicted thermal diffusion factor differs by less than 15% from the simulation results of Lennard-Jones mixtures, even at densities well exceeding the critical density.
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  • 文章类型: Journal Article
    在本文中,确定热量的可能性,沉积在硅衬底上的TiO2薄膜的弹性和几何特性,厚度为30μm,在20至20kHz的频率范围内,用神经网络进行了分析。为此,几何(厚度),热(热扩散率,线性膨胀系数)和基板的电子参数在两层模型中已知且恒定,同时改变了以下纳米层薄膜参数:厚度,膨胀和热扩散率。用三个神经网络分别分析了薄膜的这三个参数的预测。所有这些都由第四个神经网络连接在一起。结果表明,神经网络,同时分析了所有三个参数,达到了最高的精度,因此,使用仅对一个参数提供预测的网络不太可靠。获得的结果表明,将神经网络应用于确定支撑基板上薄膜的热弹性特性,可以非常准确地估计其特性。
    In this paper, the possibility of determining the thermal, elastic and geometric characteristics of a thin TiO2 film deposited on a silicon substrate, with a thickness of 30 μm, in the frequency range of 20 to 20 kHz with neural networks were analysed. For this purpose, the geometric (thickness), thermal (thermal diffusivity, coefficient of linear expansion) and electronic parameters of substrates were known and constant in the two-layer model, while the following nano-layer thin-film parameters were changed: thickness, expansion and thermal diffusivity. Predictions of these three parameters of the thin-film were analysed separately with three neural networks. All of them together were joined by a fourth neural network. It was shown that the neural network, which analysed all three parameters at the same time, achieved the highest accuracy, so the use of networks that provide predictions for only one parameter is less reliable. The obtained results showed that the application of neural networks in determining the thermoelastic properties of a thin film on a supporting substrate enables the estimation of its characteristics with great accuracy.
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